CN1135923C - Herbicide for killing graminaceous weed in latifolious crop field - Google Patents
Herbicide for killing graminaceous weed in latifolious crop field Download PDFInfo
- Publication number
- CN1135923C CN1135923C CNB011275243A CN01127524A CN1135923C CN 1135923 C CN1135923 C CN 1135923C CN B011275243 A CNB011275243 A CN B011275243A CN 01127524 A CN01127524 A CN 01127524A CN 1135923 C CN1135923 C CN 1135923C
- Authority
- CN
- China
- Prior art keywords
- ethyl
- quizalotop
- oil
- quizalofop
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a quizalofop-p-ethyl herbicide for grassy weeds of broadleaf crop fields. The quizalofop-p-ethyl herbicide is prepared by adding an emulsifying agent, a synergistic agent and a solvent to quizalofop-p-ethyl, and the weight content of the quizalofop-p-ethyl is from 10.1 to 30.0%. The quizalofop-p-ethyl herbicide is prepared from the components of quizalofop-p-ethyl, 26 to 40% of emulsifying agent, 1.0 to 10.0% of synergistic agent and surplus solvent, wherein the dosage of the quizalofop-p-ethyl is transformed from 10.1 to 30.0% of quizalofop-p-ethyl. The quizalofop-p-ethyl herbicide has the advantages of high content, strong agricultural chemical effects, senior weed application, short effect taking time, less dosage, low use cost, good use effect, low temperature climatic condition suitability, arid climatic condition suitability, good rain wash resistance performance and good application performance.
Description
Technical field
The present invention relates to a kind of weed killer herbicide, be specially the agent of a kind of killing graminaceous weed in latifolious crop field Quizalotop-ethyl herbicide, be a kind of Quizalotop-ethyl missible oil.
Background technology
The Quizalotop-ethyl herbicide agent has obtained applying widely with its unique advantage, but existing Quizalotop-ethyl herbicide agent, the content of its Quizalotop-ethyl lower (below 5%), a little less than the drug effect, can not be used for elder weed (5-7 leaf phase), responding time is long, and using dosage is big, the use cost height, result of use is poor, and especially under low temperature, dry climate condition, drug effect reduces obviously, and the resistance of rainwater washing against poor performance has directly influenced its application performance.
Summary of the invention
Technical problem to be solved by this invention is: provide a kind of Quizalotop-ethyl content higher herbicide for killing graminaceous weed in latifolious crop field, strong drug action, can be used for elder weed, responding time is short, and using dosage is little, and use cost is low, result of use is good, the suitable low temperature of energy, dry climate condition, and the resistance of rainwater washing against performance is good, and application performance is good.
Herbicide for killing graminaceous weed in latifolious crop field of the present invention adds emulsifier, synergist and solvent by Quizalotop-ethyl and makes, and wherein the weight content of Quizalotop-ethyl is 10.1～30.0%.
Usually the weight of batching consists of:
10.1 Quizalotop-ethyl raw material consumption, emulsifier 26～40%, synergist 1.0～10.0%, surplus that～30.0% Quizalotop-ethyl is converted to are solvent.
Optimum weight consists of:
10.5 Quizalotop-ethyl raw material consumption, emulsifier 26～35%, synergist 2.0～5.0%, surplus that～20.0% Quizalotop-ethyl is converted to are solvent.
Wherein:
The chemical name of Quizalotop-ethyl is (R)-2-[4-(6-chloro-quinoxaline-Z-base oxygen) phenoxy group] ethyl propionate, chemical constitution is:
In the practice, the effective body of Quizalotop-ethyl adds with the form of former powder of Quizalotop-ethyl or Quizalotop-ethyl mother liquor.The effective body burden of Quizalotop-ethyl 〉=90% in the former powder of Quizalotop-ethyl, the effective body burden of Quizalotop-ethyl 〉=40% in the Quizalotop-ethyl mother liquor.
Solvent for use, synergist, emulsifier are commercially available industrial goods among the present invention.
Solvent for use is one or more the arbitrary proportion combination in aromatic hydrocarbons, aliphatic hydrocarbon, alicyclic, alcohol, ketone, ether, vegetable oil, halogenated alkane, dimethyl formamide, methyl-sulfoxide, acetonitrile, the chlorobenzene, mixed solvent with the strong methyl alcohol of dissolving power, chloroform, dimethyl formamide, acetone etc. and compositions such as benzene,toluene,xylene is good, is easy to obtain the product of premium properties.
Wherein:
Aromatic hydrocarbons has: benzene,toluene,xylene, naphthalene, Fluhyzon, arylhydrocarbon in diesel oil etc.
Aliphatic hydrocarbon, alicyclic have: white gas, diesel oil, white oil, machine oil, diesel oil etc.
Alcohol has: methyl alcohol, ethanol, propyl alcohol, isopropyl alcohol, butanols, isobutanol, glycerine, ethylene glycol etc.
Ketone has: cyclohexanone, MEK, acetone, isophorone; Ether is: glycol ether, propylene glycol etc.
Vegetable oil has: rapeseed oil, cotton seed oil, turpentine wet goods.
Halogenated alkane has: carrene, chloroform, trichloroethanes, carbon tetrachloride etc.
Used synergist, emulsifier are conventional synergist, emulsifier, as synergist azone, JSE-1, JSE-2 etc. are arranged, and emulsifier has 8227# emulsifier, 8220# emulsifier etc.
The preparation method of weed killer herbicide of the present invention and conventional preparation method are similar, carry out in two steps:
(1) dissolving: with a part of solvent suction heat automatically mixing kettle (band high-speed shearing machine, can in whipping process, heat up automatically, high-speed stirred also is beneficial to emulsifying effectiveness) in, take by weighing and obtain Quizalotop-ethyl former powder of the needed Quizalotop-ethyl of effective content missible oil or Quizalotop-ethyl mother liquor input mixing kettle.Start clipper and stirred 20～30 minutes, fluid temperature reaches 40～50 ℃ in the still, and Quizalotop-ethyl stops when all dissolving stirring.
(2) emulsification: add the solvent of synergist, emulsifier and surplus in mixing kettle, stirred 30～50 minutes, temperature in the kettle reaches 60～70 ℃, and sampling detects and obtains product.
Weed killer herbicide product of the present invention is light yellow homogeneous liquid, does not have visible missible oil and precipitation.
Weed killer herbicide of the present invention is applicable to farmlands such as most of broad leaf crops, vegetables, fruit tree, Chinese medicine, and applicable crops has:
[1] Cruciferae: rape, Chinese cabbage, cauliflower, radish etc.;
[2] pulse family: soybean, peanut, mung bean, red bean, broad bean, pea, Kidney bean, clover etc.;
[3] Solanaceae: tomato, capsicum, potato, eggplant etc.;
[4] Curcurbitaceae: watermelon, muskmelon, pumpkin, sponge gourd, tobacco etc.;
[5] Liliaceae: shallot, garlic, leek, day lily etc.;
[6] Umbelliferae: carrot, caraway, fennel, celery etc.;
[7] Chinese medicine class: safflower, the Radix Astragali, red butch clover, isatis root, Radix Glycyrrhizae, matrimony vine etc.;
[8] fruit tree: citrus, apple, pears, pineapple, bamboo grows, grape, pepper, tea place, mulberry field etc.;
[9] cotton, peppermint, lettuce, Chinese yam, flax, konjaku etc.
Herbicidal spectrum: annual and perennial grassy weeds such as lady's-grass, wild oat, barnyard grass grass, green foxtail, setaria glauca, Ye Li, eleusine indica, amur foxtail, india lovegrass, moleplant seed, bromegrass, lolium temulentum, millet genus, annual bluegrass, Paspalum distichum, Bermuda grass, cogongrass, quackgrass, reed.
Use age and method:
Before the 4 leaf phases of weeds during high humidity with low amount, 4 leaf phases leaf phase to 5 with in amount, as weeds 6 leaves more than the phase, weather arid, low temperature, then consumption height.Method: first dilute with water, the cauline leaf spraying is handled again.
Use in most of broad leaf crops, vegetables, fruit tree, Chinese medicine field, dosage is few, in the spraying of weeds 3-7 leaf phase cauline leaf, most of grassy weeds is had excellent preventive effect, weeds flavescence in 2 days, cauline leaf necrosis in 3-4 days, the death of 6-9 leaf weeds.
The advantage of weed killer herbicide of the present invention:
1, active constituent content brings up to 10.1～30%, strong drug action, and using dosage is little, and use cost is low, and result of use is good, can be used for elder weed, and responding time is short.Evidence is compared with original like product operating position, and every mu of consumption reduces more than 65%, and drug effect improves more than 15%, responding time 1～2 day in advance; For elder weed (5-7 leaf phase), drug effect is obvious, and the like product optimum period wide ranges than original can have more the 1-2 leaf phase; And low temperature, arid climatic conditions are to the drug effect influence not quite.
2, the resistance of rainwater washing against performance is good, executes to rain in back 1 hour, and drug effect is not had influence, reduces 1 hour than like product, improves application performance greatly.
3, active constituent content brings up to 10.1～30%, has reduced solvent load (most of solvent, as: benzene, dimethylbenzene etc. have pollution to environment), thereby has reduced the environmental pollution to the crop farmland.
4, product design is big, saves packing, is convenient to transportation.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1:10.8% Quizalotop-ethyl emulsifiable solution herbicide
Ingredient groups becomes:
113.68 kilograms in the former powder of 95% Quizalotop-ethyl;
Solvent: 150 kilograms in acetone, 341.32 kilograms of commercial xylenes;
45 kilograms of synergist: JSE-1;
Emulsifier: 350 kilograms of 8220# emulsifier.
The preparation method:
(1) dissolving: with 150 kilograms of industrial acetones, 160 kilograms of commercial xylene suction mixing kettles, take by weighing 95% the former powder of Quizalotop-ethyl and drop into mixing kettle for 113.68 kilograms, start stirring, 20-30 minute, temperature in the kettle reaches 40～50 ℃, and the former powder of Quizalotop-ethyl stops when all dissolving stirring.
(2) emulsification: with 45 kilograms of JSE-1 synergist, 350 kilograms of 8220# emulsifier and surplus is 181.32 kilograms dimethylbenzene suction mixing kettle, continues to start stirring, and 30-50 minute, temperature in the kettle reached 60～70 ℃, stopped to stir.
(3) sampling detects: missible oil outward appearance, color, active constituent content, stability of emulsion etc., and filter qualified back, and the suction storage tank is distributed into product.
Embodiment 2:12.5% Quizalotop-ethyl emulsifiable solution herbicide
Ingredient groups becomes:
131.58 kilograms in the former powder of 95% Quizalotop-ethyl;
Solvent: 160 kilograms of dimethyl formamides, 423.42 kilograms of commercial xylenes;
Synergist: 25 kilograms of azones;
Emulsifier: 260 kilograms of 8227# emulsifier.
The preparation method:
(1) dissolving: with 160 kilograms of industrial dimethyl formamides, 200 kilograms of commercial xylene suction mixing kettles, take by weighing 95% the former powder of Quizalotop-ethyl and drop into mixing kettle for 131.58 kilograms, start stirring, 20-30 minute, temperature in the kettle reaches 40～50 ℃, and the former powder of Quizalotop-ethyl stops when all dissolving stirring.
(2) emulsification: with 25 kilograms of azones, 260 kilograms of 8227# emulsifier and surplus is 223.42 kilograms dimethylbenzene suction mixing kettle, continues to start stirring, and 30-50 minute, temperature in the kettle reached 60～70 ℃, stopped to stir.
(3) sampling detects: missible oil outward appearance, color, active constituent content, stability of emulsion etc., and filter qualified back, and the suction storage tank is distributed into product.
Other embodiment ingredient groups becomes to see Table 1, and the preparation method is basic identical with embodiment 1, embodiment 2.
Table 1, the embodiment composition table (weight percent composition) of preparing burden
| Embodiment | Quizalotop-ethyl | Solvent | Synergist | Emulsifier |
| Embodiment 3 | The former powder 12 of 95% Quizalotop-ethyl | Acetone 26 dimethylbenzene 30 | Azone 4 | 8227# 28 |
| Embodiment 4 | The former powder 22 of 95% Quizalotop-ethyl | Acetone 20 dimethylbenzene 25 | JSE-2 3 | 8227# 30 |
| Embodiment 5 | The former powder 16 of 95% Quizalotop-ethyl | Dimethylbenzene 51 | Azone 4 | 8227# 29 |
| Embodiment 6 | The former powder 18 of 95% Quizalotop-ethyl | Benzene 15 chloroforms 32 | JSE-1 3 | 8220# 32 |
| Embodiment 7 | The former powder 25 of 95% Quizalotop-ethyl | Toluene 25 methyl alcohol 20 | Azone 2 | 8220# 28 |
| Embodiment 8 | The former powder 28 of 90% Quizalotop-ethyl | Dimethylbenzene 14 dimethyl formamides 30 | JSE-1 2 | 8227# 26 |
| Embodiment 9 | The former powder 22 of 90% Quizalotop-ethyl | Toluene 20 chloroforms 23 | Azone 6 | 8220# 29 |
| Embodiment 10 | 60% Quizalotop-ethyl mother liquor 40 | Acetone 12 commercial xylenes 14 | Azone 4 | 8227# 30 |
| Embodiment 11 | 60% Quizalotop-ethyl mother liquor 20 | Methyl alcohol 18 toluene 28 | Azone 8 | 8220# 26 |
| Embodiment 12 | The former powder 19 of 95% Quizalotop-ethyl | White oil 12 toluene 38 | Azone 5 | 8227# 26 |
| Embodiment 13 | The former powder 13 of 95% Quizalotop-ethyl | Glycol ether 10 benzene 20 dimethylbenzene 20 | JSE-1 4 | 8227# 33 |
| Embodiment 14 | The former powder 20 of 95% Quizalotop-ethyl | Turpentine oil 10 acetone 41 | Azone 3 | 8220# 26 |
| Embodiment 15 | The former powder 24 of 95% Quizalotop-ethyl | Chloroform 20 toluene 26 | Azone 4 | 8227# 26 |
| Embodiment 16 | The former powder 16 of 95% Quizalotop-ethyl | Acetone 12 toluene 14 chloroforms 4 dimethylbenzene 20 | JSE-2 4 | 8227# 30 |
| Embodiment 17 | The former powder 18 of 95% Quizalotop-ethyl | Chlorobenzene 28 acetone 20 | Azone 8 | 8220# 26 |
Claims (9)
1, a kind of herbicide for killing graminaceous weed in latifolious crop field adds emulsifier, synergist and solvent by Quizalotop-ethyl and makes, and it is characterized in that the weight of preparing burden consists of:
10.8 Quizalotop-ethyl raw material consumption, 8220# emulsifier or 8227# emulsifier 26～40%, synergist 1.0～10.0%, surplus that～30.0% Quizalotop-ethyl is converted to are solvent;
Make by following method:
(1) dissolving: in the mixing kettle of heating automatically with a part of solvent suction band high-speed shearing machine, take by weighing and obtain Quizalotop-ethyl former powder of the needed Quizalotop-ethyl of effective content missible oil or Quizalotop-ethyl mother liquor input mixing kettle, starting clipper stirred 20～30 minutes, fluid temperature reaches 40～50 ℃ in the still, and Quizalotop-ethyl stops when all dissolving stirring;
(2) emulsification: add the solvent of synergist, emulsifier and surplus in mixing kettle, stirred 30～50 minutes, temperature in the kettle reaches 60～70 ℃, and sampling detects and obtains product.
2, weed killer herbicide according to claim 1 is characterized in that the weight of preparing burden consists of:
10.8 Quizalotop-ethyl raw material consumption, 8220# emulsifier or 8227# emulsifier 26～35%, synergist 2.0～5.0%, surplus that～20.0% Quizalotop-ethyl is converted to are solvent.
3, weed killer herbicide according to claim 1 and 2 is characterized in that solvent is one or more the arbitrary proportion combination in aromatic hydrocarbons, aliphatic hydrocarbon, alicyclic, alcohol, ketone, ether, vegetable oil, halogenated alkane, dimethyl formamide, methyl-sulfoxide, acetonitrile, the chlorobenzene.
4, weed killer herbicide according to claim 3 is characterized in that aromatic hydrocarbons is: benzene,toluene,xylene, naphthalene, Fluhyzon, arylhydrocarbon in diesel oil.
5, weed killer herbicide according to claim 3 is characterized in that aliphatic hydrocarbon, alicyclic are: white gas, diesel oil, white oil, machine oil, diesel oil.
6, weed killer herbicide according to claim 3 is characterized in that alcohol is: methyl alcohol, ethanol, propyl alcohol, isopropyl alcohol, butanols, isobutanol, glycerine, ethylene glycol.
7, weed killer herbicide according to claim 3 is characterized in that ketone is: cyclohexanone, MEK, acetone, isophorone; Ether is: glycol ether, propylene glycol.
8, weed killer herbicide according to claim 3 is characterized in that vegetable oil is: rapeseed oil, cotton seed oil, turpentine oil.
9, weed killer herbicide according to claim 3 is characterized in that halogenated alkane is: carrene, chloroform, trichloroethanes, carbon tetrachloride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011275243A CN1135923C (en) | 2001-09-30 | 2001-09-30 | Herbicide for killing graminaceous weed in latifolious crop field |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011275243A CN1135923C (en) | 2001-09-30 | 2001-09-30 | Herbicide for killing graminaceous weed in latifolious crop field |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1357233A CN1357233A (en) | 2002-07-10 |
| CN1135923C true CN1135923C (en) | 2004-01-28 |
Family
ID=4667468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011275243A Expired - Fee Related CN1135923C (en) | 2001-09-30 | 2001-09-30 | Herbicide for killing graminaceous weed in latifolious crop field |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1135923C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107624763A (en) * | 2017-10-13 | 2018-01-26 | 南京扬子鸿利源化学品有限责任公司 | A kind of Herbicide Jing quizalofop-ethyl EC containing Synergistic plant oil and preparation method thereof |
| WO2019230621A1 (en) * | 2018-05-28 | 2019-12-05 | 日産化学株式会社 | Emulsifiable pesticide composition |
-
2001
- 2001-09-30 CN CNB011275243A patent/CN1135923C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1357233A (en) | 2002-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1905796A (en) | Pesticidal compositions | |
| CN110037014B (en) | Compound synergist containing lecithin and D-limonene and preparation method and application thereof | |
| CN1135923C (en) | Herbicide for killing graminaceous weed in latifolious crop field | |
| WO2017045268A1 (en) | Insecticide with high content of pyrethrin | |
| CN1105497C (en) | Insecticidal and miticidal compositions | |
| CN101371659B (en) | Adjuvant composition with pesticide synergistic function | |
| CN103636611B (en) | Ultra-low volume liquid containing tebufenpyrad | |
| CN101836662B (en) | Liriomyza sativae attractant and application thereof | |
| CN1810123A (en) | Botanical pesticide prepared with calamus | |
| CN102302003A (en) | Interference repellent for leguminivora glycinivorella and preparation method of interference repellent | |
| CN1153599A (en) | Plant pesticide | |
| CN1288983C (en) | Xanthoxylin insecticide and its preparation method | |
| CN103053575A (en) | Nicosulfuron-atrazine mixed herbicide | |
| Wahba | Antifeedant activity of three essential oils and their nanoemulsions against the rice weevil Sitophilus oryzae (L.) | |
| CN113508825A (en) | Ecological pesticide, preparation method, preparation and application thereof | |
| CN1029287C (en) | Suspended emulsion of sym-triazbenzene-amide herbicides | |
| CN1095331C (en) | Ammonium ethoxalate and ethoxyfluoro oxal ether mixture and producing method thereof | |
| CN108782573B (en) | Acaricidal composition of D-limonene and rotenone and application thereof | |
| CN102283231A (en) | Oil suspending agent composition containing nicosulfuron and fluroxypyr | |
| CN1784966A (en) | Herbicide for killing the grass family weeds in broad-leaved crops fields | |
| CN110150329A (en) | The insecticide and its processing method of capsaicine and purple stem boneset extract compounding | |
| CN1243668A (en) | Mixture of benazolin-ethyl, quizalofop-p-ethyl and ethametsulfron and preparing process thereof | |
| CN1593142A (en) | Mixed herbicide | |
| CN1060912C (en) | Metribuzin-amide herbicide composition and preparation thereof | |
| CN112274967A (en) | Methyl ester mixed extractant and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20040128 Termination date: 20160930 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |