CN113578193A - Novel granulator - Google Patents

Novel granulator Download PDF

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Publication number
CN113578193A
CN113578193A CN202110972017.3A CN202110972017A CN113578193A CN 113578193 A CN113578193 A CN 113578193A CN 202110972017 A CN202110972017 A CN 202110972017A CN 113578193 A CN113578193 A CN 113578193A
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CN
China
Prior art keywords
granulator
ammonia
coulter
pipe
distributor
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Pending
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CN202110972017.3A
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Chinese (zh)
Inventor
何贵波
杨家富
陆光福
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Yunnan Hongxiang Chemical Co ltd
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Yunnan Hongxiang Chemical Co ltd
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Priority to CN202110972017.3A priority Critical patent/CN113578193A/en
Publication of CN113578193A publication Critical patent/CN113578193A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/12Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic in rotating drums

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Fertilizers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention discloses a novel granulator which comprises a granulator barrel, wherein a central beam pipe is axially arranged at the center of the interior of the granulator barrel, a plurality of coulters are arranged on the outer wall of the central beam pipe, a distributor pipe is arranged on the outer side of the central beam pipe, a plurality of ammonia nozzles are arranged on the distributor pipe, the included angle between the ammonia spraying rays of the ammonia nozzles and the axial parallel line of the granulator barrel is 0-45 degrees, and the installation angle of the coulters is 51-90 degrees, namely the angle between the plumb line of the central pipe beam of the granulator barrel and the coulters. In this novel granulator, be favorable to the granulator that the bold material rolls out in the granulator, avoid the bold material to be blockked by ammonia distributor, coulter and continue to grow up by the ground paste spraying repeatedly and material bonding, better protection the interior annex of granulator, be favorable to improving granulation granule quality, material bonding on reduction ammonia distributor and the coulter reduces the interior scale deposit of granulator and scabs, reduces granulator transmission equipment load, and accessory ground paste pipe, ground paste shower nozzle life in the extension granulator.

Description

Novel granulator
Technical Field
The invention relates to the technical field of chemical product production equipment, in particular to a novel granulator.
Background
An ammoniation rotary drum granulator is a key device for producing ammonium phosphate products (DAP and GMAP) and various NPK compound fertilizers, an ammonia distributor and a bracket (a colter for short) for fixing the ammonia distributor in the ammoniation rotary drum granulator are core components of the granulator, the installation positions and angles of the ammonia distributor and the colter are key factors influencing the production load of the granulator, the granulation quality and the particle size distribution, the ammonia distributor and the colter of the traditional ammoniation granulator are designed and installed in the axial direction or the radial direction of the granulator, the installation angle is designed according to the rotating speed of a cylinder body, the installation angle is traditionally installed on one side (namely one side in the positive rotation direction) in the material turning direction, and the installation angle is 5-50 degrees (the angle is the included angle between a central pipe beam of the granulator and the ammonia distributor or the colter along the vertical line). The granulator with the ammonia distributor and the coulter arranged in the angle range has the following problems:
1. the slurry sprayed by the slurry spray head is easy to adhere to the ammonia distributor and the coulter, and is adhered into large blocks along with the increase of the adhesive materials on the ammonia distributor and the coulter, so that the rubber plate on the inner wall of the granulator is rubbed, the load of the granulator is increased, and the transmission equipment of the granulator is damaged in severe cases; meanwhile, the abrasion of the rubber plate of the granulator is aggravated, the service life of the granulator is shortened, and the service life of the rubber plate can only reach about 20 days under severe conditions. Secondly, the large materials adhered to the ammonia distributor and the coulter block the materials in the granulator from stably moving forward, the operation speed of the granulated materials in each spraying granulation area is fast and slow, the retention time is short, the times and the quantity of the granulated materials sprayed and coated in the granulation area are different, and the materials discharged from the granulator are uneven in dryness and wetness, differentiated in two poles of granularity, large, small, rough and unsmooth in particle and poor in roundness.
2. The bold material that bonds on ammonia distributor and coulter to and the bold material that bonds at central tubular beams top, along with the rotation of granulator, rub, the extrusion, part bold material can drop to the granulation material bed, drop at the ammonia distributor, the bold material between the coulter, receive the ammonia distributor, the blockking of coulter, unable normal roll shifts out the granulator, along with the granulator rotates, bold material is spouted the coating many times repeatedly in the granulation district, bold material constantly grows up, be spouted the moisture by the ground paste in the area of adding, the material that the cohesiveness is stronger is rolled by bold material and is bonded, form bigger bold material very fast, big reaching about 2000kg, more can't roll out granulation area influence production normal clear, along with the granulator rotates, bold material has three aspect very unfavorable influence:
(1) the granulation rubber plate is damaged by smashing, and when the granulation rubber plate is seriously damaged, a new rubber plate is smashed one day;
(2) the ammonia distributor and the coulter are deformed due to extrusion and damage, the ammoniation granulation effect is influenced, and the ammonia distributor and the coulter are directly extruded and broken in serious cases, so that the ammonia loss is increased, and the production is forced to stop.
(3) The large material crushes and crushes the granules which are sprayed, coated and granulated, so that the granulated granular materials have uneven and irregular sizes and poor roundness;
slurry pipes and nozzles in the granulator are easily extruded and damaged by large materials, and the granulation condition is increasingly poor;
3. the ammonia distributor and the coulter are easy to wear and corrode, the ammonia distributor and the coulter need to be replaced at least one year, the ammonia distributor and the coulter are arranged in a region where slurry is sprayed, the slurry is sprayed out and then is easy to spray on the ammonia distributor and the coulter, the slurry with low pH value corrodes the ammonia distributor and the coulter, and in addition, the ammonia distributor and the coulter are completely buried in a granulating material bed, so that the material bed is worn greatly due to repeated operation of the material bed.
4. The device is low in operation rate and frequent in operation and shutdown, once the large materials of the granulator are bonded to a certain extent, the load of the granulator is rapidly increased, the current is increased, the fluctuation is large, the granulation and granulation are poor, the granulator needs to be stopped to clean the large materials in the granulator for 1-2 times almost every shift, the cleaning time is 1-2 hours every time, and the labor intensity and the safety risk of cleaning are increased.
Disclosure of Invention
The invention aims to provide a novel granulator to solve the problems in the prior art.
In order to achieve the purpose, the invention provides a novel granulator which comprises a granulator barrel, wherein a central beam pipe is axially installed at the center of the inside of the granulator barrel, a plurality of coulters are installed on the outer wall of the central beam pipe, a distributor pipe is installed on the outer side of the central beam pipe, a plurality of ammonia nozzles are installed on the distributor pipe, the included angle between the ammonia spraying ray of each ammonia nozzle and the axial parallel line of the granulator barrel is 0-45 degrees, the specific angle can be adjusted according to the rotating speed of the barrel, the material characteristics and the height of a granulator material bed, the installation angle of each coulter, namely the angle between the vertical line of the central beam of the granulator barrel and the coulters, is 51-90 degrees, and the specific angle can be adjusted according to the granulating rotating speed and the material characteristics.
Preferably, the cylinder of the granulator is horizontally arranged, and the central beam pipe is horizontally arranged at the axis of the cylinder of the granulator.
Preferably, both ends of the central beam pipe are rotatably connected with the inner wall of the granulator cylinder through bearings.
Preferably, the outer end of the distributor pipe outside the central beam pipe is connected with an ammonia distributor, the ammonia distributor uses various forms of special liquid and aerosol material media including, but not limited to, liquid ammonia, gas ammonia, water, oil and the like, and the ammonia distributor includes, but not limited to, various forms of equipment, machinery and derived special objects special for distributing reaction liquid and aerosol material media.
Preferably, the coulter is fixedly installed on the central pipe beam of the granulator through bolts.
Preferably, the distributor pipe outside the central beam pipe is fixedly arranged on the coulter through a bolt.
As preferred, the inside of center beam pipe is close to coulter department and installs the fixed plate, the one end of fixed plate is rotated through the one end of pivot with the coulter and is connected, the coulter can rotate around the one end of fixed plate, the lug is installed to the one end outer wall that states the coulter, two angle limiting plates are installed to the one end of fixed plate, the angle limiting plate can carry out spacingly with the rotation range of coulter, makes the movable angle between center beam plumb line of granulator barrel and the coulter is 51-90.
Preferably, the coulter is made of 304 stainless steel materials, and the surface of the coulter is coated with a perfluoropolyether coating.
Preferably, the distributor pipe outside the central beam pipe is an integrated ammonia distributor pipe, the ammonia nozzles are arranged at equal intervals along the outer wall of the integrated ammonia distributor pipe, and the outer wall of the integrated ammonia distributor pipe is provided with integrated nozzles close to the ammonia nozzles.
Preferably, the distributor pipe on the outer side of the central beam pipe is a split ammonia distributor pipe, the split ammonia distributor pipe is arranged in parallel with the coulter and is tightly attached to the coulter, the ammonia nozzles are distributed on two sides of the tail end of the split ammonia distributor pipe, and the two sides of the tail end of the split ammonia distributor pipe, which are close to the ammonia nozzles, are provided with round, oval or rectangular split nozzles.
Compared with the prior art, the invention has the beneficial effects that:
1. in this novel granulator, be favorable to the interior bold material of granulator to roll out the granulator, avoid the bold material to be blockked by ammonia distributor, coulter and to continue growing up by ground paste spraying repeatedly and material bonding, better protection the interior annex of granulator, be favorable to improving granulation granule quality.
2. Greatly reduces the material adhesion on the ammonia distributor and the coulter, greatly reduces the scaling and scabbing in the granulator, reduces the load of the transmission equipment of the granulator, and can reduce the load of the granulation motor by 20-25 percent under the same production load.
3. The service life of the granulating rubber plate is prolonged by 3-6 times, and is prolonged from 1-3 months to 3-6 months.
4. The service life of the ammonia distributor and the coulter is prolonged by more than 3 times, and the ammonia distributor and the coulter do not need to be replaced within 3 years.
5. The service life of the accessory slurry pipe and the slurry nozzle in the granulator is prolonged to reach more than 3 times of the original service life.
6. High granulation rate, uniform particle size distribution, round and smooth particles and obviously improved appearance quality of products.
7. The device has high operating rate, the times of parking and cleaning the tubular reactor are greatly reduced, the continuous operating time can reach about 15-20 days, the operating rate is greatly improved, and the device yield can be improved by 10-15%.
Drawings
FIG. 1 is a schematic front view of the structure of example 1 of the present invention;
FIG. 2 is a schematic side view of example 1 of the present invention;
FIG. 3 is a schematic view of the structure of an integrated ammonia distributor tube according to the present invention;
FIG. 4 is an enlarged view of a portion of FIG. 2A in accordance with the present invention;
FIG. 5 is a schematic structural view of example 2 of the present invention;
FIG. 6 is a second schematic structural view of embodiment 2 of the present invention;
FIG. 7 is a schematic structural view of a split ammonia distributor tube according to the present invention.
The various reference numbers in the figures mean:
1. a granulator cylinder; 2. a central tubular beam; 21. a fixing plate; 22. an angle limiting plate; 3. an ammonia nozzle; 4. a coulter; 41. a bump; 5. an integrated ammonia distributor tube; 51. an integrated spout; 6. a split ammonia distributor tube; 61. split type spout.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", and the like, indicate orientations and positional relationships based on those shown in the drawings, and are used only for convenience of description and simplicity of description, and do not indicate or imply that the equipment or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be considered as limiting the present invention.
Example 1
The invention provides a novel granulator, as shown in figures 1-4, which comprises a granulator barrel 1, wherein a central beam pipe 2 is axially arranged at the inner center of the granulator barrel 1, a plurality of coulters 4 are arranged on the outer wall of the central beam pipe 2 and are used for cutting and granulating, a distributor pipe is arranged on the outer side of the central beam pipe 2 and is used for mounting a plurality of ammonia nozzles 3 on the distributor pipe and is used for ammonia spraying operation, the included angle between the ammonia spraying line of the ammonia nozzles 3 and the axial parallel line of the granulator barrel 1 is 0-45 degrees, the preferred embodiment is 45 degrees, large materials in the granulator can be favorably rolled out of the granulator, the large materials are prevented from being repeatedly sprayed by slurry and being bonded by the ammonia distributor and continuously growing, accessories in the granulator are better protected, the quality of granulated particles can be favorably improved, the specific angle can be adjusted according to the rotating speed of the barrel, the material characteristics and the height of a granulator bed, installation angle of coulter 4 is angle between 2 plumb lines of center tubular beams of granulator barrel 1 and coulter 4 for 51-90, specific angle can be according to granulation rotational speed and material characteristic adjustment, this embodiment is preferred 51, be favorable to the granulator interior bold material to roll out the granulator, avoid bold material to be blockked by the coulter and to be sprayed repeatedly and the material bonds continues to grow up by the ground paste, better protection the interior annex of granulator, be favorable to improving granulation granule quality, still install tubular reactor in the granulator barrel 1, be used for spraying the ground paste and carry out the granulation.
In this embodiment, granulator barrel 1 is the level setting, and central beam pipe 2 is located the axle center department level setting of granulator barrel 1, guarantees fixedly, and the granulator barrel 1 of being convenient for is stable in rotation.
Specifically, the both ends of central beam tube 2 pass through the bearing rotation with the inner wall of granulator barrel 1 and be connected, make things convenient for central beam tube 2 to stabilize the installation, granulator barrel 1 can rotate at will.
Further, the outer end of the distributor pipe outside the central beam pipe 2 is connected with an ammonia distributor, the ammonia distributor uses various forms of special liquid and aerosol material media including, but not limited to, liquid ammonia, gas ammonia, water, oil and the like, and the ammonia distributor includes, but not limited to, various forms of equipment and machinery special for distributing reaction liquid and aerosol material media and specific special objects derived from the equipment and machinery.
Further, the coulter 4 is fixedly installed on the central pipe beam 2 of the granulator through bolts, so that the coulter 4 is convenient to detach and install and is convenient to maintain or replace in time when damaged.
Furthermore, the distributor pipe outside the central beam pipe 2 is fixedly arranged on the coulter 4 through a bolt, so that the distributor pipe is convenient to disassemble and maintain, and the stable ammonia spraying operation on the granulator barrel 1 is ensured.
Furthermore, a fixing plate 21 is installed in the center beam tube 2 close to the coulter 4, one end of the fixing plate 21 is rotatably connected with one end of the coulter 4 through a rotating shaft, the coulter 4 can rotate around one end of the fixing plate 21, a convex block 41 is installed on the outer wall of one end of the coulter 4, two angle limiting plates 22 are installed at one end of the fixing plate 21, the angle limiting plates 22 can limit the rotating range of the coulter 4, the moving angle between the vertical line of the center tube beam 2 of the granulator cylinder 1 and the coulter 4 is 51-90 degrees, and the coulter 4 is guaranteed to be installed and fixed within an allowable range firstly due to angle change.
Furthermore, the coulter 4 is made of 304 stainless steel, the 304 stainless steel has excellent stainless corrosion resistance and better intergranular corrosion resistance, the service life of the coulter 4 can be greatly prolonged, the surface of the coulter is coated with a perfluoropolyether coating, the coulter has the performances of hydrophobicity, oil discharge, dirt resistance and the like, a good oil stain prevention effect can be achieved on the surface of the coulter 4, the coulter is convenient to clean, and the coulter is not easy to be corroded and damaged.
Further, the distributor pipe in the 2 outsides of central beam pipe adopts integral type ammonia distributor pipe 5, and ammonia nozzle 3 is equidistant arrangement setting along the outer wall of integral type ammonia distributor pipe 5, and integral type spout 51 has been seted up to the outer wall of integral type ammonia distributor pipe 5 near 3 departments of ammonia nozzle, guarantees to carry out the even ammonia operation of spouting.
Example 2
In order to further guarantee the stability of ammonia injection operation, avoid equipment to rock the influence to the distributor pipe, the distributor pipe in the 2 outsides of central beam pipe adopts split type ammonia distributor pipe 6, split type ammonia distributor pipe 6 and coulter 4 parallel arrangement, and split type ammonia distributor pipe 6 hugs closely coulter 4, make every split type ammonia distributor pipe 6 stable erection, avoid equipment to rock the influence to it, ammonia nozzle 3 distributes in the terminal both sides of split type ammonia distributor pipe 6, carry out the ammonia injection operation simultaneously, guarantee that ammonia injection is even, the terminal both sides of split type ammonia distributor pipe 6 are close to ammonia nozzle 3 department and have been seted up circularly, oval or rectangular split type spout 61, evenly spout ammonia from each position through split type spout 61, be convenient for carry out the granulation.
When the novel granulator is used, firstly, in the production process of ammonium phosphate or compound fertilizer, phosphoric acid or cleaning solution and ammonia are added into a tubular reactor in a granulator barrel 1, slurry with a certain neutralization degree is reacted by the tubular reactor and sprayed out from a nozzle of the tubular reactor and evenly sprayed on a material bed of each granulation area in the granulator, a colter 4 cuts and separates the slurry in different material bed areas, the material bed is positioned on the inner wall of the granulator barrel 1 and rolls along with the rotation of the granulator barrel 1, the particle materials on the material bed are repeatedly coated on the surface by the slurry sprayed out from the tubular reactor while continuously rolling and rotating, and secondary ammonia sprayed to the material bed by a distributor pipe through an ammonia nozzle 3 is rapidly reacted with the slurry sprayed on the particle surface while the slurry is sprayed and coated on the particle surface, so that the neutralization degree of the slurry on the particle surface is improved on one hand, the neutralization degree or the PH value required by the product quality and the process index is achieved, and on the other hand, the secondary ammonia sprayed by the ammonia distributor and the slurry on the particle surface generate exothermic reaction, so that the water on the particle surface is rapidly evaporated, and the nutrient and the water of the product reach the required indexes.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and the preferred embodiments of the present invention are described in the above embodiments and the description, and are not intended to limit the present invention. The scope of the invention is defined by the appended claims and equivalents thereof.

Claims (10)

1. A novel granulator comprises a granulator barrel (1), and is characterized in that: the granulator is characterized in that a central beam tube (2) is axially installed at the center of the inner part of the granulator cylinder body (1), a plurality of coulters (4) are installed on the outer wall of the central beam tube (2), a distributor tube is installed on the outer side of the central beam tube (2), a plurality of ammonia nozzles (3) are installed on the distributor tube, the included angle between the ammonia spraying ray of each ammonia nozzle (3) and the parallel line of the axis of the granulator cylinder body (1) is 0-45 degrees, the specific angle can be adjusted according to the cylinder rotating speed, the material characteristics and the height of a granulator material bed, the installation angle of each coulter (4), namely the angle between the plumb line of the central beam (2) of the granulator cylinder body (1) and the coulter (4), is 51-90 degrees, and the specific angle can be adjusted according to the granulation rotating speed and the material characteristics.
2. The new pelletizer as set forth in claim 1, characterized in that: the granulator barrel (1) is horizontally arranged, and the central beam pipe (2) is horizontally arranged at the axis of the granulator barrel (1).
3. The new pelletizer as set forth in claim 1, characterized in that: and the two ends of the central beam pipe (2) are rotatably connected with the inner wall of the granulator barrel (1) through bearings.
4. The new pelletizer as set forth in claim 1, characterized in that: the outer end of the distributor pipe at the outer side of the central beam pipe (2) is connected with an ammonia distributor, the ammonia distributor uses various forms of special liquid and aerosol material media such as liquid ammonia, gas ammonia, water, oil and the like, and the ammonia distributor includes various forms of equipment and machinery special for distributing reaction liquid and aerosol material media and special derived objects thereof.
5. The new pelletizer as set forth in claim 1, characterized in that: the coulter (4) is fixedly arranged on the central pipe beam (2) of the granulator through bolts.
6. The new pelletizer as set forth in claim 1, characterized in that: and the distributor pipe on the outer side of the central beam pipe (2) is fixedly arranged on the coulter (4) through a bolt.
7. The new pelletizer as set forth in claim 1, characterized in that: the inside of center beam pipe (2) is close to coulter (4) department and installs fixed plate (21), the one end of fixed plate (21) is rotated through the one end of pivot with coulter (4) and is connected, coulter (4) can rotate around the one end of fixed plate (21), state the one end outer wall of coulter (4) and install lug (41), two angle limiting plates (22) are installed to the one end of fixed plate (21), angle limiting plate (22) can carry on spacingly with the rotation range of coulter (4), make the movable angle between center beam pipe (2) plumb line and coulter (4) of granulator barrel (1) is 51-90.
8. The new pelletizer as set forth in claim 1, characterized in that: the coulter (4) is made of 304 stainless steel materials, and the surface of the coulter is coated with a perfluoropolyether coating.
9. The new pelletizer as set forth in claim 1, characterized in that: the distributor pipe outside the central beam pipe (2) adopts an integrated ammonia distributor pipe (5), the ammonia nozzles (3) are arranged at equal intervals along the outer wall of the integrated ammonia distributor pipe (5), and integrated nozzles (51) are arranged on the outer wall of the integrated ammonia distributor pipe (5) close to the ammonia nozzles (3).
10. The new pelletizer as set forth in claim 1, characterized in that: the distributor pipe outside the central beam pipe (2) adopts a split type ammonia distributor pipe (6), the split type ammonia distributor pipe (6) is arranged in parallel with the coulter (4), the coulter (4) is tightly attached to the split type ammonia distributor pipe (6), the ammonia nozzles (3) are distributed on two sides of the tail end of the split type ammonia distributor pipe (6), and the two sides of the tail end of the split type ammonia distributor pipe (6) are close to the ammonia nozzles (3) and are provided with round, oval or rectangular split type nozzles (61).
CN202110972017.3A 2021-08-24 2021-08-24 Novel granulator Pending CN113578193A (en)

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CN202110972017.3A CN113578193A (en) 2021-08-24 2021-08-24 Novel granulator

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CN202110972017.3A CN113578193A (en) 2021-08-24 2021-08-24 Novel granulator

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1379761A (en) * 1970-11-20 1975-01-08 Cros Sa Process for the manufacture of ammonium phosphate fertilizers
CN101391934A (en) * 2008-10-24 2009-03-25 江苏阿波罗复合肥有限公司 Ammoniation granulator and composite fertilizer production novel technique
CN201510860U (en) * 2009-09-22 2010-06-23 王新月 Spraying granulation and coating device for large-scale continuous multi-unit fluidized bed
CN201644006U (en) * 2010-04-22 2010-11-24 神华集团有限责任公司 Horizontal solid-liquid mixer
CN202462686U (en) * 2012-02-08 2012-10-03 浙江嘉化集团股份有限公司 Coulter device
CN203284213U (en) * 2013-05-28 2013-11-13 瓮福(集团)有限责任公司 Equipment for producing high-nutrient monoammonium phosphate by double-tube reactor technology
CN208449252U (en) * 2018-05-29 2019-02-01 云南祥丰金麦化工有限公司 A kind of pelletizer of three-tube type
CN208617710U (en) * 2018-07-25 2019-03-19 宜昌鄂中化工有限公司 The production system of ammonification high-concentration compound fertilizer

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1379761A (en) * 1970-11-20 1975-01-08 Cros Sa Process for the manufacture of ammonium phosphate fertilizers
CN101391934A (en) * 2008-10-24 2009-03-25 江苏阿波罗复合肥有限公司 Ammoniation granulator and composite fertilizer production novel technique
CN201510860U (en) * 2009-09-22 2010-06-23 王新月 Spraying granulation and coating device for large-scale continuous multi-unit fluidized bed
CN201644006U (en) * 2010-04-22 2010-11-24 神华集团有限责任公司 Horizontal solid-liquid mixer
CN202462686U (en) * 2012-02-08 2012-10-03 浙江嘉化集团股份有限公司 Coulter device
CN203284213U (en) * 2013-05-28 2013-11-13 瓮福(集团)有限责任公司 Equipment for producing high-nutrient monoammonium phosphate by double-tube reactor technology
CN208449252U (en) * 2018-05-29 2019-02-01 云南祥丰金麦化工有限公司 A kind of pelletizer of three-tube type
CN208617710U (en) * 2018-07-25 2019-03-19 宜昌鄂中化工有限公司 The production system of ammonification high-concentration compound fertilizer

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