CN113307830A - 金属卡宾烯烃易位催化剂 - Google Patents

金属卡宾烯烃易位催化剂 Download PDF

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Publication number
CN113307830A
CN113307830A CN202110611820.4A CN202110611820A CN113307830A CN 113307830 A CN113307830 A CN 113307830A CN 202110611820 A CN202110611820 A CN 202110611820A CN 113307830 A CN113307830 A CN 113307830A
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CN
China
Prior art keywords
substituted
phenyl
alkyl
hydrocarbyl
aryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110611820.4A
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English (en)
Chinese (zh)
Inventor
M·A·吉阿德罗
M·S·特里默
王利盛
N·H·杜菲
A·M·约翰斯
N·J·罗达克
B·A·菲亚门戈
J·H·菲利普斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Umicore Corp And Lianghe Co
Umicore AG and Co KG
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Umicore Corp And Lianghe Co
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Filing date
Publication date
Application filed by Umicore Corp And Lianghe Co filed Critical Umicore Corp And Lianghe Co
Publication of CN113307830A publication Critical patent/CN113307830A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3324—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from norbornene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3325—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other polycyclic systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Catalysts (AREA)
  • Polymerization Catalysts (AREA)
CN202110611820.4A 2015-09-24 2016-09-23 金属卡宾烯烃易位催化剂 Pending CN113307830A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562222989P 2015-09-24 2015-09-24
US62/222,989 2015-09-24
CN201680055546.4A CN108779134B (zh) 2015-09-24 2016-09-23 金属卡宾烯烃易位催化剂

Related Parent Applications (1)

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Publications (1)

Publication Number Publication Date
CN113307830A true CN113307830A (zh) 2021-08-27

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CN202110611820.4A Pending CN113307830A (zh) 2015-09-24 2016-09-23 金属卡宾烯烃易位催化剂
CN201680055546.4A Active CN108779134B (zh) 2015-09-24 2016-09-23 金属卡宾烯烃易位催化剂

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Country Status (10)

Country Link
US (1) US10501488B2 (https=)
EP (1) EP3353187B1 (https=)
JP (2) JP7013370B2 (https=)
KR (1) KR20180059489A (https=)
CN (2) CN113307830A (https=)
BR (1) BR112018005823A2 (https=)
CA (1) CA2999864A1 (https=)
MX (1) MX2018003639A (https=)
PL (1) PL3353187T3 (https=)
WO (1) WO2017053690A1 (https=)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL3353187T3 (pl) * 2015-09-24 2021-11-22 Umicore Ag & Co. Kg Katalizatory metatezy olefin na bazie karbenu metalu
KR102670566B1 (ko) * 2019-01-18 2024-05-31 광주과학기술원 루테늄 착화합물, 이의 제조를 위한 리간드 및 이의 용도
WO2020214399A2 (en) * 2019-03-28 2020-10-22 University Of Florida Research Foundation, Inc. High temperature bulk metathesis polymerization
CN115819724A (zh) * 2022-12-27 2023-03-21 上海中化科技有限公司 环氧-环烯烃树脂组合物、热固性树脂材料及其制备方法

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US6077805A (en) * 1997-03-06 2000-06-20 Ciba Specialty Chemicals Corporation Hexacoordinated ruthenium or osmium carbene catalysts
CN101594937A (zh) * 2006-11-21 2009-12-02 加州理工学院 含有亚噻唑-2-基配体的烯烃复分解反应引发剂
CN103402628A (zh) * 2011-01-14 2013-11-20 加州理工学院 Z-选择性烯烃复分解催化剂及其合成步骤
WO2014134333A1 (en) * 2013-02-27 2014-09-04 Materia, Inc. Metal carbene olefin metathesis two catalyst composition
CN104220418A (zh) * 2012-03-14 2014-12-17 优美科股份公司及两合公司 钌基复分解催化剂以及用于其制备的前体
CN104371044A (zh) * 2013-12-19 2015-02-25 上海克琴化工科技有限公司 一种钌金属催化剂的制备及其在开环易位聚合反应中的应用
CN108779134B (zh) * 2015-09-24 2023-10-03 优美科股份公司及两合公司 金属卡宾烯烃易位催化剂

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US4899005A (en) 1987-11-19 1990-02-06 The B. F. Goodrich Company Method for preparing cycloolefin copolymers with improved heat stability
US5204427A (en) 1989-11-01 1993-04-20 Nippon Zeon Co., Ltd. Method of making ring-opened polynorbornene polymers using pot life extending agents
TW350851B (en) 1995-01-31 1999-01-21 Ciba Sc Holding Ag Polymerizable composition and process for the preparation of network polymer
US5728785A (en) 1995-07-07 1998-03-17 California Institute Of Technology Romp polymerization in the presence of peroxide crosslinking agents to form high-density crosslinked polymers
US5939504A (en) 1995-12-07 1999-08-17 Advanced Polymer Technologies Method for extending the pot life of an olefin metathesis polymerization reaction
DE19815275B4 (de) 1998-04-06 2009-06-25 Evonik Degussa Gmbh Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese
JP5066656B2 (ja) 1998-09-10 2012-11-07 ユニバーシティ・オブ・ニュー・オーリンズ・リサーチ・アンド・テクノロジー・ファウンデーション・インコーポレーテッド カルベンリガンドを持った触媒錯体
DE19902439A1 (de) 1999-01-22 2000-08-03 Aventis Res & Tech Gmbh & Co Homo- und heterobimetallische Alkylidenkomplexe des Rutheniums mit N-heterocyclischen Carbenliganden und deren Anwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese
US6409875B1 (en) 1999-02-05 2002-06-25 Materia, Inc. Metathesis-active adhesion agents and methods for enhancing polymer adhesion to surfaces
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EP2251360B1 (en) 2001-08-29 2013-07-31 California Institute of Technology Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms
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CN103402628A (zh) * 2011-01-14 2013-11-20 加州理工学院 Z-选择性烯烃复分解催化剂及其合成步骤
CN104220418A (zh) * 2012-03-14 2014-12-17 优美科股份公司及两合公司 钌基复分解催化剂以及用于其制备的前体
WO2014134333A1 (en) * 2013-02-27 2014-09-04 Materia, Inc. Metal carbene olefin metathesis two catalyst composition
CN104371044A (zh) * 2013-12-19 2015-02-25 上海克琴化工科技有限公司 一种钌金属催化剂的制备及其在开环易位聚合反应中的应用
CN108779134B (zh) * 2015-09-24 2023-10-03 优美科股份公司及两合公司 金属卡宾烯烃易位催化剂

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Also Published As

Publication number Publication date
KR20180059489A (ko) 2018-06-04
JP2022010098A (ja) 2022-01-14
US10501488B2 (en) 2019-12-10
JP7013370B2 (ja) 2022-01-31
JP7810545B2 (ja) 2026-02-03
EP3353187A4 (en) 2019-05-01
CN108779134A (zh) 2018-11-09
CN108779134B (zh) 2023-10-03
BR112018005823A2 (en) 2018-10-16
MX2018003639A (es) 2019-04-25
WO2017053690A1 (en) 2017-03-30
US20180265532A1 (en) 2018-09-20
EP3353187B1 (en) 2021-07-21
EP3353187A1 (en) 2018-08-01
JP2018537546A (ja) 2018-12-20
PL3353187T3 (pl) 2021-11-22
CA2999864A1 (en) 2017-03-30

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