CN113520935B

CN113520935B - Color multifunctional barrier cream and preparation method thereof

Info

Publication number: CN113520935B
Application number: CN202110632814.7A
Authority: CN
Inventors: 王雨星; 高晓燕; 倪伶俐; 唐屿昕; 刘希燃; 谢尔尔; 冯良东
Original assignee: Huaiyin Institute of Technology
Current assignee: Huaiyin Institute of Technology
Priority date: 2021-06-07
Filing date: 2021-06-07
Publication date: 2023-06-09
Anticipated expiration: 2041-06-07
Also published as: CN113520935A

Abstract

The invention discloses a color multifunctional barrier cream and a preparation method thereof. The formula of the color multifunctional isolation cream mainly comprises the following components: 5-10 parts of chamomile extract, 5-10 parts of liquorice extract, 5-10 parts of grape seed oil, 5-10 parts of arbutin, 1-5 parts of hyaluronic acid, 1-5 parts of vitamin E, 1-5 parts of ginsenoside, 10-15 parts of shea butter, 5-10 parts of surface modified zinc oxide/attapulgite based maya blue composite pigment and 20-30 parts of distilled water. The invention also provides a preparation method of the colored multifunctional isolation cream, and the prepared isolation cream integrates coloring and sun screening, has the effects of moisturizing, whitening, resisting bacteria, diminishing inflammation, resisting oxidation and resisting ultraviolet, can be used for color matching, can be used for preparing isolation creams with different colors, and is suitable for the needs of different makeup occasions.

Description

Color multifunctional barrier cream and preparation method thereof

Technical Field

The invention relates to the technical field of daily cosmetics, in particular to a colored multifunctional isolation cream integrating coloring and sun screening and having the effects of whitening, resisting bacteria and diminishing inflammation, resisting oxidation and resisting ultraviolet and a preparation method thereof.

Background

The isolation cream is one of important skin care products for daily skin protection, and mainly plays a role in sun protection and reducing the irritation of adverse factors to the skin. Sunscreens commonly used in make-up creams fall into two categories, organic sunscreens and physical sunscreens. The organic sun-screening agent is released in a low energy form after absorbing ultraviolet rays, so that direct damage of the ultraviolet rays is avoided, and the organic sun-screening agent is usually aromatic compounds and is harmful to human bodies after long-term use; the physical sun-screening agent is mainly inorganic powder titanium dioxide and zinc oxide, is mainly used for blocking ultraviolet rays by refraction, is harmless to human bodies, but is easy to cause the problems of skin dryness, oil discharge, pore blockage, difficult absorption, poor air permeability and the like due to high surface energy and poor skin compatibility after long-term use.

The color isolation cream not only can isolate and prevent sunburn, but also has the effects of concealing and adjusting skin color, and is similar to foundation. Therefore, attention has been paid to people loving beauty in recent years, and the colors of the barrier creams can be roughly divided into six categories, namely, near skin color, purple, white, blue and gold, and the effects of modifying the skin colors of different colors are different. The common colorant in the color isolation cream is an inorganic pigment, has the advantages of light fastness, heat resistance, good solvent resistance and strong hiding power, but has low tinting strength, poor color vividness, high toxicity of partial metal salt or oxide and poor compatibility with skin, and can cause the problems of skin dryness, pore blockage, oil discharge and the like besides the safety problem in long-term use.

Therefore, development and research of a color multifunctional barrier cream which is safe and healthy and can fundamentally improve skin problems are urgently needed.

Disclosure of Invention

The invention aims to: aiming at the problems existing in the prior art, the invention aims to provide the colored multifunctional spacer cream and the preparation method thereof, wherein the spacer cream integrates a sun-screening agent and a colorant, is a zinc oxide/mayan blue-like composite pigment modified by a natural surfactant, is safe and environment-friendly, has good compatibility with skin, is easy to clean, can not block pores, has the effects of moisturizing, whitening, resisting bacteria, diminishing inflammation, resisting oxidation and resisting ultraviolet, and is suitable for the needs of different cosmetic occasions.

The technical scheme is as follows: a color multifunctional isolation cream is prepared from the following raw materials in parts by weight: 5-10 parts of chamomile extract, 5-10 parts of liquorice extract, 5-10 parts of grape seed oil, 5-10 parts of arbutin, 1-5 parts of hyaluronic acid, 1-5 parts of vitamin E, 1-5 parts of ginsenoside and 10-15 parts of shea butter; 5-10 parts of surface modified zinc oxide/attapulgite-based mayan blue composite pigment and 20-30 parts of distilled water.

The invention provides a preparation method of a color multifunctional isolation cream, which comprises the following steps: s1: preparing a modified mayan blue-like composite pigment; (1) Uniformly mixing the organic pigment molecules with the purified attapulgite clay, and then putting the mixture into a baking oven at 100-200 ℃ to bake 24-48 h to obtain attapulgite clay-based mayan blue organic/inorganic hybrid pigment; (2) Zinc acetate is weighed and dissolved in absolute ethyl alcohol to obtain solution A; dissolving a natural surfactant in ethanol, adding attapulgite-based mayan blue organic/inorganic hybrid pigment into the ethanol, and stirring the mixture at a constant temperature of between 40 and 50 ℃ to form a suspension B; dropwise adding the solution A into the suspension B, stirring for 10-13 hours at 50-80 ℃, centrifuging and grinding to obtain the surface modified zinc oxide/mayan blue-like composite pigment; s2: preparing color multifunctional isolation cream; (1) Adding the surface modified zinc oxide/mayan blue-like composite pigment into distilled water, and uniformly stirring to obtain a mixed solution A; (2) Uniformly mixing chamomile extract, licorice extract, grape seed oil, arbutin, hyaluronic acid, vitamin E, ginsenoside and shea butter to obtain a mixed solution B; (3) Adding the mixed solution B into the mixed solution A, heating to 80-85 ℃ for emulsification, emulsifying for 20-30 min, cooling to 50-60 ℃, vacuumizing, cooling to below 40 ℃, and discharging.

Preferably, in the step S1 (1), the mass ratio of the organic pigment molecules to the purified attapulgite clay is 1-15:100.

Preferably, in the step S1 (2), the mass ratio of zinc acetate to absolute ethyl alcohol is 3:100; the mass ratio of the natural surfactant to the attapulgite-based mayan blue organic/inorganic hybrid pigment is 1-5:100; the mass ratio of the attapulgite-based mayan blue organic/inorganic hybrid pigment to the absolute ethyl alcohol is 5-20:100; the mass ratio of the zinc acetate to the mayan blue-like organic/inorganic hybrid pigment is 2-9:100.

Preferably, in the step S2 (1), the mass ratio of the surface modified zinc oxide/attapulgite-based mayan blue composite pigment to distilled water is 10:40-60.

Preferably, the organic pigment molecule is isatin, indigo, methyl violet, methylene blue, congo red, alizarin yellow or a commercially available cosmetic organic pigment.

Preferably, the purified attapulgite clay is sieved through a 200 mesh sieve.

Preferably, the natural surfactant is any one or combination of linseed oil, olive oil, coconut oil, argan oil, avocado oil, grape seed oil, palm oil, jojoba oil, sweet almond oil, evening primrose oil or calendula oil containing unsaturated fatty acids.

The beneficial effects are that: (1) The colored multifunctional spacer cream has the functions of modifying skin color and preventing sunburn, has multiple functions of moisturizing, whitening, resisting bacteria and resisting oxidation, and is safe and environment-friendly in raw materials and free of irritation to skin.

(2) The colored multifunctional spacer cream integrates a sun-screening agent and a colorant, and is a surface modified zinc oxide/mayan blue-like composite pigment. The surface modified zinc oxide/attapulgite-based mayan blue composite pigment is a attapulgite-based organic/inorganic hybrid pigment, takes attapulgite as a carrier, has the effects of controlling oil and resisting inflammation, and the attapulgite is nano-scale powder, thus playing a role in sun protection; the zinc oxide/attapulgite-based mayan blue-like composite pigment is prepared by depositing zinc oxide on the surface of a mayan blue-like pigment. On one hand, zinc oxide is used for plugging a concave soil pore canal, so that the weather resistance and the stability of the pigment are enhanced, and on the other hand, the pigment is used as a common sun-screening agent, and the zinc oxide and the concave soil are synergistic to enhance the sun-screening effect of the spacer cream.

(3) According to the colored multifunctional spacer cream, the zinc oxide/attapulgite-based mayan blue composite pigment is modified by the natural surfactant, so that the surface energy of the pigment is reduced on one hand, the pigment is stably stored in the spacer cream, and on the other hand, the pigment has good compatibility with skin and is easy to clean, and the problems of dry skin and pore blockage caused by inorganic powder are solved.

(4) The color multifunctional isolation cream disclosed by the invention has the following functions of other raw materials: the chamomile extract mainly has the functions of diminishing inflammation, sterilizing, resisting allergy and whitening; the licorice extractive solution has the main effects of whitening, sun-screening and ultraviolet resistance; the grape seed oil has the main functions of antioxidation and whitening; the main function of the hyaluronic acid is water supplementing and moisturizing; the arbutin has the main functions of sterilizing, diminishing inflammation and whitening; the main function of vitamin E is antioxidation; the ginsenoside has the main functions of antioxidation and antibiosis; the shea butter has the main functions of moisturizing, resisting oxidation and diminishing inflammation. The surface modified zinc oxide/attapulgite-based mayan blue composite pigment has the main functions of serving as a color agent, resisting ultraviolet, resisting bacteria and diminishing inflammation.

Detailed Description

The present invention will be described in detail with reference to the following embodiments.

Embodiment 1:

s1: preparation of surface modified zinc oxide/attapulgite-based mayan blue-isatin composite pigment

(1) Uniformly mixing 1 g isatin and 10 g purified attapulgite clay, and then putting the mixture into a baking oven at 150 ℃ to bake 36 h to obtain attapulgite clay-based mayan blue-isatin organic/inorganic hybrid pigment;

(2) Dissolving 0.2725 g zinc acetate in 20 ml absolute ethyl alcohol to form a solution A; dissolving 0.2. 0.2 g linseed oil in 30 ml absolute ethyl alcohol, then adding 10 g attapulgite-based maya blue-isatin organic/inorganic hybrid pigment, and stirring at a constant temperature of 40 ℃ to form a suspension B; and (3) dropwise adding the solution A into the suspension B, stirring at 60 ℃ for 12 h, centrifuging and grinding to obtain the linseed oil modified zinc oxide/attapulgite-based mayan blue-isatin composite pigment.

S2: preparation of color multifunctional isolation cream

(1) Adding 5 g linseed oil modified zinc oxide/attapulgite-based mayan blue-indigo red composite pigment into 10 ml distilled water, and uniformly stirring to obtain a mixed solution A;

(2) Uniformly stirring chamomile extract 5 g, licorice extract 5 g, grape seed oil 5 g, arbutin 5 g parts, hyaluronic acid 2 g, vitamin E1 g, ginsenoside 2 g and shea butter 12 g to obtain a mixed solution B;

(3) Adding the mixed solution B into the mixed solution A, heating to 80 ℃ for emulsification, emulsifying for 30 min, cooling to 50 ℃, vacuumizing, cooling to below 40 ℃, and discharging.

Embodiment 2:

s1: preparation of surface modified zinc oxide/attapulgite-based mayan blue-acid red composite pigment

(1) Mixing 1.5 g commercial cosmetic pigment acid red with 10 g purified attapulgite clay uniformly, and then putting the mixture into a 130 ℃ oven for baking 48 h to obtain attapulgite clay-based mayan blue-acid red organic/inorganic hybrid pigment;

(2) Dissolving 0.545 g zinc acetate in 20 ml absolute ethyl alcohol to form a solution A; 0.2. 0.2 g coconut oil is dissolved in 30 ml absolute ethanol, then 10 g attapulgite-based maya blue-acid red organic/inorganic hybrid pigment is added, and stirred at a constant temperature of 50 ℃ to form a suspension B; and (3) dropwise adding the solution A into the suspension B, stirring at 60 ℃ for 12 h, centrifuging and grinding to obtain the coconut oil modified zinc oxide/attapulgite-based mayan blue-acid red composite pigment.

S2: preparation of color multifunctional isolation cream

(1) Adding 5 g coconut oil modified zinc oxide/attapulgite based mayan blue-acid red composite pigment into 10 ml distilled water, and stirring uniformly to obtain a mixed solution A;

(2) Uniformly stirring chamomile extract 5 g, licorice extract 5 g, grape seed oil 5 g parts, arbutin 5 g parts, hyaluronic acid 2 g, vitamin E1 g, ginsenoside 2 g and shea butter 12 g to obtain a mixed solution B;

Embodiment 3:

s1: preparation of surface modified zinc oxide/attapulgite-based mayan blue-acid violet composite pigment

(1) Mixing 1 g commercial cosmetic pigment acid violet and 10 g purified attapulgite clay uniformly, and then putting the mixture into a baking oven at 150 ℃ to bake 36 h to obtain attapulgite clay-based mayan blue-acid violet organic/inorganic hybrid pigment;

(2) Dissolving 0.2725 g zinc acetate in 20 ml absolute ethyl alcohol to form a solution A; dissolving 0.2. 0.2 g grape seed oil in 30 ml absolute ethanol, then adding 10 g attapulgite-based maya blue-acid violet organic/inorganic hybrid pigment, and stirring at a constant temperature of 40 ℃ to form a suspension B; and (3) dropwise adding the solution A into the suspension B, stirring at 60 ℃ for 12 h, centrifuging and grinding to obtain the grape seed oil modified zinc oxide/attapulgite-based mayan blue-acid violet composite pigment.

S2: preparation of color multifunctional isolation cream

(1) Adding the 5 g grape seed oil modified zinc oxide/attapulgite-based mayan blue-acid violet composite pigment into 10 ml distilled water, and uniformly stirring to obtain a mixed solution A;

(2) Uniformly stirring chamomile extract 5 g, licorice extract 5 g, grape seed oil 5 g parts, arbutin 5 g parts, hyaluronic acid 1-2 g, vitamin E1 g, ginsenoside 2 g and shea butter 12 g to obtain a mixed solution B;

Example product index evaluation

(1) Evaluation of physicochemical Properties

The physical and chemical index detection is carried out on the color multifunctional isolation cream obtained by the embodiment of the invention according to the relevant standard of QB/T1857-2013 skin cream, and the data are shown in table 1.

TABLE 1 results of sensory, physicochemical, and health index tests of color multifunctional barrier creams of the invention

(2) Evaluation of Sun-screening Performance

The color multifunctional spacer cream obtained in the above embodiment of the invention is detected by adopting an SPF (sun protection index) -290s analysis system, a blank background curve of a carrier is firstly drawn on the SPF-290s analysis system, and a spotter is used for uniformly spotting 2mg/cm on a transparent film ² After the samples are dried, 10 points are randomly detected, corresponding light wavelength is drawn, the detection result of the samples is calculated, the SPF value and the standard deviation are obtained, each sample is detected for 5 times, and the result is shown as follows:

table 2 SPF (sun protection factor) test results of examples

Group of	Example 1	Example 2	Example 3
				SPF value	22±0.35	23±0.21	21±0.48

(3) Sensory evaluation

The effect of the color multifunctional spacer cream is evaluated through trial experiments. The color multifunctional barrier cream prepared by the embodiment is used for carrying out a comparison experiment with the commercial barrier cream. 120 women 18-22 years old were selected and arbitrarily equally divided into four groups. The first three groups of colored multifunctional barrier creams prepared in examples 1, 2 and 3 respectively, and the comparative example is commercial barrier cream, which is used for one month. The effect of the above-prepared mayan blue-like lipstick was evaluated by visually observing the restoration of the face and the manifestations of various functions. The results are shown in Table 3.

TABLE 3 experimental results

Group of	Color	Moisture and preserve moisture	Spreadability of	Degree of wound healing
					Example 1	Full and moderate color	Excellent quality	Excellent quality	Obvious healing
Example 2	Full and moderate color	Excellent quality	Excellent quality	Obvious healing
					Example 3	Full and moderate color	Excellent quality	Excellent quality	Obvious healing
Comparative example	Full and moderate color	Good quality	Good quality	Healing is not obvious

In conclusion, the color multifunctional isolation cream developed by the invention has good colorability, moisturizing property and smearing property, and has sun-screening, anti-inflammatory and healing effects.

The foregoing embodiments are merely illustrative of the technical concept and features of the present invention, and are intended to enable those skilled in the art to understand the present invention and to implement the same, not to limit the scope of the present invention. All equivalent changes or modifications made according to the spirit of the present invention should be included in the scope of the present invention.

Claims

1. The color multifunctional isolation cream is characterized by being prepared from the following raw materials in parts by weight: 5-10 parts of chamomile extract, 5-10 parts of liquorice extract, 5-10 parts of grape seed oil, 5-10 parts of arbutin, 1-5 parts of hyaluronic acid, 1-5 parts of vitamin E, 1-5 parts of ginsenoside, 10-15 parts of shea butter, 5-10 parts of surface modified zinc oxide/attapulgite based maya blue composite pigment and 20-30 parts of distilled water;

the preparation method of the color multifunctional isolation cream comprises the following steps:

s1: preparation of modified mayan blue-like composite pigment

(1) Uniformly mixing the organic pigment molecules with the purified attapulgite clay, and then putting the mixture into a baking oven at 100-200 ℃ to bake 24-48 h to obtain attapulgite clay-based mayan blue organic/inorganic hybrid pigment;

(2) Zinc acetate is weighed and dissolved in absolute ethyl alcohol to obtain solution A;

dissolving a natural surfactant in ethanol, adding attapulgite-based mayan blue organic/inorganic hybrid pigment into the ethanol, and stirring the mixture at a constant temperature of between 40 and 50 ℃ to form a suspension B;

dropwise adding the solution A into the suspension B, stirring for 10-13 hours at 50-80 ℃, centrifuging and grinding to obtain the surface modified zinc oxide/mayan blue-like composite pigment;

s2: preparation of color multifunctional isolation cream

(1) Adding the surface modified zinc oxide/mayan blue-like composite pigment into distilled water, and uniformly stirring to obtain a mixed solution A;

(2) Uniformly mixing chamomile extract, licorice extract, grape seed oil, arbutin, hyaluronic acid, vitamin E, ginsenoside and shea butter to obtain a mixed solution B;

(3) Adding the mixed solution B into the mixed solution A, heating to 80-85 ℃ for emulsification, emulsifying for 20-30 min, cooling to 50-60 ℃, vacuumizing, cooling to below 40 ℃, and discharging.

2. The colored multifunctional barrier cream of claim 1, wherein: in the step S1 (1), the mass ratio of the organic pigment molecules to the purified attapulgite clay is 1-15:100.

3. The colored multifunctional barrier cream of claim 1, wherein: in the step S1 (2), the mass ratio of zinc acetate to absolute ethyl alcohol is 3:100;

the mass ratio of the natural surfactant to the attapulgite-based mayan blue organic/inorganic hybrid pigment is 1-5:100;

the mass ratio of the attapulgite-based mayan blue organic/inorganic hybrid pigment to the absolute ethyl alcohol is 5-20:100;

the mass ratio of the zinc acetate to the attapulgite-based mayan blue organic/inorganic hybrid pigment is 2-9:100.

4. The colored multifunctional barrier cream of claim 1, wherein: in the step S2 (1), the mass ratio of the surface modified zinc oxide/attapulgite-based mayan blue composite pigment to distilled water is 10:40-60.

5. The colored multifunctional barrier cream of any one of claims 1 to 4, characterized in that: the organic pigment molecule is indigo red, indigo blue, methyl violet, methylene blue, congo red, alizarin yellow.

6. The colored multifunctional barrier cream of any one of claims 1 to 4, characterized in that: the purified attapulgite clay is sieved by a 200-mesh sieve.

7. The colored multifunctional barrier cream of any one of claims 1 to 4, characterized in that: the natural surfactant is one or more of linseed oil, olive oil, coconut oil, argan oil, avocado oil, grape seed oil, palm oil, jojoba oil, sweet almond oil, evening primrose oil and calendula oil containing unsaturated fatty acid.