CN113465999A - Tidal zone soil ammonia volatilization's normal position capture device - Google Patents

Tidal zone soil ammonia volatilization's normal position capture device Download PDF

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Publication number
CN113465999A
CN113465999A CN202110749822.XA CN202110749822A CN113465999A CN 113465999 A CN113465999 A CN 113465999A CN 202110749822 A CN202110749822 A CN 202110749822A CN 113465999 A CN113465999 A CN 113465999A
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ammonia
water level
wind speed
sleeve
capture device
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白军红
王亚琪
陈国柱
张光亮
王伟
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Beijing Normal University
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Beijing Normal University
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/24Suction devices
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01DMEASURING NOT SPECIALLY ADAPTED FOR A SPECIFIC VARIABLE; ARRANGEMENTS FOR MEASURING TWO OR MORE VARIABLES NOT COVERED IN A SINGLE OTHER SUBCLASS; TARIFF METERING APPARATUS; MEASURING OR TESTING NOT OTHERWISE PROVIDED FOR
    • G01D21/00Measuring or testing not otherwise provided for
    • G01D21/02Measuring two or more variables by means not covered by a single other subclass

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  • General Physics & Mathematics (AREA)
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  • Life Sciences & Earth Sciences (AREA)
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  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The invention provides an in-situ capture device for ammonia volatilization of soil in tidal zone, which comprises: water level and wind speed sensing device, ammonia normal position capture device includes: the waterproof barrel is connected with the sleeve through a screw lifting assembly; the cover body is arranged above the waterproof cylinder body, a water level signal receiver is arranged on the bottom surface of the cover body and is in communication connection with the water level and wind speed sensing device, and the water level signal receiver is connected with the screw lifting assembly through a water level transmission line; sponge and ammonia absorption bottle are set up to the inside upper and lower interval of sleeve, and ammonia absorption bottle embeds ammonia nitrogen analysis appearance probe, and ammonia nitrogen analysis appearance probe links to each other with microcircuit control unit, and microcircuit control unit installs on telescopic inside wall, and microcircuit control unit and cloud service platform communication are connected. By adopting the technical scheme, the accuracy of the measurement result is improved, ammonia does not need to be leached again, and the measurement process is simpler.

Description

Tidal zone soil ammonia volatilization's normal position capture device
Technical Field
The invention relates to the technical field of ecological environment detection of tidal zones, in particular to an in-situ capturing device for ammonia volatilization of soil in tidal zones.
Background
Ammonia volatilization is an important way for nitrogen nutrition loss, and ammonia entering the atmosphere can enter a natural ecological system again along with dry and wet sedimentation, so that the nitrogen content in soil and water is increased, and a series of environmental problems such as water eutrophication, soil acidification, biological diversity reduction and the like are caused. The ammonia volatilization process is not only influenced by the physical and chemical properties of soil such as pH, cation exchange capacity and the like, but also closely related to natural environmental factors such as illumination, temperature, moisture, wind speed and the like. Due to the rise and fall of tidal water, a narrow and long zone is repeatedly located between the high tide line and the low tide line near the sea-land boundary line, and the narrow and long zone is called as a tidal zone. The tidal zone has more frequent water level fluctuation and more variable weather has more influence on the accurate determination of the ammonia volatilization of the soil.
In the related art, the common collection method for ammonia volatilization adopts a ventilation method in many cases. The sampling device is made of a polyvinyl chloride hard plastic pipe, and two pieces of sponges uniformly soaked in a phosphoglycerol solution (a mixed aqueous solution of 5% phosphoric acid and 4% glycerol) are respectively placed in the plastic pipe at a certain distance. During sampling measurement, the sponge at the lower layer of the sampling device is taken out and is completely immersed into 300mL of KCl solution (1mol/L), oscillation is carried out for 1h, and the content of ammonium nitrogen in the leaching solution is measured by an indophenol blue colorimetric method. The following technical drawbacks exist:
(1) the sampling device is directly exposed in the air, so that the upper sponge layer is often influenced by the sedimentation process of the rain, snow and other atmosphere, and if the sampling device is applied to the tidal zone and other areas which are easily influenced by water level fluctuation, the seawater carrying exogenous impurities flows backwards into the ventilating device, so that the accuracy of the measuring result is influenced;
(2) during measurement, ammonia needs to be leached again, the leaching liquor in the sponge needs to be extruded by means of a tool, the operation is complicated, and measurement errors are easy to cause;
(3) the sponge soaked in the glycerol phosphate solution is easy to slide in the plastic tube, and the continuity of the sampling process and the stability of the measuring result are seriously influenced.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art or the related art.
Therefore, the invention aims to provide the in-situ capturing device for ammonia volatilization of soil in the tidal zone, which is simple in structure, can be networked to realize automatic control, can avoid interference of precipitation of atmospheric air such as rain, snow and the like, and can automatically adjust the height according to the water level change of the tidal zone to prevent seawater from flowing backward to enter the ammonia capturing device. This volatile normal position capture device of soil ammonia is taken to morning and evening tides has reduced the influence of environmental change to ammonia collection process to a certain extent, has improved the accuracy of testing result, need not to leach again to ammonia moreover, and the testing process is comparatively simple. The tidal zone soil ammonia volatilization in-situ capturing device can detect the captured ammonia concentration in real time, and transmits the obtained detection data to the cloud service platform through the microcircuit control unit, so that the times of experimenters to sampling places are reduced, and the experiment efficiency is improved.
In order to achieve the purpose, the technical scheme of the invention provides an in-situ capture device for ammonia volatilization of soil in a tidal zone, which comprises: water level and wind speed sensing device, ammonia normal position capture device includes: the waterproof barrel is sleeved outside the sleeve and is connected with the sleeve through a screw lifting assembly; the cover body is arranged above the waterproof cylinder body and connected with the waterproof cylinder body through a support column, a water level signal receiver is arranged on the bottom surface of the cover body and is in communication connection with the water level and wind speed sensing device, and the water level signal receiver is connected with the screw lifting assembly through a water level transmission line; sponge and ammonia absorption bottle are set up to the inside upper and lower interval of sleeve, ammonia absorption bottle embeds ammonia nitrogen analysis appearance probe, ammonia nitrogen analysis appearance probe links to each other with microcircuit control unit, microcircuit control unit installs on the telescopic inside wall, microcircuit control unit and cloud service platform communication are connected.
In this scheme, through sleeve and waterproof barrel cooperation setting, through the relative position height of screw rod lifting unit control waterproof barrel and sleeve, can prevent effectively that rising tide water from entering into in the ammonia normal position capture device. The top of waterproof barrel sets up the lid, has played the effect of keeping out the wind and keeping out the rain to a certain extent, and simultaneously, the bottom surface installation water level signal receiver of lid can receive the water level signal of sending by water level and wind speed sensing device, and water level signal receiver passes through the water level transmission line with screw rod lifting unit and links to each other, and screw rod lifting unit can adjust the height of waterproof barrel in advance according to water level signal, reduces the tidal zone comparatively frequent water level fluctuation and to the volatile accurate survey influence of soil ammonia. Through setting up sponge and ammonia absorption bottle at the inside upper and lower interval of sleeve, the built-in ammonia nitrogen analysis appearance probe of ammonia absorption bottle, can the ammonia concentration in the direct detection ammonia absorption bottle, and transmit the testing result to cloud service platform through little circuit control unit, the usable computer remote monitoring of experimenter or utilize the mobile phone to use the inquiry, make things convenient for the experimenter at any time, record the experimental data everywhere, need not to leach again ammonia during the survey, and easy operation has not only improved the experimental efficiency, and the measuring error has been reduced, the accuracy and the stability of measuring result are all better.
Specifically, the water level and wind speed sensing device is arranged at the lower part of an ammonia in-situ capturing device in seawater in a tidal area close to the shore and is fixed at the position 5cm away from the surface soil of the tidal zone. When the tide water rises, the water level and wind speed sensing device transmits a water level signal to the water level signal receiver, and the water level signal receiver rises the waterproof barrel through the screw lifting assembly, so that the accompanying tide water is prevented from entering the ammonia gas collecting sleeve, and the interference to an experimental result is caused. The volatile ammonia of soil permeates the ammonia absorption bottle and is absorbed by the absorption liquid, and the ammonia nitrogen analysis appearance probe of installation can directly detect the ammonia concentration in the ammonia absorption bottle to transmit the testing result to cloud service platform through microcircuit control unit.
Preferably, a wind speed signal receiver is installed on the top surface of the cover body, the wind speed signal receiver is in communication connection with the water level and wind speed sensing device, a roller shutter assembly is installed around the cover body, and the roller shutter assembly comprises: the roller shutter axle that the cooperation set up with roll up the curtain, the one end of rolling up the roller shutter axle links to each other with rolling up the curtain motor, roll up the curtain motor with wind speed signal receiver passes through the wind speed transmission line and links to each other, roll up the curtain motor control roll up the rotation of curtain axle and thus the height of adjusting roll curtain.
In this scheme, the wind speed signal receiver of installation on the lid top surface can receive the wind speed signal who is sent by water level and wind speed sensing device, and wind speed signal receiver passes through the wind speed transmission line and links to each other with rolling up the curtain motor, thereby it can be according to the rotatory height of adjusting the roll curtain of wind speed signal control roll curtain axle to roll up the curtain motor to prevent rain, snow edgewise entering ammonia normal position trapping apparatus, ensured that the sampling process is difficult for receiving the interference of open-air environment, further ensured experimental data's accuracy.
Preferably, the water level and wind speed sensing apparatus includes: fixing a column; the signal emitter is arranged on the fixed column; the wind speed detector is arranged above the signal transmitter and is connected with the signal transmitter; the water level detector is arranged below the signal transmitter through a bearing steel wire and is connected with the signal transmitter; the protective shell is arranged below the signal transmitter, and the water level detector is sleeved in the protective shell; the signal transmitter is in communication connection with the water level signal receiver and the wind speed signal receiver.
In this scheme, can install water level and wind speed sensing device in the regional sea water of morning and evening tides through the fixed column, signal transmitter can transmit water level, the wind speed data that wind speed detector, water level detector measured in real time to ammonia normal position capture device's water level signal receiver and wind speed signal receiver respectively. The water level detector is installed below the signal transmitter through the bearing steel wire, the balance stability is good, the protective shell is sleeved outside the water level detector, the stability and the accuracy of water level detection are guaranteed, and seawater corrosion and damage to the water level and wind speed sensing device caused by microorganism adhesion can be effectively prevented. The protective casing is made of monel.
Specifically, the signal emitter, the water level signal receiver, the wind speed signal receiver are built in with the network communication module that the microcircuit controller electricity is connected, and the signal emitter can be networked with water level signal receiver, wind speed signal receiver, carries out the transmission of water level, wind speed data.
Preferably, the screw elevating assembly includes: screw rod elevator motor and fixed block that the cooperation set up, one of screw rod elevator motor and fixed block is installed on the lateral wall of waterproof barrel, and another is installed on telescopic lateral wall, screw rod elevator motor with the fixed block passes through the screw rod and links to each other, screw rod elevator motor with water level signal receiver passes through the water level transmission line and links to each other, screw rod elevator motor passes through the screw rod adjustment waterproof barrel for telescopic height.
The screw rod lifting motor is generally installed on the outer side wall of the waterproof cylinder body so as to be connected with a water level signal receiver installed on the bottom surface of the cover body.
Preferably, an upper layer of supporting block and a lower layer of supporting block are fixedly installed on the inner side wall of the sleeve, the circular plate is fixed inside the sleeve through the lower layer of supporting block, the ammonia gas absorption bottle is located below the circular plate, and a bottle opening of the ammonia gas absorption bottle is connected with the inner circle of the circular plate to form a circular cap shape.
In this scheme, fixed firm nature of ring board, ammonia absorption bottle is better, is difficult for landing downwards.
Preferably, the ammonia gas absorption bottle is a Goerts fabric absorption bottle, the ammonia gas absorption bottle is filled with a glycerol phosphate absorption liquid, the circular ring plate is an organic glass circular ring plate, the outer diameter of a bottle opening of the ammonia gas absorption bottle is equal to the inner diameter of the circular ring plate, the outer diameter of the circular ring plate is equal to the inner diameter of the sleeve, and the ammonia nitrogen analyzer probe is arranged on the side wall of the ammonia gas absorption bottle close to the bottom of the bottle.
In this scheme, the ammonia absorption bottle contains a large amount of phosphoric acid glycerine solution, and the lateral wall is close to bottle bottom department and installs ammonia nitrogen analyzer probe, can directly detect the ammonia concentration in the absorption bottle, and the ammonia absorption bottle is Goerts fabric absorption bottle, and waterproof ventilation function is better, can be so that the volatile ammonia of soil sees through the bottle and is absorbed by the absorption liquid.
Preferably, the sponge is soaked with a glycerol sulfate solution and fixed inside the sleeve through an upper layer of supporting block, and the sponge is placed above the ammonia gas absorption bottle.
Preferably, the diameter of the sponge is equal to the inner diameter of the sleeve.
In this scheme, the sponge is soaked with the sulfuric acid glycerine solution, fixes in telescopic inside through upper supporting shoe, and the diameter of sponge equals with telescopic internal diameter, is difficult for landing downwards.
Preferably, the upper and lower two-layer supporting block comprises 6 same horizontal triangle organic glass boards, wherein, upper strata supporting block, lower floor's supporting block comprise 3 same horizontal triangle organic glass boards along circumference evenly distributed respectively.
In this scheme, upper supporting shoe, lower floor's supporting shoe comprise 3 same horizontal triangle organic glass boards along circumference to evenly distributed respectively, can provide comparatively even holding power for sponge, ring board, have ensured the balanced steadiness of sponge, ring board, make it difficult downward landing.
Preferably, the sleeve, the waterproof cylinder and the protective shell are all stainless steel pieces, and the surfaces of the sleeve, the waterproof cylinder and the protective shell are coated with anticorrosive paint.
In this scheme, sleeve, waterproof barrel, protection casing are stainless steel spare to brushing anticorrosive paint on the surface, can effectively prevent that sea water from corroding and the microorganism adheres to the damage to sampling device.
The in-situ capturing device for ammonia volatilization of soil in tidal zone provided by the invention has the following beneficial technical effects:
(1) the in-situ capturing device for ammonia volatilization of soil in tidal zone is used for monitoring ammonia volatilization of tidal zone, has smart and simple structure, convenient operation and use and important practical application value, can effectively prevent seawater, rain and snow from entering an ammonia gas collecting container, improves the accuracy of experimental data, can realize automatic control and improves the experimental efficiency.
(2) Utilize water level detector monitoring water level change condition, carry out the transmission of water level data through signal transmitter, water level signal receiver, according to water level data control screw rod elevator motor, utilize screw rod elevator motor to adjust the height of waterproof barrel in advance, prevent that rising tide water from getting into ammonia normal position trapping apparatus to reduce the tidal zone comparatively frequent water level fluctuation and to the volatile accurate survey influence of soil ammonia, promote survey accuracy and stability.
(3) The wind speed detector is used for detecting the wind speed change condition, the signal transmitter and the water level signal receiver are used for transmitting wind speed data, the roller shutter motor is controlled according to the wind speed data, the roller shutter shaft is rotated by the roller shutter motor to adjust the height of the roller shutter in advance, the ammonia gas collecting device can be protected from being influenced by the dry and wet sedimentation process of the atmosphere such as rain, snow and the like, the interference of field environmental factors is reduced, and the accuracy of an experimental result is improved.
(4) The ammonia absorption bottle contains a large amount of phosphoric acid glycerine solution, and the lateral wall is close to bottle bottom department and installs ammonia nitrogen analysis appearance probe, can the ammonia concentration in the direct detection absorption bottle to transmit the testing result to cloud service platform through little circuit control unit, make things convenient for the experimenter at any time, take notes experimental data everywhere, need not to leach again ammonia during the survey, and easy operation has not only improved experimental efficiency, has reduced the determination error moreover, and the accuracy and the stability of determination result are all better.
(5) The sleeve, the waterproof cylinder and the protective shell are all stainless steel parts, and the surface of the sleeve is coated with anticorrosive paint, so that seawater corrosion and damage to the sampling device caused by microorganism adhesion can be effectively prevented.
Additional aspects and advantages of the invention will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the invention.
Drawings
The above and/or additional aspects and advantages of the present invention will become apparent and readily appreciated from the following description of the embodiments, taken in conjunction with the accompanying drawings of which:
FIG. 1 shows a schematic structural diagram of an ammonia in-situ capture device according to one embodiment of the invention;
figure 2 shows a water level and wind speed sensing device according to one embodiment of the present invention,
wherein, the corresponding relation between the reference numbers and the components in fig. 1 and fig. 2 is as follows:
10 ammonia gas in-situ capturing device, 102 sleeve, 104 waterproof cylinder, 106 screw lifting component, 1062 screw lifting motor, 1064 fixed block, 1066 screw, 108 cover body, 110 support column, 112 water level signal receiver, 114 water level transmission line, 116 sponge, 118 ammonia gas absorption bottle, 120 ammonia nitrogen analyzer probe, 122 microcircuit control unit, 124 wind speed signal receiver, 126 rolling curtain component, 1262 rolling curtain shaft, 1264 rolling curtain, 1266 rolling curtain motor, 128 upper layer support block, 130 lower layer support block, 132 circular ring plate and 134 wind speed transmission line;
20 water level and wind speed sensing device, 202 fixed column, 204 signal emitter, 206 wind speed detector, 208 water level detector, 210 bearing steel wire, 212 protection shell.
Detailed Description
In order that the above objects, features and advantages of the present invention can be more clearly understood, a more particular description of the invention will be rendered by reference to the appended drawings. It should be noted that the embodiments and features of the embodiments of the present application may be combined with each other without conflict.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention, however, the present invention may be practiced in other ways than those specifically described herein, and therefore the scope of the present invention is not limited by the specific embodiments disclosed below.
An in-situ capture device for ammonia volatilization of soil in tidal zones according to an embodiment of the invention is specifically described below with reference to fig. 1 and 2.
Referring to fig. 1 and 2, the in-situ capture device for ammonia volatilization in soil in a tidal zone according to the embodiment of the invention comprises a water level and wind speed sensing device 20 and an ammonia in-situ capture device 10. As shown in fig. 2, the ammonia gas in-situ capturing device 10 includes a sleeve 102, a waterproof cylinder 104, a screw 1066 lifting assembly 106, a cover 108, a water level signal receiver 112, a wind speed signal receiver 124, a roller shutter assembly 126, and the like. The waterproof cylinder 104 is sleeved outside the sleeve 102, the waterproof cylinder 104 and the sleeve 102 are both stainless steel pieces, and anticorrosive paint is coated on the surfaces of the waterproof cylinder 104 and the sleeve 102, so that seawater corrosion and damage to the sampling device caused by microorganism adhesion can be effectively prevented. The screw lifting motor 1062 is installed on the outer side wall of the waterproof cylinder 104, the fixing block 1064 is installed on the outer side wall of the sleeve 102, the screw lifting motor 1062 adjusts the height of the waterproof cylinder 104 through the screw 1066, and one end of the screw 1066 is fixed on the outer side wall of the sleeve 102 through the fixing block 1064. The cover body 108 is square, and is connected above the waterproof cylinder body 104 by 4 support columns 110 with equal length, and the support columns 110 are organic glass columns. A water level signal receiver 112 is installed on the bottom surface of the cover 108, the water level signal receiver 112 is in communication connection with the water level and wind speed sensing device 20, and the water level signal receiver 112 is connected with the screw lifting motor 1062 through a water level transmission line 114. The water level and wind speed sensing device 20 transmits water level data to the water level signal receiver 112 in a network mode, the water level signal receiver 112 controls the opening and closing of the screw lifting motor 1062 through the water level transmission line 114 according to the water level data, and the screw lifting motor 1062 can raise the height of the waterproof cylinder 104 through the screw 1066 before the tide water flows to the ammonia gas capturing device. Sponge 116 and ammonia absorption bottle 118 are set up to the inside upper and lower interval of sleeve 102, ammonia absorption bottle 118 embeds ammonia nitrogen analysis appearance probe 120, ammonia nitrogen analysis appearance probe 120 links to each other with microcircuit control unit 122, microcircuit control unit 122 is installed on the inside wall of sleeve 102, microcircuit control unit 122 is connected with cloud service platform communication, ammonia nitrogen analysis appearance probe 120 can transmit detected data to cloud service platform through microcircuit control unit 122, the usable computer remote monitoring of experimenter or utilize the inquiry of cell-phone application, make things convenient for the experimenter at any time, record experimental data everywhere, need not to leach again ammonia during the survey, moreover, the steam generator is simple in operation, the experimental efficiency has been improved, and the determination error has been reduced, the accuracy and the stability of determination result are all better.
Further, as shown in fig. 2, the wind speed signal receiver 124 is installed on the top surface of the cover 108, the roller blind assembly 126 is installed around the cover 108, the cover 108 has a square shape, a set of roller blind assemblies 126 is installed on each side, the roller blind assemblies 126 include a roller blind shaft 1262, a roller blind 1264 and a roller blind motor 1266, and one end of the roller blind shaft 1262 is connected to the roller blind motor 1266. The wind speed signal receiver 124 is communicatively connected to the water level and wind speed sensing device 20. The wind speed signal receiver 124 controls the roller shutter motor 1266 to rotate and lift the roller shutter 1264 through the wind speed transmission line 134 according to the wind speed data, so that rain and snow are prevented from entering the ammonia in-situ capturing device 10 from the side, the sampling process is not easily interfered by the field environment, and the accuracy of experimental data is further guaranteed.
Further, as shown in fig. 2, the ammonia gas absorption bottle 118 is a golts fabric absorption bottle, the ammonia gas absorption bottle 118 contains glycerol phosphate absorption liquid, and is waterproof and breathable, and the ammonia nitrogen analyzer probe 120 is installed at a position, close to the bottom of the bottle, of the side wall of the ammonia gas absorption bottle 118, and can transmit detection data to the cloud service platform through the microcircuit control unit 122. Two-layer supporting shoe about sleeve 102 inside wall fixed mounting, ring board 132 is fixed in sleeve 102's inside through lower floor's supporting shoe 130, ring board 132 is the organic glass ring, ammonia absorption bottle 118 is in the below of ring board 132 and the bottleneck of ammonia absorption bottle 118 is connected with the interior circle of ring board 132 and is the round cap form, the bottleneck external diameter of ammonia absorption bottle 118 equals the internal diameter of ring board 132, the external diameter of ring board 132 equals the internal diameter of sleeve 102, ammonia absorption bottle 118 installs firmly and is difficult for the landing. The sponge 116 soaked with the glycerol sulfate solution is placed above the ammonia gas absorption bottle 118, the sponge 116 is fixed inside the sleeve 102 through an upper layer of supporting blocks 128, and the diameter of the sponge 116 is equal to the inner diameter of the sleeve 102 and is not easy to slide.
Further, as shown in fig. 2, the upper and lower two-layer supporting blocks are composed of 6 same horizontal triangular organic glass plates, wherein the upper layer supporting block 128 and the lower layer supporting block 130 are respectively composed of 3 same horizontal triangular organic glass plates uniformly distributed along the circumferential direction. Can provide comparatively even holding power for sponge 116, ring plate 132, ensure the balanced steadiness of sponge 116, ring plate 132, make it difficult downward landing.
Further, as shown in fig. 1, the water level and wind speed sensing apparatus 20 includes: a fixed column 202, a signal emitter 204, a wind speed detector 206, a water level detector 208, a protective housing 212, and the like. The signal emitter 204 is installed on the fixed column 202, the signal emitter 204 is connected with the water level detector 208 through the bearing steel wire 210, the water level detector 208 is located below the signal emitter 204, and the wind speed detector 206 is installed above the signal emitter 204. The water level detector 208 is externally sleeved with a protective shell 212, the protective shell 212 is installed below the signal emitter 204, and the protective shell is made of Monel alloy. The signal transmitter 204 is connected with the water level signal receiver 112 and the wind speed signal receiver 124 in a communication way. When the tide rises or the wind speed increases, the signal transmitter 204 transmits the data measured by the water level detector 208 and the wind speed detector 206 in real time to the water level signal receiver 112 and the wind speed signal receiver 124 of the ammonia in-situ capturing device 10 in a networking manner.
The height of the waterproof cylinder 104 may be adjusted by manually controlling the screw lifting motor 1062, and the roller shade 1264 may be adjusted by manually controlling the roller shade motor 1266.
The use process of the in-situ capturing device for ammonia volatilization of soil in tidal zone provided by the invention is as follows:
the water level and wind speed sensing device 20 is installed in seawater close to the shore, the lower part of the ammonia in-situ capturing device 10 is fixed at the position 5cm away from the soil layer of the surface layer of the tidal zone, and the bottom surface of the ammonia absorption bottle 118 is 6cm away from the soil layer. When the tide water rises, the water level detector 208 transmits a water level signal to the water level signal receiver 112 through the signal transmitter 204, and the water level signal receiver 112 raises the waterproof cylinder 104 through the screw lifting motor 1062, so as to prevent the tide water from entering the ammonia gas collecting sleeve 102 to interfere with the experimental result. The weather of rain and snow in the tidal zone area is often windy, when the wind speed of the tidal zone is high, the wind speed detector 206 transmits the wind speed signal to the wind speed signal receiver 124 through the signal transmitter 204, and the wind speed signal receiver 124 lowers the roller shutter 1264 through the roller shutter motor 1266, so that the precipitation of the atmosphere such as rain and snow is prevented from being blown into the ammonia gas collecting sleeve 102 by wind, and the safety of the experimental device and the accuracy of the experimental result are ensured. In the ammonia collection process, the volatile ammonia of soil sees through the bottle of ammonia absorption bottle 118 and is absorbed by the absorption liquid, and the ammonia analysis appearance probe of installation at the bottom of the bottle can directly detect the ammonia concentration in the ammonia absorption bottle 118 to transmit the testing result to cloud service platform through microcircuit control unit 122, make things convenient for the experimenter to look over the testing result, reduce the manual liquid operation of getting, improve experimental efficiency.
In the present invention, the terms "first", "second", and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance; the term "plurality" means two or more unless expressly limited otherwise. The terms "mounted," "connected," "fixed," and the like are to be construed broadly, and for example, "connected" may be a fixed connection, a removable connection, or an integral connection; "coupled" may be direct or indirect through an intermediary. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
In the description of the present invention, it is to be understood that the terms "upper", "lower", "left", "right", "front", "rear", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplification of description, but do not indicate or imply that the referred device or unit must have a specific direction, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention.
In the description herein, the description of the terms "one embodiment," "some embodiments," "specific embodiments," etc., means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. An in-situ capture device for ammonia volatilization of soil in tidal zone, which is characterized by comprising: water level and wind speed sensing device, ammonia normal position capture device includes:
the waterproof barrel is sleeved outside the sleeve and is connected with the sleeve through a screw lifting assembly;
the cover body is arranged above the waterproof cylinder body and connected with the waterproof cylinder body through a support column, a water level signal receiver is arranged on the bottom surface of the cover body and is in communication connection with the water level and wind speed sensing device, and the water level signal receiver is connected with the screw lifting assembly through a water level transmission line;
sponge and ammonia absorption bottle are set up to the inside upper and lower interval of sleeve, ammonia absorption bottle embeds ammonia nitrogen analysis appearance probe, ammonia nitrogen analysis appearance probe links to each other with microcircuit control unit, microcircuit control unit installs on the telescopic inside wall, microcircuit control unit and cloud service platform communication are connected.
2. The tidal zone soil ammonia volatilization in situ capture device as set forth in claim 1,
the top surface of lid installs wind speed signal receiver, wind speed signal receiver with water level and wind speed sensing device communication connection, the curtain subassembly is rolled up in the installation all around of lid, it includes to roll up the curtain subassembly: the roller shutter axle that the cooperation set up with roll up the curtain, the one end of rolling up the roller shutter axle links to each other with rolling up the curtain motor, roll up the curtain motor with wind speed signal receiver passes through the wind speed transmission line and links to each other, roll up the curtain motor control roll up the rotation of curtain axle and thus the height of adjusting roll curtain.
3. The tidal zone soil ammonia volatilization in situ capture device as set forth in claim 1, wherein the water level and wind speed sensing device comprises:
fixing a column;
the signal emitter is arranged on the fixed column;
the wind speed detector is arranged above the signal transmitter and is connected with the signal transmitter;
the water level detector is arranged below the signal transmitter through a bearing steel wire and is connected with the signal transmitter;
the protective shell is arranged below the signal transmitter, and the water level detector is sleeved in the protective shell;
the signal transmitter is in communication connection with the water level signal receiver and the wind speed signal receiver.
4. The tidal belt soil ammonia volatilization in situ capture device of claim 1, wherein the screw lifting assembly comprises:
screw rod elevator motor and fixed block that the cooperation set up, one of screw rod elevator motor and fixed block is installed on the lateral wall of waterproof barrel, and another is installed on telescopic lateral wall, screw rod elevator motor with the fixed block passes through the screw rod and links to each other, screw rod elevator motor with water level signal receiver passes through the water level transmission line and links to each other, screw rod elevator motor passes through the screw rod adjustment waterproof barrel for telescopic height.
5. The tidal zone soil ammonia volatilization in situ capture device as set forth in claim 1,
the inner side wall of the sleeve is fixedly provided with an upper layer of supporting block and a lower layer of supporting block, the circular plate is fixed inside the sleeve through the lower layer of supporting block, the ammonia gas absorption bottle is located below the circular plate, and a bottle opening of the ammonia gas absorption bottle is connected with the inner circle of the circular plate to form a circular cap shape.
6. The tidal zone soil ammonia volatilization in situ capture device as set forth in claim 5,
the ammonia gas absorption bottle is a Golters fabric absorption bottle, the ammonia gas absorption bottle is filled with a glycerol phosphate absorption liquid, the circular ring plate is an organic glass circular ring plate, the outer diameter of the bottle mouth of the ammonia gas absorption bottle is equal to the inner diameter of the circular ring plate, the outer diameter of the circular ring plate is equal to the inner diameter of the sleeve,
the ammonia nitrogen analyzer probe is arranged on the side wall of the ammonia gas absorption bottle close to the bottom of the ammonia gas absorption bottle.
7. The tidal zone soil ammonia volatilization in situ capture device as set forth in claim 5,
the sponge is soaked with a glycerol sulfate solution and fixed inside the sleeve through an upper layer of supporting block, and the sponge is placed above the ammonia gas absorption bottle.
8. The tidal zone soil ammonia volatilization in situ capture device as set forth in claim 7,
the diameter of the sponge is equal to the inner diameter of the sleeve.
9. The tidal zone soil ammonia volatilization in situ capture device as set forth in claim 5,
the upper and lower two-layer supporting shoe comprises 6 same horizontal triangle organic glass boards, wherein, upper strata supporting shoe, lower floor's supporting shoe comprise 3 same horizontal triangle organic glass boards along circumference evenly distributed respectively.
10. The tidal zone soil ammonia volatilization in situ capture device as set forth in claim 3,
the sleeve, the waterproof barrel and the protection shell are all stainless steel pieces, and the surface of the sleeve is coated with anticorrosive paint.
CN202110749822.XA 2021-07-01 2021-07-01 Tidal zone soil ammonia volatilization's normal position capture device Pending CN113465999A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118031135A (en) * 2024-04-15 2024-05-14 吉林大学 Ocean platform combustible gas leaks with detector of patrolling and examining

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118031135A (en) * 2024-04-15 2024-05-14 吉林大学 Ocean platform combustible gas leaks with detector of patrolling and examining
CN118031135B (en) * 2024-04-15 2024-06-11 吉林大学 Ocean platform combustible gas leaks with detector of patrolling and examining

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