CN113583486A - Sterilization temperature-resistant coating and preparation method and use method thereof - Google Patents

Sterilization temperature-resistant coating and preparation method and use method thereof Download PDF

Info

Publication number
CN113583486A
CN113583486A CN202110865337.9A CN202110865337A CN113583486A CN 113583486 A CN113583486 A CN 113583486A CN 202110865337 A CN202110865337 A CN 202110865337A CN 113583486 A CN113583486 A CN 113583486A
Authority
CN
China
Prior art keywords
temperature
resistant
coating
resistant coating
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110865337.9A
Other languages
Chinese (zh)
Inventor
冯杰超
朱洪江
李淑艳
李宏民
欧庆根
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Sifang Victory New Materials Co ltd
Original Assignee
Guangdong Sifang Victory New Materials Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Sifang Victory New Materials Co ltd filed Critical Guangdong Sifang Victory New Materials Co ltd
Priority to CN202110865337.9A priority Critical patent/CN113583486A/en
Publication of CN113583486A publication Critical patent/CN113583486A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/38Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0806Silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a sterilization temperature-resistant coating which comprises organic and inorganic high-temperature-resistant resin, a sterilization deodorant, a first solvent, a second solvent, aluminum powder and a coating auxiliary agent, wherein the organic and inorganic high-temperature-resistant resin is SF605 resin, the first solvent is butyl acetate and ethyl acetate, and the second solvent is trimethylbenzene and butanone. The sterilization temperature-resistant coating provided by the invention uses organic and inorganic high-temperature-resistant resin, so that the temperature resistance limit can reach 450 ℃, and the sterilization temperature-resistant coating can still keep good glossiness and adhesive force even being in a 400 ℃ environment for a long time, and has deodorization and sterilization effects; trimethylbenzene is dried slowly, the dissolving capacity is poor, the butyl acetate dissolving capacity is strong, the trimethylbenzene is quick to dry, and the first solvent and the second solvent are matched for use, so that the organic and inorganic high-temperature-resistant resin is uniformly dissolved and uniformly distributed in the coating, and the construction spraying of the whole coating system is facilitated. The sterilization temperature-resistant coating can be widely applied to the inner walls of ovens, microwave ovens, disinfection cabinets, electric cookers and frying pans.

Description

Sterilization temperature-resistant coating and preparation method and use method thereof
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to a sterilization temperature-resistant coating as well as a preparation method and a use method thereof.
Background
The prior temperature-resistant coating is mainly divided into the following four types: 1. pure silicon or polyester modified organic silicon system is adopted as the temperature-resistant coating, the temperature resistance limit is below 350 ℃, and the conditions of pulverization, paint fading, poor mechanical property and the like can occur when the coating is used at high temperature for a long time; 2. the ceramic system is used as a temperature-resistant coating, the temperature-resistant limit is below 350 ℃, the brittleness is high, the higher the temperature is, the higher the risk of cracking and paint falling is, the hardness is high, and the mechanical property is poor; 3. an engineering plastic system is adopted as a temperature-resistant coating, the temperature-resistant limit is below 400 ℃, the construction conditions are harsh, and the long-term heat loss is serious; 4. polytetrafluoroethylene is used as a temperature-resistant coating, which can resist 400 ℃ for a long time, but is forbidden in America and part of European Union countries. The four types of temperature-resistant coatings have advantages and disadvantages, but at present, deodorizing and sterilizing functional coatings which have the advantages of temperature resistance of 400-450 ℃, no toxicity, less heat loss, no cracking, hardness of more than 3H and good light and color retention are still lacking in the market.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide a bactericidal temperature-resistant coating which can resist the temperature of 400-450 ℃, is durable in temperature resistance and has bactericidal property.
The invention is realized by the following technical scheme:
the bactericidal temperature-resistant coating comprises organic and inorganic high-temperature-resistant resin, a bactericidal deodorant, a first solvent, a second solvent, aluminum powder and a coating auxiliary agent, wherein the organic and inorganic high-temperature-resistant resin is SF605 resin, the first solvent is butyl acetate and ethyl acetate, and the second solvent is trimethylbenzene and butanone.
The sterilization temperature-resistant coating provided by the invention uses organic and inorganic high-temperature-resistant resin, so that the temperature resistance limit can reach 450 ℃, the sterilization temperature-resistant coating can not fade when being in a 400 ℃ environment for a long time, and good glossiness and adhesive force can be still kept; the trimethylbenzene is dried slowly, the dissolving capacity is poor, the butyl acetate dissolving capacity is strong, the trimethylbenzene is quick to dry, and the first solvent and the second solvent are matched for use, so that the organic and inorganic high-temperature-resistant resin is dissolved uniformly and distributed uniformly in the coating, and the construction spraying of the whole coating system is facilitated; the aluminum powder belongs to an effect pigment, the aluminum powder is used for increasing the surface effect of a coating, so that the bactericidal temperature-resistant coating has a glittering effect, and the aluminum powder is added to have a synergistic effect with other components, so that the temperature resistance durability of the whole coating is improved; the organic and inorganic high-temperature resistant resin is matched and cooperated with the sterilization deodorant and other paint auxiliaries, so that the sterilization temperature resistant paint has the effects of deodorization and sterilization and has excellent optical performance, mechanical performance and processability. The sterilization temperature-resistant coating can be widely applied to the inner walls of ovens, microwave ovens, disinfection cabinets, electric cookers and frying pans.
Further, the sterilizing deodorant is a zinc oxide and silver compound ceramic glaze sterilizing agent. The proper sterilization deodorant is selected, so that the proper sterilization effect is ensured, and the sterilization deodorant has good compatibility with other components.
Further, the sterilization temperature-resistant coating comprises 53-60% by weight of organic-inorganic high-temperature-resistant resin, 2-5% by weight of sterilization deodorant, 5-7% by weight of first solvent, 8-10% by weight of second solvent and 1.5-2% by weight of aluminum powder. The sterilization temperature-resistant coating has good chemical property and mechanical property by proper proportion.
Further, the sterilization temperature-resistant coating comprises 3.5-5% by weight of butyl acetate, 1.5-2% by weight of ethyl acetate, 4-5% by weight of trimethylbenzene and 4-5% by weight of butanone. The solvent with proper proportion is selected, and the slow-drying trimethylbenzene with poor dissolving capacity and the fast-drying butyl acetate with strong dissolving capacity are matched for use, so that the dissolving rate of the organic-inorganic high-temperature-resistant resin is adjusted, the organic-inorganic high-temperature-resistant resin is better blended with other components, and the organic-inorganic high-temperature-resistant resin has excellent construction spraying performance.
Further, the coating auxiliary agent comprises an anti-settling agent, talcum powder, a flatting agent and a defoaming agent. The anti-settling agent is used for regulating and controlling rheological property; the talcum powder is used for extinction; the leveling agent is used for reducing surface tension and promoting the sterilization temperature-resistant coating to form a flat and smooth coating after being dried; the defoaming agent is used for eliminating foams generated in the processing process of the sterilizing temperature-resistant coating and foams generated in the spraying and baking process of the coating.
Further, the bactericidal temperature-resistant coating comprises 1-1.5 wt% of anti-settling agent, 8-10 wt% of talcum powder, 0.2-0.5 wt% of flatting agent and 0.2-0.5 wt% of defoaming agent. The paint additive can better enhance the optical property, the mechanical property, the processing property and the like by proper proportion.
Further, the sterilization temperature-resistant paint also comprises a temperature-resistant pigment, wherein the temperature-resistant pigment comprises at least one of copper chromium black, manganese iron black and iron oxide red. The temperature-resistant pigment is used for hyperchromia, and the copper-chromium black has pure color, good blackness and heat resistance; the manganese iron black is a black pigment with a slightly red phase and has good temperature resistance; the iron oxide red as a pigment has good heat resistance and strong colorability.
Further, the bactericidal temperature-resistant coating comprises 6-7% of copper-chromium black, 1-2% of manganese-iron black and 0.2-0.3% of iron oxide red by weight. The color of the sterilizing temperature-resistant coating is prepared according to a proper proportion, and the sterilizing temperature-resistant coating has temperature resistance.
The invention also provides a preparation method of the bactericidal temperature-resistant coating, which comprises the following steps:
mixing aluminum powder, a first solvent and organic-inorganic high-temperature-resistant resin to obtain a first mixture; mixing organic and inorganic high-temperature-resistant resin, temperature-resistant pigment, a sterilization deodorant, part of coating auxiliary agent and a second solvent to obtain a second mixture; adding part of the coating auxiliary agent and the organic-inorganic high-temperature-resistant resin into the finished second mixture to obtain a third mixture; and mixing the first mixture and the third mixture to obtain the bactericidal temperature-resistant coating.
According to the preparation method of the sterilization temperature-resistant coating, the organic-inorganic high-temperature-resistant resin is mixed with the first solvent and the second solvent respectively, the organic-inorganic high-temperature-resistant resin in the first mixture has high solubility and is quick-drying when being dissolved in the first solvent, if the first solvent is used alone, the whole coating system is abnormally quick-drying, and the coating cannot obtain a good spreading effect during construction spraying; the solubility of the organic-inorganic high-temperature resistant resin in the second mixture is moderate and the organic-inorganic high-temperature resistant resin is dried slowly when the organic-inorganic high-temperature resistant resin is dissolved in the second solvent, and the second mixture also comprises other components such as a sterilization deodorant, a temperature-resistant pigment, a coating auxiliary agent and the like, so that the slow drying is favorable for the fusion of the organic-inorganic high-temperature resistant resin and the other components, the first mixture is added into the second mixture, namely the two solvents with different dissolution rates are mixed for use, the regulation and control of the dissolution rate of the organic-inorganic high-temperature resistant resin are favorable, and the organic-inorganic high-temperature resistant resin and the other components are uniformly mixed. The sterilization temperature-resistant coating is anticorrosive, and the sterilization temperature-resistant coating which is high-temperature resistant, uniformly distributed and has sterilization performance is prepared.
The invention also provides a using method of the sterilization temperature-resistant coating, wherein the sterilization temperature-resistant coating is sprayed on a workpiece to form a coating film, and the coating film is dried after leveling; wherein the thickness of the coating film is 15 to 23 μm.
The application method of the sterilization temperature-resistant coating can form a coating film with good temperature resistance, sterilization and mechanical properties on a workpiece, and if the thickness of the coating film is too thin, the heat preservation and color retention performances are poor, and if the thickness of the coating film is too thick, high-temperature cracking and other situations are easily caused.
Detailed Description
The invention provides a sterilization temperature-resistant coating, which comprises organic and inorganic high-temperature-resistant resin, a sterilization deodorant, a first solvent, a second solvent, aluminum powder and a coating auxiliary agent, wherein the organic and inorganic high-temperature-resistant resin is SF605 resin of Aupaly coating Co., Ltd, the first solvent is butyl acetate and ethyl acetate, and the second solvent is trimethylbenzene and butanone.
The sterilization temperature-resistant coating provided by the invention uses organic and inorganic high-temperature-resistant resin, so that the temperature resistance limit can reach 450 ℃, and the sterilization temperature-resistant coating can still keep good glossiness and adhesive force even being in a 400 ℃ environment for a long time, and has deodorization and sterilization effects; the trimethylbenzene is dried slowly, the dissolving capacity is poor, the butyl acetate dissolving capacity is strong, the trimethylbenzene is quick to dry, and the first solvent and the second solvent are matched for use, so that the organic and inorganic high-temperature-resistant resin is dissolved uniformly and distributed uniformly in the coating, and the construction spraying of the whole coating system is facilitated; the aluminum powder belongs to an effect pigment, the aluminum powder is used for increasing the surface effect of a coating, so that the bactericidal temperature-resistant coating has a glittering effect, and the aluminum powder is added to have a synergistic effect with other components, so that the temperature resistance durability of the whole coating is improved; the organic and inorganic high-temperature resistant resin is matched and cooperated with the sterilization deodorant and other paint auxiliaries, so that the sterilization temperature resistant paint has the effects of deodorization and sterilization and has excellent optical performance, mechanical performance and processability. The sterilization temperature-resistant coating can be widely applied to the inner walls of ovens, microwave ovens, disinfection cabinets, electric cookers and frying pans.
Preferably, the sterilizing and deodorizing agent is a zinc oxide and silver compound ceramic glaze sterilizing agent. The proper sterilization deodorant is selected, so that the proper sterilization effect is ensured, and the sterilization deodorant has good compatibility with other components.
Preferably, the sterilization temperature-resistant coating comprises 53-60% of organic-inorganic high-temperature-resistant resin, 2-2.5% of sterilization deodorant, 5-7% of first solvent, 8-10% of second solvent and 1.5-2% of aluminum powder by weight. The sterilization temperature-resistant coating has good chemical property and mechanical property by proper proportion.
More preferably, the sterilization temperature-resistant coating comprises 3.5-5% by weight of butyl acetate, 1.5-2% by weight of ethyl acetate, 4-5% by weight of trimethylbenzene and 4-5% by weight of butanone. The solvent with proper proportion is selected, and the slow-drying trimethylbenzene with poor dissolving capacity and the fast-drying butyl acetate with strong dissolving capacity are matched for use, so that the dissolving rate of the organic-inorganic high-temperature-resistant resin is adjusted, the organic-inorganic high-temperature-resistant resin is better blended with other components, and the organic-inorganic high-temperature-resistant resin has excellent construction spraying performance.
Preferably, the coating auxiliary agent comprises an anti-settling agent, talcum powder, a leveling agent and an antifoaming agent. The anti-settling agent is used for regulating and controlling rheological property; the talcum powder is used for extinction; the leveling agent is used for reducing surface tension and promoting the sterilization temperature-resistant coating to form a flat and smooth coating after being dried; the defoaming agent is used for eliminating foams generated in the processing process of the sterilizing temperature-resistant coating and foams generated in the spraying and baking process of the coating.
More preferably, the bactericidal temperature-resistant coating comprises 1-1.5 wt% of anti-settling agent, 8-10 wt% of talcum powder, 0.2-0.5 wt% of flatting agent and 0.2-0.5 wt% of defoaming agent. The paint additive can better enhance the optical property, the mechanical property, the processing property and the like by proper proportion.
Preferably, the sterilization temperature-resistant paint further comprises a temperature-resistant pigment, and the temperature-resistant pigment comprises at least one of copper chromium black, manganese iron black and iron oxide red. The temperature-resistant pigment is used for hyperchromia, and the copper-chromium black has pure color, good blackness and heat resistance; the manganese iron black is a black pigment with a slightly red phase and has good temperature resistance; the iron oxide red has good heat resistance and strong colorability.
Preferably, the bactericidal temperature-resistant coating comprises 6% -7% of copper-chromium black, 1% -2% of manganese-iron black and 0.2% -0.35% of iron oxide red. The color of the sterilizing temperature-resistant coating is prepared according to a proper proportion, and the sterilizing temperature-resistant coating has temperature resistance.
The invention also provides a preparation method of the sterilizing temperature-resistant coating, which comprises the following steps:
mixing aluminum powder, a first solvent and organic-inorganic high-temperature-resistant resin to obtain a first mixture;
mixing organic and inorganic high-temperature-resistant resin, temperature-resistant pigment, a sterilization deodorant, part of coating auxiliary agent and a second solvent to obtain a second mixture;
adding part of the coating auxiliary agent and the organic-inorganic high-temperature-resistant resin into the finished second mixture to obtain a third mixture;
and mixing the first mixture and the third mixture to obtain the sterilizing temperature-resistant coating.
According to the preparation method of the sterilization temperature-resistant coating, the organic-inorganic high-temperature-resistant resin is mixed with the first solvent and the second solvent respectively, the organic-inorganic high-temperature-resistant resin in the first mixture has high solubility and is quick-drying when being dissolved in the first solvent, the whole coating system is abnormally quick-drying, and the coating cannot obtain a good spreading effect during construction spraying; the solubility of the organic-inorganic high-temperature resistant resin in the second mixture is moderate and the organic-inorganic high-temperature resistant resin is dried slowly when the organic-inorganic high-temperature resistant resin is dissolved in the second solvent, and the second mixture also comprises other components such as a sterilization deodorant, a temperature-resistant pigment coating auxiliary agent and the like, so that the slow drying is beneficial to the fusion of the organic-inorganic high-temperature resistant resin and the other components, the first mixture is added into the second mixture, the regulation of the dissolution rate of the organic-inorganic high-temperature resistant resin is facilitated, and the organic-inorganic high-temperature resistant resin and the other components are uniformly mixed. The sterilization temperature-resistant coating is anticorrosive, and the sterilization temperature-resistant coating which is high-temperature resistant, uniformly distributed and has sterilization performance is prepared.
In a specific embodiment, aluminum powder is mixed with a first solvent and an organic-inorganic high temperature resistant resin to obtain a first mixture. After the aluminum powder is diluted, organic and inorganic high-temperature-resistant resin is added to play a role in flowing; and adding the organic-inorganic mixture into the second mixture, mixing with a sterilizing deodorant, a temperature-resistant pigment and a coating auxiliary agent, and grinding to reach the fineness requirement of 10 micrometers.
The invention also provides a using method of the sterilizing temperature-resistant coating, which comprises the following steps:
spraying the sterilization temperature-resistant coating on a workpiece to form a coating, leveling and drying; wherein the thickness of the coating film is 15 to 23 μm.
The application method of the sterilization temperature-resistant coating can form a coating film with good temperature resistance, sterilization and mechanical properties on a workpiece, and if the thickness of the coating film is too thin, the heat preservation and color retention performances are poor, and if the thickness of the coating film is too thick, high-temperature cracking and other situations are easily caused.
Example 1
This example 1 provides a bactericidal and temperature-resistant paint, which includes 53 wt% of organic-inorganic high-temperature-resistant resin, 2 wt% of bactericidal deodorant, 3.5 wt% of butyl acetate, 1.5 wt% of ethyl acetate, 4 wt% of trimethylbenzene, 4 wt% of butanone, 1 wt% of anti-settling agent, 6 wt% of copper-chromium black, 1 wt% of manganese-iron black, 8 wt% of talc powder, 0.2 wt% of leveling agent, 0.2 wt% of defoaming agent, 0.2 wt% of iron oxide red, and 1.5 wt% of aluminum powder.
Specifically, the anti-settling agent is at least one of bentonite and fumed silica; the leveling agent is an organic silicon or organic fluorine leveling agent, and specifically can be a BYK306 leveling agent or a BYK310 leveling agent; the defoaming agent is an organic silicon defoaming agent.
The sterilization temperature-resistant coating provided by the embodiment 1 has a temperature-resistant limit of 450 ℃, can be used at 400 ℃ for a long time, has excellent gloss retention and good adhesive force, has a continuous deodorization and sterilization effect, has boiling resistance and steam resistance, meets the national standards of RoHS and Chinese food safety and food health regulations approved by corresponding export countries such as FDA and LFGB, and provides a detection qualification report issued by a qualification-related organization.
The embodiment 1 provides a preparation method of a bactericidal temperature-resistant coating, which includes the following steps:
mixing and uniformly dispersing aluminum powder, 1.5% butyl acetate and ethyl acetate, adding 8% by weight of organic-inorganic high-temperature-resistant resin, and uniformly dispersing to obtain a first mixture;
adding 25 weight percent of organic-inorganic high-temperature-resistant resin into an operating cylinder, adding an anti-settling agent, copper-chromium black, manganese-iron black, a sterilizing deodorant, iron oxide red, trimethylbenzene and butanone while dispersing, uniformly dispersing, and grinding until the fineness is less than or equal to 10 mu m to obtain a second mixture;
adding 20% of organic-inorganic high-temperature-resistant resin into the second mixture, adding talcum powder, adding 2% of butyl acetate, cleaning the edge of the reaction container, dispersing for 15min until the fineness is less than or equal to 15 mu m, and then adding a leveling agent and a defoaming agent to obtain a third mixture;
the first mixture was added to the third mixture using a 180 mesh screen and dispersed at medium speed for 15 min.
The invention also provides a using method of the sterilizing temperature-resistant coating, which comprises the following steps:
the workpiece is pretreated, and dirt and dust on the surface are thoroughly removed;
spraying the sterilization temperature-resistant coating on a workpiece to form a coating film, leveling for 5-8min, and drying at 380-400 ℃ for 15 min. Wherein the coating film has a thickness of 15 to 23 μm, in a specific embodiment 18 to 23 μm. Since the coating film is a functional coating film, the heat-retaining color retention property is poor if the coating film is too thin, and the foaming is easy if the coating film is too thick, and the mechanical properties are relatively poor.
Example 2
This example 2 provides a bactericidal and temperature-resistant coating, which includes 60% by weight of organic-inorganic high-temperature-resistant resin, 2.5% by weight of bactericidal deodorant, 5% by weight of butyl acetate, 2% by weight of ethyl acetate, 5% by weight of trimethylbenzene, 5% by weight of butanone, 1.5% by weight of anti-settling agent, 7% by weight of copper-chromium black, 2% by weight of manganese-iron black, 10% by weight of talc, 0.5% by weight of leveling agent, 0.5% by weight of defoaming agent, 0.3% by weight of iron oxide red, and 2% by weight of aluminum powder. Specifically, the anti-settling agent is at least one of bentonite and fumed silica; the leveling agent is an organic silicon or organic fluorine leveling agent, and specifically can be a BYK306 leveling agent or a BYK310 leveling agent; the defoaming agent is an organic silicon defoaming agent.
The mechanical properties of the bactericidal temperature-resistant coating described in example 1-2 were measured, and the measurement results are shown in table 1-1:
TABLE 1-1 measurement results of mechanical properties of bactericidal temperature-resistant paint
Figure BDA0003187080620000081
Figure BDA0003187080620000091
The performance of the commercially available temperature-resistant coating is detected, and the detection results are shown in tables 1-2:
TABLE 1-2 mechanical performance test results for commercially available temperature resistant coatings
Figure BDA0003187080620000092
Figure BDA0003187080620000101
As can be seen from comparison of tables 1-1 and 1-2, examples 1 and 2 have good hardness, good heat resistance, a temperature resistance limit of 450 ℃, stable use at 400 ℃, good adhesion, and steam resistance. The sterilization temperature-resistant coating can be widely applied to the inner walls of ovens, microwave ovens, disinfection cabinets, electric cookers and woks, and is high-temperature-resistant and steam-resistant.
The present invention is not limited to the above-described embodiments, and various modifications and variations of the present invention are intended to be included within the scope of the claims and the equivalent technology of the present invention if they do not depart from the spirit and scope of the present invention.

Claims (10)

1. The sterilization temperature-resistant coating is characterized in that:
the paint comprises organic and inorganic high-temperature-resistant resin, a sterilization deodorant, a first solvent, a second solvent, aluminum powder and a paint auxiliary agent, wherein the organic and inorganic high-temperature-resistant resin is SF605 resin of Opaili paint company Limited, the first solvent is butyl acetate and ethyl acetate, and the second solvent is trimethylbenzene and butanone.
2. The bactericidal temperature-resistant coating of claim 1, wherein:
the sterilizing deodorant is a zinc oxide and silver compound ceramic glaze bactericide.
3. The bactericidal temperature-resistant coating of claim 1, wherein:
the bactericidal temperature-resistant coating comprises 53-60% by weight of organic-inorganic high-temperature-resistant resin, 2-5% by weight of bactericidal deodorant, 5-7% by weight of first solvent, 8-10% by weight of second solvent and 1.5-2% by weight of aluminum powder.
4. The bactericidal temperature-resistant coating of claim 3, wherein:
the bactericidal temperature-resistant coating comprises 3.5-5% by weight of butyl acetate, 1.5-2% by weight of ethyl acetate, 4-5% by weight of trimethylbenzene and 4-5% by weight of butanone.
5. The bactericidal temperature-resistant coating of claim 1, wherein;
the coating auxiliary agent comprises an anti-settling agent, talcum powder, a flatting agent and a defoaming agent.
6. The bactericidal temperature-resistant coating of claim 5, wherein:
the bactericidal temperature-resistant coating comprises 1-1.5 wt% of anti-settling agent, 8-10 wt% of talcum powder, 0.2-0.5 wt% of flatting agent and 0.2-0.5 wt% of defoaming agent.
7. The bactericidal temperature-resistant coating of claim 1, wherein:
the paint also comprises a temperature-resistant pigment, wherein the pigment comprises at least one of copper chromium black, manganese iron black and iron oxide red.
8. The bactericidal temperature-resistant coating of claim 7, wherein:
the bactericidal temperature-resistant coating comprises 6-7% of copper-chromium black, 1-2% of manganese-iron black and 0.2-0.3% of iron oxide red by weight.
9. The preparation method of the bactericidal temperature-resistant coating according to any one of claims 1 to 8, which is characterized by comprising the following steps:
the method comprises the following steps:
mixing aluminum powder, a first solvent and organic-inorganic high-temperature-resistant resin to obtain a first mixture;
mixing organic and inorganic high-temperature-resistant resin, temperature-resistant pigment, a sterilization deodorant, part of coating auxiliary agent and a second solvent to obtain a second mixture;
adding part of the coating auxiliary agent and the organic-inorganic high-temperature-resistant resin into the finished second mixture to obtain a third mixture;
and mixing the first mixture and the third mixture to obtain the bactericidal temperature-resistant coating.
10. The use method of the bactericidal temperature-resistant coating according to any one of claims 1 to 8, characterized by comprising the following steps:
spraying the sterilization temperature-resistant coating on a workpiece to form a coating, leveling and drying; wherein the thickness of the coating film is 15 to 23 μm.
CN202110865337.9A 2021-07-29 2021-07-29 Sterilization temperature-resistant coating and preparation method and use method thereof Pending CN113583486A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110865337.9A CN113583486A (en) 2021-07-29 2021-07-29 Sterilization temperature-resistant coating and preparation method and use method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110865337.9A CN113583486A (en) 2021-07-29 2021-07-29 Sterilization temperature-resistant coating and preparation method and use method thereof

Publications (1)

Publication Number Publication Date
CN113583486A true CN113583486A (en) 2021-11-02

Family

ID=78252057

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110865337.9A Pending CN113583486A (en) 2021-07-29 2021-07-29 Sterilization temperature-resistant coating and preparation method and use method thereof

Country Status (1)

Country Link
CN (1) CN113583486A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100791049B1 (en) * 2006-07-28 2008-01-03 한국전기연구원 Manufacturing method of organic~inorganic hybrid sol solutions composed of polymeric resins with inorganic nanoparticles modified by organosilanes, and the materials
CN101654593A (en) * 2008-08-18 2010-02-24 深圳佳德威油漆有限公司 Method for preparing high-temperature resistant antibacterial non-stick paint
CN102030906A (en) * 2010-11-16 2011-04-27 北方涂料工业研究设计院 Preparation of organic-inorganic hybrid resin for high temperature resistant heavy anti-corrosion paint
CN103819987A (en) * 2014-01-07 2014-05-28 江门市制漆厂有限公司 Waterborne organic/inorganic hybrid plastic coating and preparation method thereof
CN107406718A (en) * 2016-03-09 2017-11-28 长濑产业株式会社 Coating fluid composition, the forming method of coated film, the manufacture method of coating fluid composition, the manufacture device of coating fluid composition and carbonated coating fluid composition modulation composition
CN111154397A (en) * 2020-01-07 2020-05-15 浙江钱浪涂料科技有限公司 High-temperature-resistant anticorrosive primer for metal structure surface and preparation method thereof
CN111849341A (en) * 2020-07-22 2020-10-30 绵阳麦思威尔科技有限公司 Organic-inorganic nano hybrid water-based high-temperature-resistant anticorrosive paint and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100791049B1 (en) * 2006-07-28 2008-01-03 한국전기연구원 Manufacturing method of organic~inorganic hybrid sol solutions composed of polymeric resins with inorganic nanoparticles modified by organosilanes, and the materials
CN101654593A (en) * 2008-08-18 2010-02-24 深圳佳德威油漆有限公司 Method for preparing high-temperature resistant antibacterial non-stick paint
CN102030906A (en) * 2010-11-16 2011-04-27 北方涂料工业研究设计院 Preparation of organic-inorganic hybrid resin for high temperature resistant heavy anti-corrosion paint
CN103819987A (en) * 2014-01-07 2014-05-28 江门市制漆厂有限公司 Waterborne organic/inorganic hybrid plastic coating and preparation method thereof
CN107406718A (en) * 2016-03-09 2017-11-28 长濑产业株式会社 Coating fluid composition, the forming method of coated film, the manufacture method of coating fluid composition, the manufacture device of coating fluid composition and carbonated coating fluid composition modulation composition
CN111154397A (en) * 2020-01-07 2020-05-15 浙江钱浪涂料科技有限公司 High-temperature-resistant anticorrosive primer for metal structure surface and preparation method thereof
CN111849341A (en) * 2020-07-22 2020-10-30 绵阳麦思威尔科技有限公司 Organic-inorganic nano hybrid water-based high-temperature-resistant anticorrosive paint and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
曾晓鹰等主编: "《电子束固化涂料及应用》", 31 December 2014, 天津大学出版社 *

Similar Documents

Publication Publication Date Title
EP2099874B1 (en) Pigment-based non-aqueous ink-jet inks
KR100622883B1 (en) Water-based primer composition for fluororesin coating
WO2019233161A1 (en) Water-based heat-resistant paint and preparation method thereof
CN104059440B (en) The water-borne coatings that a kind of weathering resistance is high
CN101525518B (en) Water-based non-stick polyether sulphone coating containing no perfluorooctanoic acid and method for preparing same
CN105524548A (en) Water-based, environment-friendly and high-temperature coating and preparation method thereof
CN113583486A (en) Sterilization temperature-resistant coating and preparation method and use method thereof
CN113214737A (en) Heat-resistant coating, preparation method thereof and non-stick pan
CN112708333A (en) Boiling-resistant powder coating composition
CN101255312A (en) Solvent type organic silicon thermostable paint and production method thereof
CA3014217C (en) Multi-color paint: diy easy roller application formulation by thixotropic resins in continuous phase
CN110283481A (en) A kind of inorganic coating, substrate and preparation method thereof
JP4919726B2 (en) Aqueous paint composition
KR20130081630A (en) Ceramic coating composition and coated article
CN109423101A (en) A kind of polyamide wax anti-settling agent
JPS5847430B2 (en) Composition for forming heat-resistant film
CN109439146A (en) Anti-skidding superhard fire-retardant floor coatings
KR102368483B1 (en) Manufacturing method of ceramic paint compositions
CN104109429A (en) Water-based transferring back coating, and preparation method and application thereof
JP3693446B2 (en) Oil-based ink for marking pens
US20180163065A1 (en) Ceramic printing ink composition having antibacterial function
KR100619597B1 (en) Black coloring method for mounting member
JPS62132981A (en) Composition for protecting coated surface
JPS63248863A (en) Pigment composition
CN115449274A (en) Water-based coil coating and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20211102