CN108821722A - A kind of semidry method Ardealite block and its processing technology - Google Patents

A kind of semidry method Ardealite block and its processing technology Download PDF

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Publication number
CN108821722A
CN108821722A CN201810886428.9A CN201810886428A CN108821722A CN 108821722 A CN108821722 A CN 108821722A CN 201810886428 A CN201810886428 A CN 201810886428A CN 108821722 A CN108821722 A CN 108821722A
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China
Prior art keywords
parts
agent
water
rosemary
semidry method
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CN201810886428.9A
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Chinese (zh)
Inventor
冯宗林
封信超
陈正强
叶其富
何强
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HANFENG DECORATIVE MATERIAL CO Ltd ZUNYI
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HANFENG DECORATIVE MATERIAL CO Ltd ZUNYI
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Priority to CN201810886428.9A priority Critical patent/CN108821722A/en
Publication of CN108821722A publication Critical patent/CN108821722A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/142Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
    • C04B28/143Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being phosphogypsum
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

This programme discloses a kind of semidry method Ardealite block of building material technical field, including raw material and its parts by weight be:950~1000 parts of phosphogypsum powder, 3~8 parts of hydrogen fluoride auxiliary agent, 1~5 part of water-reducing agent, 1~5 part of dispersing agent, 3~8 parts of retarder, 3~8 parts of reinforcing agent.Using in this programme semidry method Ardealite block and its processing technology can significantly reduce the water absorption rate of ardealite and improve its compression strength.

Description

A kind of semidry method Ardealite block and its processing technology
Technical field
The present invention relates to building material technical field, in particular to a kind of semidry method Ardealite block and its processing technology.
Background technique
In the numerous utilization ways of ardealite, only building resource is only the best way for realizing that ardealite largely utilizes Diameter.Ardealite building resourceization is not only big to the consumption amount of ardealite, and no new pollutant generates, and can also reach energy conservation, section The useless purpose of soil, benefit, helps to solve ardealite pollution problem.Presently commercially available Ardealite block water absorption rate 30% or so, And major part is only used for inner wall of building, since its big water absorption rate and application range are narrow, strongly limits Ardealite block Using.Therefore preparation intensity is high, and low water absorption, the Ardealite block of simple production process will greatly improve the utilization of ardealite Rate.
Summary of the invention
It is raw to solve existing Ardealite block the invention is intended to provide a kind of semidry method Ardealite block and its processing technology Water paste ratio is very high during production, and intensity is low, the problem that arid cycle is grown.
One of this programme semidry method Ardealite block and its processing technology, including raw material and its parts by weight be: 950~1000 parts of phosphogypsum powder, 3~8 parts of hydrogen fluoride auxiliary agent, 1~5 part of water-reducing agent, 1~5 part of dispersing agent, 3~8 parts of retarder and 3~8 parts of reinforcing agent.
The beneficial effect of this programme:Water-reducing agent plays the role of enhancing mobility and lubrication;Dispersing agent can increase degranulation Ability reduces time and energy required for completing dispersion process, after ardealite adds water mix, since ardealite granulin molecule draws The effect of power, makes ardealite starch to form flocculent structure, is wrapped in 10%~30% mixing water among ardealite particle, no Free-flowing and lubricating action can be participated in, to affect the mobility of concrete mix;Since diminishing agent molecule can orient It is adsorbed in ardealite particle surface, makes ardealite particle surface with same charge (usually negative electrical charge), forms electrostatic row Reprimand effect, promotes ardealite particle mutually to disperse, and flocculent structure is destroyed, and releases by wrapping portion water, flowing is participated in, to have Effect ground increases the mobility of concrete mix;Retarder reduces ardealite hydration rate and aquation heat, extends setting time; The setting rate and gain in strength rate of reinforcing agent adjustable concrete at different temperatures;Hydrogen fluoride auxiliary agent can assist above-mentioned object Matter gives full play to effectiveness, and reduces the usage amount of mentioned component, reduces mixing time, and rosemary can reduce in air bacterium and micro- Biology, the cilium of Caladium bicolor can adsorb the dust particle in air, effectively purification air, moreover it is possible to increase humidity, sterilizing;Rosemary With Caladium bicolor can reduce ardealite stirring when dust fly upward and mixture in bacterial component.
Further, the raw material further includes:Rosemary and Caladium bicolor, parts by weight are:1~5 part of rosemary and floral leaf 1~5 part of taro.Rosemary can reduce bacterium and microorganism in air, and the cilium of Caladium bicolor can adsorb the dust particle in air, have Effect purification air, moreover it is possible to increase humidity, sterilizing;Dust flying upward and mixing when rosemary and Caladium bicolor can reduce ardealite stirring Close bacterial component in object.
Further, each raw material and its parts by weight are:960 parts of phosphogypsum powder, 4 parts of hydrogen fluoride auxiliary agent, water-reducing agent 5 Part, 1 part of dispersing agent, 3 parts of retarder, 8 parts of reinforcing agent, 2 parts of rosemary and 2 parts of Caladium bicolor.Less fluorine is added into phosphogypsum powder Change hydrogen auxiliary agent, needs to be added more water-reducing agents and reinforcing agent increases mixture mobility, while reducing dispersing agent and slow setting The addition of agent prevents mixture rapid condensation.
Further, each raw material and its parts by weight are:980 parts of phosphogypsum powder, 6 parts of hydrogen fluoride auxiliary agent, water-reducing agent 4 Part, 2 parts of dispersing agent, 5 parts of retarder, 7 parts of reinforcing agent, 3 parts of rosemary and 3 parts of Caladium bicolor.Appropriate fluorine is added into phosphogypsum powder Change hydrogen auxiliary agent, the addition for reducing water-reducing agent can reduce the mobility of mixture.
Further, each raw material and its parts by weight are:1000 parts of phosphogypsum powder, 8 parts of hydrogen fluoride auxiliary agent, water-reducing agent 2 Part, 4 parts of dispersing agent, 6 parts of retarder, 3 parts of reinforcing agent, 5 parts of rosemary and 5 parts of Caladium bicolor.It is added into phosphogypsum powder compared with polyfluoro The usage amount of other compositions can be reduced by changing hydrogen auxiliary agent, can also reduce mixing time.
Further, a kind of processing technology of semidry method Ardealite block includes the following steps:
(1) prepare raw material:Prepare raw material by above-mentioned parts by weight;
(2) Raw material processing:To be added after phosphogypsum powder and hydrogen fluoride auxiliary agent and dispersant phosphogypsum powder weight 30~ 36% water is stood 5~8 minutes, sequentially adds water-reducing agent, retarder, reinforcing agent, rosemary and Caladium bicolor later, will It is put into forced stirrer, stirs 30~60 seconds, obtains mixture;
(3) transfer formation:Said mixture is sent into molding machine, until its molding obtains semidry method Ardealite block.
First water will be added after phosphogypsum powder and hydrogen fluoride auxiliary agent and dispersant, hydrogen fluoride auxiliary agent can reduce the use of water Amount, while dispersing agent is first added and can avoid forming flocculent structure after phosphogypsum powder is directly mixed with water, it is stood, can make to disperse Agent gives full play to effectiveness, adds water-reducing agent, retarder and reinforcing agent later under the action of hydrogen fluoride auxiliary agent, can reduce diminishing Agent, retarder and reinforcing agent dosage.
Further, before rosemary and Caladium bicolor being added, by rosemary and Caladium bicolor, it, which is put into salt water, impregnates 2 hours, dries in the air It is dry, by slag it is mixed after with abrasive wheel be ground to 30~50 microns.Impregnating in salt water can sterilize, and dry and be convenient for after immersion Blend, mixed later with slag, waste material utilization is carried out to slag, slag can increase the intensity of ardealite, with rosemary and Caladium bicolor blends simultaneously can increase coefficient of friction, and reduction blends the time, and increase blends area.
Further, the water-reducing agent is polycarboxylate high performance water-reducing agent.Polycarboxylate high performance water-reducing agent is to cement etc. Many powder body material peptizaitons are good, and cost performance is higher.
Specific embodiment
Below by the further details of explanation of specific embodiment:
Embodiment 1:
A kind of processing technology of semidry method Ardealite block, includes the following steps:
(1) prepare raw material:Each raw material and its parts by weight are:Build 960 parts of phosphogypsum powder, 4 parts of hydrogen fluoride auxiliary agent, poly- carboxylic 5 parts of sour series high-performance dehydragent, 1 part of dispersing agent, 3 parts of retarder, 8 parts of reinforcing agent, 2 parts of rosemary and 2 parts of Caladium bicolor;
(2) Raw material processing:By rosemary and Caladium bicolor, it, which is put into salt water, impregnates 2 hours, dries, by diameter 300mm's 30~50 microns are ground to abrasive wheel after slag is mixed, it is mixed with other raw materials, is put into closed action of forced stirring In machine, the tap water of phosphogypsum powder weight 30%-36% is added, stirring obtains mixture in 30~60 seconds;
(3) transfer formation:Said mixture is sent into molding machine, until its molding obtains semidry method Ardealite block.
Embodiment 2:
A kind of processing technology of semidry method Ardealite block, includes the following steps:
(1) prepare raw material:Each raw material and its parts by weight are:Build 980 parts of phosphogypsum powder, 6 parts of hydrogen fluoride auxiliary agent, poly- carboxylic 4 parts of sour series high-performance dehydragent, 2 parts of dispersing agent, 5 parts of retarder, 7 parts of reinforcing agent, 3 parts of rosemary and 3 parts of Caladium bicolor;
(2) Raw material processing:By rosemary and Caladium bicolor, it, which is put into salt water, impregnates 2 hours, dries, by diameter 300mm's 30~50 microns are ground to abrasive wheel after slag is mixed, it is mixed with other raw materials, is put into closed action of forced stirring In machine, the tap water of phosphogypsum powder weight 30%-36% is added, stirs 30~60 seconds, obtains mixture;
(3) transfer formation:Said mixture is sent into molding machine, until its molding obtains semidry method Ardealite block.
Embodiment 3:
A kind of processing technology of semidry method Ardealite block, includes the following steps:
(1) prepare raw material:Each raw material and its parts by weight are:1000 parts of phosphogypsum powder, 8 parts of hydrogen fluoride auxiliary agent, polycarboxylic acids 2 parts of series high-performance dehydragent, 4 parts of dispersing agent, 6 parts of retarder, 3 parts of reinforcing agent, 5 parts of rosemary and 5 parts of Caladium bicolor;
(2) Raw material processing:By rosemary and Caladium bicolor, it, which is put into salt water, impregnates 2 hours, dries, by diameter 400mm mine 30~50 microns are ground to abrasive wheel after slag is mixed, it is mixed with other raw materials, is put into closed forced stirrer In, the tap water of phosphogypsum powder weight 30%-36% is added, stirs 30~60 seconds, obtains mixture;
(3) transfer formation:Said mixture is sent into molding machine, until its molding obtains semidry method Ardealite block.
Embodiment 4:A kind of processing technology of semidry method Ardealite block, includes the following steps:
(1) prepare raw material:Each raw material and its parts by weight are:Build 960 parts of phosphogypsum powder, 4 parts of hydrogen fluoride auxiliary agent, poly- carboxylic 2 parts of sour series high-performance dehydragent, 4 parts of dispersing agent, 6 parts of retarder and 3 parts of reinforcing agent;
(2) Raw material processing:To be added after phosphogypsum powder and hydrogen fluoride auxiliary agent and dispersant phosphogypsum powder weight 30~ 36% water is stood 5~8 minutes, sequentially adds water-reducing agent, retarder and reinforcing agent later, put it into action of forced stirring In machine, stirs 30~60 seconds, obtain mixture;
(3) transfer formation:Said mixture is sent into molding machine, until its molding obtains semidry method Ardealite block.
Control group:Prepare the raw materials such as building gypsum, modified starch, retarder, water-reducing agent and water, is put into waterpower calcined abrasive Raw material slurry is stirred into pulp grinder, and it is spare to be then pumped into slurry conservation tank;Foaming agent and water launch such as foaming agent preparation tank in proportion It stirs evenly, it is spare to be pumped into foaming agent conservation tank;It is spare that coagulant and the boosted conveying equipment of gesso raw material enter feed bin; Slurry in slurry conservation tank is pumped into blender using metering pump, and foaming agent enters stirring after foaming using dynamic foaming device Machine, coagulant and land plaster enter blender after claiming metering using fully automatic culculating belt, and then all main and supplementary materials are in blender It is mixed into qualified calcium plaster;Finally calcium plaster is put into molding machine and is formed.
Carry out experimental control, wherein as a control group using traditional Ardealite block processing technology, of the invention 4 Embodiment is experimental group, is compared by water absorption rate to Ardealite block and compression strength, obtains following data:
Classification Water absorption rate (%) Compression strength (MPa)
Embodiment 1 18.2 9.5
Embodiment 2 16.5 11.9
Embodiment 3 17.3 10.9
Embodiment 4 18.9 8.7
Comparative example 24.9 6.5
As can be seen from the above table, using processing technology of the invention, traditional technology is compared, energy significant difference goes out passing through Above data will be obvious that using the water absorption rate of the technique ardealite in the present invention down to 16%~19%, far below existing 24.9% in technology;Compression strength is up to 8.5MPa~12MPa, is much larger than 6.5MPa in the prior art, therefore, the present invention Suitable for promoting the use.
What has been described above is only an embodiment of the present invention, and the common sense such as well known specific structure and characteristic are not made herein in scheme Excessive description.It, without departing from the structure of the invention, can be with it should be pointed out that for those skilled in the art Several modifications and improvements are made, these also should be considered as protection scope of the present invention, these all will not influence what the present invention was implemented Effect and patent practicability.The scope of protection required by this application should be based on the content of the claims, in specification The records such as specific embodiment can be used for explaining the content of claim.

Claims (8)

1. a kind of semidry method Ardealite block, it is characterised in that:Including raw material and its parts by weight be:Phosphogypsum powder 950~ 1000 parts, 3~8 parts of hydrogen fluoride auxiliary agent, 1~5 part of water-reducing agent, 1~5 part of dispersing agent, 3~8 parts of retarder and 3~8 parts of reinforcing agent.
2. semidry method Ardealite block according to claim 1, it is characterised in that:The raw material further includes:Rosemary and Caladium bicolor, parts by weight are:1~5 part and 1~5 part of Caladium bicolor of rosemary.
3. semidry method Ardealite block according to claim 2, it is characterised in that:960 parts of phosphogypsum powder, hydrogen fluoride auxiliary agent 4 parts, 5 parts of water-reducing agent, 1 part of dispersing agent, 3 parts of retarder, 8 parts of reinforcing agent, 2 parts of rosemary and 2 parts of Caladium bicolor.
4. semidry method Ardealite block according to claim 2, it is characterised in that:980 parts of phosphogypsum powder, hydrogen fluoride auxiliary agent 6 parts, 4 parts of water-reducing agent, 2 parts of dispersing agent, 5 parts of retarder, 7 parts of reinforcing agent, 3 parts of rosemary and 3 parts of Caladium bicolor.
5. semidry method Ardealite block according to claim 2, it is characterised in that:1000 parts of phosphogypsum powder, hydrogen fluoride help 8 parts of agent, 2 parts of water-reducing agent, 4 parts of dispersing agent, 6 parts of retarder, 3 parts of reinforcing agent, 5 parts of rosemary and 5 parts of Caladium bicolor.
6. the processing technology of semidry method Ardealite block according to any one of claim 2~5, it is characterised in that:Packet Include following steps:
(1) prepare raw material:Prepare raw material by above-mentioned parts by weight;
(2) Raw material processing:Phosphogypsum powder weight 30~36% will be added after phosphogypsum powder and hydrogen fluoride auxiliary agent and dispersant Water, stood 5~8 minutes, sequentially add water-reducing agent, retarder, reinforcing agent, rosemary and Caladium bicolor later, put Enter in forced stirrer, stirs 30~60 seconds, obtain mixture;
(3) transfer formation:Said mixture is sent into molding machine, until its molding obtains semidry method Ardealite block.
7. the processing technology of semidry method Ardealite block according to claim 6, it is characterised in that:Rosemary and flower is added Before leaf taro, by rosemary and Caladium bicolor, it, which is put into salt water, impregnates 2 hours, dries, by slag it is mixed after ground with abrasive wheel It is milled to 30~50 microns.
8. the processing technology of semidry method Ardealite block according to claim 7, it is characterised in that:The water-reducing agent is poly- Carboxylic acid series high-performance dehydragent.
CN201810886428.9A 2018-08-06 2018-08-06 A kind of semidry method Ardealite block and its processing technology Pending CN108821722A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111995407A (en) * 2020-08-10 2020-11-27 遵义汉丰装饰材料有限责任公司 Fireproof and mildew-proof building block and preparation process thereof
CN113461397A (en) * 2021-01-26 2021-10-01 遵义汉丰装饰材料有限责任公司 Semi-dry production method for preparing phosphogypsum building block in mechanized and continuous mode and phosphogypsum building block
CN115432052A (en) * 2022-11-08 2022-12-06 安徽森科新材料有限公司 Production method of gypsum hollow building block and material loading and conveying equipment thereof

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CN104326703A (en) * 2014-04-15 2015-02-04 达州洪福科技开发有限公司 Method for preparing foamed concrete block from various industrial solid wastes in a compounding manner
CN106495631A (en) * 2016-10-09 2017-03-15 合肥广能新材料科技有限公司 Ardealite block and preparation method thereof

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KR101242568B1 (en) * 2012-11-14 2013-03-19 주식회사 백중개발 Block composer using bottom ash and phospho-gypsum
CN104326703A (en) * 2014-04-15 2015-02-04 达州洪福科技开发有限公司 Method for preparing foamed concrete block from various industrial solid wastes in a compounding manner
CN106495631A (en) * 2016-10-09 2017-03-15 合肥广能新材料科技有限公司 Ardealite block and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111995407A (en) * 2020-08-10 2020-11-27 遵义汉丰装饰材料有限责任公司 Fireproof and mildew-proof building block and preparation process thereof
CN113461397A (en) * 2021-01-26 2021-10-01 遵义汉丰装饰材料有限责任公司 Semi-dry production method for preparing phosphogypsum building block in mechanized and continuous mode and phosphogypsum building block
CN113461397B (en) * 2021-01-26 2022-04-15 遵义汉丰装饰材料有限责任公司 Semi-dry production method for preparing phosphogypsum building block in mechanized and continuous mode and phosphogypsum building block
CN115432052A (en) * 2022-11-08 2022-12-06 安徽森科新材料有限公司 Production method of gypsum hollow building block and material loading and conveying equipment thereof
CN115432052B (en) * 2022-11-08 2023-02-28 安徽森科新材料有限公司 Production method of gypsum hollow building block and material loading and conveying equipment thereof

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