CN113418423A - Novel environment-friendly nitrate emission material and proportion thereof - Google Patents

Novel environment-friendly nitrate emission material and proportion thereof Download PDF

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Publication number
CN113418423A
CN113418423A CN202011219738.9A CN202011219738A CN113418423A CN 113418423 A CN113418423 A CN 113418423A CN 202011219738 A CN202011219738 A CN 202011219738A CN 113418423 A CN113418423 A CN 113418423A
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China
Prior art keywords
proportion
parts
friendly
nitrate
novel environment
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Pending
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CN202011219738.9A
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Chinese (zh)
Inventor
马克·斯皮尔
袁春生
周思剑
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Hunan Xinyu Fireworks Manufacturing Co ltd
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Hunan Xinyu Fireworks Manufacturing Co ltd
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Priority to CN202011219738.9A priority Critical patent/CN113418423A/en
Publication of CN113418423A publication Critical patent/CN113418423A/en
Pending legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42AMMUNITION; BLASTING
    • F42BEXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B4/00Fireworks, i.e. pyrotechnic devices for amusement, display, illumination or signal purposes
    • F42B4/30Manufacture

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Engineering & Computer Science (AREA)
  • Toys (AREA)

Abstract

The invention provides a novel environment-friendly nitrate-emitting material and a proportion thereof, and relates to the field of firework manufacturing. The novel environment-friendly nitrate emitting material and the proportion thereof comprise the following steps: weighing the following raw materials in parts by weight: the paint comprises 13-20 parts of carbon powder, 12-19 parts of phenolic resin, 5-12 parts of paint chips, 15-22 parts of potassium hydrogen phthalate and 55-62 parts of potassium perchlorate, wherein the carbon powder comprises the following components in parts by weight: phenolic resin: painting a piece: potassium hydrogen phthalate: the proportion of potassium perchlorate is 4: 3: 2: 3: 12; carbon powder, phenolic resin, paint chips, potassium hydrogen phthalate and potassium perchlorate are sequentially added into the potassium perchlorate and are fully and uniformly stirred, the stirring environment is 15-20 ℃, the stirring time is 30 minutes, and the stirring container and the stirring rod are made of wood materials. The firework has the advantages that the firework launching requires less saltpeter launching amount, the launching effect is good, the required firework tube is shorter, the space of the firework tube is shorter, the production cost of fireworks is greatly reduced, the profit space of the fireworks is larger, the resource saving and utilization efficiency is higher, and the production cost is better controlled.

Description

Novel environment-friendly nitrate emission material and proportion thereof
Technical Field
The invention relates to the technical field of firework manufacturing, in particular to a novel environment-friendly nitrate-emitting material and a proportion thereof.
Background
Fireworks are also called fireworks, fireworks and firecracker, and the definition of fireworks and crackers according to the standard of Chinese fireworks and crackers-safety and quality is as follows: the firework powder is used as a raw material for producing the acousto-optic color entertainment products. The invention is invented by people working in China earlier, and is often used in grand ceremonies or performances, and the only activity of applying fireworks in the same day and in the same day in China and the world is taken as a cross-year (except evening) activity. The fireworks are similar to the firecrackers in structure, and the structure of the fireworks comprises black powder and a fuse. In order to achieve good performance effect, a great amount of gunpowder for launching and explosion is filled in fireworks and display shells, and the varieties of the fireworks are various. According to the burning effect, there are thirteen main categories: spraying flowers, rotating and lifting, rockets, spitting beads, small fireworks, smog, modeling toys, combined fireworks, line incense, friction cannons, display shells and the like; the firework can be divided into more than 3000 cold light fireworks, fireworks display, pot flower, Roman candles, rockets, electro-optical fireworks, stage fireworks, cold fireworks, instant fireworks, torch fireworks, toy fireworks, firecrackers, stage fountains, shelf fireworks, day scene fireworks and the like.
In the prior art, the firework has large volume, complex formula for emitting saltpeter, large demand and poor emission effect, and has certain requirements on the height of an emission barrel of the firework, so that the production cost of the firework is higher.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a novel environment-friendly nitre emission material and a proportion thereof, and solves the problems of poor emission effect and complex formula of the emitted nitre.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: a novel environment-friendly nitrate-emitting material and a proportion thereof comprise the following steps:
weighing the following raw materials in parts by weight: the paint comprises 13-20 parts of carbon powder, 12-19 parts of phenolic resin, 5-12 parts of paint chips, 15-22 parts of potassium hydrogen phthalate and 55-62 parts of potassium perchlorate, wherein the carbon powder comprises the following components in parts by weight: phenolic resin: painting a piece: potassium hydrogen phthalate: the proportion of potassium perchlorate is 4: 3: 2: 3: 12;
adding carbon powder, phenolic resin, paint chips, potassium hydrogen phthalate and potassium perchlorate into potassium perchlorate in sequence, stirring uniformly under the condition of 15-20 ℃ for 30 minutes, preparing launching nitre by adopting insulation treatment, and then filling the launching nitre into a short-tube fireworks display.
Preferably, nozzle stub salute firecrackers include the base, base upper surface position runs through the fixedly connected with urceolus, the urceolus is hollow setting, and both ends are opening setting and opening position and all bond through glue and have sealed scraps of paper, and the thickness of sealed scraps of paper is for the oiled paper piece that is no longer than 0.5 millimeter, the urceolus inner wall has the inner tube through the fixed bonding of glue, be hollow setting in the inner tube, inner tube inner wall top fixedly connected with inner tube top mud, the inner tube inner wall is close to bottom position fixedly connected with inner tube sediment, inner tube sediment upper surface position runs through fixedly connected with inner tube and crosses the fire and draws.
Preferably, the position of the inner wall of the outer barrel, which is close to the bottom, is fixedly connected with outer barrel bottom mud, and the position of the outer barrel, which is positioned above the outer barrel bottom mud, is provided with emission saltpeter.
Preferably, the inner wall of the inner cylinder is fixedly connected with an isolation paper sheet close to the bottom, tail effect gunpowder is filled between the isolation paper sheet and bottom mud of the inner cylinder, and the inner cylinder fire-crossing fuse is fixedly connected with the isolation paper sheet in a penetrating manner.
Preferably, a lead is fixedly connected to the outer wall of the outer barrel at a position close to the position for launching the nitre in a penetrating manner, and the lead is in contact with the launching nitre.
Preferably, the inner tube is located and is filled with the explosive between inner tube top mud and the inner tube sediment, the inner tube is located and is located the explosive and fill between inner tube top mud and the inner tube sediment and be equipped with bright pearl.
Preferably, the thickness of the release paper sheet does not exceed 2 mm.
Preferably, the height of the outer cylinder is 130 mm, the outer diameter is 37 mm, and the inner diameter is 30 mm, the height of the base is 30 mm, the outer diameter is 50 mm, and the inner diameter is 37 mm, the height of the inner cylinder is 75 mm, the outer diameter of the inner cylinder is 27 mm, and the inner diameter is 24 mm.
Preferably, the outer cylinder and the inner cylinder are made of paper materials, and the outer surface of the outer cylinder and the outer surface of the inner cylinder are subjected to waterproof treatment.
(III) advantageous effects
The invention provides a novel environment-friendly nitrate-emitting material and a proportion thereof. The method has the following beneficial effects:
the firework disclosed by the invention has the advantages that the firework is simple in firework emitting material, convenient to produce and manufacture, less in required firework emitting amount and good in emitting effect, the required firework emitting pipeline is shorter, the space is saved, the production cost of fireworks is greatly reduced, the profit space of fireworks is larger, and the selling price is reduced.
Drawings
FIG. 1 is a front view of a spool salute gun according to the present invention;
fig. 2 is a cross-sectional view of the short tube salute of the present invention.
Wherein, 1, a base; 2. a lead wire; 3. an outer cylinder; 4. inner cylinder bottom mud; 5. igniting the inner cylinder; 6. an inner barrel; 7. jacking mud on the inner cylinder; 8. bottom mud of the outer cylinder; 9. bright beads; 10. explosive blasting; 11. tail effects; 12. emitting nitre; 13. a release paper sheet.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example (b):
as shown in fig. 1-2, an embodiment of the present invention provides a novel environment-friendly nitrate-emitting material and a mixture ratio thereof, including the following steps:
weighing the following raw materials in parts by weight: the paint comprises 20 parts of carbon powder, 15 parts of phenolic resin, 5-12 parts of paint chips, 15-22 parts of potassium hydrogen phthalate and 55-62 parts of potassium perchlorate, wherein the carbon powder comprises the following components in parts by weight: phenolic resin: painting a piece: potassium hydrogen phthalate: the proportion of potassium perchlorate is 4: 3: 2: 3: 12;
adding carbon powder, phenolic resin, paint chips, potassium hydrogen phthalate and potassium perchlorate into potassium perchlorate in sequence, stirring uniformly under the condition of 15-20 ℃ for 30 minutes, preparing the launching nitrate 12 by adopting insulation treatment, and then filling the launching nitrate 12 into a short-tube fireworks display.
Nozzle stub salute includes base 1, base 1 upper surface position runs through fixedly connected with urceolus 3, urceolus 3 is hollow setting, both ends are that opening setting and opening position all bond through glue and have sealed scraps of paper, the thickness of sealed scraps of paper is for the oiled paper piece that is no longer than 0.5 millimeter, 3 inner walls of urceolus have inner tube 6 through the fixed bonding of glue, be hollow setting in the inner tube 6, inner tube top mud 7 in the 6 inner wall top fixedly connected with of inner tube, the inner tube 6 inner wall is close to bottom position fixedly connected with inner tube sediment 4, the inner tube sediment 4 upper surface position runs through fixedly connected with inner tube and crosses the fire 5.
The inner wall of the outer barrel 3 is fixedly connected with outer barrel bottom mud 8 near the bottom, and the position of the outer barrel 3 above the outer barrel bottom mud 8 is provided with emission saltpeter 12. The inner wall of the inner cylinder 6 is fixedly connected with an isolation paper sheet 13 near the bottom, a tail effect gunpowder 11 is filled between the isolation paper sheet 13 and the inner cylinder bottom mud 4, and the inner cylinder fire-passing fuse 5 and the isolation paper sheet 13 are fixedly connected in a penetrating way.
The outer wall of the outer cylinder 3 is fixedly connected with a lead 2 in a penetrating way at a position close to the position of the launching saltpeter 12, and the lead 2 is contacted with the launching saltpeter. The inner barrel 6 is positioned between the inner barrel top mud 7 and the inner barrel bottom mud 4 and is filled with the explosive 10, and the inner barrel 6 is positioned between the inner barrel top mud 7 and the inner barrel bottom mud 4 and is filled with the bright beads 9 in the explosive 10.
The thickness of the release paper sheet 13 does not exceed 2 mm. The height of the outer cylinder 3 is 130 mm, the outer diameter is 37 mm, and the inner diameter is 30 mm, the height of the base 1 is 30 mm, the outer diameter is 50 mm, and the inner diameter is 37 mm, the height of the inner cylinder 6 is 75 mm, the outer diameter of the inner cylinder 6 is 27 mm, and the inner diameter is 24 mm. The outer barrel 3 and the inner barrel 6 are made of paper materials, and the outer surface of the outer barrel is subjected to waterproof treatment, so that fireworks are prevented from being wetted and cannot be launched.
Data comparison table for traditional saltpeter emission and saltpeter emission of the invention (height of 200 m)
Explosive quantity Height of outer cylinder Cost per gram of emitted nitre
The invention relates to a propellant nitrate 63g 280mm 0.7 yuan
Traditional shooting mirabilite 80g 130mm 1 Yuan
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (9)

1. The novel environment-friendly nitrate emitting material and the proportion thereof are characterized by comprising the following steps:
weighing the following raw materials in parts by weight: the paint comprises 13-20 parts of carbon powder, 12-19 parts of phenolic resin, 5-12 parts of paint chips, 15-22 parts of potassium hydrogen phthalate and 55-62 parts of potassium perchlorate, wherein the carbon powder comprises the following components in parts by weight: phenolic resin: painting a piece: potassium hydrogen phthalate: the proportion of potassium perchlorate is 4: 3: 2: 3: 12;
adding carbon powder, phenolic resin, paint chips, potassium hydrogen phthalate and potassium perchlorate into potassium perchlorate in sequence, fully and uniformly stirring the mixture under the stirring environment of 15-20 ℃ for 30 minutes, preparing the launching nitre (12) by adopting insulation treatment, and filling the launching nitre (12) into a short-tube fireworks display.
2. The novel environment-friendly nitrate-emitting material and the proportion thereof according to claim 1 are characterized in that: the nozzle stub salute firecrackers include base (1), base (1) upper surface position runs through fixedly connected with urceolus (3), urceolus (3) are hollow setting, and both ends are that opening setting and opening position all bond through glue and have sealed scraps of paper, and the thickness of sealed scraps of paper is for the oily scraps of paper that is no longer than 0.5 millimeter, urceolus (3) inner wall has inner tube (6) through the fixed bonding of glue, be hollow setting in inner tube (6), inner tube (6) inner wall top position fixedly connected with inner tube top mud (7), inner tube (6) inner wall is close to bottom position fixedly connected with inner tube bottom mud (4), inner tube bottom mud (4) upper surface position runs through fixedly connected with inner tube and crosses fire (5).
3. The novel environment-friendly nitrate-emitting material and the proportion thereof according to claim 2 are characterized in that: the inner wall of the outer barrel (3) is close to the bottom and fixedly connected with outer barrel bottom mud (8), and the outer barrel (3) is arranged above the outer barrel bottom mud (8) and provided with emission saltpeter (12).
4. The novel environment-friendly nitrate-emitting material and the proportion thereof according to claim 2 are characterized in that: the inner wall of the inner barrel (6) is fixedly connected with an isolation paper sheet (13) close to the bottom, tail effect gunpowder (11) is filled between the isolation paper sheet (13) and the inner barrel bottom mud (4), and the inner barrel fire-passing fuse (5) is fixedly connected with the isolation paper sheet (13) in a penetrating mode.
5. The novel environment-friendly nitrate-emitting material and the proportion thereof according to claim 2 are characterized in that: the outer wall of the outer barrel (3) is close to the position of the emission saltpeter (12) and penetrates through the lead (2) to be fixedly connected with the emission saltpeter, and the lead (2) is in contact with the emission saltpeter.
6. The novel environment-friendly nitrate-emitting material and the proportion thereof according to claim 2 are characterized in that: the explosive charge (10) is filled in the position between the inner barrel top mud (7) and the inner barrel bottom mud (4) where the inner barrel (6) is located, and the bright beads (9) are filled in the explosive charge (10) where the inner barrel (6) is located between the inner barrel top mud (7) and the inner barrel bottom mud (4).
7. The novel environment-friendly nitrate-emitting material and the proportion thereof according to claim 4 are characterized in that: the thickness of the separation paper sheet (13) is not more than 2 mm.
8. The novel environment-friendly nitrate-emitting material and the proportion thereof according to claim 2 are characterized in that: the height of the outer cylinder (3) is 130 mm, the outer diameter is 37 mm, the inner diameter is 30 mm, the height of the base (1) is 30 mm, the outer diameter is 50 mm, the inner diameter is 37 mm, the height of the inner cylinder (6) is 75 mm, the outer diameter of the inner cylinder (6) is 27 mm, and the inner diameter is 24 mm.
9. The novel environment-friendly nitrate-emitting material and the proportion thereof according to claim 2 are characterized in that: the outer cylinder (3) and the inner cylinder (6) are made of paper materials, and the outer surface of the outer cylinder is subjected to waterproof treatment.
CN202011219738.9A 2020-11-05 2020-11-05 Novel environment-friendly nitrate emission material and proportion thereof Pending CN113418423A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011219738.9A CN113418423A (en) 2020-11-05 2020-11-05 Novel environment-friendly nitrate emission material and proportion thereof

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Application Number Priority Date Filing Date Title
CN202011219738.9A CN113418423A (en) 2020-11-05 2020-11-05 Novel environment-friendly nitrate emission material and proportion thereof

Publications (1)

Publication Number Publication Date
CN113418423A true CN113418423A (en) 2021-09-21

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08136195A (en) * 1994-11-10 1996-05-31 Hamazawa Shikan Kk Paper tube for fireworks
CN103396276A (en) * 2013-08-07 2013-11-20 醴陵恒达烟花有限公司 Propellant for fireworks and crackers
CN103626612A (en) * 2013-12-02 2014-03-12 湖南明义烟花集团有限公司 Environment-friendly sulfur-free propellant formula
CN104058906A (en) * 2014-06-27 2014-09-24 湖南飞宇新材料有限公司 Sulfur-free ring stabilizing agent propellant powder
CN104557352A (en) * 2015-01-05 2015-04-29 浏阳市诚发科技有限公司 Sulfur-free environment-friendly gun propellant
CN105481618A (en) * 2015-12-29 2016-04-13 钟祥市丰山烟花有限责任公司 Sulfur-free shoot charge for fireworks and preparation method thereof
CN205561667U (en) * 2016-03-12 2016-09-07 浏阳市豪美烟花贸易有限公司 Color paper firecracker
CN207600311U (en) * 2017-07-18 2018-07-10 陈露 A kind of firework structure
CN109029145A (en) * 2018-09-13 2018-12-18 浏阳市达丰出口花炮厂 A kind of pyrotechnical of the effective tail medicine structure of inner cylinder bottom surface band

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08136195A (en) * 1994-11-10 1996-05-31 Hamazawa Shikan Kk Paper tube for fireworks
CN103396276A (en) * 2013-08-07 2013-11-20 醴陵恒达烟花有限公司 Propellant for fireworks and crackers
CN103626612A (en) * 2013-12-02 2014-03-12 湖南明义烟花集团有限公司 Environment-friendly sulfur-free propellant formula
CN104058906A (en) * 2014-06-27 2014-09-24 湖南飞宇新材料有限公司 Sulfur-free ring stabilizing agent propellant powder
CN104557352A (en) * 2015-01-05 2015-04-29 浏阳市诚发科技有限公司 Sulfur-free environment-friendly gun propellant
CN105481618A (en) * 2015-12-29 2016-04-13 钟祥市丰山烟花有限责任公司 Sulfur-free shoot charge for fireworks and preparation method thereof
CN205561667U (en) * 2016-03-12 2016-09-07 浏阳市豪美烟花贸易有限公司 Color paper firecracker
CN207600311U (en) * 2017-07-18 2018-07-10 陈露 A kind of firework structure
CN109029145A (en) * 2018-09-13 2018-12-18 浏阳市达丰出口花炮厂 A kind of pyrotechnical of the effective tail medicine structure of inner cylinder bottom surface band

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Application publication date: 20210921