CN113443926A - Digital protective glaze ink with dry particle effect and application thereof - Google Patents
Digital protective glaze ink with dry particle effect and application thereof Download PDFInfo
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- CN113443926A CN113443926A CN202110812370.5A CN202110812370A CN113443926A CN 113443926 A CN113443926 A CN 113443926A CN 202110812370 A CN202110812370 A CN 202110812370A CN 113443926 A CN113443926 A CN 113443926A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention belongs to the field of ceramic ink, and discloses digital protective glaze ink with a dry particle effect and application thereof. The digital protective glaze ink comprises solvent, auxiliary agent and powder material, wherein the powder material is made of Al2O3、SiO2CaO and MgO. The digital protective glaze ink of some examples of the invention has good color property, and can prepare ceramics with obvious dry particle effect. The defect that the ceramic or rock plate with the micro-three-dimensional structure with the dry particle effect is difficult to prepare by ceramic ink-jet printing is overcome.
Description
Technical Field
The invention relates to the field of ceramics, in particular to a digital protective glaze ink with a dry particle effect and application thereof.
Background
With the rapid domestic fire explosion of rock plates, the number of rock plate production enterprises increases, and the development and innovation of the rock plates are gradually paid attention.
The decorative effect of the rock plate depends to a large extent on the decorative properties of the digital protective glaze. The new digital protective glaze with decorative effect will bring new difference to the development and innovation of the rock plate.
The existing digital protective glaze is mainly a high-calcium system, the produced rock plate surface is mainly a matte surface, and the pursuit is the texture of stone. At present, the ceramic tiles produced by adopting dry granules on the market have semi-concave-convex dry granule effect on the surface, and have high customer acceptance due to special texture and transparent feeling. The existing ceramic tile with dry grain effect can only be produced by dry grains. And dry particle production is adopted, so that the production cost is relatively high on one hand, and the production process is relatively complicated to switch on the other hand.
The ceramic ink-jet printing can conveniently realize the production of the personalized ceramic tile, has relatively simple production process and high efficiency, and is more and more popular with people. The digital protective glaze ink is used in the ceramic ink-jet printing process. The digital protective glaze ink consists of inorganic material, solvent, suspending agent, etc. In order to meet the requirement of ink-jet printing, the particle size of the inorganic particles is generally less than 1 μm, and compared with the conventional dry particles, the properties of the inorganic particles are greatly changed, so that the micro-stereoscopic effect of half-unevenness is difficult to obtain. Furthermore, the consumption of the digital protective glaze ink is generally less, the printing thickness is very thin, and the dry particle effect is more difficult to form. In the prior art, digital protective glaze ink with certain three-dimensional effect cannot be realized.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a digital protective glaze ink with a dry particle effect and application thereof.
The technical scheme adopted by the invention is as follows:
in a first aspect of the present invention, there is provided:
the digital protective glaze ink with dry particle effect comprises a solvent, an auxiliary agent and powder, wherein the oxide of the powder comprises Al in parts by weight2O3: 1 to 3 parts of SiO2: 70-80 parts of CaO: 15-20 parts of MgO: 0.5-2 parts.
In some examples, the digital protective glaze ink comprises 40-60 parts of solvent, 30-55 parts of powder, 3-7 parts of auxiliary agent, 0-3 parts of surfactant and 0-0.5 part of anti-settling agent.
In some examples, the solvent is one or more of hydrocarbon and ester solvents.
In some examples, the solvent is selected from at least one of isooctyl cocoate, isopropyl laurate, isooctyl palmitate, myristate, TOTAL PW 24-27H, TOTAL PW 25-28H, TOTAL PW 26-29H, TOTAL PW 28-32H, TOTAL PW 30-35H, TOTAL PW 30-36H, and TOTAL PW 30-38H.
In some examples, the hyperdispersant is selected from at least one of Nippondi Lamberti 1028, Nippondi Lamberti 1087, Dow dispersant 20015, Dow dispersant 20018, Dow dispersant 20020.
In some examples, the surfactant is selected from at least one of sorbitan fatty acid ester series surfactants, TWEEN series surfactants.
In some examples, the anti-settling agent is at least one of a polyamide wax, an oxidized polyethylene.
In some examples, the powder has a D99 < 1 μm.
In some examples, an appropriate amount of organic dye is also added.
In a second aspect of the present invention, there is provided:
a dry-grain effect ceramic having a surface pattern printed using the digitally protected glaze ink of the first aspect of the invention during its preparation.
The invention has the beneficial effects that:
the digital protective glaze ink of some examples of the invention can prepare ceramics with obvious dry particle effect, and breaks through the defect that the existing ceramic printing ink is difficult to prepare ceramics or rock plates with micro three-dimensional structures with dry particle effect.
The digital protective glaze ink of some examples of the invention has good color performance.
Drawings
FIG. 1 is a photograph of a tile obtained by printing and firing the dry particle effect digital protective glaze ink of example 1.
Detailed Description
In a first aspect of the present invention, there is provided:
the digital protective glaze ink with dry particle effect comprises a solvent, an auxiliary agent and powder, wherein the oxide of the powder comprises Al in parts by weight2O3: 1 to 3 parts of SiO2: 70-80 parts of CaO: 15-20 parts of MgO: 0.5-2 parts.
In some examples, the digital protective glaze ink comprises 40-60 parts of solvent, 30-55 parts of powder, 3-7 parts of auxiliary agent, 0-3 parts of surfactant and 0-0.5 part of anti-settling agent.
In some examples, the solvent is one or more of hydrocarbon and ester solvents.
The solvent has no special requirement, so long as the powder can be well dispersed, and simultaneously the viscosity and the surface tension required by the ceramic ink-jet printing can be met. The selection can be made according to the specific requirements of the ceramic ink-jet printing. In some examples, the solvent is selected from at least one of isooctyl cocoate, isopropyl laurate, isooctyl palmitate, myristate, TOTAL PW 24-27H, TOTAL PW 25-28H, TOTAL PW 26-29H, TOTAL PW 28-32H, TOTAL PW 30-35H, TOTAL PW 30-36H, and TOTAL PW 30-38H.
In some examples, the hyperdispersant is selected from at least one of Nippondi Lamberti 1028, Nippondi Lamberti 1087, Dow dispersant 20015, Dow dispersant 20018, Dow dispersant 20020. The hyper-dispersant can better disperse the powder in the solvent and improve the stability of the ink.
In some examples, the surfactant is selected from at least one of sorbitan fatty acid ester series surfactants, TWEEN series surfactants. The surfactant can adjust the surface tension of the ink, so that the ink meets the requirements of ceramic ink-jet printing.
In some examples, the anti-settling agent is at least one of a polyamide wax, an oxidized polyethylene. The anti-settling agent can further slow down the settling of the powder.
In some examples, the powder has a D99 < 1 μm.
In some examples, an appropriate amount of organic dye is also added. The organic dye can visually display printed patterns in the ceramic ink-jet printing process, and can be decomposed at high temperature in the subsequent firing process, so that the display and color development of the display effect are not influenced.
In a second aspect of the present invention, there is provided:
a dry-grain effect ceramic having a surface pattern printed using the digitally protected glaze ink of the first aspect of the invention during its preparation.
The technical scheme of the invention is further explained by combining the embodiment and the experimental data.
In the following examples, the preparation method of the digital protective glaze ink comprises:
s1) preparing powder;
s2) mixing the solvent, the powder and the auxiliary agent raw materials uniformly, and then grinding until the particle size D50 is less than 500 nm.
S3), if necessary, after all parameters are detected to be qualified, adding 0.03% of organic dye pigment for ceramics into the ink, stirring and dissolving uniformly, filtering through a multistage filter element with the diameter of 1 mu m, and packaging after filtering to obtain the finished product of the digital protective glaze ink.
Example 1
The digital protective glaze ink with the dry particle effect is prepared according to the following formula, wherein the inorganic chemical components in parts by weight of oxides are as follows:
Al2O3: 1.5 parts of (A) a reaction product,
SiO2: 80 parts of (a) a water-soluble polymer,
CaO: 15 parts of (a) to (b),
MgO: 2 portions of
The ink comprises the following components in percentage by mass:
45% of powder;
200203% of Dow dispersant;
200183% of Dow dispersant;
TOTAL PW 25-28H 48.5%；
TWEEN30 0.1%；
0.4 percent of polyamide wax.
Example 2
The digital protective glaze ink with the dry particle effect is prepared according to the following formula, wherein the inorganic chemical components in parts by weight of oxides are as follows:
Al2O3: 1 part of (A) and (B),
SiO2: 75 parts of (a) a water-soluble polymer,
CaO: 20 parts of (by weight), and mixing the components,
MgO: 1 part of
The ink comprises the following components in percentage by mass:
42% of powder material;
200206% of Dow dispersant;
52 percent of isopropyl laurate.
Example 3
The digital protective glaze ink with the dry particle effect is prepared according to the following formula, wherein the inorganic chemical components in parts by weight of oxides are as follows:
Al2O3: 3 parts of (a) to (b),
SiO2: 78 parts of (a) to (b),
CaO: 17 parts of (a) to (b),
MgO: 0.5 portion
The ink comprises the following components in percentage by mass:
42% of powder material;
200205% of Dow dispersant;
200181% of Dow dispersant;
32% of isopropyl laurate;
TOTAL PW 25-28H 20%。
example 4
The digital protective glaze ink with the dry particle effect is prepared according to the following formula, wherein the inorganic chemical components in parts by weight of oxides are as follows:
Al2O3: 3 parts of (a) to (b),
SiO2: 70 parts of (a) to (b),
CaO: 20 parts of (by weight), and mixing the components,
MgO: 2 portions of
The ink comprises the following components in percentage by mass:
55% of powder material;
ningbodi Lamberti 10876%;
40% of isopropyl laurate;
sorbitan fatty acid ester 801.5%;
0.5 percent of oxidized polyethylene.
Example 5
The digital protective glaze ink with the dry particle effect is prepared according to the following formula, wherein the inorganic chemical components in parts by weight of oxides are as follows:
Al2O3: 2 parts of (a) to (b),
SiO2: 75 parts of (a) a water-soluble polymer,
CaO: 18 parts of (a) to (b),
MgO: 0.5 portion
The ink comprises the following components in percentage by mass:
30% of powder;
200157% of Dow dispersant;
60% of isopropyl laurate;
sorbitan fatty acid ester 603%.
Example 6
The digital protective glaze ink with the dry particle effect is prepared according to the following formula, wherein the inorganic chemical components in parts by weight of oxides are as follows:
Al2O3: 1 part of (A) and (B),
SiO2: 76 parts of (a) to (b),
CaO: 17 parts of (a) to (b),
MgO: 1 part of
The ink comprises the following components in percentage by mass:
39% of powder;
200205% of Dow dispersant;
30% of isooctyl palmitate;
24% of myristate;
TWEEN201.8%；
0.2 percent of polyamide wax.
Comparative example 1:
the difference from example 2 is that Al is contained in the powder2O3The amount of the corresponding SiO is adjusted to 5 parts2The amount of (B) was adjusted to 71 parts.
Comparative example 2:
the difference from example 2 is that the amount of CaO in the powder was adjusted to 17 parts and the amount of MgO was adjusted to 4 parts.
And (3) effect detection:
the colorimetric values of the color charts printed by using the protective glaze ink of the embodiment 2 of the invention are shown in table 1.
As can be seen from the data in the table, the protective glaze ink of example 2 has good color development performance after printing, while comparative examples 1 and 2 have poor color development effect. The protection glaze of the embodiment 2 has purer black color development, reddish red brown, darker blue, yellow and orange color development and more brilliant color. The comparative example was bluish-green in black, yellowish in red-brown and pale in other colors.
As can be seen from the color development chroma values of all colors, the ceramic tile prepared by the protective glaze has good color development performance. Description of Al2O3And the amount of MgO has a very significant effect on the performance of the protective glaze ink.
Example 2 the sample brick fired after the protective glaze ink was printed was tested by the ceramic research institute of Foshan City, Inc., and the test standards were GB/T3810.7-2016, GB/T3810.13-2016, JC/T872-2000. The results are shown in Table 2.
As can be seen from the data in Table 2, the sample brick has good chemical corrosion resistance, Mohs hardness up to 6, glazed wear resistance up to 3 grade and excellent performance.
FIG. 1 is a photograph of a tile obtained by printing and firing the dry particle effect digital protective glaze ink of example 2. As can be seen from the figure, the fired tile had a distinct dry grain effect and the color development was relatively uniform throughout.
The foregoing is a more detailed description of the invention and is not to be taken in a limiting sense. It will be apparent to those skilled in the art that simple deductions or substitutions without departing from the spirit of the invention are within the scope of the invention.
Claims (10)
1. A digital protective glaze ink with dry particle effect comprises a solvent, an auxiliary agent and powder, and is characterized in that: the oxide weight portion of the powder is Al2O3: 1 to 3 parts of SiO2: 70-80 parts of CaO: 15-20 parts of MgO: 0.5-2 parts.
2. The digital protective glaze ink as set forth in claim 1, wherein: the digital protective glaze ink comprises 40-60 parts of solvent, 30-55 parts of powder, and an auxiliary agent which specifically comprises 3-7 parts of hyperdispersant, 0-3 parts of surfactant and 0-0.5 part of anti-settling agent.
3. The digital protective glaze ink as set forth in claim 1, wherein: the solvent is one or more of hydrocarbon and ester solvents.
4. The digital protective glaze ink as set forth in claim 1, wherein: the solvent is at least one selected from isooctyl cocoate, isopropyl laurate, isooctyl palmitate, myristate, TOTAL PW 24-27H, TOTAL PW 25-28H, TOTAL PW 26-29H, TOTAL PW 28-32H, TOTAL PW 30-35H, TOTAL PW 30-36H and TOTAL PW 30-38H.
5. The digital protective glaze ink as set forth in claim 2, wherein: the hyperdispersant is at least one selected from Nippondi Lamberti 1028, Nippondi Lamberti 1087, Dow dispersant 20015, Dow dispersant 20018 and Dow dispersant 20020.
6. The digital protective glaze ink as set forth in claim 2, wherein: the surfactant is at least one of sorbitan fatty acid ester series surfactant and TWEEN series surfactant.
7. The digital protective glaze ink as set forth in claim 2, wherein: the anti-settling agent is at least one of polyamide wax and oxidized polyethylene.
8. The digital protective glaze ink as set forth in claim 1, wherein: the D99 of the powder is less than 1 mu m.
9. The digital protective glaze ink as set forth in claim 1, wherein: also contains proper amount of organic dye.
10. A dry-grain effect ceramic, characterized in that: the preparation process uses the digital protective glaze ink as claimed in any one of claims 1 to 8.
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| CN202110812370.5A CN113443926B (en) | 2021-07-19 | 2021-07-19 | Digital protective glaze ink with dry particle effect and application thereof |
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