CN113512734A - Solid electrolyte electrolytic tank device adopting anion exchange membrane - Google Patents
Solid electrolyte electrolytic tank device adopting anion exchange membrane Download PDFInfo
- Publication number
- CN113512734A CN113512734A CN202110791771.7A CN202110791771A CN113512734A CN 113512734 A CN113512734 A CN 113512734A CN 202110791771 A CN202110791771 A CN 202110791771A CN 113512734 A CN113512734 A CN 113512734A
- Authority
- CN
- China
- Prior art keywords
- diaphragm
- threaded
- close
- plate
- rotating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
- C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/02—Diaphragms; Spacing elements characterised by shape or form
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The invention relates to the technical field of electrolysis, and discloses a solid electrolyte electrolytic cell device adopting an anion exchange membrane, which comprises a cell body, wherein an anode and a cathode are respectively arranged on the left side and the right side in a cell body cavity, a diaphragm is fixedly arranged in the middle in the cell body cavity, guide mechanisms are respectively arranged between the anode and the diaphragm as well as between the cathode and the diaphragm, and each guide mechanism comprises a waterproof motor and a shield. According to the solid electrolyte electrolytic tank device adopting the anion exchange membrane, when the threaded sleeve reciprocates up and down on the threaded column, the limiting rod B and the limiting rod A reciprocate up and down, the rotation of the threaded sleeve drives the rotating plate to rotate, the rotation of the rotating plate drives the fan plate to rotate, the rotation of the fan plate realizes stirring of liquid in the cavity of the tank body, the liquid is accelerated to pass through the diaphragm, so that the liquid in the cavity of the tank body can better contact with the anode and the cathode, and the reaction efficiency is accelerated.
Description
Technical Field
The invention relates to the technical field of electrolysis, in particular to an electrolytic cell device adopting an anion exchange membrane solid electrolyte.
Background
Also called membrane cell electrolysis method, is a method which separates the unit electrolysis cell into an anode chamber and a cathode chamber by utilizing an anion-cation exchange membrane to separate the electrolysis products. The ion membrane electrolysis is a new technology developed on the basis of ion exchange resin (see ion exchanger). The ion exchange membrane has the characteristic of selective permeability to anions and cations, allows ions with one charge to pass through and limits the ions with the opposite charge to pass through, so as to achieve the purposes of concentration, desalination, purification and electrochemical synthesis.
The electrolysis trough of prior art is after long-term work, and the incrustation scale can be produced to inevitable on the diaphragm, leads to liquid can't circulate and exchange through the diaphragm, and secondly prior art's positive pole stick and negative machine stick also can condense incrustation scale and dirty after long-term work, lead to the efficiency of point solution reaction to reduce, and current technique often needs artifical jack-up manual dismantlement and change the diaphragm, washs the incrustation scale above, not only wastes time and energy, and efficiency is lower moreover. To this end, we propose a solid electrolyte cell apparatus employing an anion exchange membrane.
Disclosure of Invention
The invention mainly solves the technical problems in the prior art and provides an electrolytic cell device adopting an anion exchange membrane solid electrolyte.
In order to achieve the purpose, the invention adopts the following technical scheme that the solid electrolyte electrolytic tank device adopting the anion exchange membrane comprises a tank body, wherein the left side and the right side in the cavity of the tank body are respectively provided with an anode and a cathode, the middle part in the cavity of the tank body is fixedly provided with a diaphragm, guide mechanisms are respectively arranged between the anode and the diaphragm as well as between the cathode and the diaphragm, each guide mechanism comprises a waterproof motor and a protective cover, the waterproof motor is fixedly arranged on the front side wall surface of the protective cover, the output end of the waterproof motor movably penetrates through the front side wall surface of the protective cover through a bearing, the output end of the waterproof motor is fixedly connected with a rotating rod, the rear end of the rotating rod is movably arranged in the rear side wall surface of the protective cover through a bearing, the top of the protective cover is rotatably connected with threaded columns which are distributed at equal intervals, one ends of the threaded columns in the cavity of the protective cover are respectively fixedly provided with a helical gear B, and the helical gear A which corresponds to the helical gear B is fixedly arranged on the outer wall of the rotating rod, the helical gear A is meshed with the helical gear B, limiting plates are fixedly arranged at the tops of the threaded columns, threaded sleeves are connected to the outer walls of the threaded columns in a threaded mode, guide columns and threaded rods which correspond to the threaded columns in the left and right directions are fixedly arranged on the wall surface of the bottom in the cavity of the tank body, the guide columns are located on one sides close to the diaphragm, the threaded rods are located on one sides close to corresponding anodes and cathodes, threaded cylinders are connected to the outer walls of the threaded rods in a threaded mode, limiting rods A are fixedly arranged on one sides, close to the threaded cylinders, of the threaded sleeves, rotating balls are fixedly arranged at one ends, far away from the threaded sleeves, of the limiting rods A, the rotating balls are movably arranged on the annular outer walls of the threaded cylinders, rotating balls are fixedly arranged on the bottom wall surfaces of the threaded cylinders, fan plates are fixedly arranged on the annular outer walls of the rotating balls, hard bristles capable of rotationally washing the anodes and the cathodes are fixedly arranged on the arc outer walls of the fan plates, and limiting rods B are fixedly arranged on one sides, close to the guide columns, of the threaded sleeves, the limiting groove is formed in one end, away from the threaded sleeve, of the limiting rod B, the limiting groove is movably penetrated through by the guide column, the linkage plate is fixedly mounted on one side wall face, close to the diaphragm, of the limiting groove, the extensible plate capable of extending is arranged on one side wall face, close to the diaphragm, of the linkage plate, the cleaning plate is arranged on one side wall face, close to the diaphragm, of the extensible plate, and the soft bristles capable of conducting friction cleaning on the outer wall of the diaphragm are fixedly mounted on one side wall face, close to the diaphragm, of the cleaning plate.
Preferably, the annular outer wall of the threaded cylinder is provided with a rotating groove, the rotating groove is annular, the rotating ball is movably clamped in the rotating groove, the fan plates are fan-shaped, the number of the fan plates on the outer wall of each rotating plate is two, the fan plates on the two rotating plates are in a mutually symmetrical state, and the hard bristles are uniformly distributed on the arc-shaped outer walls of the fan plates.
Preferably, an upper group of telescopic rods and a lower group of telescopic rods are fixedly mounted on the inner wall of one side, away from the diaphragm, of the limiting groove, a guide ball is fixedly mounted on the wall surface of one side, close to the guide post, of each telescopic rod, and a vertical groove corresponding to the position of the guide ball is formed in the wall surface of one side, close to the telescopic rod, of the guide post.
Preferably, the guide ball is movably clamped in the vertical groove, and the outer walls of the two telescopic rods are sleeved with the supporting springs.
Preferably, the expansion plate is movably clamped in a side wall surface of the linkage plate close to the diaphragm, a sliding groove is formed in the side wall surface of the linkage plate close to the diaphragm, a sliding plate is fixedly mounted on the side wall surface of the expansion plate far away from the diaphragm, the sliding plate is movably clamped in the sliding groove, the outer wall of the expansion plate movably penetrates through the side wall surface of the linkage plate close to the diaphragm, a shaking rod is fixedly mounted on the inner wall of the sliding groove, and a permanent magnet A is fixedly mounted on the side wall surface of the sliding plate close to the shaking rod.
Preferably, the shaking rod is annular, and the shaking rod and the permanent magnet A have the same magnetic pole.
Preferably, a permanent magnet B is fixedly mounted on the wall surface of one side, away from the diaphragm, of the permanent magnet A, the permanent magnet B movably penetrates through the inner walls of the shaking rod, the linkage plate and the limiting rod B, one end, away from the diaphragm, of the permanent magnet B extends into the limiting groove, and a stroke groove is formed in the wall surface of one side, close to the diaphragm, of the guide post.
Preferably, one end, far away from the diaphragm, of the permanent magnet B is located in the stroke groove, a linkage ball is fixedly mounted at one end, located in the stroke groove cavity, of the permanent magnet B, and the linkage ball is limited in the stroke groove.
Preferably, the inner wall of the stroke groove is fixedly provided with rubber bulges which are distributed at equal intervals up and down, and the rubber bulges are in an arc-shaped bulge state.
Advantageous effects
The invention provides an electrolytic bath device adopting anion exchange membranes as solid electrolytes. The method has the following beneficial effects:
(1) when the threaded sleeve reciprocates up and down on the threaded column, the limiting rod B and the limiting rod A are driven to reciprocate up and down, the rotating of the threaded sleeve drives the rotating plate to rotate, the rotating of the rotating plate drives the fan plate to rotate, the rotating of the fan plate drives the liquid in the cavity of the tank body to be stirred, the liquid is accelerated to pass through the diaphragm, and the liquid in the cavity of the tank body can be better contacted with the anode and the cathode, so that the reaction efficiency is accelerated.
(2) According to the solid electrolyte electrolytic tank device adopting the anion exchange membrane, the rotation of the fan plate drives the hard bristles to rotate, and the hard bristles can rub against the outer walls of the anode and the cathode by rotating, so that dirt and smudge on the anode and the cathode are cleaned, and the working efficiency of the anode and the cathode is improved.
(3) According to the anion exchange membrane solid electrolyte electrolytic tank device, the limiting rod B drives the linkage plate to reciprocate up and down, the linkage plate drives the expansion plate and the cleaning plate to reciprocate up and down, and the cleaning plate drives the soft bristles to continuously make frictional contact with the outer wall of the diaphragm, so that dirt on the outer wall of the diaphragm and dirt in liquid are removed, scale on the diaphragm is finally removed, the problem that the dirt on the diaphragm is blocked due to long-term operation of the diaphragm is solved, and the working efficiency of the anion exchange membrane solid electrolyte electrolytic tank device is improved.
(4) According to the solid electrolyte electrolytic tank device adopting the anion exchange membrane, the diaphragm does not need to be periodically disassembled for cleaning, so that the labor intensity of workers is reduced, the service life of the diaphragm is prolonged, and the electrolytic efficiency of the solid electrolyte electrolytic tank adopting the anion exchange membrane is improved.
(5) According to the solid electrolyte electrolytic tank device adopting the anion exchange membrane, under the magnetic pole repulsion action of the permanent magnet A and the shaking rod, the cleaning plate and the soft brush hair can be closely close to the outer wall of the diaphragm, so that the contact friction force between the soft brush hair and the outer wall of the diaphragm is increased, and the reciprocating cleaning efficiency of the diaphragm is improved.
(6) According to the solid electrolyte electrolytic tank device adopting the anion exchange membrane, when the linkage ball does up-and-down reciprocating motion in the stroke tank, the linkage ball is continuously extruded and jacked by the rubber bulges in an elastic manner, so that the permanent magnet B continuously jacks up the expansion plate and the cleaning plate in an elastic manner, the soft bristles can continuously shake, rub and clean the outer wall of the diaphragm, and when the soft bristles shake and clean the outer wall of the diaphragm, washed scale can shake and fall, so that the scale removing efficiency is improved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below. It should be apparent that the drawings in the following description are merely exemplary, and that other embodiments can be derived from the drawings provided by those of ordinary skill in the art without inventive effort.
The structures, ratios, sizes, and the like shown in the present specification are only used for matching with the contents disclosed in the specification, so as to be understood and read by those skilled in the art, and are not used to limit the conditions that the present invention can be implemented, so that the present invention has no technical significance, and any structural modifications, changes in the ratio relationship, or adjustments of the sizes, without affecting the effects and the achievable by the present invention, should still fall within the range that the technical contents disclosed in the present invention can cover.
FIG. 1 is a front cross-sectional view of the present invention;
FIG. 2 is an enlarged view taken at A of FIG. 1 in accordance with the present invention;
FIG. 3 is an enlarged view of the invention at B of FIG. 1;
FIG. 4 is an enlarged view of the invention at C of FIG. 3;
FIG. 5 is an enlarged view taken at D of FIG. 3 in accordance with the present invention;
FIG. 6 is a perspective view of the guide mechanism of the present invention;
FIG. 7 is an enlarged view of the invention at E of FIG. 6;
fig. 8 is an enlarged view of the invention at F in fig. 6.
Illustration of the drawings:
1. a trough body; 11. an anode; 12. a cathode; 13. a diaphragm; 2. a guide mechanism; 21. a waterproof motor; 22. a shield; 23. a threaded post; 24. rotating the rod; 25. a bevel gear A; 26. a bevel gear B; 27. a limiting plate; 28. a threaded sleeve; 29. a threaded rod; 3. a threaded barrel; 31. rotating the ball; 32. a rotating groove; 33. a rotating plate; 34. a fan plate; 35. hard bristles; 36. a limiting rod A; 37. a limiting rod B; 38. a guide post; 39. a limiting groove; 4. a linkage plate; 41. a retractable plate; 42. cleaning the plate; 43. soft bristles; 5. a telescopic rod; 51. a support spring; 52. a guide ball; 53. a vertical slot; 54. a linkage ball; 55. a stroke slot; 56. a rubber bulge; 57. a slide plate; 58. a chute; 59. a permanent magnet A; 6. a permanent magnet B; 61. the rod is shaken.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example (b): an electrolytic cell device adopting anion exchange membrane solid electrolyte, as shown in figures 1-8, comprises a cell body 1, wherein the left side and the right side in the cavity of the cell body 1 are respectively provided with an anode 11 and a cathode 12, the middle part in the cavity of the cell body 1 is fixedly provided with a diaphragm 13, guide mechanisms 2 are respectively arranged between the anode 11 and the diaphragm 13 and between the cathode 12 and the diaphragm 13, each guide mechanism 2 comprises a waterproof motor 21 and a shield 22, the waterproof motor 21 is fixedly arranged on the front side wall surface of the shield 22, the output end of the waterproof motor 21 movably penetrates through the front side wall surface of the shield 22 through a bearing, the output end of the waterproof motor 21 is fixedly connected with a rotating rod 24, the rear end of the rotating rod 24 is movably arranged in the rear side wall surface of the shield 22 through a bearing, the top of the shield 22 is rotatably connected with threaded columns 23 which are distributed at equal intervals, one ends of the threaded columns 23 in the cavity of the shield 22 are respectively and fixedly provided with a bevel gear B26, a helical gear A25 corresponding to the helical gear B26 is fixedly installed on the outer wall of the rotating rod 24, the helical gear A25 is meshed with the helical gear B26, a limit plate 27 is fixedly installed at the top of the threaded column 23, a threaded sleeve 28 is connected to the outer wall of the threaded column 23 in a threaded manner, a guide column 38 and a threaded rod 29 corresponding to the left and right of the threaded column 23 are fixedly installed on the inner bottom wall surface of the cavity of the tank body 1, the guide column 38 is positioned at one side close to the diaphragm 13, the threaded rod 29 is positioned at one side close to the corresponding anode 11 and cathode 12, a threaded barrel 3 is connected to the outer wall of the threaded rod 29 in a threaded manner, a limit rod A36 is fixedly installed at one side of the threaded sleeve 28 close to the threaded barrel 3, a rotating ball 31 is fixedly installed at one end of the limit rod A36 far away from the threaded sleeve 28, the rotating ball 31 is movably installed on the annular outer wall of the threaded barrel 3, a rotating ball 31 is fixedly installed on the bottom wall surface of the threaded barrel 3, the ring-shaped outer wall of the rotating ball 31 is fixedly provided with a fan plate 34, the arc-shaped outer wall of the fan plate 34 is fixedly provided with hard brush hair 35 which can rotate and wash the anode 11 and the cathode 12, the ring-shaped outer wall of the thread cylinder 3 is provided with a rotating groove 32, the rotating groove 32 is ring-shaped, the rotating ball 31 is movably clamped in the rotating groove 32, the fan plate 34 is fan-shaped, the number of the fan plates 34 on the outer wall of each rotating plate 33 is two, the fan plates 34 on the two rotating plates 33 are in a mutually symmetrical state, the hard brush hair 35 is uniformly distributed on the arc-shaped outer wall of the fan plate 34, one side of the thread sleeve 28 close to the guide post 38 is fixedly provided with a limit rod B37, one end of the limit rod B37 far away from the thread sleeve 28 is provided with a limit groove 39, the guide post 38 movably penetrates through the limit groove 39, one side wall surface of the limit groove 39 close to the diaphragm 13 is fixedly provided with a linkage plate 4, one side wall surface of the linkage plate 4 close to the diaphragm 13 is provided with a telescopic expansion plate 41, a cleaning plate 42 is arranged on one side wall surface of the expansion plate 41 close to the diaphragm 13, soft bristles 43 capable of performing friction cleaning on the outer wall of the diaphragm 13 are fixedly arranged on one side wall surface of the cleaning plate 42 close to the diaphragm 13, upper and lower groups of expansion rods 5 are fixedly arranged on one side wall surface of the limiting groove 39 far from the diaphragm 13, a guide ball 52 is fixedly arranged on one side wall surface of the expansion rod 5 close to the guide post 38, a vertical groove 53 corresponding to the position of the guide ball 52 is formed on one side wall surface of the guide post 38 close to the expansion rod 5, the guide ball 52 is movably clamped in the vertical groove 53, supporting springs 51 are sleeved on the outer walls of the two expansion rods 5, the expansion plate 41 is movably clamped in one side wall surface of the linkage plate 4 close to the diaphragm 13, a sliding groove 58 is formed in one side wall surface of the linkage plate 4 close to the diaphragm 13, a sliding plate 57 is fixedly arranged on one side wall surface of the expansion plate 41 far from the diaphragm 13, and the sliding plate 57 is movably clamped in the sliding groove 58, the outer wall of the telescopic plate 41 movably penetrates through one side wall surface of the linkage plate 4 close to the diaphragm 13, the inner wall of the sliding groove 58 is fixedly provided with a shaking rod 61, one side wall surface of the sliding plate 57 close to the shaking rod 61 is fixedly provided with a permanent magnet A59, the shaking rod 61 is annular, the magnetic poles of the shaking rod 61 and the permanent magnet A59 are the same, one side wall surface of the permanent magnet A59 far away from the diaphragm 13 is fixedly provided with a permanent magnet B6, the permanent magnet B6 movably penetrates through the inner walls of the shaking rod 61, the linkage plate 4 and the limiting rod B37, one end of the permanent magnet B6 far away from the diaphragm 13 extends into the limiting groove 39, one side wall surface of the guide post 38 close to the diaphragm 13 is provided with a stroke groove 55, one end of the permanent magnet B6 far away from the diaphragm 13 is positioned in the stroke groove 55, one end of the permanent magnet B6 positioned in the stroke groove 55 cavity is fixedly provided with a linkage ball 54, the linkage ball 54 is limited in the stroke groove 55, the inner wall of the stroke groove 55 is fixedly provided with rubber bulges 56 which are distributed at equal intervals up and down, the rubber protrusion 56 is in a state of an arc protrusion.
The working principle of the invention is as follows: after the cavity of the tank body 1 is filled with liquid and when redox reaction operation is required, the working switches of the two waterproof motors 21 are turned on, the two waterproof motors 21 work to drive the rotating rod 24 to rotate, the helical gear A25 rotates to drive the helical gear A25 to rotate, the helical gear A25 is meshed with the helical gear B26, the helical gear B26 rotates, the helical gear B26 rotates to drive the threaded column 23 to rotate, the threaded sleeve 28 is in threaded connection with the outer wall of the threaded column 23, the two waterproof motors 21 are forward and reverse rotating motors, the threaded sleeve 28 is limited by the limiting rod B37 and the limiting rod A36, the forward and reverse rotation of the threaded column 23 can enable the threaded sleeve 28 to move up and down on the threaded column 23, when the threaded sleeve 28 moves up and down on the threaded column 23, the limiting rod B37 and the limiting rod A36 are driven to reciprocate up and down, and the threaded sleeve 3 is in threaded connection with the outer wall of the threaded rod 29, when the limiting rod A36 drives the threaded cylinder 3 to reciprocate up and down through the rotating ball 31, the threaded cylinder 3 is rotated, the rotating ball 31 slides in the rotating groove 32, the rotating plate 33 is driven to rotate by the rotation of the threaded cylinder 3, the fan plate 34 is driven to rotate by the rotation of the rotating plate 33, the liquid in the cavity of the tank body 1 is stirred by the rotation of the fan plate 34, the liquid passes through the diaphragm 13 in an accelerating manner, so that the liquid in the cavity of the tank body 1 can better contact with the anode 11 and the cathode 12, the reaction efficiency is accelerated, the hard bristles 35 can be driven to rotate by the rotation of the fan plate 34, the outer walls of the anode 11 and the cathode 12 can be rubbed by the rotation of the hard bristles 35, dirt and filth on the anode 11 and the cathode 12 can be cleaned, the working efficiency of the anode 11 and the cathode 12 is improved, and when the limiting rod B37 is driven by the threaded sleeve 28 to reciprocate up and down, under the elastic force of the supporting spring 51, the guide ball 52 can be stabilized in the vertical groove 53, so that the limiting rod B37 is limited, meanwhile, the limiting rod B37 drives the linkage plate 4 to reciprocate up and down, the linkage plate 4 drives the expansion plate 41 and the cleaning plate 42 to reciprocate up and down, and the cleaning plate 42 drives the soft bristles 43 to continuously make frictional contact with the outer wall of the diaphragm 13, so that the dirt on the outer wall of the diaphragm 13 and the dirt in the liquid are removed, finally, the scale on the diaphragm 13 is removed, the problem that the dirt on the diaphragm 13 is blocked due to long-term work of the diaphragm 13 is solved, and the working efficiency of the anion exchange membrane solid electrolyte electrolytic cell is improved.
The invention does not need to dismantle and clean the diaphragm 13 regularly, reduces the labor intensity of workers, prolongs the service life of the diaphragm 13, improves the electrolysis efficiency of the anion exchange membrane solid electrolyte electrolytic cell,
under the action of magnetic pole repulsion of the permanent magnet A59 and the shaking rod 61, the cleaning plate 42 and the soft brush bristles 43 can be closely close to the outer wall of the diaphragm 13, so that the contact friction force between the soft brush bristles 43 and the outer wall of the diaphragm 13 is increased, the reciprocating cleaning efficiency of the diaphragm 13 is improved, when the linkage ball 54 reciprocates up and down in the stroke groove 55, the linkage ball 54 is continuously extruded and jacked up by the rubber bulge 56 in an elastic manner, so that the permanent magnet B6 continuously jacks up the expansion plate 41 and the cleaning plate 42 in an elastic manner, the soft brush bristles 43 can continuously shake, rub and clean the outer wall of the diaphragm 13, and when the soft brush bristles 43 shake and clean the outer wall of the diaphragm 13, washed scale can shake and fall, so that the scale removing efficiency is improved.
When the threaded sleeve 28 reciprocates up and down on the threaded column 23, the stop rod B37 and the stop rod A36 are driven to reciprocate up and down, the stop rod B37 and the stop rod A36 are driven to reciprocate up and down, the rotation of the threaded sleeve 3 drives the rotating plate 33 to rotate, the rotating plate 33 drives the fan plate 34 to rotate, the rotation of the fan plate 34 realizes stirring of liquid in the cavity of the tank body 1, and the liquid in the cavity of the tank body 1 can better contact with the anode 11 and the cathode 12 by accelerating the liquid to pass through the diaphragm 13, so that the reaction efficiency is accelerated, the rotation of the fan plate 34 drives the hard bristles 35 to rotate, the rotation of the hard bristles 35 can rub the outer walls of the anode 11 and the cathode 12, so that dirt and dirt on the anode 11 and the cathode 12 are cleaned, and the working efficiency of the anode 11 and the cathode 12 is improved, the limiting rod B37 of the invention drives the linkage plate 4 to do up-and-down reciprocating motion, the linkage plate 4 drives the expansion plate 41 and the cleaning plate 42 to do up-and-down reciprocating motion, the cleaning plate 42 drives the soft brush bristles 43 to do continuous friction contact with the outer wall of the diaphragm 13, thereby realizing the removal of dirt on the outer wall of the diaphragm 13 and dirt in liquid, finally realizing the removal of water scale on the diaphragm 13, avoiding the problem that the dirt is blocked due to the long-term work of the diaphragm 13, improving the working efficiency of the anion exchange membrane solid electrolyte electrolytic cell of the invention, eliminating the need of cleaning the diaphragm 13 by periodical disassembly, reducing the labor intensity of workers, improving the service life of the diaphragm 13, and also improving the electrolytic efficiency of the anion exchange membrane solid electrolyte electrolytic cell, under the magnetic pole repulsion action of the permanent magnet A59 and the shaking rod 61, the cleaning plate 42 and the soft brush bristles 43 can be closely close to the outer wall of the diaphragm 13, so that the contact friction force between the soft brush bristles 43 and the outer wall of the diaphragm 13 is increased, and the efficiency of the invention for cleaning the diaphragm 13 in a reciprocating manner is improved.
The foregoing shows and describes the general principles and broad features of the present invention and advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (9)
1. The utility model provides an adopt anion exchange membrane solid state electrolyte electrolysis trough device, includes cell body (1), and positive pole (11) and negative pole (12) are installed respectively to the cell body (1) intracavity left and right sides, and cell body (1) intracavity middle part fixed mounting has diaphragm (13), its characterized in that: guide mechanisms (2) are respectively arranged between the anode (11) and the diaphragm (13) and between the cathode (12) and the diaphragm (13), each guide mechanism (2) comprises a waterproof motor (21) and a shield (22), the waterproof motor (21) is fixedly arranged on the front side wall surface of the shield (22), the output end of the waterproof motor (21) movably penetrates through the front side wall surface of the shield (22) through a bearing, the output end of the waterproof motor (21) is fixedly connected with a rotating rod (24), the rear end of the rotating rod (24) is movably arranged in the rear side wall surface of the shield (22) through a bearing, threaded columns (23) which are distributed at equal intervals are rotatably connected to the top of the shield (22), helical gears B (26) are respectively and fixedly arranged at one ends of the threaded columns (23) which are positioned in the cavities of the shields (22), helical gears A (25) which correspond to the helical gears B (26) in position are fixedly arranged on the outer wall of the rotating rod (24), the bevel gear A (25) is meshed with the bevel gear B (26), limiting plates (27) are fixedly mounted at the tops of the threaded columns (23), threaded sleeves (28) are connected to the outer walls of the threaded columns (23) in a threaded mode, guide columns (38) and threaded rods (29) corresponding to the threaded columns (23) in the left and right directions are fixedly mounted on the wall surface of the inner bottom of the cavity of the tank body (1), the guide columns (38) are located on one side close to the diaphragm (13), and the threaded rods (29) are located on one side close to the corresponding anode (11) and the corresponding cathode (12);
the outer wall of the threaded rod (29) is in threaded connection with a threaded cylinder (3), one side, close to the threaded cylinder (3), of the threaded sleeve (28) is fixedly provided with a limiting rod A (36), one end, far away from the threaded sleeve (28), of the limiting rod A (36) is fixedly provided with a rotating ball (31), the rotating ball (31) is movably arranged on the annular outer wall of the threaded cylinder (3), the bottom wall surface of the threaded cylinder (3) is fixedly provided with the rotating ball (31), the annular outer wall of the rotating ball (31) is fixedly provided with a fan plate (34), the arc-shaped outer wall of the fan plate (34) is fixedly provided with hard bristles (35) capable of rotating and washing the anode (11) and the cathode (12), one side, close to the guide column (38), of the threaded sleeve (28) is fixedly provided with a limiting rod B (37), one end, far away from the threaded sleeve (28), of the limiting rod B (37) is provided with a limiting groove (39), the guide post (38) movably penetrates through the limiting groove (39), a linkage plate (4) is fixedly mounted on one side wall face, close to the diaphragm (13), of the limiting groove (39), a telescopic expansion plate (41) capable of stretching is arranged on one side wall face, close to the diaphragm (13), of the linkage plate (4), a cleaning plate (42) is arranged on one side wall face, close to the diaphragm (13), of the expansion plate (41), and soft bristles (43) capable of performing friction cleaning on the outer wall of the diaphragm (13) are fixedly mounted on one side wall face, close to the diaphragm (13), of the cleaning plate (42).
2. A solid state electrolyte cell apparatus employing anion exchange membranes as claimed in claim 1 wherein: the rotating groove (32) is formed in the annular outer wall of the threaded cylinder (3), the rotating groove (32) is annular, the rotating ball (31) is movably clamped in the rotating groove (32), the fan plates (34) are fan-shaped, the number of the fan plates (34) on the outer wall of each rotating plate (33) is two, the fan plates (34) on the two rotating plates (33) are in a mutually symmetrical state, and the hard brush bristles (35) are uniformly distributed on the arc-shaped outer walls of the fan plates (34).
3. A solid state electrolyte cell apparatus employing anion exchange membranes as claimed in claim 1 wherein: two sets of telescopic link (5) from top to bottom are fixed to be installed on the one side inner wall of diaphragm (13) is kept away from in spacing groove (39), and fixed mounting has guide ball (52) on the side wall face that telescopic link (5) are close to guide post (38), offers on the side wall face that guide post (38) are close to telescopic link (5) and erects groove (53) with guide ball (52) position correspondence.
4. A solid state electrolyte cell apparatus employing anion exchange membranes according to claim 3 wherein: the guide balls (52) are movably clamped in the vertical grooves (53), and the outer walls of the two telescopic rods (5) are sleeved with the supporting springs (51).
5. A solid state electrolyte cell apparatus employing anion exchange membranes as claimed in claim 1 wherein: expansion plate (41) activity block is in linkage plate (4) is close to a lateral wall face of diaphragm (13), link plate (4) are close to and have seted up spout (58) in a lateral wall face of diaphragm (13), fixed mounting has slide (57) on the lateral wall face of diaphragm (13) is kept away from in expansion plate (41), and slide (57) activity block is in spout (58), the outer wall activity of expansion plate (41) runs through a lateral wall face that linkage plate (4) are close to diaphragm (13), the inner wall fixed mounting of spout (58) has twiddle pole (61), fixed mounting has permanent magnet A (59) on the lateral wall face that slide (57) are close to twiddle pole (61).
6. The solid state electrolyte cell apparatus using anion exchange membrane according to claim 5, wherein: the shaking rod (61) is annular, and the magnetic poles of the shaking rod (61) and the permanent magnet A (59) are the same.
7. The solid state electrolyte cell apparatus using anion exchange membrane according to claim 5, wherein: permanent magnet A (59) keep away from on the lateral wall face of diaphragm (13) fixed mounting have permanent magnet B (6), and the inner wall of shaking pole (61), linkage plate (4) and gag lever post B (37) is run through in the activity of permanent magnet B (6), and permanent magnet B (6) keep away from the one end of diaphragm (13) and stretch into in spacing groove (39), has seted up stroke groove (55) on the lateral wall face that guide post (38) are close to diaphragm (13).
8. A solid state electrolyte cell apparatus employing anion exchange membranes according to claim 7 wherein: one end, far away from the diaphragm (13), of the permanent magnet B (6) is located in the stroke groove (55), a linkage ball (54) is fixedly mounted at one end, located in the cavity of the stroke groove (55), of the permanent magnet B (6), and the linkage ball (54) is limited in the stroke groove (55).
9. A solid state electrolyte cell apparatus employing anion exchange membranes according to claim 7 wherein: the inner wall of the stroke groove (55) is fixedly provided with rubber bulges (56) which are distributed at equal intervals up and down, and the rubber bulges (56) are in an arc-shaped bulge state.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110791771.7A CN113512734B (en) | 2021-07-13 | 2021-07-13 | Solid electrolyte electrolytic tank device adopting anion exchange membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110791771.7A CN113512734B (en) | 2021-07-13 | 2021-07-13 | Solid electrolyte electrolytic tank device adopting anion exchange membrane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113512734A true CN113512734A (en) | 2021-10-19 |
| CN113512734B CN113512734B (en) | 2023-07-25 |
Family
ID=78067033
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110791771.7A Active CN113512734B (en) | 2021-07-13 | 2021-07-13 | Solid electrolyte electrolytic tank device adopting anion exchange membrane |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113512734B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114807972A (en) * | 2022-05-27 | 2022-07-29 | 广东卡沃罗氢科技有限公司 | Electrolytic tank structure for producing hydrogen by electrolyzing pure water |
| CN114855200A (en) * | 2022-04-13 | 2022-08-05 | 四川帝威能源技术有限公司 | Water electrolysis hydrogen plant protector |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB191011693A (en) * | 1910-05-11 | 1911-06-12 | Jean Billiter | Improvements in or relating to the Electrolysis of Liquids. |
| GB735372A (en) * | 1952-01-31 | 1955-08-17 | Titan Co Inc | Improvements in or relating to a new or improved electrolytic cell of the diaphragm type |
| JP2005334694A (en) * | 2004-05-24 | 2005-12-08 | Okayama Prefecture | Electrolytic water producer |
| CN108114955A (en) * | 2018-02-02 | 2018-06-05 | 赵鹏飞 | A kind of cleaning device of container inner wall |
| CN109173532A (en) * | 2018-09-29 | 2019-01-11 | 嘉兴学院 | A kind of electric automatization cleaner |
| CN110404894A (en) * | 2019-07-30 | 2019-11-05 | 贵州成黔科技开发有限公司 | A kind of electrode apparatus for eliminating sludge |
| CN111468448A (en) * | 2018-10-26 | 2020-07-31 | 桂兆林 | Descaling equipment and method for square mahjong mat |
| CN111807479A (en) * | 2020-09-03 | 2020-10-23 | 山东龙安泰环保科技有限公司 | Solid electrolyte electrolytic tank device adopting anion exchange membrane |
| CN111805666A (en) * | 2020-07-16 | 2020-10-23 | 张辉 | Wood board coloring cleaning device based on bevel gear transmission |
| CN212895002U (en) * | 2020-08-13 | 2021-04-06 | 四川帝威能源技术有限公司 | Safety protection device of water electrolysis hydrogen production device |
-
2021
- 2021-07-13 CN CN202110791771.7A patent/CN113512734B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB191011693A (en) * | 1910-05-11 | 1911-06-12 | Jean Billiter | Improvements in or relating to the Electrolysis of Liquids. |
| GB735372A (en) * | 1952-01-31 | 1955-08-17 | Titan Co Inc | Improvements in or relating to a new or improved electrolytic cell of the diaphragm type |
| JP2005334694A (en) * | 2004-05-24 | 2005-12-08 | Okayama Prefecture | Electrolytic water producer |
| CN108114955A (en) * | 2018-02-02 | 2018-06-05 | 赵鹏飞 | A kind of cleaning device of container inner wall |
| CN109173532A (en) * | 2018-09-29 | 2019-01-11 | 嘉兴学院 | A kind of electric automatization cleaner |
| CN111468448A (en) * | 2018-10-26 | 2020-07-31 | 桂兆林 | Descaling equipment and method for square mahjong mat |
| CN110404894A (en) * | 2019-07-30 | 2019-11-05 | 贵州成黔科技开发有限公司 | A kind of electrode apparatus for eliminating sludge |
| CN111805666A (en) * | 2020-07-16 | 2020-10-23 | 张辉 | Wood board coloring cleaning device based on bevel gear transmission |
| CN212895002U (en) * | 2020-08-13 | 2021-04-06 | 四川帝威能源技术有限公司 | Safety protection device of water electrolysis hydrogen production device |
| CN111807479A (en) * | 2020-09-03 | 2020-10-23 | 山东龙安泰环保科技有限公司 | Solid electrolyte electrolytic tank device adopting anion exchange membrane |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114855200A (en) * | 2022-04-13 | 2022-08-05 | 四川帝威能源技术有限公司 | Water electrolysis hydrogen plant protector |
| CN114855200B (en) * | 2022-04-13 | 2023-08-22 | 四川帝威能源技术有限公司 | Water electrolysis hydrogen plant protector |
| CN114807972A (en) * | 2022-05-27 | 2022-07-29 | 广东卡沃罗氢科技有限公司 | Electrolytic tank structure for producing hydrogen by electrolyzing pure water |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113512734B (en) | 2023-07-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN113512734B (en) | Solid electrolyte electrolytic tank device adopting anion exchange membrane | |
| CN211413063U (en) | Quartz groove convenient to clearance | |
| CN111807479B (en) | Solid electrolyte electrolytic tank device adopting anion exchange membrane | |
| CN113521855A (en) | Impurity filtering device for industrial sewage treatment | |
| CN212053514U (en) | Energy-concerving and environment-protective type warmhouse booth machine of removing snow | |
| CN212143794U (en) | Glass test tube's belt cleaning device | |
| CN211897122U (en) | Metal surface treatment device | |
| CN210495379U (en) | Drainage device for water area treatment | |
| CN211897123U (en) | Surface treatment device for metal shell of electronic product | |
| CN216918645U (en) | Water floating pond for spunlace circulating water treatment device | |
| CN214653852U (en) | Inclined plate sedimentation tank convenient to clean | |
| CN215745182U (en) | Be used for honeysuckle efficient belt cleaning device | |
| CN115318689A (en) | Dustproof device and dustproof method for computer | |
| CN215232299U (en) | Scraper mechanism of inclined plate sedimentation tank | |
| CN113617763A (en) | New material research and development is with supplementary cleaning device of experiment pond inside | |
| CN215560720U (en) | Ion membrane of zero polar distance electrolytic bath | |
| CN220559888U (en) | Recovery device for positive electrode and negative electrode plate of wet battery | |
| CN114481283B (en) | Electrolytic rust removing device for hardware | |
| CN114983268B (en) | Automatic cleaning device for inner wall of door frame | |
| CN220111746U (en) | Cleaning device after anodic oxidation groove processing | |
| CN219951238U (en) | Quantitative water supplementing mechanism for water electrolysis hydrogen production equipment | |
| CN217857689U (en) | Barrel-plating self-cleaning device | |
| CN213707849U (en) | Domestic wastewater treatment device | |
| CN218795440U (en) | Quick blending instrument for injection | |
| CN218372547U (en) | Chemical electrolytic tank |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |