CN205796927U - Reverse-flow integration activated coke smoke eliminator - Google Patents

Reverse-flow integration activated coke smoke eliminator Download PDF

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CN205796927U
CN205796927U CN201620761065.2U CN201620761065U CN205796927U CN 205796927 U CN205796927 U CN 205796927U CN 201620761065 U CN201620761065 U CN 201620761065U CN 205796927 U CN205796927 U CN 205796927U
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activated coke
flue
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primary
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董方亮
贾晓辉
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Dalian Engineering Construction Co Ltd
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Dalian Engineering Construction Co Ltd
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Abstract

This utility model relates to a kind of reverse-flow integration activated coke smoke eliminator, this device is up-down structure, primary adsorption section is in the lower section of secondary absorption section, primary adsorption section is provided with gives vent to anger flue into gas flue, primary activity coke bed layer, one-level, and secondary absorption section is provided with secondary inlet flue, spray ammonia component, secondary gas distributor, second order activity coke bed layer and two grades of flues of giving vent to anger and constitutes.In primary adsorption section, flue gas being carried out desulfurization process, secondary absorption section carries out denitration to the flue gas through once desulfurization and secondary desulfuration processes.Secondary inlet section spray ammonia is effectively improved system denitration efficiency.Overcome the defect that desulfurization section activated coke is lumpd by denitration product pollution or inactivated.Improve the Sulfur capacity utilization rate in different purification functions district, reduce circulating load, and then reduce the operation consumption of activated coke.Activated coke utilization rate is high, not easy in inactivation and mechanical loss is little, air flow method uniformly, compact conformation, pressure drop is little, stable and reliable operation.

Description

Reverse-flow integration activated coke smoke eliminator
Technical field:
This utility model relates to SO in a kind of flue gas dry cleaning device, especially removing flue gas2、NOX, dust, hydrargyrum, two The reverse-flow integration activated coke smoke eliminator of the pollutant such as English.
Background technology:
China's industrial gas emission standard is increasingly stricter, to controlling SO in waste gas2、NOXThe pressure of discharge capacity is bigger.Mesh Front flue gases purification technology in a wet process is main, consumes great lot of water resources, easily causes secondary pollution, and can not desulfurization simultaneously take off Nitre, produces theory run counter to China energy-saving and emission-reduction, green industry.
Flue Gas Purification Technology Using Activated Coke is a kind of renewable, dry FGD process technology of resourcebility, utilizes activated coke Characterization of adsorption, the dust in pollutant, SO in efficient removal flue gas2、NOX, hydrargyrum, the pollutant such as two English, moreover it is possible to removing wet method Technology is difficult to the SO removed3, it is to avoid the series connection construction of different pollutant purification devices in flue gas, simultaneously can also to ultra-fine Dust (PM10) has certain purification.Be applicable to purify coal-fired flue-gas, gas from oil burning, flue gas of refuse burning, heavy oil divide Solve flue gas and sintering flue gas etc..
Adsorption-type desulfurizing tower and adsorption-type denitrating tower are the nucleus equipments of activated coke dry FGD process device.Industry at present The fixed bed desulphurization denitration technology that mostly is of middle application and moving bed desulphurization denitration technology, the wherein treatment quantity of fixed bed unit Relatively low, it is impossible to adapting to industrial production demand, and moving bed is big due to the optimum contact area of gas-solid, purification efficiency is high, treating capacity The advantage such as big, has higher industrial application value.Wherein moving bed desulphurization denitration technology presses the side of contact of flue gas and activated coke Formula is divided into and flows, adverse current and three kinds of modes of cross-flow.Parallel type operation mass transfer force is relatively low;Activated coke during cross-current type operation Can not be fully utilized, exist and be not fully contacted the phenomenon being just discharged with flue gas, thus activated coke consumption is big, circulating load is also Greatly.And the activated coke in counterflow moving bed, its activity is along tower top to being gradually lowered at the bottom of tower, and the final activated coke discharged is almost Being complete deactivation, activated coke is fully utilized with the whole process of smoke contacts, and therefore activated coke consumption is little, and circulating load is also Little, thus reduce regeneration energy consumption and operating cost.
But existing counter-current operation technology exists after activated coke is introduced into denitration region and enters back into desulfurization zone.Denitration reaction generates NH4HSO4(NH4)2SO4It is liquid between 147~350 DEG C, is generally solid in adsorptive reactor, and has temperature fluctuation Time may liquefy, therefore one layer of sticky mass may be adhered in activated coke surface.And now activated coke enters back into desulfurization zone Time, activated coke can be lumpd because of the existence of attachment or block absorption duct, thus activity is greatly lowered.
A kind of flue gas desulfurization and denitrification tower based on activated carbon disclosed in CN203043829U, it is simply that typical counter-current operation, Activated coke enters back into desulfurization zone after being introduced into denitration region.Denitration product is easily occurred to make activated coke inactivation affect de-during practical operation Sulfur effect.
Summary of the invention:
The purpose of this utility model is that for above-mentioned the deficiencies in the prior art, it is provided that a kind of reverse-flow integration activity Burnt smoke eliminator.
The purpose of this utility model is achieved through the following technical solutions:
Reverse-flow integration activated coke smoke eliminator, this device is up-down structure, and primary adsorption section 10 is two grades of suctions The lower section of attached section 20, primary adsorption section 10 bottom is provided with into gas flue 51, one-level gas distributor 14, and middle part is provided with primary activity Coke bed layer 13, one-level are given vent to anger flue 61, one-level feed bin 12 and two grades of discharging channels 26, and two grades of discharging channels 26 are provided with two with top Level hopper 25 is through, and the discharge bucket 40 being provided with bottom two grades of discharging channels 26 and primary adsorption section 10 is through;Primary adsorption section Being secondary absorption section 20 on 10, secondary absorption section 20 is provided with secondary inlet flue 52, is provided with spray ammonia in secondary inlet flue 52 Component 30, is provided with secondary gas distributor 24,23, two grades of feed bin 22 of second order activity coke bed layer and two grades on spray ammonia component 30 and goes out Gas flue 62, is provided through primary activity Jiao's passage 15 of secondary absorption section 20 in secondary absorption section 20, top is provided with one-level and lives Property Jiao's entrance 11 and second order activity Jiao's entrance 21 are constituted.
One-level flue 61 of giving vent to anger turns on two grading gas flues 52.
Primary activity Jiao's entrance 11 turns on one-level feed bin 12.
Second order activity Jiao's entrance and described two grades of feed bins conducting.
One-level gas distributor 14 and secondary gas distributor 24 are half jacket type structure opened wide, and flue gas is spacious by half The chuck partition 141 opened enters primary activity coke bed layer 13, then the half chuck partition opened wide through secondary gas distributor 24 241 enter second order activity coke bed layer 23.
Beneficial effect: this utility model uses upper and lower two-stage reaction structure, by activated coke to flue gas in primary adsorption section Carrying out once desulfurization process, flue gas is fully contacted with activated coke, the SO of the overwhelming majority in flue gas2Absorbed.Secondary absorption section is right Flue gas through once desulfurization carries out denitration and secondary desulfuration processes.Now amount of sulfur contenting in smoke is the lowest, and secondary inlet section spray ammonia can To be effectively improved system denitration efficiency.Upper and lower two-stage reaction structure is used to overcome desulfurization section activated coke by denitration product pollution Caking or the defect of inactivation.In same tower, the activated coke speed of service of I and II adsorption section can be regulated respectively, fully Improve the Sulfur capacity utilization rate in different purification functions district, reduce circulating load, and then reduce the operation consumption of activated coke.Activated coke Utilization rate is high, not easy in inactivation and mechanical loss is little, air flow method uniformly, compact conformation, pressure drop is little, stable and reliable operation.
Accompanying drawing illustrates:
Fig. 1 is reverse-flow integration activated coke smoke eliminator structure chart.
Fig. 2 is the half chuck dividing wall structure figure opened wide of gas distributor 14/24 in Fig. 1.
100 apparatus main bodies, 10 primary adsorption sections, 11 primary activity Jiao's entrances, 12 one-level feed bins, 13 primary activity coke beds Layer, 14 one-level gas distributors, 15 primary activity Jiao's passages, 20 secondary absorption sections, 21 second order activity Jiao's entrances, 22 2 grades of material Storehouse, 23 second order activity coke bed layers, 24 secondary gas distributors, 25 2 grades of hoppers, 26 2 grades of discharging channels, 30 spray ammonia components, 40 discharge buckets, 51 one-level inlet air stack, 52 secondary inlet flues, 61 one-levels give vent to anger flue, 62 2 grades of flues of giving vent to anger, and 141/241 The half chuck partition opened wide.
Detailed description of the invention:
With embodiment, this utility model is described in further detail below in conjunction with the accompanying drawings.
The gas cleaning principle of reverse-flow integration activated coke smoke eliminator is as follows:
Flue gas to be clean is imported reverse-flow integration activated coke smoke eliminator by one-level inlet air stack and purifies. Flue gas initially enters the one-level gas distributor 14 of primary adsorption section, through the half chuck partition 141 opened wide evenly into one-level Activated coke bed 13, gives vent to anger flue through entering one-level after primary activity coke bed layer from the bottom to top, and this process is that once desulfurization is clean Change processes, simultaneously removing heavy metal and dust.
Flue gas through once desulfurization purified treatment enters secondary inlet flue 52 and spray from one-level flue 61 removal of giving vent to anger After the ammonia mixing of ammonia component ejection under the effect of secondary gas distributor, evenly into second order activity coke bed layer, carry out Denitration and secondary desulfuration purify.
Activated coke slowly moves downward after primary activity Jiao's entrance 11 enters one-level feed bin 12, in moving process with treat The smoke contacts processed, carries out once desulfurization process, finally falls in discharge bucket, draw off after regenerating gas, and circulation makes With.
Activated coke slowly moves downward after second order activity Jiao's entrance 21 enters two grades of feed bins 22, with one in moving process Smoke contacts after secondary desulfurization, carries out a denitration process to gas and secondary desulfuration processes, and first the activated coke after contact falls Entering two grades of hoppers, finally fall in discharge bucket, after drawing off regeneration together with the activated coke discharged with primary adsorption section, circulation makes With.
As it is shown in figure 1, reverse-flow integration activated coke smoke eliminator, this device is up-down structure, primary adsorption section 10 in the lower section of secondary absorption section 20, and primary adsorption section 10 bottom is provided with into gas flue 51, one-level gas distributor 14, and middle part sets Have primary activity coke bed layer 13, one-level to give vent to anger flue 61, one-level feed bin 12 and two grades of discharging channels 26, two grades of discharging channels 26 with It is through that top is provided with two grades of hoppers 25, and the discharge bucket 40 being provided with bottom two grades of discharging channels 26 and primary adsorption section 10 is through; Being secondary absorption section 20 on primary adsorption section 10, secondary absorption section 20 is provided with secondary inlet flue 52, secondary inlet flue 52 Inside it is provided with spray ammonia component 30, on spray ammonia component 30, is provided with secondary gas distributor 24,23, two grades of feed bin of second order activity coke bed layer 22 and two grades of flues 62 of giving vent to anger, it is provided through primary activity Jiao's passage 15 of secondary absorption section 20, top in secondary absorption section 20 It is provided with primary activity Jiao's entrance 11 and second order activity Jiao's entrance 21 is constituted.
One-level flue 61 of giving vent to anger turns on two grading gas flues 52.Primary activity Jiao's entrance 11 turns on one-level feed bin 12. Second order activity Jiao's entrance and described two grades of feed bins conducting.
One-level gas distributor 14 and secondary gas distributor 24 are half jacket type structure opened wide, and flue gas is spacious by half The chuck partition 141 opened enters primary activity coke bed layer 13, then the half chuck partition opened wide through secondary gas distributor 24 241 enter second order activity coke bed layer 23.
Preliminary clearning flue gas enters reverse-flow integration activated coke smoke eliminator from one-level inlet air stack 51, upwards transports Move, move from the top down in the half unlimited chuck partition 141 and primary activity coke bed layer 13 of one-level gas distributor 14 Activated coke contacts, the SO in the dirt-carrying flue gas moved up2、NOX, dust, hydrargyrum, the pollutant such as two English are moved from the top down Activated coke absorption after, discharge through one-level flue 61 of giving vent to anger, adsorbed the SO in flue gas2、NOX, dust, hydrargyrum, two English etc. pollute The activated coke removal primary activity coke bed layer 13 of thing falls into discharge bucket 40.Do not carry or on a small quantity through what one-level gave vent to anger that flue 61 discharges Residual contamination thing flue gas enters secondary absorption section 20 through secondary inlet flue 52, warp again after mixing with the ammonia of spray ammonia component 30 ejection The activity moved from the top down in the chuck partition 241 that in secondary gas distributor 24 half opens wide and second order activity coke bed layer 23 Burnt contact, activated coke adsorbs the NO moving up in flue gas againXWith a small amount of SO2After, discharge, through two grades of flues 62 of giving vent to anger NO in absorption flue gasXAnd SO2Activated coke removal second order activity coke bed layer 20, by the two grades of rows being provided with in primary adsorption section 10 Material passage 26 sends into discharge bucket 40.Dirt-carrying activated coke and the dirt-carrying of secondary absorption section 20 discharge that primary adsorption section 10 is discharged are active Jiao all removes reverse-flow integration activated coke smoke eliminator by discharge bucket 40, gives activated coke activating and regenerating device and carries out Activating and regenerating is to reuse.Sulphuric acid is reclaimed while activating and regenerating.

Claims (5)

1. a reverse-flow integration activated coke smoke eliminator, it is characterised in that: this device is up-down structure, primary adsorption Section (10) is in the lower section of secondary absorption section (20), and primary adsorption section (10) bottom is provided with inlet air stack (51), the distribution of one-level gas Device (14), middle part is provided with primary activity coke bed layer (13), one-level is given vent to anger flue (61), one-level feed bin (12) and two grades of discharging channels (26), it is through that two grades of discharging channels (26) and top are provided with two grades of hoppers (25), two grades of discharging channels (26) and primary adsorption The discharge bucket (40) that section (10) bottom is provided with is through;It is secondary absorption section (20) on primary adsorption section (10), secondary absorption section (20) it is provided with secondary inlet flue (52), is provided with spray ammonia component (30) in secondary inlet flue (52), on spray ammonia component (30) It is provided with secondary gas distributor (24), second order activity coke bed layer (23), two grades of feed bins (22) and two grades of flues of giving vent to anger (62), two grades Being provided through primary activity Jiao's passage (15) of secondary absorption section (20) in adsorption section (20), top is provided with primary activity Jiao's entrance (11) constitute with second order activity Jiao's entrance (21).
2. according to the reverse-flow integration activated coke smoke eliminator described in claim 1, it is characterised in that: one-level is given vent to anger cigarette Road (61) and two grading gas flue (52) conductings,
3. according to the reverse-flow integration activated coke smoke eliminator described in claim 1, it is characterised in that: primary activity is burnt Entrance (11) turns on one-level feed bin (12).
The most reverse-flow integration activated coke smoke eliminator, it is characterised in that: described second order activity Burnt entrance (21) and described two grades of feed bins (22) conducting.
5. according to the reverse-flow integration activated coke smoke eliminator described in claim 1, it is characterised in that: one-level gas divides Cloth device (14) and secondary gas distributor (24) are half jacket type structure opened wide, and flue gas is by the half chuck partition opened wide (141) enter primary activity coke bed layer (13), then enter through the half chuck partition (241) opened wide of secondary gas distributor (24) Enter second order activity coke bed layer (23).
CN201620761065.2U 2016-07-18 2016-07-18 Reverse-flow integration activated coke smoke eliminator Active CN205796927U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107243222A (en) * 2017-07-31 2017-10-13 北京国电电科院节能技术有限公司 A kind of active coke desulphurizing device suitable for flue gas desulfurization
CN108310974A (en) * 2018-04-16 2018-07-24 英特佳(大连)环境工程技术有限公司 A kind of reverse-flow flue gas purifying method of bilayer and device
CN108392945A (en) * 2018-04-13 2018-08-14 邯郸钢铁集团设计院有限公司 A kind of upper and lower overlaying structure of activated carbon adsorption device module group
CN110652852A (en) * 2019-10-08 2020-01-07 中国科学院过程工程研究所 Flue gas purifying device
CN113559704A (en) * 2021-08-05 2021-10-29 邯郸钢铁集团设计院有限公司 Sintering machine flue gas desulfurization denitration adsorption equipment

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107243222A (en) * 2017-07-31 2017-10-13 北京国电电科院节能技术有限公司 A kind of active coke desulphurizing device suitable for flue gas desulfurization
CN108392945A (en) * 2018-04-13 2018-08-14 邯郸钢铁集团设计院有限公司 A kind of upper and lower overlaying structure of activated carbon adsorption device module group
CN108310974A (en) * 2018-04-16 2018-07-24 英特佳(大连)环境工程技术有限公司 A kind of reverse-flow flue gas purifying method of bilayer and device
CN110652852A (en) * 2019-10-08 2020-01-07 中国科学院过程工程研究所 Flue gas purifying device
CN113559704A (en) * 2021-08-05 2021-10-29 邯郸钢铁集团设计院有限公司 Sintering machine flue gas desulfurization denitration adsorption equipment
CN113559704B (en) * 2021-08-05 2023-10-13 河北大河邯钢设计院有限公司 Flue gas desulfurization and denitrification adsorption device of sintering machine

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