CN113546748A - Machine-made sand flotation and magnetic separation combined mica removing process - Google Patents

Machine-made sand flotation and magnetic separation combined mica removing process Download PDF

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Publication number
CN113546748A
CN113546748A CN202110812314.1A CN202110812314A CN113546748A CN 113546748 A CN113546748 A CN 113546748A CN 202110812314 A CN202110812314 A CN 202110812314A CN 113546748 A CN113546748 A CN 113546748A
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Prior art keywords
flotation
magnetic separation
product
machine
sand
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金雯雯
陈炳金
夏忠勇
陈桂木
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Ninghua Richangsheng New Material Co ltd
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Ninghua Richangsheng New Material Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B7/00Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/02Magnetic separation acting directly on the substance being separated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/02Magnetic separation acting directly on the substance being separated
    • B03C1/30Combinations with other devices, not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation

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  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses a flotation and magnetic separation combined mica removing process for machine-made sand, which relates to the field of sand production and comprises a slurry mixing procedure, a flotation procedure, a magnetic separation procedure, a sand washing procedure, a concentration procedure and a filtering procedure. Compared with the prior art, the invention has the beneficial effects that: the invention adopts a wet process, and compared with the traditional dry process, the invention has the advantages of no dust and environmental friendliness; the invention adopts a combined process of magnetic separation and flotation, and is suitable for various micas in the sand; the present invention can obtain mica as side product for other use.

Description

Machine-made sand flotation and magnetic separation combined mica removing process
Technical Field
The invention relates to the field of sandstone production, in particular to a flotation and magnetic separation combined mica removing process for machine-made sand.
Background
With the development of economic society, the basic construction plays an important role in the development of economy in China, particularly in key projects, the requirement on gravels is higher and higher, mica is a harmful component of sand used for the key projects, the requirement (not more than 2%) of the construction sand in the national standard GBT14684-2011 on the content of the mica is better for the key projects, and the lower the content of the mica is, the better the content of the mica is. The traditional technology adopts an air force method to remove mica, but a large amount of dust is discharged in the process of removing mica by the air force method, so that environmental dust pollution is easily caused. In addition, it is difficult to achieve a desired separation effect by only one method for sand containing biotite and muscovite. Therefore, different methods for removing mica need to be combined to reduce the mica content in the sand, so as to improve the quality of the sand for key engineering.
Disclosure of Invention
The invention aims to overcome the defects in the prior art, and provides a machine-made sand flotation and magnetic separation combined mica removing process which has the advantages of good mica removing effect and high production efficiency.
The purpose of the invention is achieved by the following technical scheme: a machine-made sand flotation and magnetic separation combined mica removing process comprises the following steps:
step one, a size mixing procedure: fully mixing the raw material sand with water, and adding a regulator, an inhibitor and a collector to obtain a mixed product a;
step two, a flotation process: performing flotation on the product a obtained in the step one through flotation equipment to obtain a product b positioned in a foam layer of the flotation equipment and a product c positioned in a slurry layer of the flotation equipment;
step three, a magnetic separation process: carrying out magnetic separation on the product b obtained in the step two through magnetic separation equipment to obtain a product d adsorbed by the magnetic separation equipment and a product e not adsorbed by the magnetic separation equipment;
step four, a sand washing procedure: washing sand of the product d obtained in the step three through sand washing equipment to obtain sand f and waste water g after mica removal;
step five, a concentration process: concentrating the product c obtained in the step two through concentration and dehydration equipment to obtain concentrated ore pulp h and wastewater i;
step six, a filtering process: and D, filtering the concentrated ore pulp h obtained in the step five through a filtering device to obtain mica j and wastewater k.
As a further technical scheme, the water content percentage of the product a in the step one is 45-85% by weight.
According to a further technical scheme, the modifier in the first step is one or two of sodium carbonate and lime, and 50-2000 g of the modifier is added to each ton of dry ore.
According to a further technical scheme, in the step one, the inhibitor is one or more of sodium hexametaphosphate, carboxymethyl cellulose, water glass and starch, and 150-3000 g of the inhibitor is added to each ton of dry ore.
According to a further technical scheme, in the first step, the collecting agent is one or more of dodecylamine, octadecylamine, cocoanut oil amine, ether amine and sodium oleate, and 10-500 g of the collecting agent is added to each ton of dry ore.
As a further technical scheme, in the second step, the flotation equipment is one or more of a mechanical stirring type flotation machine, an inflatable type flotation machine and an inflatable stirring type flotation machine.
As a further technical scheme, in the third step, the magnetic separation equipment is one or more of a wet-type cylinder magnetic separator, a wet-type disc magnetic separator, a flat-plate magnetic separator and a vertical-ring high-gradient magnetic separator; the magnetic field intensity of the magnetic separator is 3000-15000 Gs.
As a further technical scheme, the sand washing equipment in the fourth step is one or more of a sand washing machine, a sieve, a hydrocyclone and a spiral classifier.
As a further technical scheme, in the step five, the concentration and dehydration equipment is one or two of a thickener and a concentration tank; and adding 2-50 g of flocculating agent per ton in the fifth step according to the weight of the solid; the concentrated ore pulp h contains water with the mass percent not more than 55%.
As a further technical scheme, the filtering equipment in the sixth step is one or two of a filter press, a spiral hill type vacuum filter, a belt type vacuum filter and a ceramic filter.
The invention has the beneficial effects that:
1. the invention adopts a wet process, and compared with the traditional dry process, the invention has the advantages of no dust and environmental friendliness;
2. the invention adopts a combined process of magnetic separation and flotation, and is suitable for various micas in the sand;
3. the present invention can obtain mica as side product for other use.
Drawings
FIG. 1 is a process flow diagram of the present invention.
Detailed Description
The invention will be described in detail below with reference to the following drawings:
example 1: a machine-made sand flotation and magnetic separation combined mica removing process comprises the following steps:
step one, a size mixing procedure: fully mixing the raw material sand with water, and adding 800g of sodium carbonate, 600g of sodium hexametaphosphate, 30g of dodecylamine and 60g of sodium oleate into each ton of dry ore to obtain a mixed product a, wherein the water content of the product a is 56% by weight;
step two, a flotation process: performing flotation on the product a obtained in the step one through a mechanical stirring type flotation machine to obtain a product b positioned in a foam layer of the flotation machine and a product c positioned in a pulp layer of the flotation machine;
step three, a magnetic separation process: carrying out magnetic separation on the product b obtained in the step two by a wet type drum magnetic separator with the magnetic field intensity of 6500Gs to obtain a product d adsorbed by the magnetic separator and a product e not adsorbed by the magnetic separator;
step four, a sand washing procedure: washing sand of the product d obtained in the step three by a wheel type sand washer to obtain sand f and waste water g after mica removal;
step five, a concentration process: concentrating the product c obtained in the step two by a thickener, and adding 28g of flocculant into each ton of the product c according to the weight of solid during concentration; obtaining concentrated ore pulp h and waste water i with the water mass fraction of 47%;
step six, a filtering process: and (4) filtering the concentrated ore pulp h obtained in the fifth step by using a spiral hill type vacuum filter to obtain mica j and wastewater k.
This example can reduce the weight percent of mica in the raw sand from 2.9% to 0.29%.
Example 2: a machine-made sand flotation and magnetic separation combined mica removing process comprises the following steps:
step one, a size mixing procedure: fully mixing the raw material sand with water, and adding 100g of sodium carbonate, 600g of CMC, 30g of ether amine and 90g of sodium oleate into each ton of dry ore to obtain a mixed product a, wherein the water content of the product a is 61 percent by weight;
step two, a flotation process: performing flotation on the product a obtained in the step one through an inflatable flotation machine to obtain a product b positioned in a foam layer of the flotation machine and a product c positioned in a pulp layer of the flotation machine;
step three, a magnetic separation process: carrying out magnetic separation on the product b obtained in the step two by a wet type cylinder magnetic separator with the magnetic field intensity of 7000Gs to obtain a product d adsorbed by the magnetic separator and a product e not adsorbed by the magnetic separator;
step four, a sand washing procedure: washing sand of the product d obtained in the step three by a wheel type sand washer to obtain sand f and waste water g after mica removal;
step five, a concentration process: concentrating the product c obtained in the step two by a thickener, and adding 25g of flocculant into each ton of the product c according to the weight of solid during concentration; obtaining concentrated ore pulp h with water content of 52% and waste water i;
step six, a filtering process: and (4) filtering the concentrated ore pulp h obtained in the fifth step by using a spiral hill type vacuum filter to obtain mica j and wastewater k.
This example can reduce the weight percent of mica in the raw sand from 2.6% to 0.11%.
Example 3: a machine-made sand flotation and magnetic separation combined mica removing process comprises the following steps:
step one, a size mixing procedure: fully mixing the raw material sand with water, and adding 500g of lime, 500g of sodium hexametaphosphate, 70g of dodecylamine and 50g of sodium oleate into each ton of dry ore to obtain a mixed product a, wherein the water content of the product a is 62% by weight;
step two, a flotation process: performing flotation on the product a obtained in the step one through an air agitation type flotation machine to obtain a product b positioned in a foam layer of the flotation machine and a product c positioned in a pulp layer of the flotation machine;
step three, a magnetic separation process: carrying out magnetic separation on the product b obtained in the step two by a wet drum magnetic separator with the magnetic field intensity of 8000Gs to obtain a product d adsorbed by the magnetic separator and a product e not adsorbed by the magnetic separator;
step four, a sand washing procedure: washing sand of the product d obtained in the step three by a wheel type sand washer to obtain sand f and waste water g after mica removal;
step five, a concentration process: concentrating the product c obtained in the step two by a thickener, and adding 35g of flocculant into each ton of the product c according to the weight of solid during concentration; obtaining concentrated ore pulp h with water content of 44% and waste water i;
step six, a filtering process: and (4) filtering the concentrated ore pulp h obtained in the fifth step through a belt type vacuum filter to obtain mica j and wastewater k.
This example can reduce the weight percent of mica in the raw material-containing sand from 1.6% to 0.06%.
Example 4: a machine-made sand flotation and magnetic separation combined mica removing process comprises the following steps:
step one, a size mixing procedure: fully mixing the raw material sand with water, and adding 1200g of sodium carbonate, 1000g of water glass, 100g of octadecylamine and 80g of sodium oleate into each ton of dry ore to obtain a mixed product a, wherein the water content of the product a is 65 percent by weight;
step two, a flotation process: performing flotation on the product a obtained in the step one through a mechanical stirring type flotation machine to obtain a product b positioned in a foam layer of the flotation machine and a product c positioned in a pulp layer of the flotation machine;
step three, a magnetic separation process: carrying out magnetic separation on the product b obtained in the step two by a wet drum magnetic separator with the magnetic field intensity of 4500Gs to obtain a product d adsorbed by the magnetic separator and a product e not adsorbed by the magnetic separator;
step four, a sand washing procedure: washing sand of the product d obtained in the step three by a wheel type sand washer to obtain sand f and waste water g after mica removal;
step five, a concentration process: concentrating the product c obtained in the step two by a thickener, and adding 40g of flocculant into each ton of the product c according to the weight of solid during concentration; obtaining concentrated ore pulp h and waste water i with the water content of 50 percent by mass;
step six, a filtering process: and (4) filtering the concentrated ore pulp h obtained in the fifth step by using a spiral hill type vacuum filter to obtain mica j and wastewater k.
This example can reduce the weight percent of mica in the raw sand from 2.3% to 0.12%.
Example 5: a machine-made sand flotation and magnetic separation combined mica removing process comprises the following steps:
step one, a size mixing procedure: fully mixing the raw material sand with water, and adding 1000g of sodium carbonate, 500g of starch, 120g of dodecylamine and 75g of sodium oleate into each ton of dry ore to obtain a mixed product a, wherein the water content of the product a is 63 percent by weight;
step two, a flotation process: performing flotation on the product a obtained in the step one through a mechanical stirring type flotation machine to obtain a product b positioned in a foam layer of the flotation machine and a product c positioned in a pulp layer of the flotation machine;
step three, a magnetic separation process: carrying out magnetic separation on the product b obtained in the step two by a wet type cylinder magnetic separator with the magnetic field intensity of 6000Gs to obtain a product d adsorbed by the magnetic separator and a product e not adsorbed by the magnetic separator;
step four, a sand washing procedure: washing sand of the product d obtained in the step three by a wheel type sand washer to obtain sand f and waste water g after mica removal;
step five, a concentration process: concentrating the product c obtained in the step two by a thickener, and adding 35g of flocculant into each ton of the product c according to the weight of solid during concentration; obtaining concentrated ore pulp h with water content of 44% and waste water i;
step six, a filtering process: and (4) filtering the concentrated ore pulp h obtained in the fifth step through a ceramic vacuum filter to obtain mica j and wastewater k.
This example can reduce the mica weight percentage in the raw material-containing sand from 1.8% to 0.05%.
Example 6: a machine-made sand flotation and magnetic separation combined mica removing process comprises the following steps:
step one, a size mixing procedure: fully mixing raw material sand with water, and adding 750g of sodium carbonate, 1500g of water glass, 150g of dodecylamine and 220g of sodium oleate into each ton of dry ore to obtain a mixed product a, wherein the water content of the product a is 59 percent by weight;
step two, a flotation process: performing flotation on the product a obtained in the step one through an inflatable flotation machine to obtain a product b positioned in a foam layer of the flotation machine and a product c positioned in a pulp layer of the flotation machine;
step three, a magnetic separation process: carrying out magnetic separation on the product b obtained in the step two by a wet type cylinder magnetic separator with the magnetic field intensity of 11000Gs to obtain a product d adsorbed by the magnetic separator and a product e not adsorbed by the magnetic separator;
step four, a sand washing procedure: washing sand of the product d obtained in the step three by a spiral classifier to obtain sand f and waste water g after mica removal;
step five, a concentration process: concentrating the product c obtained in the step two by a thickener, and adding 43g of flocculant per ton of solid weight during concentration; obtaining concentrated ore pulp h with water content of 40% and waste water i;
step six, a filtering process: and (4) filtering the concentrated ore pulp h obtained in the fifth step through a belt type vacuum filter to obtain mica j and wastewater k.
This example can reduce the weight percent of mica in the raw sand from 2.7% to 0.19%.
Compared with the prior art, the invention has the beneficial effects that:
1. the invention adopts a wet process, and compared with the traditional dry process, the invention has the advantages of no dust and environmental friendliness;
2. the invention adopts a combined process of magnetic separation and flotation, and is suitable for various micas in the sand;
3. the present invention can obtain mica as side product for other use.
It should be understood that equivalent substitutions and changes to the technical solution and the inventive concept of the present invention should be made by those skilled in the art to the protection scope of the appended claims.

Claims (10)

1. A machine-made sand flotation and magnetic separation combined mica removing process is characterized in that: the method comprises the following steps:
step one, a size mixing procedure: fully mixing the raw material sand with water, and adding a regulator, an inhibitor and a collector to obtain a mixed product a;
step two, a flotation process: performing flotation on the product a obtained in the step one through flotation equipment to obtain a product b positioned in a foam layer of the flotation equipment and a product c positioned in a slurry layer of the flotation equipment;
step three, a magnetic separation process: carrying out magnetic separation on the product b obtained in the step two through magnetic separation equipment to obtain a product d adsorbed by the magnetic separation equipment and a product e not adsorbed by the magnetic separation equipment;
step four, a sand washing procedure: washing sand of the product d obtained in the step three through sand washing equipment to obtain sand f and waste water g after mica removal;
step five, a concentration process: concentrating the product c obtained in the step two through concentration and dehydration equipment to obtain concentrated ore pulp h and wastewater i;
step six, a filtering process: and D, filtering the concentrated ore pulp h obtained in the step five through a filtering device to obtain mica j and wastewater k.
2. The machine-made sand flotation and magnetic separation combined mica removal process as claimed in claim 1, which is characterized in that: the water content of the product a in the first step is 45-85% by weight.
3. The machine-made sand flotation and magnetic separation combined mica removal process as claimed in claim 1, which is characterized in that: in the first step, the modifier is one or two of sodium carbonate and lime, and 50-2000 g of the modifier is added to each ton of dry ore.
4. The machine-made sand flotation and magnetic separation combined mica removal process as claimed in claim 1, which is characterized in that: in the first step, the inhibitor is one or more of sodium hexametaphosphate, carboxymethyl cellulose, water glass and starch, and 150-3000 g of the inhibitor is added to each ton of dry ore.
5. The machine-made sand flotation and magnetic separation combined mica removal process as claimed in claim 1, which is characterized in that: in the first step, the collecting agent is one or more of dodecylamine, octadecylamine, cocoanut amine, ether amine and sodium oleate, and 10-500 g of the collecting agent is added to each ton of dry ore.
6. The machine-made sand flotation and magnetic separation combined mica removal process as claimed in claim 1, which is characterized in that: and in the second step, the flotation equipment is one or more of a mechanical stirring type flotation machine, an inflatable flotation machine and an inflatable stirring type flotation machine.
7. The machine-made sand flotation and magnetic separation combined mica removal process as claimed in claim 1, which is characterized in that: in the third step, the magnetic separation equipment is one or more of a wet-type cylindrical magnetic separator, a wet-type disc magnetic separator, a flat magnetic separator and a vertical ring high-gradient magnetic separator; the magnetic field intensity of the magnetic separator is 3000-15000 Gs.
8. The machine-made sand flotation and magnetic separation combined mica removal process as claimed in claim 1, which is characterized in that: and in the fourth step, the sand washing equipment is one or more of a sand washing machine, a sieve, a hydrocyclone and a spiral classifier.
9. The machine-made sand flotation and magnetic separation combined mica removal process as claimed in claim 1, which is characterized in that: in the fifth step, the concentration dehydration equipment is one or two of a thickener and a concentration tank; and adding 2-50 g of flocculating agent per ton in the fifth step according to the weight of the solid; the concentrated ore pulp h contains water with the mass percent not more than 55%.
10. The machine-made sand flotation and magnetic separation combined mica removal process as claimed in claim 1, which is characterized in that: in the sixth step, the filtering equipment is one or two of a filter press, a disk mountain type vacuum filter, a belt type vacuum filter and a ceramic filter.
CN202110812314.1A 2021-07-19 2021-07-19 Machine-made sand flotation and magnetic separation combined mica removing process Pending CN113546748A (en)

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Application publication date: 20211026