CN113475797A - Mask with sterilization function - Google Patents
Mask with sterilization function Download PDFInfo
- Publication number
- CN113475797A CN113475797A CN202110886850.6A CN202110886850A CN113475797A CN 113475797 A CN113475797 A CN 113475797A CN 202110886850 A CN202110886850 A CN 202110886850A CN 113475797 A CN113475797 A CN 113475797A
- Authority
- CN
- China
- Prior art keywords
- mask
- fiber
- sterilization
- product
- function according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 25
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 24
- 239000000835 fiber Substances 0.000 claims abstract description 31
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 22
- 241000234314 Zingiber Species 0.000 claims abstract description 19
- 235000006886 Zingiber officinale Nutrition 0.000 claims abstract description 19
- 235000008397 ginger Nutrition 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002657 fibrous material Substances 0.000 claims abstract description 14
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 11
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 11
- 239000011259 mixed solution Substances 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 9
- -1 sodium triacetoxyborohydride Chemical compound 0.000 claims abstract description 9
- 239000012321 sodium triacetoxyborohydride Substances 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 229920002413 Polyhexanide Polymers 0.000 claims abstract description 5
- 239000004760 aramid Substances 0.000 claims abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 238000003763 carbonization Methods 0.000 claims description 4
- 238000010000 carbonizing Methods 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims 7
- 238000000605 extraction Methods 0.000 claims 1
- 239000000047 product Substances 0.000 abstract description 7
- 238000005406 washing Methods 0.000 abstract description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 6
- VFLDPWHFBUODDF-FCXRPNKRSA-N curcumin Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 abstract description 6
- 239000004332 silver Substances 0.000 abstract description 6
- 229910052709 silver Inorganic materials 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 238000001914 filtration Methods 0.000 abstract description 5
- 239000004148 curcumin Substances 0.000 abstract description 3
- 229940109262 curcumin Drugs 0.000 abstract description 3
- 235000012754 curcumin Nutrition 0.000 abstract description 3
- VFLDPWHFBUODDF-UHFFFAOYSA-N diferuloylmethane Natural products C1=C(O)C(OC)=CC(C=CC(=O)CC(=O)C=CC=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-UHFFFAOYSA-N 0.000 abstract description 3
- 150000002357 guanidines Chemical class 0.000 abstract description 3
- 239000002245 particle Substances 0.000 abstract description 3
- 239000012467 final product Substances 0.000 abstract description 2
- 230000002035 prolonged effect Effects 0.000 abstract description 2
- RXGSAYBOEDPICZ-UHFFFAOYSA-N 2-[6-[[amino-(diaminomethylideneamino)methylidene]amino]hexyl]-1-(diaminomethylidene)guanidine Chemical compound NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)N RXGSAYBOEDPICZ-UHFFFAOYSA-N 0.000 description 3
- 238000007873 sieving Methods 0.000 description 3
- 244000005700 microbiome Species 0.000 description 2
- 206010011409 Cross infection Diseases 0.000 description 1
- 206010029803 Nosocomial infection Diseases 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
- A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
- A41D13/1192—Protective face masks, e.g. for surgical use, or for use in foul atmospheres with antimicrobial agent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
Abstract
The invention belongs to the technical field of articles for daily use, and particularly relates to a mask with a sterilization function. The filtering layer of the mask takes ginger stalk fibers and aramid fibers as matrixes to obtain fiber materials, then the fiber materials are immersed into a mixed solution of silver nitrate and polyhexamethylene biguanide hydrochloride, sodium triacetoxyborohydride is added, and stirring reaction is carried out; and after the reaction is finished, washing the product by deionized water, dispersing the product in water, and making the product into a sheet-shaped base material. According to the invention, the curcumin, the guanidine salt and the silver act together, and the three synergistically improve the sterilization and bacteriostasis effects of the mask; the ginger stalk fiber and the aramid fiber are used in a matching way, so that the degradability of the final product is improved, and the strength of the product is ensured; because the fiber has adsorbability, more generated silver particles can be adsorbed on the surface of the fiber, the time for sterilization and bacteriostasis is prolonged, and the effects of sterilization and bacteriostasis are enhanced.
Description
Technical Field
The invention belongs to the technical field of articles for daily use, particularly relates to a mask with a sterilization function, and belongs to the technical field of articles for daily use.
Background
The mask has the function of blocking harmful gas, smell, spray, virus and other substances, and is a daily product of people at present. The existing mask mainly aims at filtration, but the mask does not have the sterilization or disinfection function, microorganisms attached to the mask or microorganisms in the mask can continuously survive for several hours, and the possibility of cross infection is greatly enhanced, so that the mask with the sterilization function needs to be researched.
Disclosure of Invention
Aiming at the problems, the invention provides the mask with the sterilization function, and the mask obtained by adopting the mask is degradable and has strong sterilization and bacteriostasis effects.
The mask with the sterilization function is characterized in that the filter layer of the mask is obtained by the following steps:
(1) mixing ginger stalk fiber and aramid fiber, and carbonizing to produce fiber material with carbon as main fiber;
(2) immersing the fiber material into a mixed solution of silver nitrate and polyhexamethylene biguanide hydrochloride, then adding sodium triacetoxyborohydride, and stirring for reaction;
(3) after the reaction is finished, the product is washed by deionized water and then dispersed in water to be made into a sheet-shaped base material, namely a filter layer of the mask.
The ginger stalk fiber is obtained by extracting ginger stalks.
The mass ratio of the ginger stalk fibers to the aramid fibers is 1: 1-5.
The carbonization temperature in the step (1) is 200-220 ℃, and the carbonization time is 2 h.
In the mixed solution in the step (2), the mass ratio of silver nitrate to polyhexamethylene biguanide hydrochloride is 1: 1-2.
In the step (2), the mass ratio of the fiber material to the mixed solution is 1: 1-5.
In the step (2), the mass of the sodium triacetoxyborohydride is 1-10 times of that of the silver nitrate.
In the step (2), the reaction temperature is 20-30 ℃, and the reaction time is 10-12 h.
In the step (3), the quantitative of the paper making is 20-30g/m2Of (2) a sheet-based material.
After the filter layer of the mask is obtained, the mask can be processed into the mask according to the technical means known in the field.
According to the invention, the ginger stalk fibers obtained by extracting ginger stalks contain curcumin, so that the ginger stalk fibers have the functions of sterilization and bacteriostasis, have high aramid fiber strength and can be used as a base material. The guanidine salt in the step (2) has the functions of sterilization and bacteriostasis, and silver generated after the reaction of the silver nitrate and the sodium triacetoxyborohydride also has the functions of sterilization and bacteriostasis. Because the fiber has certain adsorbability, the generated tiny silver particles can be attached to the surface of the fiber, and further, sufficient sterilization and bacteriostasis are ensured.
Compared with the prior art, the invention has the following beneficial effects:
(1) in the invention, the curcumin, the guanidine salt and the silver act together, and the three synergistically improve the sterilization and bacteriostasis effects of the mask.
(2) The ginger stalk fiber and the aramid fiber are used in a matching way, so that the degradability of the final product is improved, and the strength of the product is ensured.
(3) Because the fiber has adsorbability, more generated silver particles can be adsorbed on the surface of the fiber, the time for sterilization and bacteriostasis is prolonged, and the effects of sterilization and bacteriostasis are enhanced.
Detailed Description
Example 1
A mask with a sterilization function is characterized in that a filter layer of the mask is obtained by the following steps:
(1) the ginger stalk fiber extracted from 100g of ginger stalk and the aramid fiber are mixed and carbonized for 2 hours at 200 ℃ to partially separate out volatile components, and a fiber material with carbon as the main surface and fiber as the whole is generated.
(2) Dissolving 100g of silver nitrate and 100g of hexamethylene biguanide hydrochloride in 1000g of water, then adding 100g of sodium triacetoxyborohydride, adding the fiber material into the mixed solution, stirring and reacting at 20 ℃ for 12 hours, and filtering to obtain the mixed fiber.
(3) Fully washing the mixed fiber with deionized water, dispersing in water according to the concentration of 0.5% after three times of washing, and sieving with a 200-mesh sieve to obtain 30g/m2The sheet material is used as a filter layer of the mask.
After the filter layer of the mask is obtained, the mask can be processed into the mask according to the technical means known in the field.
Example 2
A mask with a sterilization function is characterized in that a filter layer of the mask is obtained by the following steps:
(1) the fiber extracted from 100g of ginger stalk and 250g of aramid fiber are mixed and carbonized for 2 hours at 210 ℃ to partially separate out volatile matters, and a fiber material with the surface mainly made of carbon and the whole fiber is generated.
(2) Dissolving 420g of silver nitrate and 630g of hexamethylene biguanide hydrochloride in 1000g of water, then adding 2100g of sodium triacetoxyborohydride, adding the fiber material into the mixed solution, stirring and reacting for 10 hours at 30 ℃, and filtering to obtain mixed fibers;
(3) fully washing the mixed fiber with deionized water, dispersing in water according to the concentration of 0.5% after three times of washing, and sieving with a 200-mesh sieve to obtain 20g/m2The sheet material is used as a filter layer of the mask.
After the filter layer of the mask is obtained, the mask can be processed into the mask according to the technical means known in the field.
Example 3
A mask with a sterilization function is characterized in that a filter layer of the mask is obtained by the following steps:
(1) the ginger stalk fiber extracted from 100g of ginger stalk is mixed with 500g of aramid fiber and carbonized for 2 hours at 220 ℃ to partially separate out volatile components, and a fiber material with carbon as the main surface and fiber as the whole is generated.
(2) Dissolving 1000g of silver nitrate and 2000g of hexamethylene biguanide hydrochloride in 1000g of water, then adding 2000g of sodium triacetoxyborohydride, adding the fiber material into the mixed solution, stirring for 12 hours at 25 ℃ for reaction, and filtering to obtain the mixed fiber.
(3) Fully washing the mixed fiber with deionized water, dispersing in water according to the concentration of 0.5% after three times of washing, and sieving with a 200-mesh sieve to obtain 30g/m2The sheet material is used as a filter layer of the mask.
After the filter layer of the mask is obtained, the mask can be processed into the mask according to the technical means known in the field.
Claims (9)
1. The mask with the sterilization function is characterized in that the filter layer of the mask is obtained by the following steps:
(1) mixing ginger fiber and aramid fiber, and carbonizing to generate a fiber material with the surface mainly made of carbon and integrally made of fiber;
(2) immersing the fiber material into a mixed solution of silver nitrate and polyhexamethylene biguanide hydrochloride, then adding sodium triacetoxyborohydride, and stirring for reaction;
(3) after the reaction is finished, the product is washed by deionized water and then dispersed in water to be made into a sheet-shaped base material, namely a filter layer of the mask.
2. The mask with bactericidal function according to claim 1, wherein the ginger fiber is obtained by ginger stalk extraction.
3. The mask with the sterilization function according to claim 1, wherein the mass ratio of the ginger stalk fibers to the aramid fibers is 1: 1-5.
4. The mask with bactericidal function as claimed in claim 1, wherein the carbonization temperature in step (1) is 200 ℃ to 220 ℃ and the carbonization time is 2 h.
5. The mask with the bactericidal function according to claim 1, wherein the mass ratio of the silver nitrate to the polyhexamethylene biguanide hydrochloride in the mixed solution of the step (2) is 1: 1-2.
6. The mask with the bactericidal function according to claim 1, wherein in the step (2), the mass ratio of the fiber material to the mixed solution is 1: 6-12.
7. The mask with a bactericidal function according to claim 1, wherein in the step (2), the mass of the sodium triacetoxyborohydride is 1 to 10 times of the mass of the silver nitrate.
8. The mask with bactericidal function according to claim 1, wherein in the step (2), the reaction temperature is 20-30 ℃ and the reaction time is 10-12 h.
9. The mask with bactericidal function according to claim 1, wherein in the step (3), the paper is made into a fixed amount of 20-30g/m2Of (2) a sheet-based material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110886850.6A CN113475797A (en) | 2021-08-03 | 2021-08-03 | Mask with sterilization function |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110886850.6A CN113475797A (en) | 2021-08-03 | 2021-08-03 | Mask with sterilization function |
Publications (1)
Publication Number | Publication Date |
---|---|
CN113475797A true CN113475797A (en) | 2021-10-08 |
Family
ID=77945282
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202110886850.6A Pending CN113475797A (en) | 2021-08-03 | 2021-08-03 | Mask with sterilization function |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113475797A (en) |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101171929A (en) * | 2007-10-19 | 2008-05-07 | 无锡汇罗新材料科技有限公司 | Method for preparing nano silver antimicrobials |
CN101731268A (en) * | 2008-11-17 | 2010-06-16 | 尖端奈米科技股份有限公司 | Nano silver porous material and manufacturing method thereof |
CN101731272A (en) * | 2009-12-24 | 2010-06-16 | 中国人民解放军军事医学科学院基础医学研究所 | Method for preparing antibacterial nanometer silver colloid |
CN104826250A (en) * | 2015-05-24 | 2015-08-12 | 阳运崎 | Long-acting sterilization pocket type multi-purpose replaceable filter element mask and mask filtering piece |
CN106758216A (en) * | 2016-12-02 | 2017-05-31 | 辽东学院 | A kind of processing method of antibacterial, uvioresistant bafta |
CN107455822A (en) * | 2017-09-12 | 2017-12-12 | 江苏纳纤新材料科技有限公司 | A kind of nanofiber micrometer fibers compound anti-mist haze mouth mask |
CN111235643A (en) * | 2020-03-20 | 2020-06-05 | 四川竹芊芊生物科技有限公司 | Method for extracting Chinese herbal medicine plant fiber |
CN111226993A (en) * | 2020-03-25 | 2020-06-05 | 华南理工大学 | Long-acting antibacterial and virucidal sanitary protective product spray and application thereof |
CN111713779A (en) * | 2020-06-30 | 2020-09-29 | 佛山市优特医疗科技有限公司 | Protective mask |
-
2021
- 2021-08-03 CN CN202110886850.6A patent/CN113475797A/en active Pending
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101171929A (en) * | 2007-10-19 | 2008-05-07 | 无锡汇罗新材料科技有限公司 | Method for preparing nano silver antimicrobials |
CN101731268A (en) * | 2008-11-17 | 2010-06-16 | 尖端奈米科技股份有限公司 | Nano silver porous material and manufacturing method thereof |
CN101731272A (en) * | 2009-12-24 | 2010-06-16 | 中国人民解放军军事医学科学院基础医学研究所 | Method for preparing antibacterial nanometer silver colloid |
CN104826250A (en) * | 2015-05-24 | 2015-08-12 | 阳运崎 | Long-acting sterilization pocket type multi-purpose replaceable filter element mask and mask filtering piece |
CN106758216A (en) * | 2016-12-02 | 2017-05-31 | 辽东学院 | A kind of processing method of antibacterial, uvioresistant bafta |
CN107455822A (en) * | 2017-09-12 | 2017-12-12 | 江苏纳纤新材料科技有限公司 | A kind of nanofiber micrometer fibers compound anti-mist haze mouth mask |
CN111235643A (en) * | 2020-03-20 | 2020-06-05 | 四川竹芊芊生物科技有限公司 | Method for extracting Chinese herbal medicine plant fiber |
CN111226993A (en) * | 2020-03-25 | 2020-06-05 | 华南理工大学 | Long-acting antibacterial and virucidal sanitary protective product spray and application thereof |
CN111713779A (en) * | 2020-06-30 | 2020-09-29 | 佛山市优特医疗科技有限公司 | Protective mask |
Non-Patent Citations (1)
Title |
---|
张美云: "《加工纸与特种纸》", 31 January 2010, 中国轻工业出版社 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107617119A (en) | A kind of delicate fragrance type sterilizing environmental protection air purifying preparation | |
CN106179247B (en) | A kind of Cr VI adsorbent and its preparation method and application | |
CN107952416B (en) | Shell powder chitosan composite microsphere for adsorbing heavy metals and preparation method thereof | |
CN104790262A (en) | Activated carbon filter paper, and preparation method and application thereof | |
KR102209425B1 (en) | Method for manufacturing deodorant using multiple function water containing minerals and deodorant manufactured by the same | |
CN112933741A (en) | Antibacterial filtering fabric and preparation method thereof | |
CN107670647B (en) | Method for preparing heavy metal ion adsorbent by using camellia oleifera shells | |
CN109012617A (en) | A kind of medicament and preparation method thereof going heavy metal ion in water removal | |
CN111235871A (en) | Antiviral filter layer prepared from copper-containing chitosan fiber and application thereof | |
CN111996796A (en) | Antibacterial and mildewproof plant traditional Chinese medicine composition, modified fibrilia and preparation method thereof | |
CN113475797A (en) | Mask with sterilization function | |
CN107720976A (en) | A kind of composition to purify water | |
CN104525138A (en) | Preparation method of novel cellulose adsorbent | |
CN105836821B (en) | A kind of dedicated sewage-treating agent of chemical fibre industry and preparation method thereof | |
CN111939877A (en) | Method for preparing adsorbent for methylene blue and organophosphorus pesticide residues in water body by using tea leaves, prepared adsorbent and application | |
CN111772263A (en) | Mask manufacturing method and mask manufactured by same | |
CN111513386A (en) | Health-care mask capable of resisting and killing virus | |
CN105969827A (en) | Method for removing fishy smell from enzymatic hydrolysate of fish protein | |
CN110965358A (en) | Negative oxygen ion mask processing technology | |
CN115584565A (en) | Slurry for spinning of fungi grass and preparation method and application thereof | |
KR20200064724A (en) | Method for Manufacturing Chamaecyparis Obtuse Water Using Zeolite and Charcoal | |
CN104383894A (en) | Filtering material with high adsorptivity for gauze mask and preparation method thereof | |
CN109251256B (en) | Modified cyclodextrin and application thereof in composite antibacterial deodorant liquid | |
CN110158175B (en) | Bamboo charcoal slurry for viscose stock solution spinning and preparation method thereof | |
KR101130175B1 (en) | Method of fabricating a porous chitosan filter for purification of water |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211008 |
|
RJ01 | Rejection of invention patent application after publication |