CN113178598A - Auxiliary start-stop device and start-stop method for oxyhydrogen fuel cell activation test - Google Patents

Auxiliary start-stop device and start-stop method for oxyhydrogen fuel cell activation test Download PDF

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Publication number
CN113178598A
CN113178598A CN202110386531.9A CN202110386531A CN113178598A CN 113178598 A CN113178598 A CN 113178598A CN 202110386531 A CN202110386531 A CN 202110386531A CN 113178598 A CN113178598 A CN 113178598A
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fuel cell
cell stack
gas
auxiliary
cathode
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CN113178598B (en
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花仕洋
吴昊
叶东浩
李柯
张海波
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Wuhan Institute of Marine Electric Propulsion China Shipbuilding Industry Corp No 712 Institute CSIC
Wuhan Hydrogen Energy and Fuel Cell Industry Technology Research Institute Co Ltd
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Wuhan Institute of Marine Electric Propulsion China Shipbuilding Industry Corp No 712 Institute CSIC
Wuhan Hydrogen Energy and Fuel Cell Industry Technology Research Institute Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/043Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • H01M8/04302Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during start-up
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/043Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • H01M8/04303Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during shut-down
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The invention relates to an auxiliary start-stop device for an oxyhydrogen fuel cell activation test, which comprises two groups of auxiliary pipelines, wherein each group of auxiliary pipelines comprises a main pipeline and a branch pipeline which are arranged in parallel, the main pipeline comprises a main pipeline which is provided with a vacuum pump and a first one-way valve in series, the branch pipelines comprise branch pipelines which are provided with second one-way valves, the flowing directions of the first one-way valves and the second one-way valves are consistent, and the air inlet ends in the flowing directions of the two groups of auxiliary pipelines are respectively used for being connected to a cathode outlet and an anode outlet of a fuel cell stack; meanwhile, the use amount of reaction gas is greatly reduced, and the test cost is reduced; the invention reduces the damage risk of the high potential to the electrode of the pile after long-time residence, and simultaneously provides a start-stop method for the activation test of the hydrogen-oxygen fuel cell.

Description

Auxiliary start-stop device and start-stop method for oxyhydrogen fuel cell activation test
Technical Field
The invention relates to the technical field of proton exchange membrane fuel cells, in particular to an auxiliary start-stop device and a start-stop method for an activation test of an oxyhydrogen fuel cell.
Background
Proton exchange membrane fuel cells have been widely used in the fields of transportation vehicles, buses, ships, underwater vehicles, spacecraft, and the like. Compared with other electric energy source type technologies, the proton exchange membrane fuel cell has many advantages, including short start-up time, small system volume, low pollutant discharge, relatively high system efficiency, low noise level, etc., and is an important potential new energy development direction in the 21 st century.
With the large scale application of proton exchange membrane fuel cells in the market, more and more fuel cell stacks are produced by manufacturers. Generally speaking, each newly assembled fuel cell stack needs to be subjected to an activation test process to ensure that the stack can fully exert performance while checking the normal use of the stack, so that a stack manufacturer is required to have enough stack test equipment. For a vehicle fuel cell, some conditions, such as start-stop conditions, are inevitably experienced during the stack activation test. Under the start-stop working condition, the oxidation of the catalyst carrier carbon material is considered to be an important factor causing the performance degradation of the battery, the root cause is that the cathode forms high potential due to the existence of an anode hydrogen/oxygen interface in the starting and stopping processes, and the frequent start-stop of the electric pile testing process increases the time of high potential. Particularly, in the traditional activation testing process, in order to ensure that the anode cavity of the galvanic pile is fully filled with hydrogen, a long-time hydrogen replacement purging process is carried out in the starting stage; on the other hand, in order to ensure that the cell stack discharges the oxidizing agent and the reducing agent inside after shutdown to reduce the voltage of the cell sheet, the shutdown phase needs a long-time inert gas purging process. This operation therefore wastes a large amount of test gas, while increasing the residence time of the cell at high potential, which is neither economical nor detrimental to the durability of the cell.
Disclosure of Invention
In view of this, it is necessary to provide an auxiliary start-stop device for an oxyhydrogen fuel cell activation test, so as to solve the technical problems in the prior art that the test gas is seriously wasted and the durability of the cell is damaged under the start-stop working condition during the stack activation test.
The invention provides an auxiliary start-stop device for an oxyhydrogen fuel cell activation test, which comprises two groups of auxiliary pipelines, wherein each group of auxiliary pipelines comprises a main pipeline and a branch pipeline which are arranged in parallel, the main pipeline comprises a main pipeline which is provided with a vacuum pump and a first one-way valve in series, the branch pipeline comprises a branch pipeline which is provided with a second one-way valve, the flow directions of the first one-way valve and the second one-way valve are consistent, and the air inlet ends of the two groups of auxiliary pipelines in the flow direction are respectively used for being connected to a cathode outlet and an anode outlet of a fuel cell stack.
Furthermore, a pressure sensor is installed at the air inlet end of each auxiliary pipeline.
The gas inlet and outlet of each auxiliary pipeline in the circulation direction are respectively connected with the corresponding gas inlet and gas outlet.
The touch screen is characterized by further comprising a touch screen, a power supply and a control system, wherein the power supply is electrically connected with the control system, the control system is respectively electrically connected with the first one-way valve, the second one-way valve, the touch screen, the two vacuum pumps and the two pressure sensors, the control system monitors the pressure difference between two sides according to the pressure sensors and controls the two vacuum pumps to be opened or closed according to the pressure difference, and the touch screen controls the first one-way valve and the second one-way valve to be opened or closed through the control system.
The invention also provides a start-stop method for the activation test of the hydrogen-oxygen fuel cell, which comprises the following steps:
s1, connecting the fuel cell stack and the auxiliary start-stop device as claimed in any one of claims 1 to 4 to an activation test line, wherein the air inlet ends of the two groups of auxiliary pipelines in the flowing direction are respectively used for being connected to the cathode outlet and the anode outlet of the fuel cell stack, so that good air tightness is ensured;
s2, opening the first one-way valve and closing the second one-way valve, and replacing the gas in the fuel cell when the first one-way valve is opened;
s3, opening the second one-way valve and closing the first one-way valve, and connecting a load for an activation test;
s4, disconnecting the load after the activation test is finished;
s5, opening the first one-way valve and closing the second one-way valve, and replacing the gas in the fuel cell during closing;
wherein the on-time fuel cell internal gas replacement comprises:
s21, purging the fuel cell stack by adopting inert gas;
s22, vacuumizing the fuel cell stack through a main pipeline;
s23, introducing reaction gas into the fuel cell stack to break vacuum of the fuel cell stack;
the fuel cell internal gas replacement at shutdown includes:
s51, vacuumizing the fuel cell stack through a main pipeline;
and S52, purging inert gas into the fuel cell stack.
Further, in the step S21, purging the fuel cell stack with the inert gas is specifically performed by purging the inert gas into the cathode chamber and the anode chamber through the cathode inlet and the anode inlet of the fuel cell stack, respectively, where the purging time is not less than 1 min.
Further, in step S22, the step of evacuating the fuel cell stack specifically includes evacuating a cathode chamber and an anode chamber through a cathode outlet and an anode outlet of the fuel cell stack, respectively, and during the evacuation, a pressure difference between the cathode outlet and the anode outlet does not exceed 20 kPa.
Further, in the step S23, the step of introducing the reactant gas into the fuel cell stack is to introduce oxygen and hydrogen into the cathode chamber and the anode chamber through the cathode inlet and the anode inlet of the fuel cell stack, respectively, and maintain the pressure of the cathode chamber and the pressure of the anode chamber at 0 to 30 kPa.
Further, step S51 is to evacuate the fuel cell stack, specifically to evacuate the cathode chamber and the anode chamber through the cathode outlet and the anode outlet of the fuel cell stack, respectively, and during evacuation, a pressure difference between the cathode outlet and the anode outlet does not exceed 20 kPa.
Further, the step S52 purging the inert gas to the inside of the fuel cell stack specifically includes respectively introducing the inert gas to the cathode chamber and the anode chamber through the cathode inlet and the anode inlet of the fuel cell stack, and maintaining the pressure of the cathode chamber and the pressure of the anode chamber at 0-30 kPa.
The start-stop method for the activation test of the hydrogen-oxygen fuel cell can greatly shorten the time of a start-up stage and a stop stage, and improve the test efficiency and the utilization rate of equipment; meanwhile, the use amount of reaction gas is greatly reduced, and the test cost is reduced; the invention also provides an auxiliary start-stop device for the activation test of the oxyhydrogen fuel cell, which can assist in implementing the method.
The foregoing is only an overview of the technical solutions of the present invention, and in order to make the technical means of the present invention more clearly understood and to be implemented in accordance with the content of the description, the following is a detailed description of preferred embodiments of the present invention.
Drawings
FIG. 1 is a schematic diagram of an internal structure of an auxiliary start-stop device for an oxyhydrogen fuel cell activation test according to an embodiment of the present invention;
FIG. 2 is a schematic external structural diagram according to a first embodiment of the present invention;
fig. 3 is a schematic diagram of a connection relationship in use according to an embodiment of the present invention.
Detailed Description
The preferred embodiments of the present invention will now be described in detail with reference to the accompanying drawings, which form a part hereof, and which together with the embodiments of the invention serve to explain the principles of the invention and not to limit its scope.
Example one
As shown in fig. 1 and fig. 2, the present embodiment provides an auxiliary start/stop device for an oxyhydrogen fuel cell activation test, including two sets of auxiliary pipelines 1, each set of auxiliary pipeline 1 includes a main pipeline 11 and a branch pipeline 12 that are arranged in parallel, the main pipeline 11 includes a main pipeline 113 that is provided with a vacuum pump 111 and a first check valve 112 in series, the branch pipeline 12 includes a branch pipeline 121 that is provided with a second check valve 122, the flow directions of the first check valve 112 and the second check valve 122 are the same, and the air inlet ends in the flow direction of the two sets of auxiliary pipelines 1 are respectively used for being connected to the cathode outlet and the anode outlet of the fuel cell stack 20.
When the auxiliary starting and stopping are carried out, the two second one-way valves 122 on the two auxiliary pipelines 1 are closed, the first one-way valve 112 is opened, the two vacuum pumps 111 are started, the fuel cell stack 20 can be effectively vacuumized, and the pumped gas flows out from the main pipeline 113; when the activation test is performed, the first check valve 112 is closed, the second check valve 122 is opened, and the excess reaction gas passing through the cathode outlet and the anode outlet of the fuel cell stack 20 flows out from the branch pipe 121.
To facilitate the detection of the air pressure on the corresponding pipe, a pressure sensor 13 is installed at the air inlet end of each auxiliary pipe 1.
In the preferred embodiment of the present application, the auxiliary start/stop device further includes a box body 2, two gas inlets 21 are arranged in parallel on one side of the box body 2, gas outlets 22 corresponding to the two gas inlets 21 are arranged in parallel on the other side of the box body, two sets of auxiliary pipelines 1 are arranged in parallel inside the box body 2, and a gas inlet end and a gas outlet end in the circulation direction of each auxiliary pipeline 1 are respectively connected to the corresponding gas inlet 21 and gas outlet 22.
In order to control the auxiliary start-stop device conveniently, the embodiment further includes a touch screen 3, a power supply 4 and a control system 5, the power supply 4 is electrically connected with the control system 5, the control system 5 is electrically connected with the first one-way valve 112, the second one-way valve 122, the touch screen 3, the two vacuum pumps 111 and the two pressure sensors 13 respectively, the control system 5 monitors the pressure difference between two sides according to the pressure sensors 13, and controls the opening or closing of the two vacuum pumps 111 according to the pressure difference, and the touch screen 3 controls the opening or closing of the first one-way valve 112 and the second one-way valve 122 through the control system 5.
The use of this embodiment is described in conjunction with the description of figure 3,
firstly, the fuel cell stack 20 and the auxiliary start-stop device are connected according to the diagram shown in fig. 3, so that good air tightness and no air leakage are ensured; then, performing a gas replacement process in the fuel cell during one-time opening, namely opening a nitrogen valve N, and performing nitrogen purging on a cathode chamber and an anode chamber of the fuel cell stack 20 for 1 min; then closing the two second one-way valves 122 on the two auxiliary pipelines 1, opening the first one-way valve 112, starting the two vacuum pumps 111, vacuumizing the cathode chamber and the anode chamber of the fuel cell stack 20, simultaneously ensuring that the pressure difference between the positive side and the negative side is controlled within 20kPa, and stopping vacuumizing when the vacuum degree reaches-90 kPa; respectively inching and opening a hydrogen inlet valve H and an oxygen inlet valve O to break the vacuum state of the cathode chamber and the anode chamber, keeping the pressure of 0-30kpa (gauge pressure), and closing the hydrogen inlet valve H and the oxygen inlet valve O; the fuel cell internal gas displacement process is then performed for a second time of opening, then the first check valve 112 is closed, the second check valve 122 is opened, at which point the load may be connected for activation testing, and after activation testing is completed, the load is disconnected.
Then, the second one-way valve 122 is closed, the first one-way valve 112 is opened, and the gas replacement process inside the fuel cell during one-time closing is carried out; starting two vacuum pumps 111, vacuumizing a cathode chamber and an anode chamber of the fuel cell stack 20, simultaneously ensuring that the pressure difference between the anode side and the cathode side is controlled within 20kPa, and stopping vacuumizing when reaching a vacuum degree of-90 kPa; then, the nitrogen valve N is opened in a inching mode to break the vacuum state of the cathode chamber and the anode chamber, the pressure is kept at 0-30kpa, and the nitrogen purging valve is closed; when the fuel cell is closed for the second time, the gas in the fuel cell is replaced, at the moment, the voltage of the single cell of the electric pile can be quickly changed from high potential to low potential, and the electric pile is filled with inert nitrogen to form a shutdown protection state and can be transferred into a warehouse for storage.
When the auxiliary start-stop device is used in the activation test of the fuel cell stack 20, the start-stop operation is realized in an auxiliary mode, the start-up stage time and the stop stage time can be greatly shortened, and the test efficiency and the equipment utilization rate are improved; meanwhile, the use amount of reaction gas is greatly reduced, and the test cost is reduced; reduces the risk of damage to the stack electrodes due to high-voltage long-time residence,
example two
The embodiment provides a start-stop method for an activation test of an oxyhydrogen fuel cell, which comprises the following steps:
s1, connecting the fuel cell stack and the auxiliary start/stop device as described in the first embodiment to an activation test line, where the air inlet ends of the two sets of auxiliary pipelines in the flowing direction are respectively used to connect to the cathode outlet and the anode outlet of the fuel cell stack, so as to ensure good air tightness;
s2, opening the first one-way valve and closing the second one-way valve, and replacing the gas in the fuel cell when the first one-way valve is opened;
s21, purging the fuel cell stack by adopting inert gas;
s22, vacuumizing the fuel cell stack through a main pipeline;
s23, introducing reaction gas into the fuel cell stack to break vacuum of the fuel cell stack;
wherein the fuel cell internal gas replacement at start-up comprises:
s21, purging the fuel cell stack by adopting inert gas; specifically, inert gas is respectively purged into a cathode cavity and an anode cavity through a cathode inlet and an anode inlet of the fuel cell stack, the purging time is not less than 1min, and in the embodiment of the application, the inert gas refers to nitrogen under the condition that no specific description is given.
S22, vacuumizing the fuel cell stack through a main pipeline; specifically, a cathode chamber and an anode chamber are respectively vacuumized through a cathode outlet and an anode outlet of the fuel cell stack, and the pressure difference between the cathode outlet and the anode outlet does not exceed 20kPa in the vacuumization process.
S23, introducing reaction gas into the fuel cell stack to break vacuum of the fuel cell stack; specifically, oxygen and hydrogen are respectively introduced into a cathode chamber and an anode chamber through a cathode inlet and an anode inlet of the fuel cell stack, and the pressure of the cathode chamber and the pressure of the anode chamber are maintained at 0-30 kPa.
It can be understood that, the content of the reaction gas inside the fuel cell stack can be effectively improved in the process of replacing the internal gas of the fuel cell during one-time opening, so that in the practical operation, a test person can independently select the number of times of replacing the internal gas of the fuel cell during opening according to the practical situation to ensure that the internal reaction gas of the fuel cell stack has sufficient purity, and in the embodiment of the application, the number of times of replacing the internal gas of the fuel cell during opening is two.
S3, opening the second one-way valve and closing the first one-way valve, and connecting a load for an activation test;
s4, disconnecting the load after the activation test is finished;
s5, opening the first one-way valve and closing the second one-way valve, and replacing the gas in the fuel cell during closing;
wherein the fuel cell internal gas replacement at shutdown comprises:
s51, vacuumizing the fuel cell stack through the main pipeline; specifically, a cathode chamber and an anode chamber are respectively vacuumized through a cathode outlet and an anode outlet of the fuel cell stack, and the pressure difference between the cathode outlet and the anode outlet does not exceed 20kPa in the vacuumization process.
S52, purging inert gas into the fuel cell stack, specifically, respectively introducing the inert gas into the cathode chamber and the anode chamber through the cathode inlet and the anode inlet of the fuel cell stack, and keeping the pressure of the cathode chamber and the pressure of the anode chamber at 0-30 kPa.
In some embodiments of the present application, since the vacuum degree standard during vacuum pumping varies from experiment to experiment, and since the vacuum pumping speed is fast at a lower vacuum degree, but as the vacuum degree becomes higher, the vacuum pumping time increases in a geometric level, in order to take into account the time cost and the vacuum degree standard, the vacuum degree standard during vacuum pumping is defined as-90 kPa, that is, when the vacuum degree of the cathode chamber or the anode chamber reaches-90 kPa, the vacuum pumping of the corresponding chamber is stopped.
Preferably, in the embodiment of the application, it should be ensured that the pressure difference between the cathode outlet and the anode outlet does not exceed 20kPa during the vacuum pumping process, so that the stability of the membrane electrode between the bipolar plates of the stack can be effectively protected, in the specific implementation, the pressure difference between the two sides is monitored in real time through a pressure sensor or a pressure gauge, and when the pressure difference is greater than 20kPa, the vacuum pump corresponding to the side with the higher vacuum degree is closed until the pressure difference between the two sides returns to within 20 kPa.
It can be understood that, the content of the reaction gas inside the fuel cell stack can be effectively reduced in the process of replacing the internal gas of the fuel cell during one-time shutdown, so that in the practical operation, a test person can autonomously select the number of times of replacing the internal gas of the fuel cell during shutdown according to the practical situation to ensure that the internal reaction gas of the fuel cell stack is sufficiently small, and in the embodiment of the application, the number of times of replacing the internal gas of the fuel cell during startup is two.
The method has the following action principle: the method comprises the steps of firstly purging a fuel cell by inert gas to enable a fuel cell stack to be filled with the inert gas, then vacuumizing to enable the pressure in the fuel cell stack to be reduced, then introducing reaction gas into the fuel cell stack, well replacing the gas in the fuel cell stack, improving the content of the reaction gas in the fuel cell stack, effectively reducing the problem of hydrogen waste caused by continuous introduction of the reaction gas, after an activation test is completed, replacing the reaction gas in the fuel cell stack by the inert gas in a mode of vacuumizing firstly and then breaking vacuum, enabling the voltage of a single cell of the stack to be rapidly changed from a high potential to a low potential, filling the inert nitrogen into the stack at the moment, and realizing a shutdown protection state. The testing efficiency and the utilization rate of equipment are improved; meanwhile, the use amount of reaction gas is greatly reduced, and the test cost is reduced; and the risk of damage to the pile electrode caused by long-time high potential residence is reduced.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that can be easily conceived by those skilled in the art within the technical scope of the present invention are also within the scope of the present invention.

Claims (10)

1. The utility model provides an supplementary device that stops that opens of oxyhydrogen fuel cell activation test, its characterized in that includes two sets of auxiliary line, every group the auxiliary line is including parallelly connected main line and the tributary pipeline that sets up, the main line is provided with the trunk line of vacuum pump and first check valve including establishing ties, the tributary pipeline is including the tributary pipeline of installing the second check valve, first check valve with the circulation direction of second check valve is unanimous, and the ascending inlet end in the circulation direction of two sets of auxiliary line is used for being connected to the cathode outlet and the positive pole export of fuel cell pile respectively.
2. The auxiliary start-stop device for the activation test of the hydrogen-oxygen fuel cell as claimed in claim 1, wherein a pressure sensor is installed at the air inlet end of each auxiliary pipeline.
3. The auxiliary start-stop device for the activation test of the hydrogen-oxygen fuel cell as claimed in claim 2, further comprising a box body, wherein two gas inlets are arranged in parallel on one side of the box body, gas outlets corresponding to the two gas inlets are arranged in parallel on the other side of the box body, two groups of auxiliary pipelines are arranged in parallel inside the box body, and a gas inlet end and a gas outlet end of each auxiliary pipeline in the flowing direction are respectively connected with the corresponding gas inlet and gas outlet.
4. The auxiliary start-stop device for the activation test of the hydrogen-oxygen fuel cell according to claim 3, further comprising a touch screen, a power supply and a control system, wherein the power supply is electrically connected with the control system, the control system is electrically connected with the first one-way valve, the second one-way valve, the touch screen, the two vacuum pumps and the two pressure sensors respectively, the control system monitors the pressure difference between two sides according to the pressure sensors and controls the two vacuum pumps to be opened or closed according to the pressure difference, and the touch screen controls the first one-way valve and the second one-way valve to be opened or closed through the control system.
5. A start-stop method for an oxyhydrogen fuel cell activation test is characterized by comprising the following steps:
s1, connecting the fuel cell stack and the auxiliary start-stop device as claimed in any one of claims 1 to 4 to an activation test line, wherein the air inlet ends of the two groups of auxiliary pipelines in the flowing direction are respectively used for being connected to the cathode outlet and the anode outlet of the fuel cell stack, so that good air tightness is ensured;
s2, opening the first one-way valve and closing the second one-way valve, and replacing the gas in the fuel cell when the first one-way valve is opened;
s3, opening the second one-way valve and closing the first one-way valve, and connecting a load for an activation test;
s4, disconnecting the load after the activation test is finished;
s5, opening the first one-way valve and closing the second one-way valve, and replacing the gas in the fuel cell during closing;
wherein the on-time fuel cell internal gas replacement comprises:
s21, purging the fuel cell stack by adopting inert gas;
s22, vacuumizing the fuel cell stack through a main pipeline;
s23, introducing reaction gas into the fuel cell stack to break vacuum of the fuel cell stack;
the fuel cell internal gas replacement at shutdown includes:
s51, vacuumizing the fuel cell stack through a main pipeline;
and S52, purging inert gas into the fuel cell stack.
6. The start-stop method for the activation test of the hydrogen-oxygen fuel cell according to claim 5, wherein in the step S21, inert gas is adopted to purge the fuel cell stack, specifically, inert gas is purged into the cathode chamber and the anode chamber through the cathode inlet and the anode inlet of the fuel cell stack respectively, and the purging time is not less than 1 min.
7. The start-stop method for the activation test of the hydrogen-oxygen fuel cell according to claim 5, wherein the step S22 of evacuating the fuel cell stack is to evacuate the cathode chamber and the anode chamber through the cathode outlet and the anode outlet of the fuel cell stack, respectively, and during the evacuation, the pressure difference between the cathode outlet and the anode outlet does not exceed 20 kPa.
8. The start-stop method for the activation test of the hydrogen-oxygen fuel cell according to claim 5, wherein in step S23, the step of introducing the reaction gas into the fuel cell stack is to introduce oxygen and hydrogen into the cathode chamber and the anode chamber through the cathode inlet and the anode inlet of the fuel cell stack, respectively, and to maintain the pressure of the cathode chamber and the anode chamber at 0 to 30 kPa.
9. The start-stop method for the activation test of the hydrogen-oxygen fuel cell according to claim 5, wherein the step S51 is to evacuate the fuel cell stack, specifically to evacuate the cathode chamber and the anode chamber through the cathode outlet and the anode outlet of the fuel cell stack, respectively, and during the evacuation, the pressure difference between the cathode outlet and the anode outlet does not exceed 20 kPa.
10. The start-stop method for the activation test of the hydrogen-oxygen fuel cell according to claim 5, wherein the step S52 is to purge the inert gas into the fuel cell stack, specifically to introduce the inert gas into the cathode chamber and the anode chamber through the cathode inlet and the anode inlet of the fuel cell stack, respectively, and to maintain the pressure of the cathode chamber and the anode chamber at 0 to 30 kPa.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113675441A (en) * 2021-08-09 2021-11-19 武汉船用电力推进装置研究所(中国船舶重工集团公司第七一二研究所) Purging protection device for fuel cell
CN113991147A (en) * 2021-10-27 2022-01-28 广东省武理工氢能产业技术研究院 Rapid activation system of proton exchange membrane fuel cell
CN116314950A (en) * 2023-04-21 2023-06-23 北京亿华通科技股份有限公司 Hydrogen fuel cell engine performance activation device and method

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005093115A (en) * 2003-09-12 2005-04-07 Matsushita Electric Ind Co Ltd Fuel cell power generating device and its operating method
CN201238067Y (en) * 2008-06-23 2009-05-13 汉能科技有限公司 Electric pile activation system of fuel cell
US20110250516A1 (en) * 2008-09-17 2011-10-13 Belenos Clean Power Holding Ag Method of shut-down and starting of a fuel cell
JP2012256611A (en) * 2006-03-10 2012-12-27 Sanyo Electric Co Ltd Activation method of fuel cell, and activation device for fuel cell
CN102891330A (en) * 2011-07-18 2013-01-23 现代自动车株式会社 Apparatus and method for activating fuel cell stack
CN103003093A (en) * 2010-07-28 2013-03-27 罗伯特·博世有限公司 Method and device for activating at least one energy management function in a vehicle
CN103259031A (en) * 2013-04-12 2013-08-21 武汉理工大学 Starting and shutdown control method for proton exchange membrane fuel cell
CN109616680A (en) * 2018-12-28 2019-04-12 中科军联(张家港)新能源科技有限公司 A kind of multichannel array type direct methanol fuel cell pile activation test platform
CN209249586U (en) * 2018-12-28 2019-08-13 中科军联(张家港)新能源科技有限公司 A kind of multichannel array type direct methanol fuel cell pile activation test platform
CN110718704A (en) * 2019-10-17 2020-01-21 江苏集萃安泰创明先进能源材料研究院有限公司 Metal hydride hydrogen storage bottle on-line activation hydrogen supply device matched with fuel cell system
CN110911716A (en) * 2019-11-25 2020-03-24 浙江锋源氢能科技有限公司 Constant-voltage activation method of fuel cell stack
CN111082108A (en) * 2019-12-30 2020-04-28 上海神力科技有限公司 Device and method for testing start-stop accelerated life of fuel cell
WO2020138338A1 (en) * 2018-12-26 2020-07-02 本田技研工業株式会社 Fuel cell activation method and apparatus
CN212693974U (en) * 2020-12-04 2021-03-12 上海韵量新能源科技有限公司 Device for evaluating fuel cell stack start-stop durability

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005093115A (en) * 2003-09-12 2005-04-07 Matsushita Electric Ind Co Ltd Fuel cell power generating device and its operating method
JP2012256611A (en) * 2006-03-10 2012-12-27 Sanyo Electric Co Ltd Activation method of fuel cell, and activation device for fuel cell
CN201238067Y (en) * 2008-06-23 2009-05-13 汉能科技有限公司 Electric pile activation system of fuel cell
US20110250516A1 (en) * 2008-09-17 2011-10-13 Belenos Clean Power Holding Ag Method of shut-down and starting of a fuel cell
CN103003093A (en) * 2010-07-28 2013-03-27 罗伯特·博世有限公司 Method and device for activating at least one energy management function in a vehicle
CN102891330A (en) * 2011-07-18 2013-01-23 现代自动车株式会社 Apparatus and method for activating fuel cell stack
CN103259031A (en) * 2013-04-12 2013-08-21 武汉理工大学 Starting and shutdown control method for proton exchange membrane fuel cell
WO2020138338A1 (en) * 2018-12-26 2020-07-02 本田技研工業株式会社 Fuel cell activation method and apparatus
CN109616680A (en) * 2018-12-28 2019-04-12 中科军联(张家港)新能源科技有限公司 A kind of multichannel array type direct methanol fuel cell pile activation test platform
CN209249586U (en) * 2018-12-28 2019-08-13 中科军联(张家港)新能源科技有限公司 A kind of multichannel array type direct methanol fuel cell pile activation test platform
CN110718704A (en) * 2019-10-17 2020-01-21 江苏集萃安泰创明先进能源材料研究院有限公司 Metal hydride hydrogen storage bottle on-line activation hydrogen supply device matched with fuel cell system
CN110911716A (en) * 2019-11-25 2020-03-24 浙江锋源氢能科技有限公司 Constant-voltage activation method of fuel cell stack
CN111082108A (en) * 2019-12-30 2020-04-28 上海神力科技有限公司 Device and method for testing start-stop accelerated life of fuel cell
CN212693974U (en) * 2020-12-04 2021-03-12 上海韵量新能源科技有限公司 Device for evaluating fuel cell stack start-stop durability

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113675441A (en) * 2021-08-09 2021-11-19 武汉船用电力推进装置研究所(中国船舶重工集团公司第七一二研究所) Purging protection device for fuel cell
CN113991147A (en) * 2021-10-27 2022-01-28 广东省武理工氢能产业技术研究院 Rapid activation system of proton exchange membrane fuel cell
CN113991147B (en) * 2021-10-27 2023-12-05 广东省武理工氢能产业技术研究院 Quick activation method for proton exchange membrane fuel cell
CN116314950A (en) * 2023-04-21 2023-06-23 北京亿华通科技股份有限公司 Hydrogen fuel cell engine performance activation device and method
CN116314950B (en) * 2023-04-21 2024-01-26 北京亿华通科技股份有限公司 Hydrogen fuel cell engine performance activation device and method

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