CN113426272A - Deodorant for treating malodorous gas of sewage plants of pharmaceutical enterprises and preparation method thereof - Google Patents
Deodorant for treating malodorous gas of sewage plants of pharmaceutical enterprises and preparation method thereof Download PDFInfo
- Publication number
- CN113426272A CN113426272A CN202110794551.XA CN202110794551A CN113426272A CN 113426272 A CN113426272 A CN 113426272A CN 202110794551 A CN202110794551 A CN 202110794551A CN 113426272 A CN113426272 A CN 113426272A
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- Prior art keywords
- deodorant
- parts
- pharmaceutical
- malodorous gas
- sewage
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/10—Oxidants
- B01D2251/108—Halogens or halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/70—Organic acids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/80—Organic bases or salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/306—Organic sulfur compounds, e.g. mercaptans
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a deodorant for treating malodorous gas of sewage plants of pharmaceutical enterprises, which comprises the following components in parts by weight: 5-25 parts of citric acid, 5-20 parts of malic acid, 2-10 parts of sodium bicarbonate, 2-6 parts of a surfactant, 20-40 parts of sodium hypochlorite, 0.5-2 parts of menthol, 2-5 parts of a dispersing agent and the balance of deionized water. The invention also discloses a preparation method of the composition. The deodorant provided by the invention has a good deodorization effect, can greatly reduce the peculiar smell emitted by the treated gas of a pharmaceutical enterprise sewage plant, and has good popularization and use values.
Description
Technical Field
The invention relates to the technical field of chemical product preparation, in particular to a deodorant for treating malodorous gas of sewage containing organic sulfur and organic amines in sewage plants of pharmaceutical enterprises and a preparation method thereof.
Background
With the progress of society, the requirements of people on the living environment are continuously increased. Pharmaceutical and chemical enterprises are indispensable important components of national economy, but the influence of sewage plants on the ambient atmospheric environment cannot be ignored, and governments of the country and all parts have more strict execution standards.
Municipal sewage malodorous gas mainly takes inorganic malodorous gas such as hydrogen sulfide, ammonia and the like as main materials and can be removed by chemical washing such as alkali washing, acid washing and the like; however, the compositions of malodorous gases in sewage plants of fine chemical enterprises are different, and the malodorous gases are mainly heterocyclic compounds, organic amine compounds, long-chain hydrocarbon compounds and the like through links such as a water treatment process and the like under the conditions of certain temperature, humidity, pressure and the like. Through gas-mass chromatography detection, the proportion of the substances in the waste gas is low, but the odor threshold value is high, and through treatment of related deodorization equipment, even if the related emission standard is met, the odor can be emitted, so that the pollution to the surrounding environment is caused to a certain extent.
The existing method for treating the stink of the sewage plant mainly comprises the following steps: biological methods, ionic methods, catalytic methods, incineration methods, adsorption and absorption methods, and the like. However, in many cases, it is difficult to effectively reduce the odor and secondary pollution is easily caused.
At present, a deodorant with good deodorization effect for treating the malodorous gas of sewage containing organic sulfur and organic amines and a preparation method thereof are lacked.
Disclosure of Invention
In view of the above-mentioned defects of the prior art, the technical object of the present invention is to provide a deodorant with good deodorizing effect for treating malodorous gas in sewage containing organic sulfur and organic amines, and a preparation method thereof.
In order to achieve the technical purpose, the invention provides a deodorant for treating malodorous gas of sewage plants of pharmaceutical enterprises, which comprises the following components in parts by weight:
further, the surfactant is sodium laurate or ethoxy sulfate.
Furthermore, the citric acid reacts with dimethylamine to generate amine salt, so that malodorous gas in the exhaust gas can be effectively reduced, and the measurement control can be realized.
The preparation method of the deodorant comprises the following steps:
accurately weighing the components in parts by weight;
and (2) mixing the components in deionized water, fully stirring and heating to 45 ℃.
The invention has the beneficial effects that:
the deodorant provided by the invention has a good deodorizing effect, particularly for malodorous gases in sewage containing organic sulfur and organic amines, can greatly reduce peculiar smell emitted by treated gases in sewage plants of pharmaceutical enterprises, and has good popularization and use values.
Detailed Description
The conception, the specific structure, and the technical effects produced by the present invention will be further described below to fully understand the objects, the features, and the effects of the present invention.
Example 1
The invention relates to a deodorant for treating malodorous gas of sewage plants of pharmaceutical enterprises, which comprises the following components in parts by weight:
the surfactant is sodium laurate or ethoxy sulfate.
The citric acid reacts with dimethylamine to generate amine salt, so that malodorous gas in the waste gas can be effectively reduced, and the metering control can be realized.
The preparation method of the deodorant comprises the following steps:
(1) accurately weighing the components in parts by weight;
(2) the components were mixed in deionized water, stirred well, and heated to 45 ℃.
Example 2
Example 2 is the same principle as example 1, except that: the invention discloses a deodorant which comprises the following components in parts by weight:
example 3
Example 3 is the same principle as example 1, except that: the invention discloses a deodorant which comprises the following components in parts by weight:
example 4
Example 4 is the same principle as example 1, except that: the invention discloses a deodorant which comprises the following components in parts by weight:
example 5
Example 5 is the same principle as example 1, except that: the invention discloses a deodorant which comprises the following components in parts by weight:
example 6
Example 6 is the same principle as example 1 except that: the invention discloses a deodorant which comprises the following components in parts by weight:
example 7
Example 7 is the same principle as example 1 except that: the invention discloses a deodorant which comprises the following components in parts by weight:
example 8
Example 8 is the same principle as example 1 except that: the invention discloses a deodorant which comprises the following components in parts by weight:
example 9
Example 9 is the same principle as example 1 except that: the invention discloses a deodorant which comprises the following components in parts by weight:
example 10
Example 10 is the same principle as example 1 except that: the invention discloses a deodorant which comprises the following components in parts by weight:
test examples
The deodorant prepared by the embodiment is subjected to a deodorization test, and the deodorant prepared by the embodiment is added into a deodorization washing tower of a sewage plant of XX certain pharmaceutical enterprise, so that the effect is good, and the odor of the gas discharged from a chimney is greatly reduced.
The continuous stable operation is carried out for 3 months, the deodorization effect is good, and each component can be increased or decreased according to the actual situation.
The test results show that the deodorant provided by the invention can greatly reduce the peculiar smell emitted by the treated gas of a pharmaceutical enterprise sewage plant, and has good popularization and use values.
When the amount of citric acid and sodium hypochlorite is large, the reaction time with respect to malodorous gases is longest. Can effectively control the foul smell of sewage containing organic amines in fine chemical industry.
The foregoing detailed description of the preferred embodiments of the invention has been presented. It should be understood that numerous modifications and variations could be devised by those skilled in the art in light of the present teachings without departing from the inventive concepts. Therefore, the technical solutions available to those skilled in the art through logic analysis, reasoning and limited experiments based on the prior art according to the concept of the present invention should be within the scope of protection defined by the claims.
Claims (4)
2. the deodorant for treating malodorous gas in sewage plants of pharmaceutical enterprises according to claim 1, wherein: the surfactant is sodium laurate or ethoxy sulfate.
3. The deodorant for treating malodorous gas in sewage plants of pharmaceutical enterprises according to claim 1, wherein: the citric acid reacts with dimethylamine to form an amine salt.
4. The method for preparing the deodorant for treating the malodorous gas generated by pharmaceutical and pharmaceutical wastewater treatment plants according to any one of claims 1 to 3, comprising the following steps:
accurately weighing the components according to the parts by weight in claim 1;
and (2) mixing the components in deionized water, fully stirring and heating to 45 ℃.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110794551.XA CN113426272A (en) | 2021-07-14 | 2021-07-14 | Deodorant for treating malodorous gas of sewage plants of pharmaceutical enterprises and preparation method thereof |
Applications Claiming Priority (1)
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CN202110794551.XA CN113426272A (en) | 2021-07-14 | 2021-07-14 | Deodorant for treating malodorous gas of sewage plants of pharmaceutical enterprises and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
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CN113426272A true CN113426272A (en) | 2021-09-24 |
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CN202110794551.XA Pending CN113426272A (en) | 2021-07-14 | 2021-07-14 | Deodorant for treating malodorous gas of sewage plants of pharmaceutical enterprises and preparation method thereof |
Country Status (1)
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109481713A (en) * | 2018-09-29 | 2019-03-19 | 壹田(广州)生活健康用品有限公司 | A kind of liquid deodorant and preparation method thereof |
CN110898604A (en) * | 2019-12-11 | 2020-03-24 | 福州利嘉特水处理环保工程有限公司 | Deodorant for household garbage and preparation method thereof |
CN111558291A (en) * | 2020-06-22 | 2020-08-21 | 江苏鑫汇林环境工程有限公司 | Coking wastewater treatment and odor deodorization system and process |
-
2021
- 2021-07-14 CN CN202110794551.XA patent/CN113426272A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109481713A (en) * | 2018-09-29 | 2019-03-19 | 壹田(广州)生活健康用品有限公司 | A kind of liquid deodorant and preparation method thereof |
CN110898604A (en) * | 2019-12-11 | 2020-03-24 | 福州利嘉特水处理环保工程有限公司 | Deodorant for household garbage and preparation method thereof |
CN111558291A (en) * | 2020-06-22 | 2020-08-21 | 江苏鑫汇林环境工程有限公司 | Coking wastewater treatment and odor deodorization system and process |
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Application publication date: 20210924 |
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