CN113527974B - Gloss oil for inorganic glass panel and preparation method thereof - Google Patents
Gloss oil for inorganic glass panel and preparation method thereof Download PDFInfo
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- CN113527974B CN113527974B CN202110796799.XA CN202110796799A CN113527974B CN 113527974 B CN113527974 B CN 113527974B CN 202110796799 A CN202110796799 A CN 202110796799A CN 113527974 B CN113527974 B CN 113527974B
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- gloss oil
- inorganic glass
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- initiator
- acrylic monomer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
- C08F230/085—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
The invention provides gloss oil for an inorganic glass panel and a preparation method thereof, wherein the gloss oil comprises 15-25 parts by mass of acrylic acid monomers, 1-5 parts by mass of Bola type surfactant, 5-15 parts by mass of initiator, 5-10 parts by mass of vinyl triethoxysilane and 50-80 parts by mass of deionized water, the Bola type surfactant and the vinyl triethoxysilane are added into the deionized water, part of the acrylic acid monomers and the initiator are added under the protection of nitrogen after uniform mixing, and after heating and heat preservation reaction, the residual acrylic monomer and the initiator are continuously dripped, the gloss oil is obtained by cooling after the Babyon reaction, the gloss oil has good bonding force with the inorganic glass panel, meanwhile, the gloss oil has good surface performance after forming a film, and provides a new technical support for spraying and printing on the surface of the inorganic glass.
Description
Technical Field
The invention relates to the technical field of coating materials, in particular to gloss oil for an inorganic glass panel and a preparation method thereof.
Background
Gloss oil is a synthetic resin, generally referred to as varnish, which is composed of a base material, an auxiliary agent and the like, is mainly used on the surface of a printed matter to play a role in protection and decoration, and simultaneously, for different printed matter materials, in order to avoid the problem of poor printing effect, the problem can be solved by coating a layer of gloss oil and then printing on the surface of the gloss oil.
However, inorganic glass materials have a certain defect in gloss oil adhesion, and inorganic glass has a smooth surface, and has poor adhesion after gloss oil application, and is easily peeled off.
Disclosure of Invention
In view of this, the invention provides a gloss oil for inorganic glass panels and a preparation method thereof.
The technical scheme of the invention is realized as follows: the invention provides gloss oil for an inorganic glass panel, which comprises the following components in parts by weight:
on the basis of the above technical scheme, preferably, the acrylic monomer is a mixture of methyl methacrylate, n-butyl acrylate, acrylic acid and hydroxyethyl methacrylate.
On the basis of the technical scheme, preferably, the acrylic monomer is methyl methacrylate, n-butyl acrylate, and the mass ratio of acrylic acid to hydroxyethyl methacrylate is 10:6:1: 3.
On the basis of the technical scheme, preferably, the Bola type surfactant is sodium polypropylene glycol disulfate.
Still more preferably, the initiator is an aqueous solution of potassium persulfate.
Based on the above technical scheme, the mass concentration of the potassium persulfate aqueous solution is preferably 3-7%.
The invention also discloses a preparation method of the gloss oil for the inorganic glass panel, which comprises the following steps:
step one, respectively weighing methyl methacrylate, n-butyl acrylate, acrylic acid and hydroxyethyl methacrylate according to the mass part ratio, and uniformly mixing and stirring to obtain an acrylic monomer mixture;
step two, weighing deionized water according to the mass part, adding a Bola type surfactant and vinyltriethoxysilane into the deionized water, stirring and heating to 45-55 ℃ until the solution is transparent, adding a half of the acrylic monomer mixture in the step one under the protective gas atmosphere, keeping the temperature and stirring for 30-60min, adding a half of the initiator, continuing to slowly raise the temperature to 70-80 ℃, keeping the temperature and reacting for 30-60min, after the reaction is finished, dropwise adding the rest of the acrylic monomer mixture, after the dropwise adding is finished, dropwise adding the rest of the initiator, after the dropwise adding is finished, keeping the temperature and reacting for 30-60min, and cooling to 20-30 ℃ to obtain the gloss oil.
On the basis of the above technical scheme, preferably, in the second step, the sum of the time for dropping the remaining acrylic monomer mixture and the time for dropping the initiator is 30-60 min.
Compared with the prior art, the gloss oil for the inorganic glass panel and the preparation method thereof have the following beneficial effects:
(1) the invention has provided a special gloss oil and its correspondent preparation method for inorganic glass panel, the formulation that the gloss oil adopts regards acrylic acid monomer as the main material, through adding Bola type surfactant active and vinyl triethoxysilane to improve the binding property between gloss oil and inorganic glass, the gloss oil of the invention adopts the aqueous raw materials at the same time, it is small to the air pollution, and the gloss oil of the invention is difficult to produce the surface viscosity after solidifying, have good application prospects;
(2) the preparation method can obtain the gloss oil applied to the inorganic glass panel, the invention adds the vinyltriethoxysilane into the raw materials, so that the gloss oil can form a silicon-oxygen bond with the inorganic glass, the bonding force is improved, the gloss oil main body material is formed by the acrylic acid monomer, and the Bola type surfactant improves the bonding force among organic, inorganic, hydrophilic and lipophilic groups, so that the gloss oil can better adapt to the application scene of the inorganic glass panel.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention.
Example 1
Respectively weighing 10kg of methyl methacrylate, 6kg of n-butyl acrylate, 1kg of acrylic acid and 3kg of hydroxyethyl methacrylate, and uniformly mixing and stirring to obtain 20kg of an acrylic monomer mixture;
weighing 65kg of deionized water, adding the deionized water into a reaction kettle, adding 2kg of sodium polypropylene glycol disulfate and 5kg of vinyl triethoxysilane into the deionized water, stirring and heating to 50 ℃ until the solution is transparent, filling nitrogen gas protective atmosphere, adding 10kg of acrylic acid monomer mixture under the protective atmosphere, continuing to keep the temperature and stirring for 30min, after the reaction is finished, adding 5kg of potassium persulfate aqueous solution with the mass concentration of 5% into the reaction kettle, continuing to heat up to 75 ℃ during the completion of the feeding, keeping the temperature and reacting for 30min, after the reaction is finished, dropwise adding the remaining 10kg of acrylic acid monomer mixture, controlling the dropwise adding time to be about 20min, after the dropwise adding is finished, dropwise adding 5kg of potassium persulfate aqueous solution, controlling the dropwise adding time to be about 10min, after the low price is finished, keeping the reaction at 75 ℃ for 30min, and then slowly cooling to 25 ℃ to obtain the gloss oil.
Example 2
Respectively weighing 7.5kg of methyl methacrylate, 4.5kg of n-butyl acrylate, 0.75kg of acrylic acid and 2.25kg of hydroxyethyl methacrylate, and uniformly mixing and stirring to obtain 15kg of an acrylic monomer mixture;
weighing 50kg of deionized water, adding the deionized water into a reaction kettle, adding 1kg of sodium polypropylene glycol disulfate and 10kg of vinyl triethoxysilane into the deionized water, stirring and heating the mixture to 45 ℃ until the solution is transparent, filling the mixture into a nitrogen protective atmosphere, adding 7.5kg of acrylic acid monomer mixture under the protective atmosphere, continuing to keep the temperature and stirring for 40min, after the reaction is finished, adding 2.5kg of potassium persulfate aqueous solution with the mass concentration of 3% into the reaction kettle, continuing to heat up the mixture to 70 ℃ after the addition is finished, keeping the temperature and reacting for 40min, dropwise adding the rest 7.5kg of acrylic acid monomer mixture after the reaction is finished, controlling the dropwise adding time to be about 30min, dropwise adding 2.5kg of potassium persulfate aqueous solution after the dropwise adding is finished, controlling the dropwise adding time to be about 20min, after the reaction is finished at a low price, keeping the temperature and reacting for 40min, and slowly cooling to 20 ℃ to obtain the gloss oil.
Example 3
Respectively weighing 12.5kg of methyl methacrylate, 7.5kg of n-butyl acrylate, 1.25kg of acrylic acid and 3.75kg of hydroxyethyl methacrylate, and uniformly mixing and stirring to obtain 25kg of an acrylic monomer mixture;
weighing 80kg of deionized water, adding the deionized water into a reaction kettle, adding 5kg of sodium polypropylene glycol disulfate and 8kg of vinyl triethoxysilane into the deionized water, stirring and heating the deionized water to 55 ℃ until the solution is transparent, filling the deionized water into the reaction kettle in a nitrogen protective atmosphere, adding 12.5kg of acrylic acid monomer mixture in the protective atmosphere, continuing to keep the temperature and stirring for 60min, after the reaction is finished, adding 7.5kg of potassium persulfate aqueous solution with the mass concentration of 7% into the reaction kettle, continuing to heat up the solution by 80 ℃ after the addition is finished, keeping the temperature and reacting for 60min, dropwise adding the rest 12.5kg of acrylic acid monomer mixture after the reaction is finished, controlling the dropwise adding time to be about 40min, dropwise adding 7.5g of potassium persulfate aqueous solution after the dropwise adding is finished, controlling the dropwise adding time to be about 20min, after the low price is finished, keeping the 80 ℃ and reacting for 60min, and then slowly cooling to 30 ℃ to obtain the gloss oil.
Comparative example 1
The raw materials and preparation method of this comparative example are the same as example 1 except that no Bola type surfactant is added.
Comparative example 2
The raw materials and preparation method of this comparative example are the same as example 1 except that vinyltriethoxysilane is not added in this comparative example.
Comparative example 3
The raw materials and preparation method of this comparative example are the same as example 1 except that in this comparative example, no Bola type surfactant is added and sodium lauryl sulfate is used instead.
The gloss oil obtained in the examples 1 to 3 and the comparative examples 1 to 3 is respectively sprayed on an inorganic glass panel, and performance measurement is carried out after curing, wherein the measurement items comprise an adhesion test, a hardness test, a boiling test and an ethanol resistance test, and the specific test results are as follows:
after the gloss oil obtained in examples 1 to 3 and comparative examples 1 to 3 was sprayed on the inorganic glass panel, a touch test was performed after curing to see whether or not there was a viscosity, and the results are shown in the following table:
| grouping | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Whether or not to be sticky | Is not sticky | Is not sticky | Is not sticky | Viscous glue | Is not sticky | Viscous glue |
From the above table, the gloss oil prepared by the invention has good adhesiveness when applied to an inorganic glass panel, wherein the adhesiveness is greatly improved mainly because the Bola type surfactant is added, and the bonding property of the gloss oil on the surface of the inorganic glass is improved through the matching of the Bola type surfactant and the vinyltriethoxysilane.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and should not be taken as limiting the scope of the present invention, which is intended to cover any modifications, equivalents, improvements, etc. within the spirit and scope of the present invention.
Claims (7)
1. The gloss oil for the inorganic glass panel is characterized by comprising the following components in parts by weight:
the Bola type surfactant is sodium polypropylene glycol disulfate.
2. The gloss oil for inorganic glass panels according to claim 1, wherein the acrylic monomer is a mixture of methyl methacrylate, n-butyl acrylate, acrylic acid and hydroxyethyl methacrylate.
3. The gloss oil for inorganic glass panels according to claim 2, wherein the acrylic monomer is methyl methacrylate, n-butyl acrylate, acrylic acid and hydroxyethyl methacrylate in a mass ratio of 10:6:1: 3.
4. The gloss oil for inorganic glass panels according to claim 1, wherein the initiator is an aqueous solution of potassium persulfate.
5. The gloss oil for inorganic glass panels according to claim 4, wherein the aqueous solution of potassium persulfate has a mass concentration of 3 to 7%.
6. The method of producing a gloss oil for inorganic glass panels according to any one of claims 1 to 5, comprising the steps of:
step one, respectively weighing methyl methacrylate, n-butyl acrylate, acrylic acid and hydroxyethyl methacrylate according to the mass part ratio, and uniformly mixing and stirring to obtain an acrylic monomer mixture;
step two, weighing deionized water according to the mass parts, adding a Bola type surfactant and vinyl triethoxysilane into the deionized water, stirring and heating to 45-55 ℃ until the solution is transparent, adding a half amount of the acrylic monomer mixture in the step one under the protective gas atmosphere, keeping the temperature and stirring for 30-60min, adding a half amount of the initiator, continuously and slowly heating to 70-80 ℃, keeping the temperature and reacting for 30-60min, after the reaction is finished, dropwise adding the rest acrylic monomer mixture, after the dropwise adding is finished, dropwise adding the rest initiator, after the dropwise adding is finished, keeping the temperature and reacting for 30-60min, cooling to 20-30 ℃ to obtain the gloss oil.
7. The method of preparing a gloss oil for an inorganic glass panel according to claim 6, wherein in the second step, the total time of dropping the remaining acrylic monomer mixture and dropping the initiator is 30 to 60 min.
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| CN202110796799.XA CN113527974B (en) | 2021-07-14 | 2021-07-14 | Gloss oil for inorganic glass panel and preparation method thereof |
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| CN202110796799.XA CN113527974B (en) | 2021-07-14 | 2021-07-14 | Gloss oil for inorganic glass panel and preparation method thereof |
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| CN113527974A CN113527974A (en) | 2021-10-22 |
| CN113527974B true CN113527974B (en) | 2022-07-26 |
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| CN114853352B (en) * | 2022-05-13 | 2023-08-25 | 江苏秀强玻璃工艺股份有限公司 | Construction process of high-temperature-resistant and acid-resistant high-temperature uv texture |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3805886C1 (en) * | 1988-02-25 | 1989-04-06 | Degussa Ag, 6000 Frankfurt, De | Radiation-curable composition for the anti-tarnish coating of organic glasses, and process for its preparation |
| CN1332180A (en) * | 2001-08-10 | 2002-01-23 | 复旦大学 | Prepn of nanometer reactive polymer microgel |
| CN102101960A (en) * | 2010-12-24 | 2011-06-22 | 大连工业大学 | High-hydroxy silicon-acrylate aqueous glass coating emulsion and synthesis method thereof |
| CN107057802A (en) * | 2017-04-28 | 2017-08-18 | 泰伦特生物工程股份有限公司 | A kind of glass grinding fluid containing bola type surfactants and preparation method and application method |
| CN109929359A (en) * | 2019-02-27 | 2019-06-25 | 江西省龙海化工有限公司 | Super hydrophilic anti-fog coating of a kind of UV solidification and preparation method thereof |
-
2021
- 2021-07-14 CN CN202110796799.XA patent/CN113527974B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3805886C1 (en) * | 1988-02-25 | 1989-04-06 | Degussa Ag, 6000 Frankfurt, De | Radiation-curable composition for the anti-tarnish coating of organic glasses, and process for its preparation |
| CN1332180A (en) * | 2001-08-10 | 2002-01-23 | 复旦大学 | Prepn of nanometer reactive polymer microgel |
| CN102101960A (en) * | 2010-12-24 | 2011-06-22 | 大连工业大学 | High-hydroxy silicon-acrylate aqueous glass coating emulsion and synthesis method thereof |
| CN107057802A (en) * | 2017-04-28 | 2017-08-18 | 泰伦特生物工程股份有限公司 | A kind of glass grinding fluid containing bola type surfactants and preparation method and application method |
| CN109929359A (en) * | 2019-02-27 | 2019-06-25 | 江西省龙海化工有限公司 | Super hydrophilic anti-fog coating of a kind of UV solidification and preparation method thereof |
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