CN113387581A - Medium-temperature transmutation glaze formula and preparation method thereof - Google Patents

Medium-temperature transmutation glaze formula and preparation method thereof Download PDF

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Publication number
CN113387581A
CN113387581A CN202110648935.0A CN202110648935A CN113387581A CN 113387581 A CN113387581 A CN 113387581A CN 202110648935 A CN202110648935 A CN 202110648935A CN 113387581 A CN113387581 A CN 113387581A
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China
Prior art keywords
parts
temperature
medium
glaze
transmutation glaze
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CN202110648935.0A
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Chinese (zh)
Inventor
李文平
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Liling United Ceramic Ware Manufacturing Co ltd
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Liling United Ceramic Ware Manufacturing Co ltd
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Priority to CN202110648935.0A priority Critical patent/CN113387581A/en
Publication of CN113387581A publication Critical patent/CN113387581A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

Abstract

The invention discloses a medium-temperature transmutation glaze formula and a preparation method thereof, wherein the formula comprises the following components: spodumene, potash feldspar, quartz, kaolin, titanium oxide, calcite, zinc oxide, talcum powder, glass powder, dolomite, high-boron frit, cobalt oxide, iron oxide and chromium oxide; compared with the prior art, the invention has the beneficial effects that: the colors and effects of the medium-temperature blue transmutation glaze, the medium-temperature titanium white transmutation glaze and the medium-temperature safflower transmutation glaze are original, the glazing concentration of the three kinds of glaze is the same as the firing temperature, the medium-temperature blue transmutation glaze, the medium-temperature titanium white transmutation glaze and the medium-temperature safflower transmutation glaze can be glazed or fired in the same environment, the stability can be improved, and the rejection rate can be reduced.

Description

Medium-temperature transmutation glaze formula and preparation method thereof
Technical Field
The invention relates to the field of ceramics, in particular to a medium-temperature transmutation glaze formula and a preparation method thereof.
Background
The glaze is a colorless or colored vitreous thin layer covering the surface of the ceramic product, and is prepared by grinding and making glaze slurry by matching mineral raw materials (feldspar, quartz, talc, kaolin, etc.) and raw materials according to a certain proportion (part of the raw materials can be made into frits first), applying the glaze slurry on the surface of a blank body, and calcining at a certain temperature. It can increase the mechanical strength, thermal stability and dielectric strength of the product, and also has the characteristics of beautifying the ware, being convenient for wiping and washing, being not eroded by the fishy smell of dust, etc. Different medium-temperature glazes are prepared by adopting different glaze pigments, the use temperature and the suitable firing atmosphere of each glaze pigment are different, so that inconvenience is brought to production, and the production cost can be greatly increased by setting up workshops in different environments.
Disclosure of Invention
The invention aims to overcome the defects that different glaze pigments used in different medium-temperature glazes are different, the use temperature and the suitable firing atmosphere are different, and inconvenience is brought to production, and the like, and provides a technical scheme capable of solving the problems.
The medium-temperature transmutation glaze formula comprises the following components: spodumene, potash feldspar, quartz, kaolin, titanium oxide, calcite, zinc oxide, talcum powder, glass powder, dolomite, high-boron frit, cobalt oxide, iron oxide and chromium oxide;
intermediate-temperature blue transmutation glaze: taking 20-35 parts of spodumene, 15-25 parts of quartz, 10-18 parts of calcite, 5-12 parts of zinc oxide, 2-8 parts of kaolin, 5-10 parts of high-boron clinker, 5-9 parts of titanium oxide and 2-6 parts of cobalt oxide according to parts by mass;
medium-temperature titanium dioxide transmutation glaze: weighing 15-25 parts of spodumene, 15-20 parts of quartz, 10-18 parts of calcite, 5-12 parts of zinc oxide, 2-8 parts of kaolin, 2-6 parts of talcum powder, 15-30 parts of high-boron frit and 5-10 parts of titanium oxide in parts by mass;
the medium-temperature safflower transmutation glaze is prepared from 25-35 parts of potassium feldspar, 3-8 parts of quartz, 2-8 parts of kaolin, 15-20 parts of talcum powder, 8-12 parts of glass powder, 12-18 parts of dolomite, 5-8 parts of titanium oxide, 3-6 parts of ferric oxide and 2-4 parts of chromium oxide by mass.
As one improvement of the technical scheme, the medium-temperature blue transmutation glaze: according to the mass portion, 30 portions of spodumene, 20 portions of quartz, 15 portions of calcite, 10 portions of zinc oxide, 5 portions of kaolin, 9 portions of high-boron frit, 7 portions of titanium oxide and 4 portions of cobalt oxide are taken.
As one improvement of the technical scheme, the medium-temperature titanium dioxide transmutation glaze: according to the mass portion, 20 portions of spodumene, 18 portions of quartz, 12 portions of calcite, 10 portions of zinc oxide, 3 portions of kaolin, 4 portions of talcum powder, 26 portions of high-boron frit and 7 portions of titanium oxide are taken.
As one improvement of the technical scheme, the medium-temperature safflower transmutation glaze is prepared by taking 30 parts of potassium feldspar, 5 parts of quartz, 5 parts of kaolin, 20 parts of talcum powder, 10 parts of glass powder, 15 parts of dolomite, 7 parts of titanium oxide, 5 parts of iron oxide and 3 parts of chromium oxide according to the mass parts.
A medium-temperature transmutation glaze formula and a preparation method thereof comprise the following steps:
s1, mixing the raw materials of any formula of the medium-temperature blue transmutation glaze, the medium-temperature titanium white transmutation glaze or the medium-temperature safflower transmutation glaze to prepare glaze;
s2, putting the glaze into a ball mill, and adding water for ball milling;
s3, obtaining glaze slip after ball milling, and sieving the glaze slip;
and S4, glazing the porcelain and firing.
As one improvement of the technical scheme, the weight ratio of the dry weight of the glaze in the S2 to the water is 3: 7.
As one improvement of the technical scheme, the ball milling time in the S2 is 22-25 hours.
As an improvement of the technical scheme, the glaze slip after the ball milling in the S3 is sieved by a 180-mesh sieve.
As one improvement of the technical scheme, the glazing concentration in the S4 is 52 ℃, and the firing temperature is 1220-1250 ℃.
Compared with the prior art, the invention has the beneficial effects that: the colors and effects of the medium-temperature blue transmutation glaze, the medium-temperature titanium white transmutation glaze and the medium-temperature safflower transmutation glaze are original, the glazing concentration of the three kinds of glaze is the same as the firing temperature, the medium-temperature blue transmutation glaze, the medium-temperature titanium white transmutation glaze and the medium-temperature safflower transmutation glaze can be glazed or fired in the same environment, the stability can be improved, and the rejection rate can be reduced.
Additional aspects and advantages of the invention will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the embodiment of the invention, the medium-temperature transmutation glaze formula comprises the following components: spodumene, potash feldspar, quartz, kaolin, titanium oxide, calcite, zinc oxide, talcum powder, glass powder, dolomite, high-boron frit, cobalt oxide, iron oxide and chromium oxide;
intermediate-temperature blue transmutation glaze: taking 20-35 parts of spodumene, 15-25 parts of quartz, 10-18 parts of calcite, 5-12 parts of zinc oxide, 2-8 parts of kaolin, 5-10 parts of high-boron clinker, 5-9 parts of titanium oxide and 2-6 parts of cobalt oxide according to parts by mass;
medium-temperature titanium dioxide transmutation glaze: weighing 15-25 parts of spodumene, 15-20 parts of quartz, 10-18 parts of calcite, 5-12 parts of zinc oxide, 2-8 parts of kaolin, 2-6 parts of talcum powder, 15-30 parts of high-boron frit and 5-10 parts of titanium oxide in parts by mass;
the medium-temperature safflower transmutation glaze is prepared from 25-35 parts of potassium feldspar, 3-8 parts of quartz, 2-8 parts of kaolin, 15-20 parts of talcum powder, 8-12 parts of glass powder, 12-18 parts of dolomite, 5-8 parts of titanium oxide, 3-6 parts of ferric oxide and 2-4 parts of chromium oxide by mass.
The first embodiment is as follows: medium-temperature blue transmutation glaze
A medium-temperature blue transmutation glaze formula and a preparation method thereof comprise the following steps:
s1, mixing 30 parts of spodumene, 20 parts of quartz, 15 parts of calcite, 10 parts of zinc oxide, 5 parts of kaolin, 9 parts of high-boron frit, 7 parts of titanium oxide and 4 parts of cobalt oxide by mass to prepare glaze;
s2, putting the glaze into a ball mill, adding water for ball milling, wherein the weight ratio of the dry weight of the glaze to the water is 3:7, and the ball milling time is 22-25 hours.
And S3, obtaining glaze slip after ball milling, and sieving the glaze slip with a 180-mesh sieve after ball milling.
S4, glazing the porcelain, wherein the glazing concentration is 52 ℃, and the firing temperature is 1220-1250 ℃.
Example two: medium-temperature titanium dioxide transmutation glaze
A medium-temperature titanium dioxide transmutation glaze formula and a preparation method thereof comprise the following steps:
s1, mixing 20 parts of spodumene, 18 parts of quartz, 12 parts of calcite, 10 parts of zinc oxide, 3 parts of kaolin, 4 parts of talcum powder, 26 parts of high-boron frit and 7 parts of titanium oxide by mass to prepare glaze;
s2, putting the glaze into a ball mill, adding water for ball milling, wherein the weight ratio of the dry weight of the glaze to the water is 3:7, and the ball milling time is 22-25 hours.
And S3, obtaining glaze slip after ball milling, and sieving the glaze slip with a 180-mesh sieve after ball milling.
S4, glazing the porcelain, wherein the glazing concentration is 52 ℃, and the firing temperature is 1220-1250 ℃.
Example three: medium-temperature safflower transmutation glaze
A medium-temperature safflower transmutation glaze formula and a preparation method thereof comprise the following steps:
s1, mixing 30 parts of potassium feldspar, 5 parts of quartz, 5 parts of kaolin, 20 parts of talcum powder, 10 parts of glass powder, 15 parts of dolomite, 7 parts of titanium oxide, 5 parts of iron oxide and 3 parts of chromium oxide according to the mass parts to prepare the glaze.
S2, putting the glaze into a ball mill, adding water for ball milling, wherein the weight ratio of the dry weight of the glaze to the water is 3:7, and the ball milling time is 22-25 hours.
And S3, obtaining glaze slip after ball milling, and sieving the glaze slip with a 180-mesh sieve after ball milling.
S4, glazing the porcelain, wherein the glazing concentration is 52 ℃, and the firing temperature is 1220-1250 ℃.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (9)

1. The medium-temperature transmutation glaze formula is characterized by comprising the following components: spodumene, potash feldspar, quartz, kaolin, titanium oxide, calcite, zinc oxide, talcum powder, glass powder, dolomite, high-boron frit, cobalt oxide, iron oxide and chromium oxide;
intermediate-temperature blue transmutation glaze: taking 20-35 parts of spodumene, 15-25 parts of quartz, 10-18 parts of calcite, 5-12 parts of zinc oxide, 2-8 parts of kaolin, 5-10 parts of high-boron clinker, 5-9 parts of titanium oxide and 2-6 parts of cobalt oxide according to parts by mass;
medium-temperature titanium dioxide transmutation glaze: weighing 15-25 parts of spodumene, 15-20 parts of quartz, 10-18 parts of calcite, 5-12 parts of zinc oxide, 2-8 parts of kaolin, 2-6 parts of talcum powder, 15-30 parts of high-boron frit and 5-10 parts of titanium oxide in parts by mass;
the medium-temperature safflower transmutation glaze is prepared from 25-35 parts of potassium feldspar, 3-8 parts of quartz, 2-8 parts of kaolin, 15-20 parts of talcum powder, 8-12 parts of glass powder, 12-18 parts of dolomite, 5-8 parts of titanium oxide, 3-6 parts of ferric oxide and 2-4 parts of chromium oxide by mass.
2. The medium-temperature transmutation glaze formula according to claim 1, characterized in that: intermediate-temperature blue transmutation glaze: according to the mass portion, 30 portions of spodumene, 20 portions of quartz, 15 portions of calcite, 10 portions of zinc oxide, 5 portions of kaolin, 9 portions of high-boron frit, 7 portions of titanium oxide and 4 portions of cobalt oxide are taken.
3. The medium-temperature transmutation glaze formula according to claim 1, characterized in that: medium-temperature titanium dioxide transmutation glaze: according to the mass portion, 20 portions of spodumene, 18 portions of quartz, 12 portions of calcite, 10 portions of zinc oxide, 3 portions of kaolin, 4 portions of talcum powder, 26 portions of high-boron frit and 7 portions of titanium oxide are taken.
4. The medium-temperature transmutation glaze formula according to claim 1, characterized in that: the medium-temperature safflower transmutation glaze is prepared from 30 parts of potassium feldspar, 5 parts of quartz, 5 parts of kaolin, 20 parts of talcum powder, 10 parts of glass powder, 15 parts of dolomite, 7 parts of titanium oxide, 5 parts of iron oxide and 3 parts of chromium oxide by mass.
5. The intermediate-temperature transmutation glaze formula and the preparation method thereof are applied to the intermediate-temperature transmutation glaze formula as claimed in claim 1, and are characterized in that: the method comprises the following steps:
s1, mixing the raw materials of any formula of the medium-temperature blue transmutation glaze, the medium-temperature titanium white transmutation glaze or the medium-temperature safflower transmutation glaze to prepare glaze;
s2, putting the glaze into a ball mill, and adding water for ball milling;
s3, obtaining glaze slip after ball milling, and sieving the glaze slip;
and S4, glazing the porcelain and firing.
6. The medium-temperature transmutation glaze formula and the preparation method thereof according to claim 1 are characterized in that: the weight ratio of the dry weight of the glaze to the water in the S2 is 3: 7.
7. The medium-temperature transmutation glaze formula and the preparation method thereof according to claim 1 are characterized in that: and the ball milling time in the S2 is 22-25 hours.
8. The medium-temperature transmutation glaze formula and the preparation method thereof according to claim 1 are characterized in that: and (3) sieving the glaze slip subjected to ball milling in the step S3 by using a 180-mesh sieve.
9. The medium-temperature transmutation glaze formula and the preparation method thereof according to claim 1 are characterized in that: the glazing concentration in the S4 is 52 ℃, and the firing temperature is 1220-1250 ℃.
CN202110648935.0A 2021-06-10 2021-06-10 Medium-temperature transmutation glaze formula and preparation method thereof Pending CN113387581A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4507392A (en) * 1983-12-08 1985-03-26 Corning Glass Works Transparent glass-ceramics of high negative expansion for use as decorative glazes
CN1962557A (en) * 2006-12-06 2007-05-16 江苏高淳陶瓷股份有限公司 Ceramic scarlet-variable glaze and its application method
CN105776862A (en) * 2016-03-25 2016-07-20 江苏宜翔陶瓷科技有限公司 Kiln change sorghum safflower glaze for high-performance ceramic container and preparation method thereof
CN107540223A (en) * 2017-10-17 2018-01-05 禹州市锦丰源瓷业有限公司 A kind of pottery jewel blue glaze of high rigidity and preparation method thereof
CN110790506A (en) * 2019-12-18 2020-02-14 湖南华联瓷业股份有限公司 Granular double-layer reaction glaze and preparation method thereof
CN110937814A (en) * 2019-12-12 2020-03-31 醴陵市湘润陶瓷制造有限公司 Matte color transmutation glaze and preparation method thereof
CN112358183A (en) * 2020-11-25 2021-02-12 湖南华联瓷业股份有限公司 High-temperature dark green transmutation reaction glaze and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4507392A (en) * 1983-12-08 1985-03-26 Corning Glass Works Transparent glass-ceramics of high negative expansion for use as decorative glazes
CN1962557A (en) * 2006-12-06 2007-05-16 江苏高淳陶瓷股份有限公司 Ceramic scarlet-variable glaze and its application method
CN105776862A (en) * 2016-03-25 2016-07-20 江苏宜翔陶瓷科技有限公司 Kiln change sorghum safflower glaze for high-performance ceramic container and preparation method thereof
CN107540223A (en) * 2017-10-17 2018-01-05 禹州市锦丰源瓷业有限公司 A kind of pottery jewel blue glaze of high rigidity and preparation method thereof
CN110937814A (en) * 2019-12-12 2020-03-31 醴陵市湘润陶瓷制造有限公司 Matte color transmutation glaze and preparation method thereof
CN110790506A (en) * 2019-12-18 2020-02-14 湖南华联瓷业股份有限公司 Granular double-layer reaction glaze and preparation method thereof
CN112358183A (en) * 2020-11-25 2021-02-12 湖南华联瓷业股份有限公司 High-temperature dark green transmutation reaction glaze and preparation method thereof

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