CN113416918A - Nitrocarburizing process for extremely-thin parts - Google Patents

Nitrocarburizing process for extremely-thin parts Download PDF

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Publication number
CN113416918A
CN113416918A CN202110593176.2A CN202110593176A CN113416918A CN 113416918 A CN113416918 A CN 113416918A CN 202110593176 A CN202110593176 A CN 202110593176A CN 113416918 A CN113416918 A CN 113416918A
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CN
China
Prior art keywords
nitrocarburizing
extremely thin
cleaning
product
thin part
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Pending
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CN202110593176.2A
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Chinese (zh)
Inventor
王建才
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Kunshan Sunmin Drilube Electronic Material Technology Co ltd
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Kunshan Sunmin Drilube Electronic Material Technology Co ltd
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Application filed by Kunshan Sunmin Drilube Electronic Material Technology Co ltd filed Critical Kunshan Sunmin Drilube Electronic Material Technology Co ltd
Priority to CN202110593176.2A priority Critical patent/CN113416918A/en
Publication of CN113416918A publication Critical patent/CN113416918A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/40Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using liquids, e.g. salt baths, liquid suspensions
    • C23C8/52Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using liquids, e.g. salt baths, liquid suspensions more than one element being applied in one step
    • C23C8/54Carbo-nitriding
    • C23C8/56Carbo-nitriding of ferrous surfaces
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/02Pretreatment of the material to be coated
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/80After-treatment

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

The invention discloses a nitrocarburizing process for an extremely thin part, which comprises the following steps of S1: s2, cleaning: removing surface grease by alkaline cleaning; s3, preheating: keeping the temperature at 350 deg.C for 30 min; s4, performing nitrocarburizing in salt bath at 580 ℃ for 60 min; obtaining a compound layer of epsilon-Fe 2-3N on the surface, wherein the surface hardness reaches 450-650 HV; s5, cooling by water cooling; s6, post-cleaning; s7, carrying out post-treatment by vibration grinding; removing dust and dirt generated on the surface of the product in the nitriding process to expose a bright, homogeneous and clean surface, and removing punched burrs; s8, rust prevention: and (5) protecting the product. The salt bath nitrocarburizing process of the invention replaces the application of a superficial carburizing quenching or nitrocarburizing process, and solves the problem of heat treatment deformation while meeting the performance requirements.

Description

Nitrocarburizing process for extremely-thin parts
Technical Field
The invention relates to the field of heat treatment, in particular to a nitrocarburizing process for an extremely thin part.
Background
In the electric switch, many metal components are stamped and formed by low-carbon cold-rolled steel plates, and the processing cost is relatively low. Although the low-carbon cold-rolled steel sheet is easy to form, the low-carbon cold-rolled steel sheet has low strength, is not wear-resistant and corrosion-resistant, and therefore corresponding heat treatment and surface treatment are usually required to achieve the final service performance;
the common heat treatment is carburizing or carbonitriding, and the treatment temperature is usually above 850 ℃, so for a low-carbon cold-rolled steel plate with complicated switch and extremely thin plate thickness (the thickness is usually less than 1.0mm), the heat treatment difficulty is correspondingly high, the deformation ratio is high, and much labor is needed for straightening after the heat treatment. At the same time, the parts of very thin parts can only allow a very shallow carburized hardened layer, otherwise the material will be significantly brittle due to the penetration of the material to a too deep depth (e.g., infiltration or near infiltration), which makes the heat treatment control very difficult and the rejection rate is also very high.
Disclosure of Invention
The invention aims to provide a nitrocarburizing process for extremely thin parts.
The invention realizes the purpose through the following technical scheme: a nitrocarburizing process for an extremely thin part comprises the following steps:
s1, charging:
s2, cleaning: removing surface grease by alkaline cleaning;
s3, preheating: keeping the temperature at 350 deg.C for 30 min;
s4, performing nitrocarburizing in salt bath at 580 ℃ for 60 min; obtaining a compound layer of epsilon-Fe 2-3N on the surface, wherein the surface hardness reaches 450-650 HV;
s5, cooling by water cooling;
s6, post-cleaning;
s7, carrying out post-treatment by vibration grinding; removing dust and dirt generated on the surface of the product in the nitriding process to expose a bright, homogeneous and clean surface, and removing punched burrs;
s8, rust prevention: and (5) protecting the product.
Further, the S1 combines the products with a heat treatment tool to make the products spaced apart.
Further, the step S6 is to wash with flowing water to remove residual salt traces on the surface of the product.
Further, the thickness of the compound layer of S4 epsilon-Fe 2-3N is about 10 μm.
Further, the S4 reaches a diffusion layer with a depth of about 0.2-0.3 mm.
Compared with the prior art, the nitrocarburizing process for the extremely thin part has the beneficial effects that: the salt bath nitrocarburizing process replaces the application of a superficial carburizing quenching or nitrocarburizing process, and solves the problem of heat treatment deformation while meeting the performance requirements.
Drawings
FIG. 1 shows a compound layer obtained by nitrocarburizing an SPCC salt bath, the thickness of which is 12 to 14 μm.
Detailed Description
A nitrocarburizing process for an extremely thin part comprises the following steps:
s1, charging: the products are combined with the heat treatment tool, so that the products are spaced and not mutually extruded, extrusion deformation in the heat treatment process can be prevented, and uniform infiltration layers can be obtained in the heat treatment process;
s2, cleaning: removing surface grease by alkaline cleaning;
s3, preheating, wherein the temperature is 350 ℃, and keeping for 30 min; drying water, forming an oxide film on the surface, and having a certain permeation promoting effect in the nitriding process; meanwhile, in order to reduce the thermal stress of salt bath heating and reduce thermal shock deformation;
s4, performing nitrocarburizing in salt bath at 580 ℃ for 60 min; a compound layer of epsilon-Fe 2-3N with the thickness of about 10 mu m is obtained on the surface, the surface hardness reaches 450-650 HV, and meanwhile, a diffusion layer with the depth of about 0.2-0.3 mm is obtained;
s5, cooling by water cooling: the rapid cooling is carried out, so that nitrogen in the diffusion layer is dissolved in the alpha-Fe to play a role in solid solution strengthening, and the strength and the fatigue resistance of the material can be improved;
s6, post-cleaning: cleaning with flowing water to remove residual salt traces on the surface of the product;
s7, post-treatment by vibration grinding: the dust and dirt generated on the surface of the product in the nitriding process are removed through vibration grinding, the bright, homogeneous and clean surface is exposed, and simultaneously the punched burrs can be removed, so that the service performance of the product is improved;
s8, rust prevention: and (5) protecting the product.
The salt bath nitrocarburizing technology is adopted in the technology, a compound layer of epsilon-Fe 2-3N with the thickness of about 10 mu m is obtained on the surface, referring to figure 1, the surface hardness reaches 450-650 HV, and a diffusion layer with the depth of about 0.2-0.3 mm can be achieved;
the invention has the following advantages:
1) by applying the method, the heat-treated product can be free of a correction process, and the yield can reach 99.9%;
2) the complex performance after the nitrocarburizing of the salt bath is as follows: the hardness, the wear resistance and the corrosion resistance are improved, so that the product is free from surface treatment such as electroplating and other procedures after heat treatment, and the processing cost of the product is greatly reduced;
3) the product processed by the process has extremely low brittleness risk.
While there have been shown and described what are at present considered the fundamental principles and essential features of the invention and its advantages, it will be apparent to those skilled in the art that the invention is not limited to the details of the foregoing exemplary embodiments, but is capable of other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims (5)

1. The nitrocarburizing process for the extremely thin part is characterized by comprising the following steps of:
s1, charging:
s2, cleaning: removing surface grease by alkaline cleaning;
s3, preheating: keeping the temperature at 350 deg.C for 30 min;
s4, performing nitrocarburizing in salt bath at 580 ℃ for 60 min; obtaining a compound layer of epsilon-Fe 2-3N on the surface, wherein the surface hardness reaches 450-650 HV;
s5, cooling by water cooling;
s6, post-cleaning;
s7, carrying out post-treatment by vibration grinding; removing dust and dirt generated on the surface of the product in the nitriding process to expose a bright, homogeneous and clean surface, and removing punched burrs;
s8, rust prevention: and (5) protecting the product.
2. The nitrocarburizing process for an extremely thin part according to claim 1, characterized in that: and S1, combining the products with a heat treatment tool to enable the products to have intervals.
3. The nitrocarburizing process for an extremely thin part according to claim 1, characterized in that: the S6 adopts flowing water to wash and remove residual salt stains on the surface of the product.
4. The nitrocarburizing process for an extremely thin part according to claim 1, characterized in that: the thickness of the compound layer of S4 epsilon-Fe 2-3N is about 10 mu m.
5. The nitrocarburizing process for an extremely thin part according to claim 4, wherein: the S4 reaches a diffusion layer with a depth of about 0.2-0.3 mm.
CN202110593176.2A 2021-05-28 2021-05-28 Nitrocarburizing process for extremely-thin parts Pending CN113416918A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110593176.2A CN113416918A (en) 2021-05-28 2021-05-28 Nitrocarburizing process for extremely-thin parts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110593176.2A CN113416918A (en) 2021-05-28 2021-05-28 Nitrocarburizing process for extremely-thin parts

Publications (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114107884A (en) * 2021-11-11 2022-03-01 贵州大学 Preparation method of pure iron for preventing salt spray corrosion
CN114889363A (en) * 2022-06-02 2022-08-12 广西科技师范学院 Coloring processing technology for non-coating of car body

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002302756A (en) * 2001-01-31 2002-10-18 Tokico Ltd Surface treated steel member and gas soft nitriding method
CN1508282A (en) * 2002-09-04 2004-06-30 ͬ�Ϳ�ҵ��ʽ���� Method for producing metal member with intensified corrosion-resisting property by salt-bath nitrizing
CN1616704A (en) * 2003-11-14 2005-05-18 上海欧本表面处理技术有限公司 Salt bath tufftriding treatment of stainless steel (IICr17) slide vane (or vane)
CN1616705A (en) * 2003-11-14 2005-05-18 上海欧本表面处理技术有限公司 Salt bath tuff-triding treatment for high speed steel (W6Mo5Cr4V2) slide vane (or vane)
CN101906607A (en) * 2009-06-04 2010-12-08 台州市百达制冷有限公司 Liquid tufftriding method of 9Cr18 or 9Cr18Mo stainless steel slip sheet (or blade)
CN103502501A (en) * 2011-03-11 2014-01-08 H.E.F.公司 Molten-salt bath for nitriding mechanical steel parts, and implementation method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002302756A (en) * 2001-01-31 2002-10-18 Tokico Ltd Surface treated steel member and gas soft nitriding method
CN1508282A (en) * 2002-09-04 2004-06-30 ͬ�Ϳ�ҵ��ʽ���� Method for producing metal member with intensified corrosion-resisting property by salt-bath nitrizing
CN1616704A (en) * 2003-11-14 2005-05-18 上海欧本表面处理技术有限公司 Salt bath tufftriding treatment of stainless steel (IICr17) slide vane (or vane)
CN1616705A (en) * 2003-11-14 2005-05-18 上海欧本表面处理技术有限公司 Salt bath tuff-triding treatment for high speed steel (W6Mo5Cr4V2) slide vane (or vane)
CN101906607A (en) * 2009-06-04 2010-12-08 台州市百达制冷有限公司 Liquid tufftriding method of 9Cr18 or 9Cr18Mo stainless steel slip sheet (or blade)
CN103502501A (en) * 2011-03-11 2014-01-08 H.E.F.公司 Molten-salt bath for nitriding mechanical steel parts, and implementation method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114107884A (en) * 2021-11-11 2022-03-01 贵州大学 Preparation method of pure iron for preventing salt spray corrosion
CN114889363A (en) * 2022-06-02 2022-08-12 广西科技师范学院 Coloring processing technology for non-coating of car body
CN114889363B (en) * 2022-06-02 2023-10-13 广西科技师范学院 Non-paint coloring processing technology for car body

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