CN113388748A - Continuous casting and rolling production process of 3003 aluminum alloy strip - Google Patents

Continuous casting and rolling production process of 3003 aluminum alloy strip Download PDF

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Publication number
CN113388748A
CN113388748A CN202110513358.4A CN202110513358A CN113388748A CN 113388748 A CN113388748 A CN 113388748A CN 202110513358 A CN202110513358 A CN 202110513358A CN 113388748 A CN113388748 A CN 113388748A
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aluminum alloy
rolling
continuous casting
production process
percent
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张冉
尚蒙非
孙守旭
任行
张凯
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Inner Mongolia Liansheng New Energy Materials Co Ltd
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Inner Mongolia Liansheng New Energy Materials Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/46Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/74Temperature control, e.g. by cooling or heating the rolls or the product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • B22D11/003Aluminium alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/14Alloys based on aluminium with copper as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/16Alloys based on aluminium with copper as the next major constituent with magnesium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/18Alloys based on aluminium with copper as the next major constituent with zinc
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/057Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with copper as the next major constituent
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Continuous Casting (AREA)
  • Metal Rolling (AREA)

Abstract

A continuous casting and rolling production process of a 3003 aluminum alloy strip comprises the following steps: smelting, refining and slagging off, degassing and filtering, continuous casting, continuous rolling and finished product annealing, wherein the 3003 aluminum alloy strip comprises the following components in percentage by mass: 0.20 to 0.30 percent of Fe0.40 to 0.50 percent of Si0.40 to 1.20 percent of Mn1.05 to 1.20 percent of Cu0.08 to 1.20 percent of Cu0.015 to 0.030 percent of Ti0.015 to 0.01 percent of Mg or less, 0.03 percent or less of Zn or less, 0.05 percent or less of other alloys and the balance of Al. The continuous casting and rolling production process of the 3003 aluminum alloy strip disclosed by the invention has the following advantages: (1) the production process adopts a continuous casting and rolling technology, reduces the subsequent cold rolling and rolling processing process, and greatly improves the production efficiency of the aluminum alloy strip; (2) the rolling temperature of the first frame of the MINO triple tandem rolling mill is higher than the crystallization temperature of the aluminum alloy, the method belongs to a hot rolling process, the crystal grains are subjected to incomplete recrystallization, the metal plasticity is improved, the deformation resistance is reduced, and meanwhile compared with the traditional cast rolling, the plate blank crystal grains are finer.

Description

Continuous casting and rolling production process of 3003 aluminum alloy strip
Technical Field
The invention belongs to the field of aluminum alloy manufacturing, and particularly relates to a continuous casting and rolling production process of a 3003 aluminum alloy strip.
Background
At present, the main production steps of manufacturing the aluminum alloy strip by adopting a cast-rolling method in China comprise smelting, cast-rolling, cold rolling, high-temperature homogenizing annealing, intermediate annealing, foil rolling and finished product annealing, and the production efficiency of the double-zero foil blank produced by the cast-rolling machine is very low.
Continuous casting and rolling are combined rolling process, the American Hatzlett continuous casting and rolling mill is adopted, aluminum alloy liquid is injected into a continuous casting machine to cast a 19mm casting blank, and then the casting blank is directly rolled by a triple continuous rolling mill, so that a plate blank with the thickness of more than 2.0mm can be produced. The prior Hatzerland process has few applications in China, immature production process technology, certain difficulty in producing complex alloys and wider plate and strip materials, and easily forms casting defects such as surface segregation, holes and the like during continuous casting.
Disclosure of Invention
The invention aims to solve the defects of the prior art and provides a continuous casting and rolling production process of a 3003 aluminum alloy strip, wherein the 3003 aluminum alloy strip comprises the following components in percentage by mass: 0.20-0.30% of Fe, 0.40-0.50% of Si, 1.05-1.20% of Mn, 0.08-1.20% of Cu, 0.015-0.030% of Ti, less than or equal to 0.01% of Mg, less than or equal to 0.03% of Zn, less than or equal to 0.05% of other alloys and the balance of Al, wherein the production process comprises the following steps:
(1) smelting: sequentially adding 20% of solid materials and 80% of electrolytic aluminum liquid by mass percent into a smelting furnace as alloy ingredients, raising the temperature of the furnace in the smelting furnace to 690 ℃, and performing electromagnetic stirring to obtain aluminum alloy melt, wherein the solid materials comprise aluminum ingots, aluminum alloy waste materials and other alloy element ingredients;
(2) refining and slagging-off: heating the aluminum alloy melt obtained in the step (1) to 725 +/-10 ℃, refining and slagging off by using a refining agent, sampling after refining and slagging off, carrying out alloy proportioning according to a detection result, carrying out electromagnetic stirring again after proportioning, and pouring the aluminum alloy melt with the adjusted components into a heat preservation furnace;
(3) degassing and filtering: heating the holding furnace, and when the furnace temperature of the holding furnace reaches 730 +/-5 ℃, degassing and filtering the aluminum alloy melt by using mixed gas of chlorine and argon;
(4) continuous casting: continuously casting the refined aluminum alloy melt into a continuous casting blank by a Hatzrett continuous casting machine, wherein the size of the continuous casting blank is 19mm multiplied by 1280mm multiplied by L;
(5) continuous rolling: rolling the continuous casting blank into a cast-rolling plate material with the size of 2.3mm multiplied by 1280mm multiplied by L by an MINO three-continuous rolling mill, wherein the thickness change of the cast-rolling plate material in the three-time rolling process is respectively 19mm-9.5mm, 9.5mm-5.7mm and 5.7mm-3.8 mm;
(6) and (5) annealing the cast-rolled plate obtained in the step (5) to obtain the 3003 aluminum alloy strip.
Preferably, the temperature of the aluminum alloy melt in the refining and slagging-off process of the step (2) is not lower than 690 ℃.
Preferably, in the step (3), a SINF online degassing device and a two-stage deep-bed filtering device are adopted to carry out degassing and filtering on the aluminum alloy melt, and the flow rates of chlorine and argon introduced into the SINF online degassing device are respectively 1.5m3H and 8.5m3/h。
Preferably, the SINF is provided with a titanium wire for grain refinement at the inlet of the line degassing device, and the titanium wire is 5Ti 1B.
Preferably, in the first half hour of the continuous casting process in the step (4), the steel brush is started to clean the HC type plate strip on the Hatzerland continuous casting machine, and after the cleaning is finished, the HC type plate strip is sprayed by using the graphite spraying system.
Preferably, in the continuous casting process in the step (4), the temperature range of the aluminum liquid in the front box of the Hatzerland continuous casting machine is 696 +/-3 ℃, the temperature range of the casting cooling water is 30 +/-3 ℃, the length of the die cavity of the casting zone is 2700mm, the casting speed is 7.0m/min, and the temperature ranges of the edge part and the middle part of the HC type plate strip at the outlet of the casting machine are 590 +/-10 ℃ and 520 +/-10 ℃ respectively.
Preferably, the final rolling temperature range of the MINO triple tandem rolling mill in the step (5) is 130-.
Has the advantages that: the invention discloses a continuous casting and rolling production process of 3003 aluminum alloy strips, which has the following advantages: (1) the production process adopts a continuous casting and rolling technology, reduces the subsequent cold rolling and rolling processing process, and greatly improves the production efficiency of the aluminum alloy strip; (2) the rolling temperature of the first frame of the MINO triple tandem rolling mill is higher than the crystallization temperature of the aluminum alloy, the method belongs to a hot rolling process, the crystal grains are subjected to incomplete recrystallization, the metal plasticity is improved, the deformation resistance is reduced, and meanwhile compared with the traditional cast rolling, the plate blank crystal grains are finer.
Detailed description of the preferred embodiments
In order to enhance the understanding of the present invention, the present invention will be described in further detail with reference to the following examples, which are only for the purpose of illustrating the present invention and are not to be construed as limiting the scope of the present invention.
A continuous casting and rolling production process of a 3003 aluminum alloy strip comprises the following components in percentage by mass: 0.20-0.30% of Fe, 0.40-0.50% of Si, 1.05-1.20% of Mn, 0.08-1.20% of Cu, 0.015-0.030% of Ti, less than or equal to 0.01% of Mg, less than or equal to 0.03% of Zn, less than or equal to 0.05% of other alloys and the balance of Al, wherein the production process comprises the following steps:
(1) smelting: sequentially adding 20% of solid materials and 80% of electrolytic aluminum liquid by mass percent into a smelting furnace as alloy ingredients, raising the temperature of the furnace in the smelting furnace to 690 ℃, and performing electromagnetic stirring to obtain aluminum alloy melt, wherein the solid materials comprise aluminum ingots, aluminum alloy waste materials and other alloy element ingredients;
(2) refining and slagging-off: heating the aluminum alloy melt obtained in the step (1) to 725 +/-10 ℃, refining and slagging off by using a refining agent, sampling after refining and slagging off, carrying out alloy proportioning according to a detection result, carrying out electromagnetic stirring again after proportioning, and pouring the aluminum alloy melt with the adjusted components into a heat preservation furnace;
(3) degassing and filtering: heating the holding furnace, and when the furnace temperature of the holding furnace reaches 730 +/-5 ℃, degassing and filtering the aluminum alloy melt by using mixed gas of chlorine and argon;
(4) continuous casting: continuously casting the refined aluminum alloy melt into a continuous casting blank by a Hatzrett continuous casting machine, wherein the size of the continuous casting blank is 19mm multiplied by 1280mm multiplied by L;
(5) continuous rolling: rolling the continuous casting blank into a cast-rolling plate material with the size of 2.3mm multiplied by 1280mm multiplied by L by an MINO three-continuous rolling mill, wherein the thickness change of the cast-rolling plate material in the three-time rolling process is respectively 19mm-9.5mm, 9.5mm-5.7mm and 5.7mm-3.8 mm;
(6) and (5) annealing the cast-rolled plate obtained in the step (5) to obtain the 3003 aluminum alloy strip.
In this embodiment, the temperature of the molten aluminum alloy is not lower than 690 ℃ during the refining and slagging-off process in step (2).
In this embodiment, in the step (3), the SINF online degassing device and the two-stage deep-bed filtering device are used to perform degassing and filtering on the aluminum alloy melt, and the flow rates of chlorine and argon introduced into the SINF online degassing device are 1.5m3H and 8.5m3/h。
In this embodiment, a titanium wire for grain refinement is provided at the inlet of the SINF on-line degassing apparatus, and the titanium wire is 5Ti 1B.
In this embodiment, in the first half hour of the continuous casting process in step (4), the steel brush is started to clean the HC-type plate strip on the hartmann continuous casting machine, and after the cleaning is completed, the HC-type plate strip is sprayed by using the graphite spraying system.
In the present embodiment, in the continuous casting process in step (4), the temperature range of the molten aluminum in the front box of the hartsantel continuous casting machine is 696 ± 3 ℃, the temperature range of the casting cooling water is 30 ± 3 ℃, the length of the cavity of the casting zone is 2700mm, the casting speed is 7.0m/min, and the temperature ranges of the edge part and the middle part of the HC-type plate strip at the outlet of the casting machine are 590 ± 10 ℃ and 520 ± 10 ℃ respectively.
In this embodiment, the final rolling temperature range of the MINO triple tandem rolling mill in the step (5) is 150 ℃ and the coil diameter is 2500mm and 130-.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (7)

1. The continuous casting and rolling production process of the 3003 aluminum alloy strip is characterized in that the 3003 aluminum alloy strip comprises the following components in percentage by mass: 0.20-0.30% of Fe, 0.40-0.50% of Si, 1.05-1.20% of Mn, 0.08-1.20% of Cu, 0.015-0.030% of Ti, less than or equal to 0.01% of Mg, less than or equal to 0.03% of Zn, less than or equal to 0.05% of other alloys and the balance of Al, wherein the production process comprises the following steps:
(1) smelting: sequentially adding 20% of solid materials and 80% of electrolytic aluminum liquid by mass percent into a smelting furnace as alloy ingredients, raising the temperature of the furnace in the smelting furnace to 690 ℃, and performing electromagnetic stirring to obtain aluminum alloy melt, wherein the solid materials comprise aluminum ingots, aluminum alloy waste materials and other alloy element ingredients;
(2) refining and slagging-off: heating the aluminum alloy melt obtained in the step (1) to 725 +/-10 ℃, refining and slagging off by using a refining agent, sampling after refining and slagging off, carrying out alloy proportioning according to a detection result, carrying out electromagnetic stirring again after proportioning, and pouring the aluminum alloy melt with the adjusted components into a heat preservation furnace;
(3) degassing and filtering: heating the holding furnace, and when the furnace temperature of the holding furnace reaches 730 +/-5 ℃, degassing and filtering the aluminum alloy melt by using mixed gas of chlorine and argon;
(4) continuous casting: continuously casting the refined aluminum alloy melt into a continuous casting blank by a Hatzrett continuous casting machine, wherein the size of the continuous casting blank is 19mm multiplied by 1280mm multiplied by L;
(5) continuous rolling: rolling the continuous casting blank into a cast-rolling plate material with the size of 2.3mm multiplied by 1280mm multiplied by L by an MINO three-continuous rolling mill, wherein the thickness change of the cast-rolling plate material in the three-time rolling process is respectively 19mm-9.5mm, 9.5mm-5.7mm and 5.7mm-3.8 mm;
(6) and (5) annealing the cast-rolled plate obtained in the step (5) to obtain the 3003 aluminum alloy strip.
2. The continuous casting and rolling production process of 3003 aluminum alloy strip according to claim 1, wherein the temperature of the molten aluminum alloy is not lower than 690 ℃ during the refining and slagging-off process of step (2).
3. The continuous casting and rolling production process of 3003 aluminum alloy strips according to claim 1, wherein in step (3), the aluminum alloy melt is degassed and filtered by an SINF online degassing device and a two-stage deep-bed filtering device, and the flow rates of chlorine and argon introduced into the SINF online degassing device are 1.5m3H and 8.5m3/h。
4. The continuous casting and rolling production process of 3003 aluminum alloy strip according to claim 3, wherein the inlet of the SINF on-line degassing device is provided with a titanium wire for grain refinement, and the titanium wire is 5Ti 1B.
5. The continuous casting and rolling production process of 3003 aluminum alloy strip according to claim 1, wherein the HC type strip of the Hatzerland continuous casting machine is cleaned by starting the steel brush half an hour before the continuous casting process of step (4), and the HC type strip is sprayed by using the graphite spraying system after the cleaning.
6. The continuous casting and rolling production process of 3003 aluminum alloy strip according to claim 1, wherein in the continuous casting of step (4), the temperature of the molten aluminum in the front box of the hart-rett continuous casting machine is 696 ± 3 ℃, the temperature of the cooling water for casting is 30 ± 3 ℃, the length of the cavity of the casting zone is 2700mm, the casting speed is 7.0m/min, and the temperature of the edge and the middle of the HC-molded strip at the outlet of the casting machine are 590 ± 10 ℃ and 520 ± 10 ℃ respectively.
7. The continuous casting and rolling production process of 3003 aluminum alloy strip according to claim 1, wherein the final rolling temperature of the MINO triple continuous rolling mill in step (5) is in the range of 130 ℃ to 150 ℃ and the coil diameter is in the range of 2000 mm to 2500 mm.
CN202110513358.4A 2021-05-11 2021-05-11 Continuous casting and rolling production process of 3003 aluminum alloy strip Pending CN113388748A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113957296A (en) * 2021-10-21 2022-01-21 江苏鼎胜新能源材料股份有限公司 Water tank main board material produced by Hazilite 3003 core material and manufacturing method thereof
CN114134358A (en) * 2021-11-12 2022-03-04 内蒙古联晟新能源材料有限公司 Continuous casting and rolling production process of 1030B aluminum plate
CN114192664A (en) * 2021-12-16 2022-03-18 内蒙古联晟新能源材料有限公司 2030mm aluminum foil material production process based on Hatzerland production line
CN114410999A (en) * 2021-12-24 2022-04-29 宁德福浦新合金科技有限公司 Continuous casting and rolling production process of 3014 aluminum alloy plate strip

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113957296A (en) * 2021-10-21 2022-01-21 江苏鼎胜新能源材料股份有限公司 Water tank main board material produced by Hazilite 3003 core material and manufacturing method thereof
CN114134358A (en) * 2021-11-12 2022-03-04 内蒙古联晟新能源材料有限公司 Continuous casting and rolling production process of 1030B aluminum plate
CN114192664A (en) * 2021-12-16 2022-03-18 内蒙古联晟新能源材料有限公司 2030mm aluminum foil material production process based on Hatzerland production line
CN114410999A (en) * 2021-12-24 2022-04-29 宁德福浦新合金科技有限公司 Continuous casting and rolling production process of 3014 aluminum alloy plate strip

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Application publication date: 20210914