CN113426432A - Production line and process for utilizing regenerated resources of saturated activated alumina pellets - Google Patents

Production line and process for utilizing regenerated resources of saturated activated alumina pellets Download PDF

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Publication number
CN113426432A
CN113426432A CN202110768911.9A CN202110768911A CN113426432A CN 113426432 A CN113426432 A CN 113426432A CN 202110768911 A CN202110768911 A CN 202110768911A CN 113426432 A CN113426432 A CN 113426432A
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temperature
pipeline
final
air
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袁朝阳
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Jiangsu Lei Jin Environmental Engineering Co ltd
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Jiangsu Lei Jin Environmental Engineering Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3433Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/345Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07CPOSTAL SORTING; SORTING INDIVIDUAL ARTICLES, OR BULK MATERIAL FIT TO BE SORTED PIECE-MEAL, e.g. BY PICKING
    • B07C7/00Sorting by hand only e.g. of mail
    • B07C7/04Apparatus or accessories for hand picking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

Abstract

The invention discloses a saturated activated alumina pellet renewable resource utilization production line and a process, which comprises a hopper, a first lifting machine, a primary rotary desorption kiln, a hot blast stove, a waste gas treatment system, a final-stage thermal desorption tower, a third lifting machine, a waste gas treatment waste heat utilization system, a rotary cooling cooler, a waste heat utilization system, a first transfer bin, a conveyor, a second transfer bin, a classification sorting inspection table, a screening machine, a second lifting machine, a regenerated finished product bin, a weighing and packaging machine and a ton package conveyor; through elementary gyration desorption kiln and final stage thermal desorption tower, carry out thermal desorption regeneration treatment to saturated active alumina bobble, through exhaust treatment system, exhaust treatment waste heat utilization system and waste heat utilization system, carry out the dust collection to dirty gas, carry out effective innocent treatment to poisonous harmful gas composition wherein, utilize the waste heat simultaneously, consequently environmental protection, the saving utilizes resource and energy, reduction in production cost hangs down.

Description

Production line and process for utilizing regenerated resources of saturated activated alumina pellets
Technical Field
The invention relates to the technical field of solid waste and hazardous waste disposal and industrial resource recovery, in particular to a production line and a process for utilizing saturated activated alumina pellet renewable resources.
Background
Hydrogen peroxide, also known as hydrogen peroxide, is commonly produced by the well-established 2-ethyl anthraquinone process (also known as the anthraquinone process). The anthraquinone process is that 2-ethyl anthraquinone and organic solvent are prepared into working solution, hydrogenation is carried out under the conditions of 3atm, 55-65 ℃ and participation of catalyst, countercurrent oxidation is carried out with air at 40-44 ℃, and hydrogen peroxide water solution products are obtained through extraction, regeneration, refining and concentration. In the post-treatment process, the active alumina pellets are required to be used for adsorbing and removing alkali and regenerating degradation products to obtain the working solution which can be recycled, and the adsorption process of the active alumina pellets cannot be reversibly regenerated. The alumina ball adsorbent must be replaced after a period of use to ensure the need for regeneration of the working fluid. Therefore, if the recycling of the alumina pellets can be realized, the cost can be greatly saved, and the alumina pellets can be regenerated through desorption reaction according to the characteristics of the alumina pellets, so that the recycling of the alumina pellets is realized. The existing equipment and process for treating and regenerating the small alumina balls are used for treating the small alumina balls, wherein the small alumina balls are subjected to desorption treatment through an activator furnace, a VOCs waste gas treatment system and a mesh belt furnace, dust is collected, and the small alumina balls are matched for refining, so that useful small alumina balls are screened out to the maximum extent, and the utilization rate of the small alumina balls is improved. In the equipment and the process for treating and regenerating the small alumina balls, equipment such as an activator furnace, a VOCs waste gas treatment system, a mesh belt furnace and the like are adopted, so that the manufacturing, production and operation costs are high.
With new content
The technical problem to be solved by the invention is to provide a production line and a process for utilizing the regenerated resources of saturated activated small alumina balls, wherein the production line and the process can be used for regenerating the small alumina balls and are low in operation energy consumption and manufacturing cost.
In order to solve the technical problems, the invention provides a saturated activated alumina pellet renewable resource utilization production line, which comprises a hopper, a first elevator, a primary rotary desorption kiln, a hot blast stove, a waste gas treatment system, a final-stage thermal desorption tower, a third elevator, a waste gas treatment waste heat utilization system, a rotary cooling cooler, a waste heat utilization system, a first transfer bin, a conveyor, a second transfer bin, a classification sorting inspection table, a sieving machine, a second elevator, a regenerated finished product bin, a weighing and packaging machine and a ton bag conveyor, wherein the hopper comprises a feed inlet and a discharge outlet, the first elevator, the second elevator and the third elevator have the same structure, the primary rotary desorption kiln comprises a feed device, a discharge device, the feed device comprises a feed inlet and an air inlet, and the discharge device comprises an air outlet and a discharge outlet, the final-stage thermal desorption tower comprises a feeding hole, a discharging hole, an air inlet and an air outlet, the rotary cooling machine comprises a feeding device and a discharging device, the feeding device comprises a feeding hole and an air outlet, and the discharging device comprises a discharging hole and an air inlet;
the discharge gate of hopper is located the top of the feed inlet of first lifting machine, the discharge gate of first lifting machine is located the top of the feed arrangement feed inlet of elementary gyration desorption kiln, the feed arrangement air intake of elementary gyration desorption kiln pass through the pipeline with the air outlet of hot-blast furnace communicates with each other, the discharge device discharge gate of elementary gyration desorption kiln is located the top of the feed inlet of third lifting machine, the discharge gate of third lifting machine is located the top of final thermal desorption tower feed inlet, the discharge arrangement air outlet of elementary gyration desorption kiln communicates with the exhaust-gas treatment system through the pipeline, the air outlet of final thermal desorption tower communicates with the exhaust-gas treatment waste heat utilization system through the pipeline, the final thermal desorption tower discharge gate is located the top of the feed inlet of gyration cooling machine feed arrangement, the final thermal desorption tower air intake communicates with the hot-blast furnace air outlet through the pipeline, the air outlet of the feeding device of the rotary cooling cooler is communicated with a waste heat utilization system through a pipeline, a discharge port of a discharging device of the rotary cooling machine is positioned above the first transfer bin, the lower end of the conveyor is positioned below a discharge port of the first transfer bin, the upper end of the conveyor is positioned above the second transfer bin, the second transfer bin is positioned above one end of the sorting and inspecting table, the other end of the sorting and inspecting table is positioned above the feeding hole of the sieving machine, the discharge hole of the sieving machine is positioned above the feeding hole of the second hoisting machine, the discharge hole of the second hoister is positioned above the feed hole of the regenerated finished product bin, the weighing and packaging machine is positioned below the regenerated finished product bin, and one end of the ton package conveyor is positioned below the weighing and packaging machine;
the waste gas treatment system comprises a first dust remover, an air-cooled cooler, an adsorption box, a first fan and an exhaust funnel, wherein an air inlet of the first dust remover is connected with an air outlet of the primary rotary desorption kiln discharging device through a pipeline;
the waste gas treatment waste heat utilization system comprises a catalytic oxidation bed, a second high-temperature fan, a second heat exchanger, a second dust remover and a second fan, wherein an air inlet of the catalytic oxidation bed is communicated with an air outlet of the final-stage thermal desorption tower through a pipeline, an air outlet of the catalytic oxidation bed is connected with an air inlet of the second high-temperature fan, an air outlet of the second high-temperature fan is connected with an air inlet of the second heat exchanger through a pipeline, an air outlet of the second heat exchanger is connected with an air inlet of the second dust remover through a pipeline, and an air outlet of the second dust remover is connected with an air inlet of the second; the air outlet of the high-temperature fan II is connected with an external waste heat utilization pipeline through a pipeline;
the waste heat utilization system comprises a third high-temperature fan, a third heat exchanger, a third dust remover and a third fan, wherein an air inlet of the third high-temperature fan is communicated with an air outlet of the feeding device of the rotary cooling cooler through a pipeline; and an air outlet of the high-temperature fan III is connected with an external waste heat utilization pipeline through a pipeline.
The quantitative conveying feeder is arranged below the hopper, a feed inlet of the quantitative conveying feeder is arranged at a discharge outlet of the hopper, and the discharge outlet of the quantitative conveying feeder is positioned above a feed inlet of the first hoister.
The conveyor is a belt type transverse rib anti-skid conveyor, and a duckbilled rubber discharge port is formed in the upper end of the belt type transverse rib anti-skid conveyor; the classification sorting inspection bench is a rubber belt conveyor with flash.
The screening machine is a rolling natural screening machine or a vibrating screening machine.
And a bin top dust collector is arranged at the top of the regenerated finished product bin.
The invention provides a production line for utilizing saturated activated alumina globule renewable resources, which comprises the following specific steps:
(1) feeding saturated active small alumina balls into a hopper, wherein the small alumina balls enter a feed port of a first hoister through a discharge port of the hopper, the small alumina balls are hoisted to a discharge port of the first hoister by the first hoister, meanwhile, high-temperature hot air of a hot blast stove enters the interior of a primary rotary desorption kiln through an air inlet of a feeding device of the primary rotary desorption kiln through a pipeline, and the high-temperature hot air of the hot blast stove enters the interior of a final thermal desorption tower through an air inlet of the final thermal desorption tower through a pipeline;
(2) the aluminum oxide pellets enter a feeding port of a feeding device of the primary rotary desorption kiln through a discharging port of a first elevator, and are subjected to heat exchange with high-temperature hot air in the primary rotary desorption kiln along with the rotation of the primary rotary desorption kiln, so that the aluminum oxide pellets are subjected to primary desorption treatment, the temperature in the primary rotary desorption kiln is not lower than 180 ℃, and the aluminum oxide pellets are pushed to a discharging device of the primary rotary desorption kiln under the action of a material guide plate in the primary rotary desorption kiln;
(3) after the small aluminum oxide balls enter the primary rotary desorption kiln discharging device, the small aluminum oxide balls enter a feeding port of a third hoister through a discharging port of the primary rotary desorption kiln discharging device, and after the small aluminum oxide balls are hoisted by the third hoister, the small aluminum oxide balls enter a feeding port of a final-stage thermal desorption tower from the discharging port;
simultaneously feeding the dust-containing and VOCs-containing high-temperature hot air waste gas subjected to heat exchange with the small aluminum oxide balls into a primary rotary desorption kiln discharging device, wherein the temperature of the dust-containing and VOCs-containing high-temperature hot air waste gas is 150-170 ℃, the dust-containing and VOCs-containing high-temperature hot air waste gas is dedusted by a deduster, then the dust-containing and VOCs-containing high-temperature hot air waste gas is fed into an air-cooled cooler for cooling, the cooled waste gas is subjected to purification treatment by an adsorption box, and the purified waste gas is discharged by a fan after reaching the standard;
(4) the alumina pellets entering the feed port of the final-stage thermal desorption tower fall into the final-stage thermal desorption tower under the action of gravity, exchange heat with high-temperature hot air in the final-stage thermal desorption tower, perform final desorption treatment on the alumina pellets, and enable the alumina pellets to obtain thorough thermal desorption regeneration, wherein the temperature in the final-stage thermal desorption tower is not higher than 750 ℃, and the alumina pellets finally enter the discharge port of the final-stage thermal desorption tower under the action of gravity,
the high-temperature hot air waste gas containing dust and VOCs after heat exchange with the small alumina balls enters a catalytic oxidation bed through an air outlet of a final-stage thermal desorption tower through a pipeline to purify the high-temperature hot air waste gas containing dust and VOCs, one part of the purified high-temperature hot air is sent to a second heat exchanger through a second high-temperature fan to carry out heat exchange, then is dedusted by a second deduster and is discharged through the second fan, and meanwhile, the other part of the high-temperature hot air is conveyed to an external waste heat utilization pipeline by the second high-temperature fan;
(5) the alumina globules enter the discharge hole of the final-stage thermal desorption tower, then enter the feeding device of the rotary cooling machine through the discharge hole of the final-stage thermal desorption tower, enter the interior of the rotary cooling machine along with the rotation of the rotary cooling machine, the heat exchange is carried out between the small alumina balls and the air entering from the air inlet of the discharging device of the rotary cooling machine, the temperature of the small alumina balls is reduced to normal temperature, the temperature of the air entering the machine is increased, under the action of a material guide plate in the rotary cooling machine, the alumina pellets are pushed to a discharging device of the rotary cooling machine, meanwhile, the air with increased temperature is pumped out through a third high-temperature fan through an air outlet of a feeding device of the rotary cooling cooler, one high-temperature gas is sent into a third heat exchanger for heat exchange, then, after dust removal by the dust remover III, the high-temperature gas is discharged by the fan III, and the other part of the high-temperature gas is conveyed into an external waste heat utilization pipeline;
(6) the aluminum oxide small balls enter a first transfer bin through a discharge hole of the rotary cooling machine discharging device after entering the rotary cooling machine discharging device, enter the lower end part of the conveyor through the discharge hole of the first transfer bin, and enter a second transfer bin from the upper end of the conveyor through the conveying of the conveyor;
(7) the alumina pellets in the second transfer bin enter one end of the classification sorting and checking table from a discharge port of the second transfer bin, move to the other end of the classification sorting and checking table along with the operation of the classification sorting and checking table, are checked and sorted by hands in the process, enter a screening machine along with the operation of the classification sorting and checking table along with the alumina pellets moving to the other end of the classification sorting and checking table, are sorted by the screening machine, enter a feed port of a second lifting machine, are lifted by the second lifting machine, and enter a regeneration finished product bin from a discharge port of the second lifting machine;
(8) the alumina pellets entering the regenerated finished product bin enter a weighing and packing machine through a discharge port of the regenerated finished product bin, the weighing and packing machine weighs and packs the alumina pellets into ton bags, and the ton bags are conveyed out through a ton bag conveyor and are supplied to a warehouse for storage and delivery.
In the first step, a quantitative conveying feeder is arranged below the hopper, a feed port of the quantitative conveying feeder is arranged at a discharge port of the hopper, and the discharge port of the quantitative conveying feeder is positioned above the feed port of the first elevator.
According to the production line and the process for utilizing the regeneration resources of the saturated activated alumina globules, the primary rotary desorption kiln and the final-stage thermal desorption tower are adopted, so that the thermal desorption regeneration treatment can be carried out on the saturated activated alumina globules, and compared with the prior art in which an activating machine furnace, a VOCs waste gas treatment system and a mesh belt furnace system are adopted, the production line and the process are low in manufacturing cost and low in operation energy consumption; meanwhile, the waste gas treatment system, the waste gas treatment waste heat utilization system and the waste heat utilization system are adopted, dust collection can be carried out, emission of toxic and harmful gases can be effectively prevented, and waste heat can be utilized simultaneously, so that the environment is protected, energy is saved, and the production cost is reduced.
Drawings
FIG. 1 is a schematic structural diagram of a production line for recycling saturated activated alumina pellets.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
In the description of the present invention, it should be noted that the terms "upper", "lower", "inner", "outer", "front", "rear", "both ends", "one end", "the other end", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplicity of description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention. Furthermore, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it is to be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "disposed," "connected," and the like are to be construed broadly, such as "connected," which may be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
Referring to fig. 1, the present invention provides a production line for recycling saturated activated alumina pellets, which comprises a hopper 51, a first lifting machine 2, a primary rotary desorption kiln 6, a third lifting machine 53, a hot blast stove 1, a waste gas treatment system, a final stage thermal desorption tower 17, a waste gas treatment waste heat utilization system, a rotary cooling machine 21, a waste heat utilization system, a first transfer bin 24, a conveyor 25, a second transfer bin 27, a sorting and inspection table 28, a screening machine 29, a second lifting machine 30, a recycled product bin 31, a weighing and packaging machine 36 and a ton bag conveyor 35. The hopper 51 comprises a feeding hole and a discharging hole, and the first elevator 2 comprises a feeding hole 49 and a discharging hole 3. The first hoisting machine 2, the third hoisting machine 53 and the second hoisting machine 30 have the same structure. The primary rotary desorption kiln 6 comprises a feeding device 5, a discharging device 8, the feeding device 5 comprises a feeding hole 4 and an air inlet, and the discharging device 8 comprises an air outlet 9 and a discharging hole 7. The final-stage thermal desorption tower 17 comprises a feed inlet 15, an air outlet 16, a discharge outlet and an air inlet 19. The rotary cooling machine 21 comprises a feeding device and a discharging device, wherein the feeding device comprises a feeding hole 18 and an air outlet 20, and the discharging device comprises a discharging hole 22 and an air inlet 23.
The primary rotary desorption kiln 6 and the rotary cooling cooler 21 both comprise rotary conveying devices, and the inner surfaces of the rotary conveying devices both comprise material guide plates. When the rotary conveying device rotates, the guide plate pushes the alumina pellets in the rotary conveying device to move forwards. The speed of the flitch pushing the alumina pellets in the rotary conveying device to move forward depends on the rotating speed of the rotary conveying device.
The discharge gate of hopper 51 is located the top of the feed inlet 49 of first lifting machine, the discharge gate 3 of first lifting machine is located the top of the feed arrangement feed inlet 4 of elementary gyration desorption kiln 6, the feed arrangement air intake of elementary gyration desorption kiln 6 pass through the pipeline with the air outlet of hot-blast furnace 1 communicates with each other, the discharging device discharge gate 7 of elementary gyration desorption kiln 6 is located the top of the feed inlet 52 of third lifting machine 53, the discharge gate 54 of third lifting machine 53 is located the top of final stage thermal desorption tower 17 feed inlet 15, the 8 air outlets 9 of the discharging device of elementary gyration desorption kiln 6 pass through the pipeline with exhaust-gas treatment system communicates with each other. And the air outlet 16 of the final-stage thermal desorption tower 17 is communicated with a waste gas treatment and waste heat utilization system through a pipeline. The discharge hole of the final thermal desorption tower 17 is positioned above the feed hole 18 of the feeding device of the rotary cooling machine 21, and the air inlet 19 of the final thermal desorption tower 17 is communicated with the air outlet of the hot blast stove 1 through a pipeline. Of course, the hot blast stove matched with the final-stage thermal desorption tower 17 can also adopt another independent hot blast stove, and also can share one hot blast stove 1 with the primary rotary desorption kiln 6.
And an air outlet 20 of the feeding device of the rotary cooling machine 21 is communicated with a waste heat utilization system through a pipeline. The discharging device discharge port 22 of the rotary cooling machine 21 is located above the first transfer bin 24, the lower end of the conveyor 25 is located below the discharge port of the first transfer bin 24, the upper end of the conveyor 25 is located above the second transfer bin 27, the second transfer bin 27 is located above one end of the classification and sorting inspection table 28, the other end of the classification and sorting inspection table 28 is located above the feed port of the screening machine 29, the discharge port of the screening machine 29 is located above the feed port 37 of the second lifting machine 30, the discharge port 32 of the second lifting machine 30 is located above the feed port of the regenerated finished product bin 31, the weighing and packaging machine 36 is located below the regenerated finished product bin 31, and one end of the ton package conveyor 35 is located below the weighing and packaging machine 36.
In order to optimize the structure and reduce the cost, the waste gas treatment system comprises a first dust remover 10, an air-cooled cooler 11, an adsorption box 12, a first fan 14 and an exhaust funnel 13. An air inlet of the first dust remover 10 is connected with an air outlet 9 of a discharging device 8 of the primary rotary desorption kiln 6 through a pipeline, an air outlet of the first dust remover 10 is connected with an air inlet of the air-cooled cooler 11, an air outlet of the air-cooled cooler 11 is connected with an air inlet of the adsorption box 12 through a pipeline, an air outlet of the adsorption box 12 is connected with an air inlet of the first fan 14, and an air outlet of the first fan 14 is communicated with the lower portion of the exhaust funnel 13.
In order to optimize the structure and reduce the cost, the waste gas treatment and waste heat utilization system comprises a catalytic oxidation bed 43, a second high-temperature fan 44, a second heat exchanger 46, a second dust remover 47 and a second fan 48, wherein an air inlet of the catalytic oxidation bed 43 is communicated with an air outlet 16 of the feeding device of the final-stage thermal desorption tower 17 through a pipeline, an air outlet of the catalytic oxidation bed 43 is connected with an air inlet of the second high-temperature fan 44, an air outlet of the second high-temperature fan 44 is connected with an air inlet of the second heat exchanger 46 through a pipeline, an air outlet of the second heat exchanger 46 is connected with an air inlet of the second dust remover 47 through a pipeline, and an air outlet of the second dust remover 47 is connected with an air inlet of the second fan 48.
In order to utilize the waste heat, the air outlet of the second high-temperature fan 44 is connected with an external waste heat utilization pipeline through a pipeline. As shown in fig. 1, in this embodiment, the air outlet of the second high-temperature fan 44 is connected to an external waste heat utilization pipeline through a waste heat output pipe 45. Of course, the air outlet of the second high temperature fan 44 can also input a part of high temperature hot air into the hot blast stove 1 through the waste heat output pipe 45, so as to reduce the operation cost of the hot blast stove 1.
In order to optimize the structure and reduce the cost, the waste heat utilization system comprises a third high-temperature fan 42, a third heat exchanger 40, a third dust remover 39 and a third fan 38. An air inlet of the third high-temperature fan 42 is communicated with an air outlet 20 of the feeding device of the rotary cooling machine 21 through a pipeline, an air outlet of the third high-temperature fan 42 is communicated with an air inlet of the third heat exchanger 40 through a pipeline, an air outlet of the third heat exchanger 40 is connected with an air inlet of the third dust remover 39 through a pipeline, and an air outlet of the third dust remover 39 is connected with an air inlet of the third fan 38.
In order to utilize the waste heat, the air outlet of the high-temperature fan III 42 is connected with an external waste heat utilization pipeline through a pipeline. As shown in fig. 1, an air outlet of the high-temperature fan iii 42 is connected to an external waste heat utilization pipe through a waste heat conveying pipe 41.
Of course, the air outlet of the third high temperature fan 42 can also input a part of high temperature hot air into the hot blast stove 1 through the waste heat conveying pipe 41, so as to reduce the operation cost of the hot blast stove 1.
In order to control the discharge amount of the hopper 51, a quantitative conveying feeder 50 is arranged below the hopper 51, the feed port of the quantitative conveying feeder 50 is arranged at the discharge port of the hopper 51, and the discharge port of the quantitative conveying feeder 50 is positioned above the feed port 49 of the first elevator 2.
In order to reduce the manufacturing cost, a commercially available belt type transverse rib antiskid conveyor is adopted as the conveyor 25. In order to facilitate discharging, the upper end of the belt type transverse rib antiskid conveyor is provided with a duckbilled rubber discharging port 26.
In order to reduce the manufacturing cost, the sorting and inspecting table 28 adopts a commercially available rubber belt conveyor with flash.
In order to reduce the manufacturing cost, the screening machine 29 is a rolling natural screening machine or a vibration screening machine which is commercially available.
In order to prevent dust from being diffused, a bin top dust collector 33 is arranged at the top of the regenerated finished product bin 31.
The invention provides a process of a saturated activated alumina pellet renewable resource utilization production line, which comprises the following specific steps:
(1) feeding saturated active small alumina balls into a hopper 51, wherein the small alumina balls enter a feeding hole 49 of a first elevator 2 through a discharging hole of the hopper 51, the first elevator 2 lifts the small alumina balls to a discharging hole 3 of the first elevator 2, meanwhile, high-temperature hot air of a hot blast stove 1 enters the interior of a primary rotary desorption kiln 6 through an air inlet of a feeding device 5 of the primary rotary desorption kiln 6 through a pipeline, and the high-temperature hot air of the hot blast stove 1 enters the interior of a final thermal desorption tower 17 through an air inlet 19 of the final thermal desorption tower 17 through a pipeline;
(2) the aluminum oxide pellets enter a feeding hole 4 of a feeding device 5 of a primary rotary desorption kiln 6 through a discharging hole 3 of a first elevator 2, the aluminum oxide pellets exchange heat with high-temperature hot air in the primary rotary desorption kiln 6 along with the rotation of the primary rotary desorption kiln 6 to carry out primary desorption treatment on the aluminum oxide pellets, the temperature in the primary rotary desorption kiln 6 is not lower than 180 ℃, and the aluminum oxide pellets are pushed to a discharging device 8 of the primary rotary desorption kiln 6 under the action of a material guide plate in the primary rotary desorption kiln 6;
(3) after the small aluminum oxide balls enter the discharging device 8 of the primary rotary desorption kiln 6, the small aluminum oxide balls enter a feeding port of a third elevator 53 through a discharging port 7 of the discharging device 8 of the primary rotary desorption kiln 6, and enter a feeding port 15 of the final thermal desorption tower 17 through a discharging port 54 after being lifted by the third elevator 53;
simultaneously feeding the high-temperature hot air waste gas containing dust and VOCs after heat exchange with the small aluminum oxide balls into a discharging device 8 of a primary rotary desorption kiln 6, wherein the temperature of the high-temperature hot air waste gas containing dust and VOCs is 150-170 ℃, the high-temperature hot air containing dust and VOCs is dedusted by a deduster I10 and then fed into an air-cooled cooler 11 for cooling, the cooled waste gas is purified by an adsorption box 12 and is discharged by a fan I11 after reaching the standard;
(4) the alumina globules entering the feed port 15 of the final-stage thermal desorption tower 17 fall into the final-stage thermal desorption tower 17 under the action of gravity, exchange heat with high-temperature hot air in the final-stage thermal desorption tower 17, and perform final desorption treatment on the alumina globules to ensure that the alumina globules are subjected to thorough thermal desorption regeneration, wherein the temperature in the final-stage thermal desorption tower 17 is not higher than 750 ℃, and the alumina globules finally enter the discharge port of the final-stage thermal desorption tower 17 under the action of gravity,
the high-temperature hot air waste gas containing dust and VOCs after heat exchange with the small alumina balls enters a catalytic oxidation bed 43 through an air outlet 16 of a final-stage thermal desorption tower 17 through a pipeline to purify the high-temperature hot air waste gas containing dust and VOCs, one part of the purified high-temperature hot air is sent to a second heat exchanger 46 through a second high-temperature fan 44 to carry out heat exchange, then is dedusted by a second deduster 47 and is discharged through a second fan 48, and meanwhile, the other part of the high-temperature hot air is sent to an external waste heat utilization pipeline through the second high-temperature fan 44;
(5) the alumina pellets enter a discharge port of a final-stage thermal desorption tower 17 and then enter a feeding device of a rotary cooling cooler 21 through the discharge port of the final-stage thermal desorption tower 17, enter the interior of the rotary cooling cooler 21 along with the rotation of the rotary cooling cooler 21, and exchange heat with air entering from an air inlet 23 of a discharge device of the rotary cooling cooler 21, at the moment, the temperature of the alumina pellets is reduced to normal temperature, the temperature of the air entering the rotary cooling cooler 21 is increased, the alumina pellets are pushed to the discharge device of the rotary cooling cooler 21 under the action of a material guide plate inside the rotary cooling cooler 21, meanwhile, the air with the increased temperature passes through an air outlet 20 of the feeding device of the rotary cooling cooler 21 and is extracted by a high-temperature fan III 42, one high-temperature gas is sent to a heat exchanger III 40 for heat exchange, and then is discharged by a fan III 38 after being dedusted by a deduster III 39, The other part of the high-temperature gas is conveyed into an external waste heat utilization pipeline;
(6) the alumina pellets enter a discharging device of a rotary cooling machine 21 and then enter a first transfer bin 24 through a discharging port 22 of the discharging device of the rotary cooling machine 21, and then enter the lower end part of a conveyor 25 through a discharging port of the first transfer bin 24 and enter a second transfer bin 27 from the upper end of the conveyor through the conveying of the conveyor 25;
(7) the alumina pellets in the second transfer bin 27 enter one end of the sorting and inspecting table 28 from the discharge port of the second transfer bin 27, move to the other end of the sorting and inspecting table 28 along with the operation of the sorting and inspecting table 28, during the process, the alumina pellets on the sorting and inspecting table 28 are sorted by hands, the alumina pellets moving to the other end of the sorting and inspecting table 28 along with the operation of the sorting and inspecting table 28 enter the sieving machine 29, after being sorted by the sieving machine 29, the qualified alumina pellets enter the feed port 37 of the second hoisting machine 30, are hoisted by the second hoisting machine 30 and then enter the regeneration finished product bin 31 through the discharge port 32 of the second hoisting machine 30;
(8) the alumina pellets entering the regenerated finished product bin 31 enter a weighing and packing machine 36 through a discharge port of the regenerated finished product bin 31, the weighing and packing machine 36 weighs and packs the alumina pellets into ton bags 34, and the ton bags 34 are sent out through a ton bag conveyor 35 to be stored in a warehouse, stored and delivered.
In the first step, a quantitative conveying and feeding machine 50 is arranged below the hopper 51, a feeding hole of the quantitative conveying and feeding machine 50 is arranged at a discharging hole of the hopper 51, and a discharging hole of the quantitative conveying and feeding machine 50 is positioned above the feeding hole 49 of the first hoister 2.
The quantitative conveying feeder 50 is arranged below the hopper 51, the feeding hole of the quantitative conveying feeder 50 is arranged at the discharging hole of the hopper 51, and the discharging hole of the quantitative conveying feeder 50 is positioned above the feeding hole 49 of the first hoisting machine 2, so that the discharging amount of the hopper 51 can be controlled.
According to the production line and the process for utilizing the regeneration resources of the saturated activated alumina globules, the primary rotary desorption kiln 6 and the final-stage thermal desorption tower 17 are adopted, so that the thermal desorption regeneration treatment can be carried out on the saturated activated alumina globules, and compared with the prior art in which an activating machine furnace, a VOCs waste gas treatment system and a mesh belt furnace system are adopted, the production line and the process have the advantages of low manufacturing cost and low operation energy consumption; meanwhile, the waste gas treatment system, the waste gas treatment waste heat utilization system and the waste heat utilization system are adopted, dust collection can be carried out, emission of toxic and harmful gas can be effectively prevented, and simultaneously, waste heat can be utilized to the maximum extent, so that the environment is protected, resources and energy are saved, and the production cost is reduced.
The foregoing shows and describes the general principles and broad features of the present invention and advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.

Claims (7)

1. A saturated activated alumina pellet renewable resource utilization production line comprises a hopper, a first lifting machine, a primary rotary desorption kiln, a hot blast stove, a waste gas treatment system, a final-stage thermal desorption tower, a third lifting machine, a waste gas treatment waste heat utilization system, a rotary cooling machine, a waste heat utilization system, a first transfer bin, a conveyor, a second transfer bin, a classification and inspection table, a screening machine, a second lifting machine, a regenerated finished product bin, a weighing and packaging machine and a ton bag conveyor, wherein the hopper comprises a feeding port and a discharging port, the first lifting machine, the second lifting machine and the third lifting machine are identical in structure, the primary rotary desorption kiln comprises a feeding device, a discharging device and a feeding device, the feeding device comprises a feeding port and an air inlet, the discharging device comprises an air outlet and a discharging port, the final-stage thermal desorption tower comprises a feeding port, a discharging port, a secondary rotary desorption tower and a waste gas recovery tower, The rotary cooling cooler comprises a feeding device and a discharging device, wherein the feeding device comprises a feeding hole and an air outlet, and the discharging device comprises a discharging hole and an air inlet; the method is characterized in that:
the discharge gate of hopper is located the top of the feed inlet of first lifting machine, the discharge gate of first lifting machine is located the top of the feed arrangement feed inlet of elementary gyration desorption kiln, the feed arrangement air intake of elementary gyration desorption kiln pass through the pipeline with the air outlet of hot-blast furnace communicates with each other, the discharge device discharge gate of elementary gyration desorption kiln is located the top of the feed inlet of third lifting machine, the discharge gate of third lifting machine is located the top of final thermal desorption tower feed inlet, the discharge arrangement air outlet of elementary gyration desorption kiln communicates with the exhaust-gas treatment system through the pipeline, the air outlet of final thermal desorption tower communicates with the exhaust-gas treatment waste heat utilization system through the pipeline, the final thermal desorption tower discharge gate is located the top of the feed inlet of gyration cooling machine feed arrangement, the final thermal desorption tower air intake communicates with the hot-blast furnace air outlet through the pipeline, the air outlet of the feeding device of the rotary cooling cooler is communicated with a waste heat utilization system through a pipeline, a discharge port of a discharging device of the rotary cooling machine is positioned above the first transfer bin, the lower end of the conveyor is positioned below a discharge port of the first transfer bin, the upper end of the conveyor is positioned above the second transfer bin, the second transfer bin is positioned above one end of the sorting and inspecting table, the other end of the sorting and inspecting table is positioned above the feeding hole of the sieving machine, the discharge hole of the sieving machine is positioned above the feeding hole of the second hoisting machine, the discharge hole of the second hoister is positioned above the feed hole of the regenerated finished product bin, the weighing and packaging machine is positioned below the regenerated finished product bin, and one end of the ton package conveyor is positioned below the weighing and packaging machine;
the waste gas treatment system comprises a first dust remover, an air-cooled cooler, an adsorption box, a first fan and an exhaust funnel, wherein an air inlet of the first dust remover is connected with an air outlet of the primary rotary desorption kiln discharging device through a pipeline;
the waste gas treatment waste heat utilization system comprises a catalytic oxidation bed, a second high-temperature fan, a second heat exchanger, a second dust remover and a second fan, wherein an air inlet of the catalytic oxidation bed is communicated with an air outlet of the final-stage thermal desorption tower through a pipeline, an air outlet of the catalytic oxidation bed is connected with an air inlet of the second high-temperature fan, an air outlet of the second high-temperature fan is connected with an air inlet of the second heat exchanger through a pipeline, an air outlet of the second heat exchanger is connected with an air inlet of the second dust remover through a pipeline, and an air outlet of the second dust remover is connected with an air inlet of the second fan; the air outlet of the high-temperature fan II is connected with an external waste heat utilization pipeline through a pipeline;
the waste heat utilization system comprises a third high-temperature fan, a third heat exchanger, a third dust remover and a third fan, wherein an air inlet of the third high-temperature fan is communicated with an air outlet of the feeding device of the rotary cooling cooler through a pipeline; and an air outlet of the high-temperature fan III is connected with an external waste heat utilization pipeline through a pipeline.
2. The saturated activated alumina pellet renewable resources utilization production line of claim 1, characterized in that: the quantitative conveying feeder is arranged below the hopper, a feed inlet of the quantitative conveying feeder is arranged at a discharge outlet of the hopper, and the discharge outlet of the quantitative conveying feeder is positioned above a feed inlet of the first hoister.
3. The saturated activated alumina pellet renewable resources utilization production line of claim 1, characterized in that: the conveyor is a belt type transverse rib anti-skid conveyor, and a duckbilled rubber discharge port is formed in the upper end of the belt type transverse rib anti-skid conveyor; the classification sorting inspection bench is a rubber belt conveyor with flash.
4. The saturated activated alumina pellet renewable resources utilization production line of claim 1, characterized in that: the screening machine is a rolling natural screening machine or a vibrating screening machine.
5. The saturated activated alumina pellet renewable resources utilization production line of claim 1, characterized in that: and a bin top dust collector is arranged at the top of the regenerated finished product bin.
6. A process for a saturated activated alumina pellet renewable resource utilization production line comprises the following specific steps:
(1) feeding saturated active small alumina balls into a hopper, wherein the small alumina balls enter a feed port of a first hoister through a discharge port of the hopper, the small alumina balls are hoisted to a discharge port of the first hoister by the first hoister, meanwhile, high-temperature hot air of a hot blast stove enters the interior of a primary rotary desorption kiln through an air inlet of a feeding device of the primary rotary desorption kiln through a pipeline, and the high-temperature hot air of the hot blast stove enters the interior of a final thermal desorption tower through an air inlet of the final thermal desorption tower through a pipeline;
(2) the aluminum oxide pellets enter a feeding port of a feeding device of the primary rotary desorption kiln through a discharging port of a first elevator, and are subjected to heat exchange with high-temperature hot air in the primary rotary desorption kiln along with the rotation of the primary rotary desorption kiln, so that the aluminum oxide pellets are subjected to primary desorption treatment, the temperature in the primary rotary desorption kiln is not lower than 180 ℃, and the aluminum oxide pellets are pushed to a discharging device of the primary rotary desorption kiln under the action of a material guide plate in the primary rotary desorption kiln;
(3) after the small aluminum oxide balls enter the primary rotary desorption kiln discharging device, the small aluminum oxide balls enter a feeding port of a third hoister through a discharging port of the primary rotary desorption kiln discharging device, and after the small aluminum oxide balls are hoisted by the third hoister, the small aluminum oxide balls enter a feeding port of a final-stage thermal desorption tower from the discharging port;
simultaneously feeding the dust-containing and VOCs-containing high-temperature hot air waste gas subjected to heat exchange with the small aluminum oxide balls into a primary rotary desorption kiln discharging device, wherein the temperature of the dust-containing and VOCs-containing high-temperature hot air waste gas is 150-170 ℃, the dust-containing and VOCs-containing high-temperature hot air waste gas is dedusted by a deduster, then the dust-containing and VOCs-containing high-temperature hot air waste gas is fed into an air-cooled cooler for cooling, the cooled waste gas is subjected to purification treatment by an adsorption box, and the purified waste gas is discharged by a fan after reaching the standard;
(4) the alumina pellets entering the feed port of the final-stage thermal desorption tower fall into the final-stage thermal desorption tower under the action of gravity, exchange heat with high-temperature hot air in the final-stage thermal desorption tower, perform final desorption treatment on the alumina pellets, and enable the alumina pellets to obtain thorough thermal desorption regeneration, wherein the temperature in the final-stage thermal desorption tower is not higher than 750 ℃, and the alumina pellets finally enter the discharge port of the final-stage thermal desorption tower under the action of gravity,
the high-temperature hot air waste gas containing dust and VOCs after heat exchange with the small alumina balls enters a catalytic oxidation bed through an air outlet of a final-stage thermal desorption tower through a pipeline to purify the high-temperature hot air waste gas containing dust and VOCs, one part of the purified high-temperature hot air is sent to a second heat exchanger through a second high-temperature fan to carry out heat exchange, then is dedusted by a second deduster and is discharged through the second fan, and meanwhile, the other part of the high-temperature hot air is conveyed to an external waste heat utilization pipeline by the second high-temperature fan;
(5) the alumina globules enter the discharge hole of the final-stage thermal desorption tower, then enter the feeding device of the rotary cooling machine through the discharge hole of the final-stage thermal desorption tower, enter the interior of the rotary cooling machine along with the rotation of the rotary cooling machine, the heat exchange is carried out between the small alumina balls and the air entering from the air inlet of the discharging device of the rotary cooling machine, the temperature of the small alumina balls is reduced to normal temperature, the temperature of the air entering the machine is increased, under the action of a material guide plate in the rotary cooling machine, the alumina pellets are pushed to a discharging device of the rotary cooling machine, meanwhile, the air with increased temperature is pumped out through a third high-temperature fan through an air outlet of a feeding device of the rotary cooling cooler, one high-temperature gas is sent into a third heat exchanger for heat exchange, then, after dust removal by the dust remover III, the high-temperature gas is discharged by the fan III, and the other part of the high-temperature gas is conveyed into an external waste heat utilization pipeline;
(6) the aluminum oxide small balls enter a first transfer bin through a discharge hole of the rotary cooling machine discharging device after entering the rotary cooling machine discharging device, enter the lower end part of the conveyor through the discharge hole of the first transfer bin, and enter a second transfer bin from the upper end of the conveyor through the conveying of the conveyor;
(7) the alumina pellets in the second transfer bin enter one end of the classification sorting and checking table from a discharge port of the second transfer bin, move to the other end of the classification sorting and checking table along with the operation of the classification sorting and checking table, are checked and sorted by hands in the process, enter a screening machine along with the operation of the classification sorting and checking table along with the alumina pellets moving to the other end of the classification sorting and checking table, are sorted by the screening machine, enter a feed port of a second lifting machine, are lifted by the second lifting machine, and enter a regeneration finished product bin from a discharge port of the second lifting machine;
(8) the alumina pellets entering the regenerated finished product bin enter a weighing and packing machine through a discharge port of the regenerated finished product bin, the weighing and packing machine weighs and packs the alumina pellets into ton bags, and the ton bags are conveyed out through a ton bag conveyor and are supplied to a warehouse for storage and delivery.
7. The process of the saturated activated alumina pellet renewable resources utilization production line of claim 6, characterized in that: in the first step, a quantitative conveying feeder is arranged below the hopper, a feed port of the quantitative conveying feeder is arranged at a discharge port of the hopper, and the discharge port of the quantitative conveying feeder is positioned above the feed port of the first elevator.
CN202110768911.9A 2021-07-07 2021-07-07 Production line and process for utilizing regenerated resources of saturated activated alumina pellets Pending CN113426432A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102728332A (en) * 2012-06-20 2012-10-17 煤炭科学研究总院 Regeneration method of desulphurization, denitration and demercuration combined activated coke and special-purpose device thereof
CN103658165A (en) * 2013-12-10 2014-03-26 北京鼎实环境工程有限公司 Energy-saving type thermal-desorption repairing treatment system for organic polluted soil
CN106914116A (en) * 2017-04-18 2017-07-04 长沙紫宸科技开发有限公司 It is a kind of to be adapted to method of the collecting carbonic anhydride with generating electricity in cement kiln flue gas
CN110523367A (en) * 2019-07-25 2019-12-03 江苏中海华核环保有限公司 A kind of processing of alumina globule generating apparatus and technique again
CN112604644A (en) * 2020-12-14 2021-04-06 江苏磊金环境工程有限公司 Thermal desorption regeneration tower equipment for saturated active alumina pellets

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102728332A (en) * 2012-06-20 2012-10-17 煤炭科学研究总院 Regeneration method of desulphurization, denitration and demercuration combined activated coke and special-purpose device thereof
CN103658165A (en) * 2013-12-10 2014-03-26 北京鼎实环境工程有限公司 Energy-saving type thermal-desorption repairing treatment system for organic polluted soil
CN106914116A (en) * 2017-04-18 2017-07-04 长沙紫宸科技开发有限公司 It is a kind of to be adapted to method of the collecting carbonic anhydride with generating electricity in cement kiln flue gas
CN110523367A (en) * 2019-07-25 2019-12-03 江苏中海华核环保有限公司 A kind of processing of alumina globule generating apparatus and technique again
CN112604644A (en) * 2020-12-14 2021-04-06 江苏磊金环境工程有限公司 Thermal desorption regeneration tower equipment for saturated active alumina pellets

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