CN113244125A - Shampoo containing sulfate locust bean gum-amino acid thickener - Google Patents
Shampoo containing sulfate locust bean gum-amino acid thickener Download PDFInfo
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- CN113244125A CN113244125A CN202110578871.1A CN202110578871A CN113244125A CN 113244125 A CN113244125 A CN 113244125A CN 202110578871 A CN202110578871 A CN 202110578871A CN 113244125 A CN113244125 A CN 113244125A
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- locust bean
- bean gum
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/678—Tocopherol, i.e. vitamin E
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
Abstract
The invention relates to a shampoo containing sulfate locust bean gum-amino acid thickener, which comprises a conditioner, a surfactant, a thickener, a humectant, an emulsion stabilizer and other additives, wherein the thickener is sulfate locust bean gum-amino acid, is obtained by carrying out sulfation reaction on natural locust bean gum and combining the natural locust bean gum with amino acid in an electrostatic adhesion mode, has a macroporous structure and high water holding capacity, and can continuously supplement water and nutrition for hair, reduce hair dryness, promote hair quality health, nourish and soften hair and restore softness and luster of the hair when being applied to shampoo.
Description
Technical Field
The invention belongs to the field of daily chemical products, and particularly relates to shampoo containing sulfate locust bean gum-amino acid thickener.
Technical Field
Since natural plant polysaccharides have a high molecular weight and a natural thickening effect, they are also widely used in the food and daily chemical industries. The locust bean gum is a natural neutral galactomannan with a molecular weight of about 30 ten thousand daltons, is mainly used as a thickener in the food daily chemical industry, and has a structure that D-mannan is connected with alpha-D-galactopyranose through beta- (1,4) glycosidic bonds at 1 and 6 positions, wherein the ratio of the galactose to the mannose is 1:4, and the locust bean gum is natural plant seed polysaccharide with high mannose content. The natural locust bean gum can be dissolved in water and can be hydrated under certain conditions to form macromolecular substances of viscous liquid or jelly liquid, but due to the fact that the molecular weight of the locust bean gum is large, the viscosity of an aqueous solution is high, and the quantity of water-insoluble substances is large, the performance of compound gel of the locust bean gum is influenced. Therefore, aiming at the defects of the natural plant polysaccharide locust bean gum, the locust bean gum is chemically modified, the water holding capacity of the locust bean gum is improved, the viscosity of a system is improved, the system is kept in a uniform and stable suspension state or emulsion state or forms gel, the stabilizing effect and the quality of an application product are improved, and the locust bean gum can be applied to shampoo.
Disclosure of Invention
In order to solve the technical problems, the invention provides a shampoo containing sulfate locust bean gum-amino acid thickener;
the shampoo is composed of a skin conditioner, a surfactant, a thickening agent, a humectant, an emulsion stabilizer and other additives;
the conditioner is one or a combination of vitamin E, olive oil PEG-7 esters, panthenol, grape seed extract and mint extract;
the surfactant is one or a combination of cocamidopropyl betaine, potassium lauryl phosphate and monolaurin decaglycerol;
the thickening agent is sulfate locust bean gum-amino acid;
the humectant is one or a combination of hyaluronic acid, glycerol and PEG-7 glycerol cocoate;
the emulsion stabilizer is one or a combination of styrene/acrylate copolymer and coco glucoside;
the preservative is one or a combination of methyl chloro isothiazolinone, methyl isothiazolinone, magnesium nitrate and magnesium chloride;
the other additives are essence and pearling agent (ethylene glycol distearate);
the structural formula of the sulfate locust bean gum-amino acid thickener is shown as the following formula (I):
in the formula R1Is one of histidine, lysine and arginine;
the preparation method of the sulfate locust bean gum-amino acid thickener comprises the following steps:
1) hydrating 2-5 g of natural locust bean gum powder at 80-85 ℃ for 10-30 min, standing overnight at room temperature, adding 100-150 mL of acetone to obtain a precipitate, filtering, extruding, washing with 50-100 mL of DMF for 2 times, filtering, and extruding to obtain activated locust bean gum; DMF-SO with a molar ratio of 2:13Mixing the solid and the activated locust bean gum according to a mass ratio of 3:1, dissolving in 4mLDMF, carrying out anhydrous reaction at 5-15 ℃ for 2-4 h to carry out sulfation with different degrees, filtering, washing with acetone, extruding and dissolving in cold water, precipitating with methanol after neutralization, and drying at 30-40 ℃ to obtain Sulfate Locust Bean Gum (SLBG);
2) dissolving 0.1g of sulfuric ester locust bean gum in 10mL of deionized water to prepare a 1% (w/v) solution, dispersing amino acid in the solution, stirring at room temperature for 12h to obtain a mixed solution with arginine content of 0.02-0.08% (w/v), stirring at room temperature for 12h, stirring and heating at 80 ℃ by magnetic force for 30min, cooling, and keeping at 4 ℃ to obtain a sulfuric ester locust bean gum-amino acid (I);
the preparation method of the shampoo containing the sulfate locust bean gum-amino acid thickener comprises the following steps:
step 2, mixing the surfactant, the humectant and the thickener according to the formula ratio, heating to 50-80 ℃, stirring for dissolving, adding the solution obtained by the treatment in the step 1, stirring uniformly, heating to 60-70 ℃, preserving heat and stirring for 0.5-2 hours;
step 3, cooling the solution treated in the step 2 to 50-60 ℃, adding an emulsion stabilizer, a preservative, an essence and a pearling agent in a formula amount, stirring uniformly, adding sodium chloride in a formula amount, and cooling to 40-45 ℃ to obtain the emulsion stabilizer;
the formula and the amount of the components are as follows: 70-80 parts of water, 5-10 parts of a conditioner, 0.5-3 parts of a surfactant, 2-6 parts of a humectant, 2-6 parts of a thickening agent, 0.5-3 parts of an emulsion stabilizer, 0.1-0.5 part of a preservative, 0.1-0.5 part of an essence, 0.1-0.5 part of a pearling agent and 0.1-0.5 part of citric acid, wherein the total is 100 parts;
preferably, the thickener in step 1 can be sulfate locust bean gum-arginine;
preferably, the thickener in the formula amount of the shampoo component can be 5 parts of sulfate locust bean gum-arginine.
Preferably, the formula amounts of the components are as follows: 75 parts of water, 10 parts of grape seed extract, 2 parts of cocamidopropyl betaine, 5 parts of glycerol, 5 parts of sulfate locust bean gum-arginine, 2 parts of coco glucoside, 0.4 part of methylisothiazolinone, 0.2 part of essence, ethylene glycol distearate and citric acid respectively, wherein the total is 100 parts;
by adopting the technical scheme, all components are uniformly dispersed, and the obtained shampoo is uniformly dispersed and is not easy to demulsify.
Compared with the prior art, the invention has the following beneficial effects:
the sulfated locust bean gum and the amino acid can be subjected to electrostatic adsorption to form a smooth pore structure, and the thickener for the shampoo has high water holding capacity, wherein the thickener prepared from the sulfated locust bean gum and the amino acid has better water holding capacity and stability when being used in the shampoo, and can solve the problems of dry hair and the like.
Drawings
FIG. 1 is an infrared spectrum of sulfate locust bean gum-histidine (a), sulfate locust bean gum-lysine (b), sulfate locust bean gum-arginine (c) and natural locust bean gum (d);
FIG. 2 is a graph showing the storage modulus of shampoo samples containing SLBG-LA, SLBG-LH, and SLBG-LY of example 1;
FIG. 3 is the energy consumption modulus of shampoo samples containing SLBG-LA, SLBG-LH, SLBG-LY from example 1;
FIG. 4 is a graph showing the effect of the SLBG-LA content on the storage modulus of shampoo in example 2;
FIG. 5 shows the effect of SLBG-LA content on the energy consumption modulus of shampoo in example 2.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the description is intended to be exemplary only, and is not intended to limit the scope of the present invention. Moreover, in the following description, descriptions of well-known structures and techniques are omitted so as to not unnecessarily obscure the concepts of the present invention.
Example 1
1) Hydrating 2g of natural locust bean gum powder at 80-85 ℃ for 30min, standing overnight at room temperature, adding 100-150 mL of acetone to obtain a precipitate, filtering, and extruding; washing with 50ml DMF for 2 times, filtering, and extruding; DMF-SO with a molar ratio of 2:13Mixing the solid and activated locust bean gum in a mass ratio of 3:1, dissolving in 4mL of DMF, carrying out anhydrous reaction at 5-15 ℃ for 2-4 h for sulfation of different degrees, filtering, washing with acetone, extruding and dissolving in cold water, neutralizing, precipitating with methanol, and drying at 30-40 ℃ to obtain Sulfate Locust Bean Gum (SLBG);
2) dissolving 100mg of sulfate locust bean gum in 10mL of deionized water to prepare 1% (w/v) solution, respectively dispersing arginine, histidine and lysine in the solution to obtain 0.08% (w/v) solution, stirring at room temperature for 12h, heating at 80 deg.C for 30min with magnetic stirring, cooling, maintaining at 4 deg.C to respectively obtain sulfate locust bean gum-arginine thickener (SLBG-LA), sulfate locust bean gum-histidine thickener (SLBG-LH) and sulfate locust bean gum-lysine thickener (SLBG-LY);
3) shampoo preparation
step 2, adding the formula amount of cocamidopropyl betaine and glycerol into SLBG-LA, SLBG-LH and SLBG-LY respectively, mixing, heating to 50-80 ℃, stirring for dissolving, adding the solution obtained by the step 1, stirring uniformly, heating to 60-70 ℃, preserving heat and stirring for 0.5-2 hours;
step 3, cooling the solution treated in the step 2 to 50-60 ℃, adding coco-glucoside, methylisothiazolinone, essence and ethylene glycol distearate in a formula amount, stirring uniformly, adding sodium chloride in a formula amount, and cooling to 40-45 ℃ to obtain the composition;
the formula and the amount of the components are as follows: 75 parts of water, 10 parts of grape seed extract, 2 parts of cocamidopropyl betaine, 5 parts of glycerol, 5 parts of sulfate locust bean gum-amino acid, 2 parts of coco glucoside, 0.4 part of methylisothiazolinone, 0.2 part of essence, ethylene glycol distearate and citric acid respectively, wherein the total is 100 parts;
the three groups of shampoo samples obtained above were subjected to water holding capacity, apparent viscosity, sensory evaluation and rheological analysis under the following measurement conditions:
1) water holding capacity: measuring by centrifuging, accurately weighing the weight of the centrifuge tube, weighing 10.0g of sample, placing into the centrifuge tube, and recording the total weight M0Then placing the mixture in a centrifuge, centrifuging the mixture for 20min at 3600rpm, pouring out water in the centrifuge tube, and weighing M again1The difference between the two weights and M0The ratio of (a) to (b) is the water holding capacity, and three parallel groups are determined for each sample;
2) and (3) measuring the apparent viscosity under the following measurement conditions: 37 ℃ and 60r/min, 1#A rotor;
3) using sensory evaluation (evaluation grade is 0-10 points);
4) rheological analysis: adding the prepared sample on a preheated sample table of a rotational rheometer, adopting a cone plate measuring system with the diameter of 40mm, changing the strain to 1 percent, increasing the temperature from 30 ℃ to 90 ℃ at the speed of 5 ℃/min, then reducing the temperature from 90 ℃ to 30 ℃ at the speed of 5 ℃/min, recording the changes of G 'and G' in the processes of increasing and reducing the temperature, and intercepting the data in a specific temperature range for analysis;
the measurement and evaluation results are shown in Table 1;
table 1: measurement results in shampoo containing SLBG-LA, SLBG-LH, SLBG-LY
The results in table 1 show that the viscosities of the shampoo samples in the three groups are not significantly different, and relatively, the SLBG-LA has larger apparent viscosity and better thickening effect than the SLBG-LH and the SLBG-LY, while the sensory evaluation of the SLBG-LA sample on dry hair is better, and the samples in the three groups are not significantly different under wet hair conditions, so that the use effect of the SLBG-LA sample is better; as shown in the results of rheological measurements in FIGS. 2 and 3, in the three shampoo samples containing SLBG-LA, SLBG-LH and SLBG-LY, arginine has better binding capacity with sulfate locust bean gum, storage modulus G 'and energy consumption modulus G' are higher, the formed molecular structure is more stable, and the binding capacity of histidine, lysine and sulfate locust bean gum is not obviously different compared with histidine and lysine.
Example 2
1) Same as example 1, step 1);
3) same as example 1, step 2), SLBG-LA was obtained;
3) shampoo preparation
step 2, mixing the cocoamidopropyl betaine, the glycerol and the sulfate locust bean gum-arginine according to the formula amount, heating to 50-80 ℃, stirring for dissolving, adding the solution obtained by the step 1, stirring uniformly, heating to 60-70 ℃, preserving heat and stirring for 0.5-2 hours;
step 3, cooling the solution treated in the step 2 to 50-60 ℃, adding coco-glucoside, methylisothiazolinone, essence and ethylene glycol distearate in a formula amount, stirring uniformly, adding sodium chloride in a formula amount, and cooling to 40-45 ℃ to obtain the composition;
the formula and the amount of the components are as follows: 75 parts of water, 10 parts of grape seed extract, 2 parts of cocamidopropyl betaine and 5 parts of glycerol, wherein 3, 4, 5 and 6 parts (marked as SLBG-LA1, SLBG-LA2, SLBG-LA3 and SLBG-LA4), 5 parts of sulfate locust bean gum-arginine, 2 parts of cocoglucoside, 0.4 part of methylisothiazolinone, 0.2 part of essence, ethylene glycol distearate and citric acid respectively are sequentially added in groups, and the total is 100 parts;
the performance of the three shampoo samples obtained above was measured (the measurement method was the same as in example 1), and the measurement and evaluation results are shown in table 2;
table 2: measurement result of addition amount of sulfate locust bean gum-arginine thickening agent on viscosity and water holding capacity of shampoo
From the results in table 2, it can be seen that the viscosity of the shampoo samples of 4 groups increases with the increase of the added amount of SLBG-LA, and when the added amount is 6 parts, the apparent viscosity of the shampoo samples is 385mPa · s, which further leads to the decrease of sensory evaluation, although the hair drying degree can be reduced, the combing of wet hair is difficult, when the added amount is less than 5 parts, the hair drying degree increases, and the moisturizing effect is not obvious, so the invention selects 5 parts of SLBG-LA added amount; the rheological results of 4 groups of shampoo samples with different SLBG-LA contents are shown in figures 4 and 5, and the storage modulus G 'and the energy consumption modulus G' of the SLBG-LA3 are higher than those of other three groups in the processes of temperature rise and temperature drop, which shows that the shampoo obtained by adding 5 parts of the thickening agent has better stability and can damage the stability by needing higher energy.
Example 3
The shampoo samples of example 1 containing SLBG-LA, SLBG-LH, SLBG-LY were subjected to FT-IR under the following layer conditions: freeze-drying the sample, grinding, and performing potassium bromide tabletting with a wavelength scanning range of 4000-400 cm-1；
The above measurement results are shown in figure 1;
in figure 1, there are locust bean gum sulfate-histidine (a), locust bean gum sulfate-lysine (b), locust bean gum sulfate-arginine (c) and natural locust bean gum (d), wherein comparing the former three and d, the fingerprint region has two obvious absorption peaks of 850cm-1And 800cm-1Indicates that it is divided intocontaining-OSO in the substructure3-a group, and d does not contain this absorption peak; 1650cm-1The appearance of a peak indicates NH2The presence of a structure; 3500 + 3300cm-1The peak of the absorption is an absorption peak of O-H, which is mainly hydrogen bonds formed by hydroxyl groups in the polysaccharide molecules, and the peak of the hydroxyl groups in (c) has a blue shift, which indicates that the hydrogen bonds in the molecules are increased.
Claims (5)
1. A shampoo containing sulfate locust bean gum-amino acid thickener is characterized in that the shampoo is composed of a conditioner, a surfactant, a thickener, a humectant, an emulsion stabilizer and other additives;
the conditioner is one or a combination of vitamin E, olive oil PEG-7 esters, panthenol, grape seed extract and mint extract;
the surfactant is one or a combination of cocamidopropyl betaine, potassium lauryl phosphate and monolaurin decaglycerol;
the thickening agent is sulfate locust bean gum-amino acid;
the humectant is one or a combination of hyaluronic acid, glycerol and PEG-7 glycerol cocoate;
the emulsion stabilizer is one or a combination of styrene/acrylate copolymer and coco glucoside;
the preservative is one or a combination of methyl chloro isothiazolinone, methyl isothiazolinone, magnesium nitrate and magnesium chloride;
the other additives are essence and pearling agent (ethylene glycol distearate).
The thickener sulfate locust bean gum-amino acid structure is shown as (I):
in the formula R1Is one of histidine, lysine and arginine.
2. A preparation method of shampoo containing sulfate locust bean gum-amino acid thickener is characterized by comprising the following steps:
step 1, adding water according to the formula amount, stirring, slowly adding a conditioner according to the formula amount, dispersing until no particles exist, adding citric acid according to the formula amount, and stirring uniformly;
step 2, mixing the surfactant, the humectant and the thickener according to the formula ratio, heating to 50-80 ℃, stirring for dissolving, adding the solution obtained by the treatment in the step 1, stirring uniformly, heating to 60-70 ℃, preserving heat and stirring for 0.5-2 hours;
step 3, cooling the solution treated in the step 2 to 50-60 ℃, adding an emulsion stabilizer, a preservative, an essence and a pearling agent in a formula amount, stirring uniformly, adding sodium chloride in a formula amount, and cooling to 40-45 ℃ to obtain the emulsion stabilizer;
the formula and the amount of the components are as follows: 70-80 parts of water, 5-10 parts of a conditioner, 0.5-3 parts of a surfactant, 2-6 parts of a humectant, 2-6 parts of a thickening agent, 0.5-3 parts of an emulsion stabilizer, 0.1-0.5 part of a preservative, 0.1-0.5 part of an essence, 0.1-0.5 part of a pearling agent and 0.1-0.5 part of citric acid, wherein the total is 100 parts;
by adopting the technical scheme, all components are uniformly dispersed, and the obtained shampoo is uniformly dispersed and is not easy to demulsify.
3. The method for preparing a shampoo containing a sulfate locust bean gum-amino acid thickener according to claim 2, wherein the thickener in the step 1 is sulfate locust bean gum-arginine.
4. The method for preparing shampoo containing sulfate locust bean gum-amino acid thickener according to claim 2, wherein the thickener in the formula amount of the shampoo component can be 5 parts of sulfate locust bean gum-arginine.
5. The method for preparing the shampoo containing the sulfate locust bean gum-amino acid thickener according to claim 2, wherein the formula amount of the components of the shampoo is as follows: 75 parts of water, 10 parts of conditioner, 2 parts of surfactant, 5 parts of humectant, 5 parts of thickener, 2 parts of emulsion stabilizer, 0.4 part of preservative, 0.2 part of essence, pearling agent and citric acid respectively, and the total is 100 parts.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202110578871.1A CN113244125A (en) | 2021-05-26 | 2021-05-26 | Shampoo containing sulfate locust bean gum-amino acid thickener |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202110578871.1A CN113244125A (en) | 2021-05-26 | 2021-05-26 | Shampoo containing sulfate locust bean gum-amino acid thickener |
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| CN202110578871.1A Withdrawn CN113244125A (en) | 2021-05-26 | 2021-05-26 | Shampoo containing sulfate locust bean gum-amino acid thickener |
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Application publication date: 20210813 |