CN113461398A - Geomagnetic functional negative oxygen ion material for motor home and indoors and preparation process thereof - Google Patents
Geomagnetic functional negative oxygen ion material for motor home and indoors and preparation process thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/16—Disinfection, sterilisation or deodorisation of air using physical phenomena
- A61L9/22—Ionisation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60H—ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
- B60H3/00—Other air-treating devices
- B60H3/0071—Electrically conditioning the air, e.g. by ionizing
- B60H3/0078—Electrically conditioning the air, e.g. by ionizing comprising electric purifying means
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/30—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by ionisation
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00422—Magnetic properties
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Abstract
The invention provides a geomagnetic functional negative oxygen ion material for a recreational vehicle and a room and a preparation process thereof, wherein every 1500mL of ethanol aqueous solution in the negative oxygen ion material comprises 0.4-0.6 kg of negative oxygen ion powder, 1.2-1.4 kg of tourmaline powder, 1.4-1.6 kg of gypsum powder, 1.4-1.6 kg of kaolin, 0.01-0.03 kg of graphene powder, 0.6-0.8 kg of calcined kaolin, 0.4-0.6 kg of Huanghe jade powder, 0.3-0.7 kg of palmite powder, 0.3-0.7 kg of opal powder and 0.04-0.06 kg of citric acid.
Description
Technical Field
The invention relates to the technical field of building functional materials, in particular to a geomagnetic functional negative oxygen ion material for motor homes and rooms and a preparation process thereof.
Background
The motor home is commonly called as 'home on wheels', has two functions of a house and a vehicle, and is a movable vehicle type with essential basic facilities at home. Along with the continuous improvement of living standard of people, the air quality requirement of a relatively closed place is also continuously improved, and the air quality is easy to have a larger difference due to small air flow phase in the space of a motor home.
At present, in order to improve and improve the indoor air quality of a motor home, an air purifier and the like are usually loaded, but the release of common negative oxygen ions is low, the release concentration of the indoor negative oxygen ions is unstable, and the aim of well and effectively cleaning and purifying air is difficult to achieve. And the existing liquid negative oxygen ion coating is difficult to be effectively used in the interior of the caravan and has high cost due to the limitation of the special environment-friendly material structure of the interior wall body of the caravan. Therefore, the solid negative oxygen ion material applicable to the interior of the caravan is provided, so that the design and the placement of carriers according to different caravans and indoor rooms can be facilitated, and the aim of continuously keeping the release concentration of high negative oxygen ions in the caravan can be fulfilled.
Disclosure of Invention
Therefore, the invention provides a geomagnetic functional negative oxygen ion material suitable for motor homes and rooms and a preparation process thereof.
The technical scheme of the invention is realized as follows:
every 1500mL of ethanol aqueous solution comprises 0.4-0.6 kg of negative oxygen ion powder, 1.2-1.4 kg of tourmaline powder, 1.4-1.6 kg of gypsum powder, 1.4-1.6 kg of kaolin, 0.01-0.03 kg of graphene powder, 0.6-0.8 kg of calcined kaolin, 0.4-0.6 kg of Huanghe jade powder, 0.3-0.7 kg of Bama stone powder, 0.3-0.7 kg of opal powder and 0.04-0.06 kg of citric acid.
More preferably, every 1500mL of ethanol water solution comprises 0.5kg of negative oxygen ion powder, 1.3kg of tourmaline powder, 1.5kg of gypsum powder, 1.5kg of kaolin, 0.02kg of graphene powder, 0.7kg of calcined kaolin, 0.5kg of Huangheyu powder, 0.5kg of palmite powder, 0.5kg of opal powder and 0.05kg of citric acid. Wherein the kaolin is conventional uncalcined kaolin.
A preparation method of a geomagnetic functional negative oxygen ion material for motor homes and rooms comprises the following steps:
step 1: adding the Bama stone powder and the opal powder into an ethanol aqueous solution according to a ratio, wherein the addition amount of the ethanol aqueous solution is 30-35% of the total amount, and soaking for 15-30 minutes to obtain a magnetic ionization mixture;
step 2: adding graphene powder into the magnetic ionization mixture, and standing for 20-30 minutes to obtain an ionization reactant I;
and step 3: adding yellow river jade powder, tourmaline powder and the balance of ethanol aqueous solution into the ionized reactant I, uniformly stirring, then adding kaolin, negative oxygen ion powder and citric acid, stirring for reacting for 8-12 minutes, and then standing for reacting for 25-35 minutes to obtain an ionized reactant II;
and 4, step 4: adding calcined kaolin and gypsum powder into the ionization reactant II, and stirring to be thick to obtain an ionization reactant III;
and 5: putting the ionized reactant III into a mould, beating and leveling;
step 6: and adding putty powder and plaster mixed by ethanol water solution on the surface of the ionization reactant III, leveling, standing and solidifying to obtain the geomagnetic functional negative oxygen ion material.
Further, the mass concentration of the ethanol water solution is 80-90%.
Further, in the step 1, the particle size of the palmite powder and the opal powder is 200-1000 meshes.
Further, in the step 3, the particle sizes of the Huanghe jade powder and the tourmaline powder are 200-1000 meshes.
Further, in the step 4, the mass ratio of the ionization reactant III, the putty powder and the plaster mixed by the alcohol-water solution is 1:5: 5.
Further, the mass ratio of the ethanol water solution to the plaster in the ethanol water solution blended plaster is 1: 3.
Compared with the prior art, the invention has the beneficial effects that: the geomagnetic functional negative oxygen ion material for motor homes and rooms is prepared by forming a magnetic ionization state by using Bama stone powder and opal powder in an ethanol water solution, combining a trace amount of graphene to form a sufficient ionization reaction, simultaneously adding Huanghe jade powder, tourmaline powder, kaolin and negative oxygen ion powder to effectively compound, effectively blending calcined kaolin and gypsum powder to form the geomagnetic functional negative oxygen ion material, mixing the solid negative oxygen ion material with putty powder and plaster to form the solid negative oxygen ion material, and controlling the temperature of the solid negative oxygen ion material to be 50-65 ℃ for roomsIn the car, the negative oxygen ions in the car as a house can stably reach 6000/m on average under the action of a certain flowing magnetic field3The release concentration is more than 20 times higher than that of the outdoor space to adapt to the requirement of adjusting the balance of positive and negative charges of the human body; simultaneously, this solid-state earth magnetism functional negative oxygen ion material can carry out carrier design and place the design according to different car as a house and room bedroom, and transportation, arrangement are simple and convenient, the use amount of the graphite alkene that has significantly reduced compares the wall body of traditional negative oxygen ion coating and whitewashes the transformation moreover, and negative oxygen ion release is stable, and is high to human security, health care nature and suitability, and cost saving benefit is obvious.
Detailed Description
In order to better understand the technical content of the invention, specific examples are provided below to further illustrate the invention.
The experimental methods used in the examples of the present invention are all conventional methods unless otherwise specified.
The materials, reagents and the like used in the examples of the present invention can be obtained commercially without specific description.
Example 1
The geomagnetic functional negative oxygen ion material for the motor home and the interior comprises 1500mL of ethanol water solution, 0.4kg of negative oxygen ion powder, 1.2kg of tourmaline powder, 1.4kg of gypsum powder, 1.4kg of kaolin, 0.01kg of graphene powder, 0.6kg of calcined kaolin, 0.4kg of Huanghe jade powder, 0.3kg of palmite powder, 0.3kg of opal powder and 0.04kg of citric acid.
Example 2
The geomagnetic functional negative oxygen ion material for the motor home and the interior comprises 1500mL of ethanol water solution, 0.6kg of negative oxygen ion powder, 1.4kg of tourmaline powder, 1.6kg of gypsum powder, 1.6kg of kaolin, 0.03kg of graphene powder, 0.8kg of calcined kaolin, 0.6kg of Huanghe jade powder, 0.7kg of palmite powder, 0.7kg of opal powder and 0.06kg of citric acid.
Example 3
The geomagnetic functional negative oxygen ion material for the motor home and the interior comprises 1500mL of ethanol water solution, 0.4kg of negative oxygen ion powder, 1.3kg of tourmaline powder, 1.5kg of gypsum powder, 1.5kg of kaolin, 0.02kg of graphene powder, 0.7kg of calcined kaolin, 0.4kg of Huanghe jade powder, 0.4kg of bambusa powder, 0.6kg of opal powder and 0.05kg of citric acid.
The preparation method of the geomagnetic functional negative oxygen ion material for motor homes and rooms in embodiments 1 to 3 includes the following steps:
(1) adding the palmite powder and the opal powder into 80% ethanol water solution which accounts for 33.3% of the total amount of the ethanol solution according to the proportion, and soaking for 15 minutes to obtain a magnetic ionization mixture; the particle size of the palmatine powder and the albumen powder is 200 meshes;
(2) adding graphene powder into the magnetic ionization mixture, and standing for 20 minutes to obtain an ionization reactant I;
(3) adding yellow river jade powder, tourmaline powder and the balance of ethanol aqueous solution into the ionized reactant I, uniformly stirring, adding kaolin, negative oxygen ion powder and citric acid, stirring for reacting for 8 minutes, and standing for reacting for 25 minutes to obtain an ionized reactant II; the particle size of the Huanghe jade powder and the tourmaline powder is 200 meshes;
(4) adding calcined kaolin and gypsum powder as additives into the ionization reactant II, and stirring to be thick to obtain an ionization reactant III;
(5) beating and leveling an ionization reactant III in a wooden material box with the specification of 6 cm in height, 18 cm in width and 30 cm in length;
(6) adding putty powder and plaster mixed by an alcohol-water solution to the surface of the ionization reactant III, wherein the mass ratio of the ionization reactant III to the putty powder to the plaster mixed by the alcohol-water solution is 1:5:5, the mass ratio of the ethanol-water solution to the plaster mixed by the ethanol-water solution is 1:3, leveling, standing and solidifying to obtain the solid geomagnetic functional negative oxygen ion material.
Example 4
The preparation method of the geomagnetic functional negative oxygen ion material for the motor home and indoors comprises the following steps:
(1) weighing the following raw materials in proportion: 0.5kg of negative oxygen ion powder, 1.3kg of tourmaline powder, 1.5kg of gypsum powder, 1.5kg of kaolin, 0.02kg of graphene powder, 0.7kg of calcined kaolin, 0.5kg of Huanghe jade powder, 0.5kg of palmite powder, 0.5kg of opal powder, 0.05kg of citric acid and 1500mL of ethanol;
(2) adding the palmite powder and the opal powder into 90% ethanol aqueous solution with the total ethanol dosage of 35% according to the proportion, and soaking for 30 minutes to obtain a magnetic ionization mixture; the particle size of the palmatine powder and the albumen powder is 600 meshes;
(3) adding graphene powder into the magnetic ionization mixture, and standing for 30 minutes to obtain an ionization reactant I;
(4) adding yellow river jade powder, tourmaline powder and the balance of ethanol aqueous solution into the ionized reactant I, uniformly stirring, adding kaolin, negative oxygen ion powder and citric acid, stirring for reacting for 12 minutes, and standing for reacting for 35 minutes to obtain an ionized reactant II; the particle size of the Huanghe jade powder and the tourmaline powder is 600 meshes;
(5) adding calcined kaolin and gypsum powder as additives into the ionization reactant II, and stirring to be thick to obtain an ionization reactant III;
(6) beating and leveling an ionization reactant III in a wooden material box with the specification of 6 cm in height, 18 cm in width and 30 cm in length;
(7) adding putty powder and plaster mixed by an alcohol-water solution to the surface of the ionization reactant III, wherein the mass ratio of the ionization reactant III to the putty powder to the plaster mixed by the alcohol-water solution is 1:5:5, the mass ratio of the ethanol-water solution to the plaster mixed by the ethanol-water solution is 1:3, leveling, standing and solidifying to obtain the solid geomagnetic functional negative oxygen ion material.
Example 5
The preparation method of the geomagnetic functional negative oxygen ion material for the motor home and indoors comprises the following steps:
(1) weighing the following raw materials in proportion: 0.5kg of negative oxygen ion powder, 1.3kg of tourmaline powder, 1.5kg of gypsum powder, 1.5kg of kaolin, 0.02kg of graphene powder, 0.7kg of calcined kaolin, 0.5kg of Huanghe jade powder, 0.5kg of palmite powder, 0.5kg of opal powder, 0.05kg of citric acid and 1500mL of ethanol;
(2) adding the palmite powder and the opal powder into 90% ethanol aqueous solution with the total ethanol dosage of 35% according to the proportion, and soaking for 20 minutes to obtain a magnetic ionization mixture; the particle size of the palmatine powder and the albumen powder is 1000 meshes;
(3) adding graphene powder into the magnetic ionization mixture, and standing for 25 minutes to obtain an ionization reactant I;
(4) adding yellow river jade powder, tourmaline powder and the balance of ethanol aqueous solution into the ionized reactant I, uniformly stirring, adding kaolin, negative oxygen ion powder and citric acid, stirring for reacting for 10 minutes, and standing for reacting for 30 minutes to obtain an ionized reactant II; the particle size of the Huanghe jade powder and the tourmaline powder is 1000 meshes;
(5) adding calcined kaolin and gypsum powder as additives into the ionization reactant II, and stirring to be thick to obtain an ionization reactant III;
(6) beating and leveling an ionization reactant III in a wooden material box with the specification of 6 cm in height, 18 cm in width and 30 cm in length;
(7) adding putty powder and plaster mixed by an alcohol-water solution to the surface of the ionization reactant III, wherein the mass ratio of the ionization reactant III to the putty powder to the plaster mixed by the alcohol-water solution is 1:5:5, the mass ratio of the ethanol-water solution to the plaster mixed by the ethanol-water solution is 1:3, leveling, standing and solidifying to obtain the solid geomagnetic functional negative oxygen ion material.
Comparative example 1
The method for preparing the geomagnetically functional oxygen anion material according to example 5, except that: the raw material formula is different, the palmite powder is not added, and the added albumen powder is 1 kg.
Comparative example 2
The method for preparing the geomagnetically functional oxygen anion material according to example 5, except that: the raw material formula is different, no Huanghe jade powder is added, and the consumption of the palmite powder and the opal powder is increased by 1 kg.
Comparative example 3
The method for preparing the geomagnetically functional oxygen anion material according to example 5, except that: the raw materials have different formulas, and 0.8kg of negative oxygen ion powder, 1.5kg of tourmaline powder, 2kg of gypsum powder, 1.5kg of kaolin, 0.02kg of graphene powder, 0.7kg of calcined kaolin, 0.1kg of Huanghe jade powder, 0.2kg of palmite powder, 0.8kg of opal powder and 0.05kg of citric acid are added into 1500mL of ethanol aqueous solution.
Comparative example 4
The method for preparing the geomagnetically functional oxygen anion material according to example 5, except that: the preparation method is different, namely, mixing the Bama stone powder, the protein stone powder, the graphene powder, the Huanghe jade powder, the tourmaline powder, the kaolin, the negative oxygen ions and the citric acid according to a proportion, adding 1500mL of ethanol water solution, stirring and reacting for 10 minutes, standing and reacting for 80 minutes, and then adding the calcined kaolin and the gypsum powder to obtain the ionized reactant III.
The different magnetic functional negative oxygen ion materials obtained by the preparation method are subjected to negative oxygen ion release concentration test, a ptc heating plate block is arranged in a wooden material box and is connected to a temperature controller by a 0.5 square insulated wire, so that the materials reach the constant temperature of 50 ℃ and 60 ℃ when in use, the materials are hung and fixed below an air conditioner in a caravan, an air negative (oxygen) ion detector is used for detecting the release concentration of the negative oxygen ions in the caravan, and the measurement results are as follows:
as can be seen from the above table, the geomagnetic functional negative oxygen ion material prepared by the invention can stably release negative oxygen ions with a concentration of 6000 negative oxygen ions/m at a temperature of 50-60 DEG C3Above, wherein the average negative oxygen ion concentration at 60 ℃ can be up to 12120/m3Compared with the comparative examples 1 to 4, the formula and the effective proportion of the negative oxygen ion material are changed in the comparative examples 1 to 3, the release concentration of the negative oxygen ion is obviously reduced, and particularly the concentration is reduced to 6000/m at 50 DEG C3The following; the proportion of the Bama stone powder, the opal powder and the Huanghe jade powder in the negative oxygen ion material is effectively adjusted, so that the negative oxygen ion material has a stable geomagnetic function, and stable release of high-concentration negative oxygen ions under the action of a certain flowing magnetic field is realized; in comparative example 4, the mixing conditions of the raw material formulas of the palmite powder, the opal and the like are changed, and the release concentration of the negative oxygen ions is obviously reduced, which shows that the invention is appliedObviously, the step-by-step ionization treatment is carried out on each raw stone, so that the release of negative oxygen ions at a certain temperature can be promoted.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.
Claims (8)
1. The utility model provides a functional negative oxygen ion material of earth magnetism for car as a house and indoor which characterized in that: every 1500mL of ethanol water solution comprises 0.4-0.6 kg of negative oxygen ion powder, 1.2-1.4 kg of tourmaline powder, 1.4-1.6 kg of gypsum powder, 1.4-1.6 kg of kaolin, 0.01-0.03 kg of graphene powder, 0.6-0.8 kg of calcined kaolin, 0.4-0.6 kg of Huanghe jade powder, 0.3-0.7 kg of palmite powder, 0.3-0.7 kg of opal powder and 0.04-0.06 kg of citric acid.
2. The geomagnetically functional oxygen anion material for a recreational vehicle and a room, according to claim 1, wherein: every 1500mL of ethanol water solution comprises 0.5kg of negative oxygen ion powder, 1.3kg of tourmaline powder, 1.5kg of gypsum powder, 1.5kg of kaolin, 0.02kg of graphene powder, 0.7kg of calcined kaolin, 0.5kg of Huanghe jade powder, 0.5kg of bara powder, 0.5kg of opal powder and 0.05kg of citric acid.
3. The method of claim 1, wherein the method comprises the steps of: the method comprises the following steps:
step 1: adding the Bama stone powder and the opal powder into an ethanol aqueous solution according to a ratio, wherein the addition amount of the ethanol aqueous solution is 30-35% of the total amount, and soaking for 15-30 minutes to obtain a magnetic ionization mixture;
step 2: adding graphene powder into the magnetic ionization mixture, and standing for 20-30 minutes to obtain an ionization reactant I;
and step 3: adding yellow river jade powder, tourmaline powder and the balance of ethanol aqueous solution into the ionized reactant I, uniformly stirring, then adding kaolin, negative oxygen ion powder and citric acid, stirring for reacting for 8-12 minutes, and then standing for reacting for 25-35 minutes to obtain an ionized reactant II;
and 4, step 4: adding calcined kaolin and gypsum powder into the ionization reactant II, and stirring to be thick to obtain an ionization reactant III;
and 5: putting the ionized reactant III into a mould, beating and leveling;
step 6: and adding putty powder and plaster mixed by ethanol water solution on the surface of the ionization reactant III, leveling, standing and solidifying to obtain the geomagnetic functional negative oxygen ion material.
4. The method of claim 1, wherein the method comprises the steps of: the mass concentration of the ethanol water solution is 80-90%.
5. The method of claim 1, wherein the method comprises the steps of: in the step 1, the particle size of the palmite powder and the opal powder is 200-1000 meshes.
6. The method of claim 1, wherein the method comprises the steps of: in the step 3, the particle sizes of the Huanghe jade powder and the tourmaline powder are 200-1000 meshes.
7. The method of claim 1, wherein the method comprises the steps of: in the step 4, the mass ratio of the ionization reactant III, the putty powder and the plaster mixed by the alcohol-water solution is 1:5: 5.
8. The method of claim 1, wherein the method comprises the steps of: the mass ratio of the ethanol water solution to the plaster in the ethanol water solution blended plaster is 1: 3.
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| CN113461398B (en) | 2022-11-08 |
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