CN113241370A - Tunneling field effect transistor based on ferroelectric doping and preparation method thereof - Google Patents

Tunneling field effect transistor based on ferroelectric doping and preparation method thereof Download PDF

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CN113241370A
CN113241370A CN202110501010.3A CN202110501010A CN113241370A CN 113241370 A CN113241370 A CN 113241370A CN 202110501010 A CN202110501010 A CN 202110501010A CN 113241370 A CN113241370 A CN 113241370A
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刘艳
闫钦元
周久人
韩根全
郝跃
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Xidian University
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Abstract

The invention discloses a tunneling field effect transistor based on ferroelectric doping and a preparation method thereof, and mainly solves the problems of uneven impurity concentration, large switching current ratio and sub-threshold swing and high power consumption of the conventional device. It includes: the field emission display device comprises a substrate (1), an oxidation layer (2) and a channel layer (3), wherein a drain electrode (11) and a source electrode (12) are respectively arranged on two sides of the channel layer, a source electrode polarization grid (6) made of ferroelectric materials, a control insulation medium grid (4) and a drain electrode polarization grid (5) made of ferroelectric materials are sequentially arranged above the channel layer, isolation insulation media (7) are arranged on two sides of the source electrode polarization grid and the drain electrode polarization grid, a source electrode polarization electrode (8) is arranged above the source electrode polarization grid, a control grid electrode (9) is arranged above the control medium grid, and a drain electrode polarization electrode (10) is arranged above the drain electrode polarization grid. The invention utilizes the ferroelectric polarization properties of the drain electrode polarization grid and the source electrode polarization grid to realize the accurate control of the carrier concentration of the source and drain doped region and improve the overall performance of the device.

Description

Tunneling field effect transistor based on ferroelectric doping and preparation method thereof
Technical Field
The invention belongs to the field of microelectronic devices, and particularly relates to a tunneling field effect transistor which can be used for manufacturing a next-generation low-power-consumption large-scale integrated circuit.
Background
With the development of integrated circuits, the size of a basic MOS transistor is continuously reduced, and excessive power consumption becomes an important factor restricting the development of integrated circuits. Therefore, the search for a new structure transistor continues to push the continuation of moore's law as one of the important hot topics in the field of integrated circuit research. The tunneling field effect transistor TFET is used as a novel physical device structure, the conduction of current between a source and a drain is realized through the principle of carrier band-to-band tunneling, and lower power consumption and low subthreshold swing amplitude can be still kept under small size. TFETs hold great promise for the next generation of new devices.
At present, the TFET carries out N-type and P-type heavy doping at a source end and a drain end, so that the source end, a channel and the drain end can form a step shape. Under the requirement of a large-scale integrated circuit, ions can be diffused to a channel by doping the source and drain regions in a conventional doping mode, and the size reduction of a device is limited. As shown in fig. 1, the gate of the device is sequentially divided into three regions, namely a left polarization gate PG1, a control gate CG and a right polarization gate PG2, the channel is sequentially divided into a source, a source region, a channel region, a drain region and a drain from left to right, PG1 and PG2 are both conventional metal-oxide-semiconductor gate structures, positive voltage and negative voltage are continuously applied to PG1 and PG2 respectively in the structure, the channel layer controlled by PG1 accumulates high-concentration holes to form the source region, and the channel layer controlled by PG2 accumulates high-concentration electrons to form the drain region, so that a field effect transistor basic functional structure is realized. Although this structure can solve the problem of ion doping diffusion, it needs to apply a constant voltage to PG1 and PG2, and the voltage fluctuation inevitably reduces the stability of the device and greatly increases the power consumption of the device.
Disclosure of Invention
The invention aims to provide a field effect tunneling transistor based on ferroelectric doping and a preparation method thereof aiming at the defects of the prior art, so that the concentration of current carriers is accurately and uniformly controlled by changing the doping mode, the working stability and the durability of the tunneling field effect transistor are improved, the power consumption and the subthreshold swing of a device are reduced, and the performance of the device is improved.
To achieve the above object, the present invention is based on a ferroelectric doped field effect tunneling transistor comprising, from bottom to top: the nano-channel structure comprises a substrate, an oxide layer and a nano-channel layer, wherein a drain electrode and a source electrode are respectively arranged on two sides of the channel layer, a source electrode polarization grid, a control insulation medium grid and a drain electrode polarization grid are sequentially arranged above the channel layer, isolation insulation media are arranged on two sides of the source electrode polarization grid and the drain electrode polarization grid, a drain electrode polarization electrode is arranged above the drain electrode polarization grid, a control grid electrode is arranged above the control medium grid, and a source electrode polarization electrode is arranged above the source electrode polarization grid, and the nano-channel structure is characterized in that:
the thickness of the channel layer is 5 nm-10 nm;
the source electrode polarization gate and the drain electrode polarization gate adopt any ferroelectric material with polarization property to realize the control of doping concentration of the channel layer with nanometer size under the excitation of pulses with different amplitudes, increase the change of the concentration gradient of carriers in the doping region and the channel region of the control gate and inhibit the diffusion of the carriers in the source electrode doping region to the channel.
Further, the ferroelectric material with polarization property comprises HZO and Al2O3、HfO2、ZrO2、BaTiO3、Cd2Nb2O7、BiFeO3、SBT、ZnSnO3And PVDF.
Furthermore, the channel is made of any one of Si, Ge, SiGe, GaN, GaAs and two-dimensional materials.
Further, the substrate is made of any one of Si, Ge, SiC, GaN, sapphire and diamond materials.
Further, it is characterized byThe oxidation is carried out by using SiO2Any one of borosilicate glass and BPSG.
Furthermore, the thickness of the drain electrode polarization grid and the source electrode polarization grid is 1 nm-40 nm, the distance between the drain electrode polarization grid electrode and the control grid electrode is 0-5 nm, and the distance between the source electrode polarization grid electrode and the control grid electrode is 0-8 nm.
In order to achieve the above object, the present invention provides a method for preparing a field effect tunneling transistor based on ferroelectric doping, which comprises the following steps:
1) selecting a substrate consisting of a substrate, an insulating oxide layer and a channel layer in sequence;
2) etching the thickness of the channel layer to 5 nm-10 nm by using an etching process;
3) growing a SiO2 medium layer with the thickness of 2-5 nm on the upper surface of the nanometer channel layer of the SOI substrate by utilizing a chemical vapor deposition process;
4) by etching process, SiO on the left and right sides of the symmetry axis of the substrate2Etching two same grooves with the width of 5-15 nm on the layer to form a control insulated dielectric gate;
5) depositing a ferroelectric material, i.e. tetrakis (dimethylamino) zirconium or HfCl, in two trenches on the upper surface of the substrate using an atomic layer deposition process4Or TEMAHf or TEMAZr or other ferroelectric elements as precursor source, H2O or O3As precursor oxygen source, with N2As a purge gas, reacting and depositing at the temperature of 250-500 ℃ to form a ferroelectric layer with the thickness of 3-11 nm;
6) etching and removing the ferroelectric layer outside the groove by using an etching process to respectively form a drain electrode polarization gate and a source electrode polarization gate;
7) growing metal on the upper surfaces of the polarization gate and the control gate by using a reactive sputtering process to form a polarization gate electrode layer;
8) etching the polarized gate electrode layer and SiO at the edge of the substrate2Etching away the layer and the channel layer to form an isolation insulating medium layer;
9) performing metal sputtering on the surface of the etched sample by using a reactive sputtering process to form a contact electrode layer;
10) etching the contact electrode layer above the polarized gate electrode layer by using an etching process, and etching the gate electrode layer metal above the contact of the polarized gate and the control gate insulating medium to form a control gate electrode;
11) and etching the metal above the isolation insulated gate dielectric by using an etching process to form a source electrode, a drain electrode polarized electrode, a source electrode polarized electrode and a drain electrode in sequence from left to right, thereby finishing the manufacture of the whole device.
Compared with the prior art, the invention has the following advantages:
firstly, the invention can complete the doping of the target region by changing the materials of the drain electrode polarization gate and the source electrode polarization gate and applying pulses to the polarization gates, compared with the traditional electrostatic doping tunneling field effect transistor, avoids the need of applying continuous and stable voltage in the doping process, can inhibit the carrier concentration fluctuation of the source and drain regions, improves the working stability of the device, reduces the energy consumption required by the doping, and prolongs the working life of the device.
Secondly, the doping concentration of the source and drain regions is accurately controlled through pulses, the carrier concentration gradient of the source and drain regions and the channel region is increased, the control capability of a control grid on a channel can be further enhanced, the on-off current ratio is increased, the power consumption and the sub-threshold swing amplitude of the device during working are reduced, and the performance of the device is improved.
Drawings
FIG. 1 is a diagram of a conventional ESD-doped tunneling field effect transistor;
FIG. 2 is a block diagram of a ferroelectric doped tunneling field effect transistor based on the present invention;
fig. 3 is a schematic flow chart of the implementation of the method for manufacturing the tunneling field effect transistor based on ferroelectric doping.
Detailed description of the invention
Referring to fig. 2, a ferroelectric doped based tunneling field effect transistor comprising from bottom to top: the substrate 1, the oxide layer 2 and the channel layer 3 are respectively a drain electrode 11 and a source electrode 12 which are positioned at two sides of the channel layer, a source electrode polarization grid 6, a control insulation medium grid 4 and a drain electrode polarization grid 5 are sequentially arranged above the channel layer, isolation insulation media 7 are arranged at two sides of the source electrode polarization grid 6 and the drain electrode polarization grid 5,and a source polarization electrode 8 is arranged above the source polarization gate 6, a control gate electrode 9 is arranged above the control insulating dielectric gate 4, and a drain polarization electrode 10 is arranged above the drain polarization gate 5. Wherein, the substrate layer 1 adopts any one of Si, Ge, SiC, GaN, sapphire and diamond; the oxide layer 2 is made of SiO2BPSG, borosilicate glass; the channel layer 3 is made of any one of Si, Ge, SiGe, GaN and GaO semiconductor materials, and the thickness of the channel layer is 5 nm-10 nm; the control insulated gate dielectric layer adopts SiO2、Si3N4、Ta2O5、TiO2One of them, the thickness range is 2-5 nm; the source electrode polarization grid 6 and the drain electrode polarization grid 5 both adopt a ferroelectric material with polarization properties, and the ferroelectric material with polarization properties comprises HZO and Al2O3、HfO2、ZrO2、BaTiO3、Cd2Nb2O7、BiFeO3、SBT、ZnSnO3PVDF (polyvinylidene fluoride), the thickness of which is 3-11nm, wherein asymmetric electric dipoles contained in unit cells of the material are directionally inverted under the action of an external electric field, and the material can keep the directional inversion characteristic after the electric field is removed, the characteristic can generate quantitative polarization charges on the surface of the material, namely, before the polarization degree of the material reaches the saturation polarization strength, the density of the surface polarization charges is in direct proportion to the applied voltage, so that pulse excitation with different amplitudes is applied to a source electrode polarization gate 6 and a drain electrode polarization gate 5, the doping concentration of a channel layer 3 can be accurately controlled, the change of the carrier concentration gradient of a doping region and a control gate channel region is increased, and the diffusion of carriers of the source electrode doping region and the drain electrode doping region to a channel is inhibited; the drain electrode 11, the source electrode 12, the source polarization electrode 8, the control gate electrode 9 and the drain polarization electrode 10 are made of any one of metal tungsten, metal titanium, metal copper, metal aluminum, metal platinum, metal iridium, metal ruthenium, tungsten nitride, titanium nitride, tantalum nitride, iridium oxide, ruthenium oxide, tungsten carbide, titanium carbide, tungsten silicide, titanium silicide and tantalum silicide.
When the device works, a negative pulse is applied to the source polarized gate electrode 8, a positive polarized pulse is applied to the drain polarized gate electrode 10, a channel layer below the source polarized gate 6 is doped with high-concentration holes, and a high-concentration electron is doped below the drain polarized gate 5, so that the function of a tunneling field effect transistor is realized.
Referring to fig. 3, the present invention presents three embodiments of fabricating a field effect tunneling transistor based on ferroelectric doping:
example 1: making Hf-based on Si substrate0.5Zr0.5O2A ferroelectric material doped silicon channel tunneling field effect transistor.
Step 1: the substrate is selected and the trench etched.
Si is selected as the substrate 1 and SiO in sequence2As an SOI substrate consisting of the insulating oxide layer 2 and Si as the channel layer 3, and etching the channel layer to 7nm using an etching process, as shown in fig. 3 (a).
Step 2: and depositing a control insulated gate dielectric layer.
Placing the etched SOI substrate into a reaction cavity, utilizing a chemical vapor deposition process, firstly extracting vacuum for 5-15 minutes in the reaction cavity, and then simultaneously introducing Si3H4And N2Taking O as a silicon source and an oxygen source, taking 75 ℃ as reaction temperature, and forming SiO with the thickness of 8nm on the surface of the SOI by inductive coupling growth2As a control insulated gate dielectric layer, fig. 3(b) is shown.
And step 3: and etching the grooves on two sides of the control polarization dielectric gate.
By etching process, SiO on the left and right sides of the symmetry axis of the SOI substrate2Two identical trenches 8nm wide are etched in the layer to form the control insulated dielectric gate 4, as shown in fig. 3 (c).
And 4, step 4: a polarized ferroelectric layer is deposited.
By utilizing an atomic layer deposition process, TEMAHf is taken as a precursor hafnium source, TEMAZr is taken as a precursor zirconium source, and O is3As a precursor oxygen source, with N2Forming an HZO ferroelectric layer with a thickness of 8nm on the trench at a reaction temperature of 260 ℃ as a purge gas, and annealing the SOI substrate at an annealing temperature of 500 DEGThe wafer is annealed for 30min to form polarization gates, and a source polarization gate 6 and a drain polarization gate 5 are formed from left to right, respectively, as shown in fig. 3 (d).
And 5: a layer of a gated electrode metal is deposited.
By using a reactive sputtering process, firstly, a molecular pump and a cold pump are used for vacuumizing a reaction cavity until the vacuum pressure is 8E-6Torr, and then, under the conditions of 350W of power and 5mTorr of Ar pressure, Al is used as a target material for sputtering the surface of the HZO polarization grid to form an Al polarization electrode layer, as shown in figure 3 (E).
Step 6: and etching the source drain metal electrode groove.
Polarizing gate electrode Al layer, SiO at the edge of the substrate2The layer and the Si channel layer are etched away to form the isolation insulating dielectric 7 and the source drain electrode metal trenches, as shown in fig. 3 (f).
And 7: and depositing a contact electrode metal layer.
By using a reactive sputtering process, firstly, a molecular pump and a cold pump are used for vacuumizing a reaction cavity until the vacuum pressure is 8E-6Torr, and then Cu is used as a target material for sputtering the surface of a sample under the conditions of 350W of power and 5mTorr of Ar pressure to form a Cu electrode as a contact electrode layer, as shown in figure 3 (g).
And 8: and etching to form a source/drain electrode, a source/drain polarized gate electrode and a control gate electrode.
8.1) etching away the contact electrode layer above the gated electrode layer;
8.2) etching the metal of the Al gate electrode layer above the contact of the polarization gate and the control gate insulating medium to form a control gate electrode 10;
8.3) SiO2The gate electrode metal above the isolated insulated gate dielectric is etched away to form the source 12, drain polarized electrode 8, source polarized electrode 9 and drain 11 from left to right as shown in fig. 3(h), completing the device fabrication.
Example 2: manufacturing method based on HfO on SiC substrate2The ferroelectric material is doped with a SiGe channel tunneling field effect transistor.
The method comprises the following steps: the substrate is selected and the trench etched.
A SiGeOI substrate consisting of SiC as the substrate 1, BPSG as the insulating oxide layer 2, and SiGe as the channel layer 3 in this order was selected, and the channel layer was etched to 9nm using an etching process, as shown in fig. 3 (a).
Step two: and depositing a control insulated gate dielectric layer.
Placing the etched SiGeOI substrate into a reaction cavity, utilizing a chemical vapor deposition process, firstly pumping vacuum for 5-15 minutes into the reaction cavity, and then simultaneously introducing Si3H4And N2And O is used as a silicon source and an oxygen source, 75 ℃ is used as a reaction temperature, and SiO2 with the thickness of 10nm is formed on the surface of the SiGeOI in an inductively coupled growth mode and is used as a control insulated gate dielectric layer, as shown in figure 3 (b).
Step three: and etching the grooves on two sides of the control polarization dielectric gate.
By etching process, SiO on the left and right sides of the symmetry axis of the SiGeOI substrate2Two identical trenches 11nm wide are etched in the layer to form the control insulated dielectric gate 4, as shown in figure 3 (c).
Step four: a polarized ferroelectric layer is deposited.
Using an atomic layer deposition process with HfCl4H2O as precursor oxygen source and N as precursor hafnium source2As a purge gas, 300 ℃ is used as a reaction temperature to deposit and form HfO with the thickness of 10nm on the surface of the SiGeOI2The ferroelectric layer is used as a polarization gate, and a source polarization gate 6 and a drain polarization gate 5 are formed from left to right, respectively, as shown in fig. 3 (d).
Step five: a layer of a gated electrode metal is deposited.
By using a reactive sputtering process, firstly, a molecular pump and a cold pump are used for vacuumizing a reaction cavity until the vacuum pressure is 8E-6Torr, and then W is used as a target material to sputter the surface of the HZO polarization grid under the conditions that the power is 350W and the Ar pressure is 5mTorr, so as to form a W polarization electrode layer, as shown in figure 3 (E).
Step six: and etching the source drain metal electrode groove.
The polarized gate electrode W layer, BPSG layer and Si channel layer at the edge of the substrate are etched away to form the isolation insulating dielectric 7 and the source drain electrode metal trench as shown in fig. 3 (f).
Step seven: and depositing a contact electrode metal layer.
7.1) utilizing a reactive sputtering process, firstly, vacuumizing a reaction cavity by using a molecular pump and a cold pump until the vacuum pressure is 8E-6Torr,
7.2) the sample surface was sputtered with Au as a target at a power of 350W and an Ar pressure of 5mTorr to form an Au electrode as a contact electrode, as shown in FIG. 2 (g).
Step eight: and etching to form a source/drain electrode, a source/drain polarized gate electrode and a control gate electrode.
The specific implementation of this step is the same as step 6 of example 1.
Example 3: production of ZrO-based on Ge substrate2Ferroelectric material Ge-doped channel tunneling field effect transistor
Step A: the substrate is selected and the trench etched.
A GOI substrate consisting of Ge as a substrate 1, borosilicate glass as an insulating oxide layer 2, and Ge as a channel layer 3 in this order was selected, and the channel layer was etched to 8nm using an etching process, as shown in fig. 3 (a).
And B: and depositing a control insulated gate dielectric layer.
Placing the etched GOI substrate into a reaction cavity, firstly extracting vacuum for 10 minutes from the reaction cavity by using a chemical vapor deposition process, and then simultaneously introducing Si3H4And N2Taking O as a silicon source and an oxygen source, taking 75 ℃ as a reaction temperature, and forming SiO with the thickness of 7nm on the surface of GOI by inductive coupling growth2As a control insulated gate dielectric layer, fig. 3(b) is shown.
And C: and etching the grooves on two sides of the control polarization dielectric gate.
By utilizing etching process, SiO on the left side and the right side of the symmetry axis of the GOI substrate2Two identical trenches 10nm wide are etched in the layer to form the control insulated dielectric gate 4, as shown in fig. 3 (c).
Step D: a polarized ferroelectric layer is deposited.
With tetrakis (dimethylamino) zirconium as the precursor zirconium source, H2O or O3As a precursor oxygen source, with N2As a purging gas, with 250 ℃ as a reaction temperature, depositing a 7nm thick ZrO2 ferroelectric layer on the surface of the GOI to be used as a polarization grid, respectively forming a source polarization grid 6 and a drain polarization grid 5 from left to right,as shown in fig. 3 (d).
Step E: a layer of a gated electrode metal is deposited.
By using a reactive sputtering process, firstly, a molecular pump and a cold pump are used for vacuumizing a reaction cavity until the vacuum pressure is 8E-6Torr, and then Ta is used as a target material for sputtering the surface of the ZrO2 polarization grid under the conditions of 350W power and 5mTorr Ar pressure to form a TaN polarization electrode layer, as shown in figure 3 (E).
Step F: and etching the source drain metal electrode groove.
The polarized gate electrode TaN layer, borosilicate glass layer and Si channel layer at the edge of the substrate are etched away to form an isolation insulating medium 7 and a source drain electrode metal trench, as shown in fig. 3 (f).
Step G: and depositing a contact electrode metal layer.
G1) By utilizing a reactive sputtering process, firstly, a molecular pump and a cold pump are used for vacuumizing a reaction cavity until the vacuum pressure is 8E-6Torr,
G2) the sample surface was sputtered using Cu as a target at a power of 350W and an Ar pressure of 5mTorr to form a Cu electrode as a contact electrode, as shown in fig. 3 (g).
Step H: and etching to form a source/drain electrode, a source/drain polarized gate electrode and a control gate electrode.
The specific implementation of this step is the same as step 6 of example 1, and device fabrication is completed
The above description is only three preferred embodiments of the present invention and should not be construed as limiting the invention in any way. It will be apparent to those skilled in the art that several modifications and finishes can be made without departing from the principles of the invention, for example, substrates including sapphire substrate materials in addition to Si, Ge and SiC are given in this example; the channel comprises GaN, GaAs and two-dimensional channel materials besides the Si, Ge and SiGe provided by the embodiment; the polarization grid is made of HZO and HfO as shown in the present example2And ZrO2Ferroelectric material, further comprising Al2O3、BaTiO3、Cd2Nb2O7、BiFeO3、SBT、PZT、ZnSnO3And a PVDF ferroelectric material; device process structure except for this embodimentGiven the planar processes, including the use of ferroelectric tunneling field effect transistors in the Nanowire, nanoshiet and FinFET type structures, these improvements and refinements should also be considered within the scope of the present invention.

Claims (9)

1. A ferroelectric doping based tunneling field effect transistor comprising from bottom to top: substrate (1), oxide layer (2) and channel layer (3), drain electrode (11) and source electrode (12) are respectively to this channel layer both sides, this nanometer channel layer top is source polarization bars (6), control insulating medium bars (4), drain electrode polarization bars (5) in proper order, source polarization bars (6) and drain electrode polarization bars (5) both sides are for keeping apart insulating medium (7), be source polarization electrode (8) above source polarization bars (6), control gate electrode (9) are above control medium bars (4), drain electrode polarization electrodes (10) are above drain electrode polarization bars (5), its characterized in that:
the thickness of the channel layer (3) is 5 nm-10 nm;
the source electrode polarization grid (6) and the drain electrode polarization grid (5) adopt any ferroelectric material with polarization property to realize the control of doping concentration of the channel layer with nanometer size under the excitation of pulses with different amplitudes, increase the change of the concentration gradient of carriers in the doping area and the channel area of the control grid and inhibit the diffusion of the carriers in the source electrode doping area to the channel.
2. The tunneling field effect transistor according to claim 1, wherein the ferroelectric material with polarization properties comprises HZO, Al2O3、HfO2、ZrO2、BaTiO3、Cd2Nb2O7、BiFeO3、SBT、PZT、ZnSnO3And PVDF.
3. A tunneling field-effect transistor according to claim 1, characterized in that the channel (3) is made of any one of Si, Ge, SiGe, GaN, GaAs, and two-dimensional material.
4. The tunneling field effect transistor according to claim 1, wherein the thickness of the drain polarization gate and the source polarization gate ranges from 1nm to 40nm, the distance between the source polarization gate electrode (8) and the control gate electrode (9) ranges from 0nm to 5nm, and the distance between the drain polarization gate electrode (10) and the control gate electrode (9) ranges from 0nm to 8 nm.
5. A tunneling field-effect transistor according to claim 1, characterized in that said substrate (1) is made of any of Si, Ge, SiC, sapphire material.
6. The tunneling field effect transistor (tffet) according to claim 1, wherein the oxidation (2) is SiO2Any one of borosilicate glass and BPSG.
7. A preparation method of a tunneling field effect transistor based on ferroelectric doping is characterized by comprising the following steps:
1) selecting a substrate consisting of a substrate (1), an insulating oxide layer (2) and a channel layer (3) in sequence;
2) etching the thickness of the channel layer to 5 nm-10 nm by using an etching process;
3) growing a SiO2 dielectric layer with the thickness of 2-5 nm on the upper surface of the nano channel layer (3) of the SOI substrate by utilizing a chemical vapor deposition process;
4) by etching process, SiO on the left and right sides of the symmetry axis of the substrate2Etching two same grooves with the width of 5-15 nm on the layer to form a control insulated dielectric gate (4);
5) depositing a ferroelectric material, i.e. tetrakis (dimethylamino) zirconium or HfCl, in two trenches on the upper surface of the substrate using an atomic layer deposition process4Or ferroelectric elements such as TEMAHf or TEMAZr as precursor source, H2O or O3As precursor oxygen source, with N2As a purge gas, reacting and depositing at the temperature of 250-500 ℃ to form a ferroelectric layer with the thickness of 3-11 nm;
6) etching and removing the ferroelectric layer outside the groove by using an etching process to respectively form a source electrode polarization gate (6) and a drain electrode polarization gate (5);
7) growing metal on the upper surfaces of the polarization gate and the control gate by using a reactive sputtering process to form a polarization gate electrode layer;
8) etching the polarized gate electrode layer and SiO at the edge of the substrate2Etching away the layer and the nano-channel layer to form an isolation insulating dielectric layer (7);
9) performing metal sputtering on the surface of the etched sample by using a reactive sputtering process to form a contact electrode layer;
10) etching the contact electrode layer above the polarized gate electrode layer by using an etching process, and etching the gate electrode layer metal above the contact of the polarized gate and the control gate insulating medium to form a control gate electrode (9);
11) and etching the metal above the isolation insulated gate dielectric (7) by using an etching process to form a source electrode (12), a source electrode polarization electrode (8), a drain electrode polarization electrode (10) and a drain electrode (11) from left to right in sequence, thereby completing the manufacture of the whole device.
8. The method as claimed in claim 7, wherein the chemical vapor deposition process in 2) is an inductively coupled growth process, wherein the reaction chamber is evacuated for 5-15 min and then Si is introduced simultaneously3H4And N2And taking O as a silicon source and an oxygen source, and reacting at the temperature of 50-100 ℃ to grow SiO 2.
9. The method of claim 7, wherein the reactive sputtering process in 6) and 8) is performed by first using a molecular pump and a cold pump to evacuate the reaction chamber until the vacuum pressure is 8E-6 Torr; then, sputtering is carried out on any one of the materials of tungsten, titanium, copper, aluminum and platinum under the conditions that the power is 350W and the Ar pressure is 5mTorr, so as to form the metal electrode.
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