CN113512734B - Solid electrolyte electrolytic tank device adopting anion exchange membrane - Google Patents
Solid electrolyte electrolytic tank device adopting anion exchange membrane Download PDFInfo
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- CN113512734B CN113512734B CN202110791771.7A CN202110791771A CN113512734B CN 113512734 B CN113512734 B CN 113512734B CN 202110791771 A CN202110791771 A CN 202110791771A CN 113512734 B CN113512734 B CN 113512734B
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
- C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/02—Diaphragms; Spacing elements characterised by shape or form
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Abstract
The invention relates to the technical field of electrolysis, and discloses a solid electrolyte electrolytic tank device adopting an anion exchange membrane, which comprises a tank body, wherein an anode and a cathode are respectively arranged at the left side and the right side in a tank cavity, a diaphragm is fixedly arranged at the middle part in the tank cavity, and guide mechanisms are respectively arranged between the anode and the diaphragm and between the cathode and the diaphragm, and each guide mechanism comprises a waterproof motor and a protective cover. According to the anion exchange membrane solid electrolyte electrolytic tank device, when the threaded sleeve reciprocates up and down on the threaded column, the limiting rod B and the limiting rod A reciprocate up and down, the rotation of the threaded cylinder drives the rotating plate to rotate, the rotation of the rotating plate drives the fan plate to rotate, the rotation of the fan plate agitates liquid in the tank cavity, the liquid is accelerated to pass through the diaphragm, and the liquid in the tank cavity can be better contacted with the anode and the cathode, so that the reaction efficiency is accelerated.
Description
Technical Field
The invention relates to the technical field of electrolysis, in particular to a solid electrolyte electrolytic tank device adopting an anion exchange membrane.
Background
The method is also called membrane electrolytic cell method, which is a method for separating electrolytic products by dividing a unit electrolytic cell into an anode chamber and a cathode chamber by utilizing an anion-cation exchange membrane. The ionic membrane electrolysis method is a new technology developed on the basis of ion exchange resins (see ion exchangers). The ion exchange membrane has selective permeation to anions and cations, and allows ions with one charge to pass through while restricting ions with opposite charges to pass through, so as to achieve the purposes of concentration, desalination, purification and electrochemical synthesis.
The electrolysis trough of prior art is after long-term work, can produce the incrustation scale on the diaphragm inevitably, leads to liquid unable to circulate and exchange through the diaphragm, and secondly anode rod and the negative machine stick of prior art also probably condense incrustation scale and dirty after long-term work, lead to the efficiency reduction of click solution reaction, and prior art often needs manual dismantlement and change the diaphragm of manual jack-up, washs above incrustation scale, not only wastes time and energy, and efficiency is lower moreover. To this end we propose a solid electrolyte electrolyzer device employing anion exchange membranes.
Disclosure of Invention
The invention mainly solves the technical problems existing in the prior art and provides an electrolytic tank device adopting an anion exchange membrane solid electrolyte.
In order to achieve the above object, the present invention adopts a technical scheme that an anion exchange membrane solid electrolyte electrolytic cell device is adopted, the solid electrolyte electrolytic cell device comprises a cell body, an anode and a cathode are respectively installed at the left side and the right side in a cell cavity, a diaphragm is fixedly installed at the middle part in the cell cavity, guide mechanisms are arranged between the anode and the diaphragm as well as between the cathode and the diaphragm, the guide mechanisms comprise a waterproof motor and a shield, the waterproof motor is fixedly installed on the front side wall surface of the shield, the output end of the waterproof motor movably penetrates through the front side wall surface of the shield through a bearing, the output end of the waterproof motor is fixedly connected with a rotating rod, the rear end of the rotating rod is movably installed in the rear side wall surface of the shield through a bearing, the top of the shield is rotatably connected with threaded columns which are distributed at equal intervals, one end of each threaded column is fixedly installed with a bevel gear B in the cell cavity, a limit plate is fixedly installed on the outer wall of the rotating column, a threaded sleeve corresponding to the bevel gear B is meshed with the bevel gear A, a limit plate is fixedly installed on the top of each of the bevel gear B, a threaded sleeve is fixedly connected with the outer wall of the threaded column, a guide column corresponding to the left side and right side of the threaded column is fixedly installed on the wall surface of the wall of the cell cavity, a guide column corresponding to the threaded sleeve is movably installed on the side of the guide column corresponding to the threaded sleeve, a threaded sleeve is fixedly installed on one side of the outer wall of the rotating shaft, which is located close to the outer wall of the rotating sleeve, which is fixedly installed on the rotating shaft, which is located close to the rotating shaft, and is fixedly installed on one side of the rotating sleeve, which is fixedly arranged on one side of the rotating shaft, and is fixedly arranged on the rotating brush is fixedly arranged and is rotatably and is fixedly arranged, and is fixedly installed on the rotating side and is rotatably arranged and is fixedly installed and is fixedly and is rotatably arranged, one side of the threaded sleeve, which is close to the guide post, is fixedly provided with a limit rod B, one end of the limit rod B, which is far away from the threaded sleeve, is provided with a limit groove, the guide post movably penetrates through the limit groove, a side wall surface of the limit groove, which is close to the diaphragm, is fixedly provided with a linkage plate, a telescopic plate which can stretch out and draw back is arranged on the side wall surface of the linkage plate, which is close to the diaphragm, a cleaning plate is arranged on the side wall surface of the telescopic plate, which is close to the diaphragm, and soft bristles which can carry out friction cleaning on the outer wall of the diaphragm are fixedly arranged on the side wall surface of the cleaning plate, which is close to the diaphragm.
Preferably, the annular outer wall of the thread cylinder is provided with a rotating groove, the rotating groove is annular, the rotating ball is movably clamped in the rotating groove, the fan plates are fan-shaped, the number of the fan plates on the outer wall of each rotating plate is two, the fan plates on the two rotating plates are in a mutually symmetrical state, and hard bristles are uniformly distributed on the arc-shaped outer walls of the fan plates.
Preferably, the upper and lower groups of telescopic rods are fixedly arranged on the inner wall of one side of the limiting groove far away from the diaphragm, a guide ball is fixedly arranged on the side wall surface of the telescopic rod close to the guide post, and a vertical groove corresponding to the position of the guide ball is formed in the side wall surface of the guide post close to the telescopic rod.
Preferably, the guide balls are movably clamped in the vertical grooves, and the outer walls of the two telescopic rods are sleeved with supporting springs.
Preferably, the expansion plate is movably clamped in a side wall surface of the linkage plate, which is close to the diaphragm, a sliding groove is formed in a side wall surface of the linkage plate, which is close to the diaphragm, a sliding plate is fixedly installed on a side wall surface of the expansion plate, which is far away from the diaphragm, and is movably clamped in the sliding groove, the outer wall of the expansion plate movably penetrates through a side wall surface of the linkage plate, which is close to the diaphragm, a shaking rod is fixedly installed on the inner wall of the sliding groove, and a permanent magnet A is fixedly installed on a side wall surface of the sliding plate, which is close to the shaking rod.
Preferably, the shaking rod is annular, and the shaking rod is the same as the magnetic pole of the permanent magnet A.
Preferably, a permanent magnet B is fixedly arranged on a side wall surface of the permanent magnet A, which is far away from the diaphragm, the permanent magnet B movably penetrates through the inner walls of the shaking rod, the linkage plate and the limiting rod B, one end of the permanent magnet B, which is far away from the diaphragm, extends into the limiting groove, and a travel groove is formed in a side wall surface of the guide post, which is close to the diaphragm.
Preferably, one end of the permanent magnet B, which is far away from the diaphragm, is positioned in the travel groove, and one end of the permanent magnet B, which is positioned in the travel groove cavity, is fixedly provided with a linkage ball, and the linkage ball is limited in the travel groove.
Preferably, rubber bulges which are distributed at equal intervals up and down are fixedly arranged on the inner wall of the travel groove, and the rubber bulges are in an arc-shaped bulge state.
Advantageous effects
The invention provides a solid electrolyte electrolytic tank device adopting an anion exchange membrane. The beneficial effects are as follows:
(1) According to the anion exchange membrane solid electrolyte electrolytic tank device, when the threaded sleeve reciprocates up and down on the threaded column, the limit rod B and the limit rod A are driven to reciprocate up and down, the rotating plate is driven to rotate by rotating the threaded cylinder, the fan plate is driven to rotate by rotating the rotating plate, the liquid in the tank cavity is stirred by rotating the fan plate, the liquid is accelerated to pass through the diaphragm, and the liquid in the tank cavity can be better contacted with the anode and the cathode, so that the reaction efficiency is accelerated.
(2) The fan plate of the invention rotates to drive the hard brush hair to rotate, and the hard brush hair can rub the outer walls of the anode and the cathode, so that dirt and dirty on the anode and the cathode are cleaned, and the working efficiency of the anode and the cathode is improved.
(3) According to the device, the limit rod B drives the linkage plate to reciprocate up and down, the linkage plate drives the expansion plate and the cleaning plate to reciprocate up and down, and the cleaning plate drives the soft bristles to continuously make friction contact with the outer wall of the diaphragm, so that dirt on the outer wall of the diaphragm and dirt in liquid are removed, scale on the diaphragm is removed, the problem that the diaphragm is blocked due to long-term operation is avoided, and the working efficiency of the device is improved.
(4) The invention does not need to regularly disassemble and clean the diaphragm, reduces the labor intensity of staff, prolongs the service life of the diaphragm, and also improves the electrolysis efficiency of the solid electrolyte electrolytic tank with the anion exchange membrane.
(5) According to the invention, under the action of the magnetic pole repulsion of the permanent magnet A and the shaking rod, the cleaning plate and the soft bristles can be closely close to the outer wall of the diaphragm, so that the contact friction force between the soft bristles and the outer wall of the diaphragm is increased, and the efficiency of reciprocating cleaning of the diaphragm is improved.
(6) According to the device for the solid electrolyte electrolytic tank with the anion exchange membrane, when the linkage ball reciprocates up and down in the stroke tank, the linkage ball is continuously extruded and jacked by the elastic force of the rubber bulge, so that the permanent magnet B continuously and elastically jacks the expansion plate and the cleaning plate, the soft bristles can continuously shake, rub and clean the outer wall of the membrane, and when the soft bristles shake and clean the outer wall of the membrane, the washed scale can shake and drop, and the cleaning efficiency of the scale is accelerated.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below. It will be apparent to those skilled in the art from this disclosure that the drawings described below are merely exemplary and that other embodiments can be derived from the drawings provided without the inventive effort.
The structures, proportions, sizes, etc. shown in the present specification are shown only for the purposes of illustration and description, and are not intended to limit the scope of the invention, which is defined by the claims, so that any structural modifications, changes in proportions, or adjustments of sizes, which do not affect the efficacy or the achievement of the present invention, should fall within the ambit of the technical disclosure.
FIG. 1 is a front cross-sectional view of the present invention;
FIG. 2 is an enlarged view of the invention at A in FIG. 1;
FIG. 3 is an enlarged view of the invention at B in FIG. 1;
FIG. 4 is an enlarged view of FIG. 3 at C in accordance with the present invention;
FIG. 5 is an enlarged view of the invention at D in FIG. 3;
FIG. 6 is a perspective view of the guide mechanism of the present invention;
FIG. 7 is an enlarged view of the invention at E in FIG. 6;
fig. 8 is an enlarged view of fig. 6 at F in accordance with the present invention.
Legend description:
1. a tank body; 11. an anode; 12. a cathode; 13. a diaphragm; 2. a guide mechanism; 21. a waterproof motor; 22. a shield; 23. a threaded column; 24. a rotating lever; 25. a bevel gear A; 26. a bevel gear B; 27. a limiting plate; 28. a threaded sleeve; 29. a threaded rod; 3. a thread cylinder; 31. a rotating ball; 32. a rotating groove; 33. a rotating plate; 34. a fan plate; 35. hard bristles; 36. a limit rod A; 37. a limit rod B; 38. a guide post; 39. a limit groove; 4. a linkage plate; 41. a telescoping plate; 42. cleaning the plate; 43. soft bristles; 5. a telescopic rod; 51. a support spring; 52. a guide ball; 53. a vertical groove; 54. a linkage ball; 55. a travel groove; 56. a rubber protrusion; 57. a slide plate; 58. a chute; 59. a permanent magnet A; 6. a permanent magnet B; 61. a dither bar.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Examples: 1-8, an anion exchange membrane solid electrolyte electrolytic cell device comprises a cell body 1, wherein an anode 11 and a cathode 12 are respectively arranged at the left side and the right side of the cavity of the cell body 1, a diaphragm 13 is fixedly arranged in the middle of the cavity of the cell body 1, a guide mechanism 2 is arranged between the anode 11 and the diaphragm 13 and between the cathode 12 and the diaphragm 13, the guide mechanism 2 comprises a waterproof motor 21 and a shield 22, the waterproof motor 21 is fixedly arranged on the front side wall surface of the shield 22, the output end of the waterproof motor 21 movably penetrates through the front side wall surface of the shield 22 through a bearing, the output end of the waterproof motor 21 is fixedly connected with a rotating rod 24, the rear end of the rotating rod 24 is movably arranged in the rear side wall surface of the shield 22 through a bearing, the top of the shield 22 is rotatably connected with equally-spaced threaded columns 23, one ends of the threaded columns 23, which are positioned in the cavity of the shield 22, are fixedly provided with bevel gears B26, the outer wall of the rotating rod 24 is fixedly provided with a bevel gear A25 which corresponds to the bevel gear B26 in position, the bevel gear A25 is meshed with the bevel gear B26, the top of the threaded column 23 is fixedly provided with a limiting plate 27, the outer wall of the threaded column 23 is in threaded connection with a threaded sleeve 28, the bottom wall surface of the cavity of the tank body 1 is fixedly provided with a guide column 38 and a threaded rod 29 which correspond to the left and right of the threaded column 23 in position, the guide column 38 is positioned on one side close to the diaphragm 13, the threaded rod 29 is positioned on one side close to the corresponding anode 11 and cathode 12, the outer wall of the threaded rod 29 is in threaded connection with a threaded cylinder 3, one side of the threaded sleeve 28 close to the threaded cylinder 3 is fixedly provided with a limiting rod A36, one end of the limiting rod A36 away from the threaded sleeve 28 is fixedly provided with a rotating ball 31, the rotating ball 31 is movably arranged on the annular outer wall of the threaded cylinder 3, the bottom wall surface of the threaded cylinder 3 is fixedly provided with the rotating ball 31, the annular outer wall of the rotating ball 31 is fixedly provided with fan plates 34, the arc-shaped outer wall of the fan plates 34 is fixedly provided with hard brush hair 35 which can rotate and brush the anode 11 and the cathode 12, the annular outer wall of the threaded cylinder 3 is provided with a rotating groove 32, the rotating groove 32 is annular, the rotating ball 31 is movably clamped in the rotating groove 32, the fan plates 34 are fan-shaped, the number of the fan plates 34 on the outer wall of each rotating plate 33 is two, the fan plates 34 on the two rotating plates 33 are in a mutually symmetrical state, the hard brush hair 35 is uniformly distributed on the arc-shaped outer wall of the fan plates 34, one side of the threaded sleeve 28, which is close to the guide post 38, is fixedly provided with a limit rod B37, one end of the limit rod B37, which is far away from the threaded sleeve 28, is provided with a limit groove 39, the guide post 38 movably penetrates the limit groove 39, one side wall surface of the limit groove 39, which is close to the diaphragm 13, is fixedly provided with a linkage plate 4, a telescopic plate 41 which can be telescopic is arranged on the side wall surface of the linkage plate 4, which is close to the diaphragm 13, a cleaning plate 42 is arranged on the side wall surface of the telescopic plate 41, which is close to the diaphragm 13, soft bristles 43 which can carry out friction cleaning on the outer wall of the diaphragm 13 are fixedly arranged on the side wall surface of the cleaning plate 42, which is close to the diaphragm 13, an upper telescopic rod 5 and a lower telescopic rod 5 are fixedly arranged on the side wall surface of the limiting groove 39, which is far away from the diaphragm 13, a guide ball 52 is fixedly arranged on the side wall surface of the telescopic rod 5, which is close to the guide post 38, a vertical groove 53 corresponding to the position of the guide ball 52 is arranged on the side wall surface of the guide post 38, the guide ball 52 is movably clamped in the vertical groove 53, supporting springs 51 are sleeved on the outer walls of the two telescopic rods 5, the telescopic plate 41 is movably clamped in the side wall surface of the linkage plate 4, which is close to the diaphragm 13, a sliding groove 58 is arranged in the side wall surface of the linkage plate 4, which is close to the diaphragm 13, the flexible board 41 is kept away from the fixed mounting of a side wall face of diaphragm 13 and has slide 57, and slide 57 movable block is in spout 58, the outer wall activity of flexible board 41 runs through the link plate 4 and is close to a side wall face of diaphragm 13, the inner wall fixed mounting of spout 58 has shake pole 61, fixed mounting has permanent magnet A59 on the side wall face of slide 57 near shake pole 61, shake pole 61 is annular, shake pole 61 is the same with the magnetic pole of permanent magnet A59, permanent magnet A59 is kept away from the fixed mounting of a side wall face of diaphragm 13 has permanent magnet B6, permanent magnet B6 activity runs through shake pole 61, link plate 4 and the inner wall of gag lever post B37, and the one end that the permanent magnet B6 kept away from diaphragm 13 stretches into in spacing groove 39, the guide post 38 is kept away from on a side wall face of diaphragm 13 and has been seted up travel groove 55, the one end that the permanent magnet B6 kept away from diaphragm 13 is located travel groove 55, and the one end that the permanent magnet B6 is located travel groove 55 intracavity is fixed mounting has ball 54, the travel groove 54 is spacing in travel groove 55, the inner wall fixed mounting of travel groove 55 has equidistant rubber bulge 56 from top to bottom, rubber bulge 56 is in the state.
The working principle of the invention is as follows: when the cavity of the tank body 1 is filled with liquid and oxidation-reduction reaction operation is needed, the working switches of the two waterproof motors 21 are started, the two waterproof motors 21 work to drive the rotating rod 24 to rotate, the bevel gear A25 rotates to drive the bevel gear A25 to rotate, the bevel gear A25 is meshed with the bevel gear B26, the bevel gear B26 rotates to drive the threaded column 23 to rotate, the threaded sleeve 28 is in threaded connection with the outer wall of the threaded column 23, the two waterproof motors 21 are all positive and negative rotation motors, the threaded sleeve 28 is limited by the limiting rod B37 and the limiting rod A36, forward and reverse rotation of the threaded column 23 can enable the threaded sleeve 28 to move up and down on the threaded column 23, when the threaded sleeve 28 reciprocates up and down on the threaded column 23, the limiting rod B37 and the limiting rod A36 are driven to reciprocate up and down, the threaded cylinder 3 is in threaded connection with the outer wall of the threaded rod 29, when the limit rod A36 drives the threaded cylinder 3 to reciprocate up and down through the rotating ball 31, the threaded cylinder 3 rotates, the rotating ball 31 slides in the rotating groove 32, the rotating ball 3 drives the rotating plate 33 to rotate, the rotating plate 33 drives the fan plate 34 to rotate, the rotating plate 34 agitates the liquid in the cavity of the tank body 1, the liquid is accelerated to pass through the diaphragm 13, the liquid in the cavity of the tank body 1 can better contact with the anode 11 and the cathode 12, so that the reaction efficiency is accelerated, the rotating of the fan plate 34 can drive the hard brush hair 35 to rotate, the rotating of the hard brush hair 35 can rub the outer walls of the anode 11 and the cathode 12, dirt and dirty on the anode 11 and the cathode 12 are cleaned, the working efficiency of the anode 11 and the cathode 12 is improved, when the threaded sleeve 28 drives the limiting rod B37 to reciprocate up and down, under the action of the elasticity of the supporting spring 51, the guide ball 52 can be firmly arranged in the vertical groove 53, so that the limiting rod B37 is limited, meanwhile, the limiting rod B37 drives the linkage plate 4 to reciprocate up and down, the linkage plate 4 drives the telescopic plate 41 and the cleaning plate 42 to reciprocate up and down, and the cleaning plate 42 drives the soft bristles 43 to make continuous friction contact with the outer wall of the diaphragm 13, thereby removing dirt on the outer wall of the diaphragm 13 and dirt in liquid, finally removing scale on the diaphragm 13, avoiding the problem of blockage of the upper scale caused by long-term operation of the diaphragm 13, and improving the working efficiency of the anion exchange membrane solid electrolyte electrolytic tank.
The invention does not need to regularly disassemble and clean the diaphragm 13, reduces the labor intensity of workers, prolongs the service life of the diaphragm 13, and also improves the electrolysis efficiency of the solid electrolyte electrolytic tank of the anion exchange membrane,
under the magnetic pole repulsive interaction of the permanent magnet a59 and the shaking rod 61, the cleaning plate 42 and the soft brush hair 43 can be close to the outer wall of the diaphragm 13, the contact friction force between the soft brush hair 43 and the outer wall of the diaphragm 13 is increased, the efficiency of the invention for cleaning the diaphragm 13 in a reciprocating manner is improved, when the linkage ball 54 reciprocates up and down in the stroke groove 55, the linkage ball 54 is continuously extruded and jacked by the elastic force of the rubber bulge 56, the permanent magnet B6 continuously and elastically jacks the telescopic plate 41 and the cleaning plate 42, the soft brush hair 43 can continuously shake and rub the outer wall of the diaphragm 13, and when the soft brush hair 43 shake and clean the outer wall of the diaphragm 13, the washed scale can shake and drop, so that the efficiency of cleaning the scale is accelerated.
When the threaded sleeve 28 reciprocates up and down on the threaded column 23, the limit rod B37 and the limit rod A36 are driven to reciprocate up and down, the threaded cylinder 3 is rotated to drive the rotating plate 33 to rotate, the rotating plate 33 is rotated to drive the fan plate 34 to rotate, the fan plate 34 is rotated to stir the liquid in the cavity of the tank body 1, the liquid is accelerated to pass through the diaphragm 13, the liquid in the cavity of the tank body 1 can better contact with the anode 11 and the cathode 12, so that the reaction efficiency is accelerated, the rotation of the fan plate 34 drives the hard brush hair 35 to rotate, the outer walls of the anode 11 and the cathode 12 can be rubbed, dirt and dirty on the anode 11 and the cathode 12 are cleaned, the working efficiency of the anode 11 and the cathode 12 is improved, the limit rod B37 of the invention drives the linkage plate 4 to reciprocate up and down, the linkage plate 4 drives the expansion plate 41 and the cleaning plate 42 to reciprocate up and down, the cleaning plate 42 drives the soft brush hair 43 to continuously make friction contact with the outer wall of the diaphragm 13, thereby removing dirt on the outer wall of the diaphragm 13 and dirt in liquid, finally removing scale on the diaphragm 13, avoiding the problem of blockage of the upper dirt caused by long-term operation of the diaphragm 13, improving the working efficiency of the anion exchange membrane solid electrolyte electrolytic tank, avoiding periodic disassembly and cleaning of the diaphragm 13, reducing the labor intensity of staff, improving the service life of the diaphragm 13, and also improving the electrolytic efficiency of the anion exchange membrane solid electrolyte electrolytic tank, the cleaning plate 42 and the soft bristles 43 can be closely contacted with the outer wall of the diaphragm 13, the contact friction force between the soft bristles 43 and the outer wall of the diaphragm 13 is increased, the efficiency of the invention for cleaning the diaphragm 13 in a reciprocating manner is improved, when the linkage ball 54 reciprocates up and down in the travel groove 55, the linkage ball 54 is continuously extruded and jacked by the elastic force of the rubber bulge 56, the permanent magnet B6 continuously elastically jacks the telescopic plate 41 and the cleaning plate 42, the soft bristles 43 can continuously shake and rub the outer wall of the diaphragm 13, and the washed scale can shake and drop when the soft bristles 43 shake and clean the outer wall of the diaphragm 13, so that the cleaning efficiency of the scale is accelerated.
The foregoing has shown and described the basic principles and main features of the present invention and the advantages of the present invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and that the above embodiments and descriptions are merely illustrative of the principles of the present invention, and various changes and modifications may be made without departing from the spirit and scope of the invention, which is defined in the appended claims. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (9)
1. The utility model provides an adopt solid electrolyte electrolytic cell device of anion exchange membrane, includes cell body (1), and positive pole (11) and negative pole (12) are installed respectively to cell body (1) intracavity left and right sides, and cell body (1) intracavity middle part fixed mounting has diaphragm (13), its characterized in that: guide mechanisms (2) are arranged between the anode (11) and the diaphragm (13) and between the cathode (12) and the diaphragm (13), the guide mechanisms (2) comprise a waterproof motor (21) and a shield (22), the waterproof motor (21) is fixedly arranged on the front side wall surface of the shield (22), the output end of the waterproof motor (21) movably penetrates through the front side wall surface of the shield (22) through a bearing, the output end of the waterproof motor (21) is fixedly connected with a rotating rod (24), the rear end of the rotating rod (24) is movably arranged in the rear side wall surface of the shield (22) through a bearing, threaded columns (23) which are distributed at equal intervals are rotatably connected to the top of the shield (22), one end of each threaded column (23) positioned in a cavity of the shield (22) is fixedly provided with a bevel gear B (26), the outer wall of the rotating rod (24) is fixedly provided with a bevel gear A (25) which corresponds to the position of the bevel gear B (26), the top of each threaded column (23) is fixedly provided with a limiting plate (27), the outer wall of the threaded column (23) is fixedly connected with a sleeve (28) of the bevel gear B (26), the inner wall of the threaded column (23) is fixedly arranged on the left side wall (38) of the cavity (1), the guide post (38) is positioned at one side close to the diaphragm (13), and the threaded rod (29) is positioned at one side close to the corresponding anode (11) and cathode (12);
the outer wall of the threaded rod (29) is in threaded connection with a threaded cylinder (3), one side of the threaded sleeve (28) close to the threaded cylinder (3) is fixedly provided with a limit rod A (36), one end of the limit rod A (36) away from the threaded sleeve (28) is fixedly provided with a rotary ball (31), the rotary ball (31) is movably arranged on the annular outer wall of the threaded cylinder (3), the bottom wall surface of the threaded cylinder (3) is fixedly provided with a rotary ball (31), the annular outer wall of the rotary ball (31) is fixedly provided with a fan plate (34), the arc-shaped outer wall of the fan plate (34) is fixedly provided with a hard brush hair (35) capable of rotating and brushing the anode (11) and the cathode (12), one side of the threaded sleeve (28) close to a guide post (38) is fixedly provided with a limit rod B (37), one end of the limit rod B (37) away from the threaded sleeve (28) is provided with a limit groove (39), the guide post (38) movably penetrates through the limit groove (39), one side wall surface of the limit groove (39) close to the diaphragm (13) is fixedly provided with a plate (4), one side wall surface of the diaphragm (13) is fixedly provided with a telescopic link plate (41), one side (41) close to the diaphragm plate (13) is provided with a telescopic link plate (41), a soft brush hair (43) which can carry out friction cleaning on the outer wall of the diaphragm (13) is fixedly arranged on one side wall surface of the cleaning plate (42) close to the diaphragm (13).
2. A solid electrolyte electrolyzer unit employing an anion exchange membrane as claimed in claim 1, characterized in that: the annular outer wall of the thread cylinder (3) is provided with a rotating groove (32), the rotating groove (32) is annular, the rotating ball (31) is movably clamped in the rotating groove (32), the fan plates (34) are fan-shaped, the number of the fan plates (34) on the outer wall of each rotating plate (33) is two, the fan plates (34) on the two rotating plates (33) are in a mutually symmetrical state, and hard brush hair (35) are uniformly distributed on the arc-shaped outer walls of the fan plates (34).
3. A solid electrolyte electrolyzer unit employing an anion exchange membrane as claimed in claim 1, characterized in that: an upper telescopic rod (5) and a lower telescopic rod (5) are fixedly arranged on the inner wall of one side, far away from the diaphragm (13), of the limiting groove (39), a guide ball (52) is fixedly arranged on the side wall surface, close to the guide post (38), of the telescopic rod (5), and a vertical groove (53) corresponding to the position of the guide ball (52) is formed in the side wall surface, close to the telescopic rod (5), of the guide post (38).
4. A solid electrolyte electrolytic cell device using an anion exchange membrane according to claim 3, wherein: the guide balls (52) are movably clamped in the vertical grooves (53), and the outer walls of the two telescopic rods (5) are sleeved with supporting springs (51).
5. A solid electrolyte electrolyzer unit employing an anion exchange membrane as claimed in claim 1, characterized in that: the flexible board (41) movable block is in linkage board (4) is close to the side wall of diaphragm (13), spout (58) have been seted up in linkage board (4) is close to the side wall of diaphragm (13), fixed mounting has slide (57) on the side wall that diaphragm (13) were kept away from to flexible board (41), and slide (57) movable block is in spout (58), the outer wall activity of flexible board (41) runs through linkage board (4) and is close to the side wall of diaphragm (13), the inner wall fixed mounting of spout (58) has shake pole (61), fixed mounting has permanent magnet A (59) on the side wall that slide (57) are close to shake pole (61).
6. A solid electrolyte electrolytic cell device using an anion exchange membrane according to claim 5, wherein: the shaking rod (61) is annular, and the magnetic poles of the shaking rod (61) and the permanent magnet A (59) are the same.
7. A solid electrolyte electrolytic cell device using an anion exchange membrane according to claim 5, wherein: a permanent magnet B (6) is fixedly mounted on a side wall surface, far away from the diaphragm (13), of the permanent magnet A (59), the permanent magnet B (6) movably penetrates through the inner walls of the shaking rod (61), the linkage plate (4) and the limiting rod B (37), one end, far away from the diaphragm (13), of the permanent magnet B (6) stretches into the limiting groove (39), and a travel groove (55) is formed in a side wall surface, close to the diaphragm (13), of the guide column (38).
8. A solid electrolyte electrolytic cell device using an anion exchange membrane according to claim 7, wherein: one end of the permanent magnet B (6) far away from the diaphragm (13) is positioned in the travel groove (55), and one end of the permanent magnet B (6) positioned in the cavity of the travel groove (55) is fixedly provided with a linkage ball (54), and the linkage ball (54) is limited in the travel groove (55).
9. A solid electrolyte electrolytic cell device using an anion exchange membrane according to claim 7, wherein: rubber bulges (56) which are distributed at equal intervals up and down are fixedly arranged on the inner wall of the travel groove (55), and the rubber bulges (56) are in an arc-shaped bulge state.
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| CN114855200B (en) * | 2022-04-13 | 2023-08-22 | 四川帝威能源技术有限公司 | Water electrolysis hydrogen plant protector |
| CN114807972B (en) * | 2022-05-27 | 2023-02-10 | 广东卡沃罗氢科技有限公司 | Electrolytic tank structure for producing hydrogen by electrolyzing pure water |
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