CN113149574B - High-temperature-resistant cement-based composite material and preparation method thereof - Google Patents
High-temperature-resistant cement-based composite material and preparation method thereof Download PDFInfo
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- CN113149574B CN113149574B CN202110618379.2A CN202110618379A CN113149574B CN 113149574 B CN113149574 B CN 113149574B CN 202110618379 A CN202110618379 A CN 202110618379A CN 113149574 B CN113149574 B CN 113149574B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
- C04B2201/52—High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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Abstract
The invention discloses a high-temperature-resistant cement-based composite material and a preparation method thereof, belonging to the technical field of building materials, wherein the composite material comprises the following raw materials: cement, quartz sand, flyash and nano SiO 2 Water, epoxy resin and curing agentGraphene oxide, a water reducing agent and polyvinyl alcohol fibers; the preparation method comprises the following steps: mixing and stirring epoxy resin and graphene oxide to obtain a mixture A; mixing nano SiO 2 Mixing and stirring a curing agent and polyvinyl alcohol fibers to obtain a mixture B; mixing cement, quartz sand and fly ash to obtain a mixture C; mixing and stirring the mixture A and the mixture B, adding the mixture C, stirring, then adding water and a water reducing agent, and stirring to obtain the cement-based composite material; the cement-based composite material disclosed by the invention has excellent compressive strength, splitting tensile strength and breaking strength, and can still keep better mechanical properties after high-temperature action.
Description
Technical Field
The invention belongs to the technical field of building materials, and particularly relates to a high-temperature-resistant cement-based composite material and a preparation method thereof.
Background
At present, cement-based materials mainly made of concrete play an important role in infrastructure construction, and are widely applied to houses and other large-scale projects. Compared with a wood structure, the cement-based composite material is a thermal inert material, can not burn like wood at a certain temperature, and has slow heat transfer and small mechanical strength loss after short-time action. However, after a long time of high temperature, various physical and chemical reactions occur in the cement-based material, which leads to a significant decrease in strength, damage to the internal structure and thus insufficient structural bearing capacity, and thus collapse of the building. Therefore, when a building is in fire, the cement-based material is easy to crack along with the high temperature generated by the fire, and the like, so that the structural bearing capacity of the building is lost. After a part of buildings are in fire, the appearance of the structure of the building is still complete in a short time, but the internal structure of the building is damaged due to the high temperature of the fire, the service life of the building is greatly shortened, and certain potential safety hazards exist in the using process. Therefore, the research on how to improve the high-temperature resistance of the cement-based material has important significance.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a high-temperature-resistant cement-based composite material and a preparation method thereof, so as to improve the mechanical property of the cement-based composite material under the action of high temperature.
In order to achieve the purpose, the invention provides the following technical scheme:
the invention provides a high-temperature-resistant cement-based composite material which comprises the following raw materials in parts by weight: 600-700 parts of cement, 400-450 parts of quartz sand, 300-350 parts of fly ash and nano SiO 2 7-10 parts of water, 350-400 parts of epoxy resin, 80-100 parts of curing agent, 30-40 parts of graphene oxide, 5-20 parts of water reducing agent and 5-10 parts of polyvinyl alcohol fiber.
Preferably, the raw materials comprise the following components in parts by weight: 650 parts of cement, 420 parts of quartz sand, 330 parts of fly ash and nano SiO 2 9 parts of water, 370 parts of epoxy resin, 35 parts of curing agent, 15 parts of graphene oxide, 10 parts of water reducing agent and 8 parts of polyvinyl alcohol fiber.
Preferably, the cement is P.O.42.5 cement.
Preferably, the epoxy resin is bisphenol a type epoxy resin; the curing agent is a normal-temperature curing agent.
Preferably, the tensile strength of the polyvinyl alcohol fiber is more than or equal to 1400MPa, and the elongation is more than or equal to 6.0%.
Preferably, the nano SiO 2 The average grain diameter is less than or equal to 35 nm.
The invention also provides a preparation method of the cement-based composite material, which comprises the following steps: mixing and stirring epoxy resin and graphene oxide to obtain a mixture A; mixing nano SiO 2 Mixing and stirring the curing agent and the polyvinyl alcohol fiber to obtain a mixture B; mixing cement, quartz sand and fly ash to obtain a mixtureC; and mixing and stirring the mixture A and the mixture B, adding the mixture C, stirring, then adding water and a water reducing agent, and stirring to obtain the cement-based composite material.
Compared with the prior art, the invention has the following beneficial effects:
according to the invention, the epoxy resin and the curing agent are added into the cement-based composite material, so that other raw materials are added into the network structure when the epoxy resin is cured to form the network structure in the preparation process, thereby obviously improving the compactness of the material and improving the mechanical property; simultaneously, nano SiO is added into the raw materials 2 And the polyvinyl alcohol fiber and the graphene oxide can generate new combination effect of the raw materials and reaction products thereof when the high-temperature effect is performed, so that the cement-based composite material can still keep better mechanical property after the high-temperature effect is performed.
Detailed Description
Reference will now be made in detail to various exemplary embodiments of the invention, the detailed description should not be construed as limiting the invention but as a more detailed description of certain aspects, features and embodiments of the invention. It is to be understood that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention.
Further, for numerical ranges in this disclosure, it is understood that each intervening value, between the upper and lower limit of that range, is also specifically disclosed. Every smaller range between any stated value or intervening value in a stated range and any other stated or intervening value in a stated range is encompassed within the invention. The upper and lower limits of these smaller ranges may independently be included or excluded in the range.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Although only preferred methods and materials are described herein, any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention. All documents mentioned in this specification are incorporated herein by reference to disclose and describe the methods and/or materials in connection with which the documents are cited. In case of conflict with any incorporated document, the present specification will control.
It will be apparent to those skilled in the art that various modifications and variations can be made in the specific embodiments of the present disclosure without departing from the scope or spirit of the disclosure. Other embodiments will be apparent to those skilled in the art from consideration of the specification. The description and examples are intended to be illustrative only.
As used herein, the terms "comprising," "including," "having," "containing," and the like are open-ended terms that mean including but not limited to.
In the following examples, the cement used was P.O.42.5 cement produced by Xinxiang Meng electro group of Henan province, the fly ash used was I-grade fly ash produced by Luoyang power plant, the water absorption range was 89-130%, the average water absorption was 106%, and the density range was 1.95-2.87 g/cm 3 Average density of 2.16g/cm 3 (ii) a The adopted quartz sand is an extra-fine quartz sand material produced by a Guyi Yuanheng water purification material factory, and the particle size range is as follows: 75-120 μm; the adopted PVA fiber is a high-strength and high-elastic modulus PVA fiber produced by Nippon Coli company, the tensile strength of the PVA fiber is 1560MPa, the Young modulus of the PVA fiber is 42GPa, and the elongation of the PVA fiber is 6.5 percent; the adopted nano SiO 2 Is loose white powdery nano SiO produced by Hangzhou Wanjing new material company Limited 2 The apparent density was 54g/L, the average particle diameter was 30nm, and the specific surface area was 200m 2 (ii)/g; the water reducing agent is a polycarboxylic acid high-efficiency water reducing agent which is produced by a Hongxiang building additive factory in Laiyang city, Shandong province, the water reducing rate is more than or equal to 23 percent, and the content of active ingredients is more than or equal to 90 percent; the graphene oxide is produced by Tangshan Jianhua technology development, LLC.
The description will not be repeated below.
Examples 1 to 3
The preparation of the cement-based composite material comprises the following steps:
(1) weighing the raw materials according to the raw material dosage in the table 1;
(2) mixing and uniformly stirring bisphenol A type E-51 epoxy resin and graphene oxide to obtain a mixture A;
(3) mixing nano SiO 2 Mixing and uniformly stirring an epoxy resin normal-temperature curing agent and polyvinyl alcohol fibers to obtain a mixture B, wherein the epoxy resin normal-temperature curing agent is triethylene tetramine;
(4) mixing and uniformly stirring cement, quartz sand and fly ash to obtain a mixture C;
(5) and (3) mixing the mixture A obtained in the step (2) and the mixture B obtained in the step (3) and uniformly stirring, then adding the mixture C obtained in the step (4), uniformly stirring, then adding water and a water reducing agent, and uniformly stirring to obtain the cement-based composite material.
In examples 1 to 3, the cement-based composite material was prepared by the above steps, but the difference was that the raw materials added were different in the mixing ratio, which is specifically shown in table 1:
TABLE 1
Example 4
The method is the same as example 1 except that in the step (4), cement, quartz sand, fly ash and 50kg of II-type ammonium polyphosphate are mixed and uniformly stirred to obtain a mixture C.
Example 5
The preparation of the cement-based composite material comprises the following steps:
(1) weighing the raw materials according to the raw material dosage in the example 1;
(2) bisphenol A type E-51 epoxy resin, graphene oxide and nano SiO 2 Mixing triethylene tetramine and polyvinyl alcohol fibers and uniformly stirring to obtain a mixture A;
(3) mixing and uniformly stirring cement, quartz sand and fly ash to obtain a mixture B;
(5) and (3) mixing the mixture A obtained in the step (2) and the mixture B obtained in the step (3), uniformly stirring, then adding water and the water reducing agent, and uniformly stirring to obtain the cement-based composite material.
Example 6
The preparation of the cement-based composite material comprises the following steps:
(1) weighing the raw materials according to the raw material dosage in the example 1;
(2) bisphenol A type E-51 epoxy resin and nano SiO 2 Mixing and stirring uniformly to obtain a mixture A;
(3) mixing and uniformly stirring graphene oxide, triethylene tetramine and polyvinyl alcohol fibers to obtain a mixture B;
(4) mixing and uniformly stirring cement, quartz sand and fly ash to obtain a mixture C;
(5) and (3) mixing the mixture A obtained in the step (2) and the mixture B obtained in the step (3) and uniformly stirring, then adding the mixture C obtained in the step (4), uniformly stirring, then adding water and a water reducing agent, and uniformly stirring to obtain the cement-based composite material.
Example 7
The difference from example 1 is that no graphene oxide is added in step (2).
Example 8
The difference from example 1 is that no nano SiO is added in step (3) 2 。
Effect verification
Placing the cement-based composite materials prepared in the examples 1-8 in a standard curing room (the temperature is 20 +/-2 ℃, and the relative humidity is more than or equal to 95%), curing for 28 days, taking out, moving to an outdoor ventilation place, drying, respectively taking 12 test pieces prepared in each example, averagely dividing the test pieces into A, B groups, wherein the A group is used for detecting the cube compressive strength, the axis compressive strength, the splitting tensile strength and the bending strength at normal temperature, the B group is subjected to high-temperature heating treatment at 800 ℃, the high-temperature heating treatment is carried out in a box-type electric furnace, the box-type electric furnace is preheated to 100 ℃, the test pieces are placed, the temperature is increased to the corresponding temperature at the speed of 10 ℃/min, the electric furnace operation display window flickers to generate a Stop after the heating is finished, at the moment, a furnace door is opened, and the test pieces are taken out, and are sprayed with water and cooled. And then placing each test piece after high-temperature treatment indoors for 3 days, and detecting the compression strength, the axial compression strength, the splitting tensile strength and the breaking strength of the cube. The cube compression strength is tested on a 200-ton electro-hydraulic servo testing machine produced by Shanghai Hualong testing instrument GmbH according to the requirements of ' basic performance testing method of building mortar ' (JGJ70-2009) '; axial compressive strength: the operation is carried out according to the requirement of chapter ninth in the mechanical property test method of mortar for steel wire mesh cement (GB/T7897-2008), and the test is carried out on a 300kN microcomputer control pressure tester of a hydraulic structure laboratory of Zhengzhou university; breaking strength: according to the requirements of chapter six in the test method for mechanical properties of mortar for steel wire mesh cement (GB/T7897-2008), the test is carried out on a 300kN microcomputer control pressure tester of a hydraulic structure laboratory of Zhengzhou university; the splitting tensile test needs to be carried out by adopting a splitting tensile fixture, a wooden filler strip is manufactured, the width of the wooden filler strip is about 20mm, the length of the wooden filler strip is slightly greater than that of the test block, the filler strip is perpendicular to the top surface of the test block during molding during the test, the filler strip is arranged between the upper arc-shaped filler block and the test block, and the filler block and the filler strip are arranged on the central line of the test block. The splitting test is also carried out on a 2000kN microcomputer control pressure testing machine, during the test, the positions of a test piece and a cushion block are continuously adjusted when the upper pressure surface of the pressure machine descends, the contact balance is ensured, the pressure can be uniformly transmitted to the test block through the cushion block and a cushion strip, the loading speed is 1.5kN/s, the loading is continuously and uniformly loaded until the test piece is damaged, the damage load is recorded, and the splitting strength is calculated according to the formula (1):
in the formula: f. of tx Splitting Strength (MPa)
F-test piece breaking load (N)
A-area of fracture surface of test piece (mm) 2 )。
The test results of the cubic compressive strength, the axial compressive strength, the splitting tensile strength and the breaking strength are shown in table 1.
TABLE 1
As can be seen from Table 1, the cement-based composite material prepared by the invention has excellent cubic compressive strength, axial compressive strength, splitting tensile strength and breaking strength at normal temperature, and after being treated at the high temperature of 800 ℃, various properties are reduced, but the good mechanical properties are still maintained, so that the cement-based composite material prepared by the invention has excellent high-temperature resistance; moreover, as can be seen from table 1, the cement-based composite material obtained by adding the raw material ii-type ammonium polyphosphate in the preparation process has the best normal-temperature mechanical properties, and after the cement-based composite material is subjected to high-temperature treatment, the reduction degree of various properties is also minimal, thereby indicating that the normal-temperature mechanical properties and the high-temperature resistance of the cement-based composite material can be effectively improved by adding a certain amount of ii-type ammonium polyphosphate in the cement-based composite material.
The above description is only for the preferred embodiment of the present invention, and the protection scope of the present invention is not limited thereto, and any person skilled in the art should be able to cover the technical scope of the present invention, the technical solution and the inventive concept of the present invention equivalent or change within the technical scope of the present invention.
Claims (5)
1. The preparation method of the high-temperature-resistant cement-based composite material is characterized by comprising the following raw materials in parts by weight: 650 parts of cement, 420 parts of quartz sand, 330 parts of fly ash and nano SiO 2 9 parts of water, 370 parts of epoxy resin, 35 parts of curing agent, 15 parts of graphene oxide, 10 parts of water reducing agent, 50 parts of II-type ammonium polyphosphate and 8 parts of polyvinyl alcohol fiber;
the preparation method of the cement-based composite material comprises the following steps: mixing and stirring epoxy resin and graphene oxide to obtain a mixture A; mixing nano SiO 2 Mixing and stirring a curing agent and polyvinyl alcohol fibers to obtain a mixture B; mixing cement, quartz sand, II-type ammonium polyphosphate and fly ash to obtain a mixture C; and mixing and stirring the mixture A and the mixture B, adding the mixture C, stirring, then adding water and a water reducing agent, and stirring to obtain the cement-based composite material.
2. The method of preparing a cementitious composite as set forth in claim 1 wherein said cement is p.o.42.5 cement.
3. The method for preparing a cement-based composite material according to claim 1, wherein the epoxy resin is a bisphenol a type epoxy resin; the curing agent is a normal-temperature curing agent.
4. The method for preparing the cement-based composite material as claimed in claim 1, wherein the polyvinyl alcohol fiber has a tensile strength of not less than 1400MPa and an elongation of not less than 6.0%.
5. The method of claim 1, wherein the nano SiO is in the form of a powder 2 The average grain diameter is less than or equal to 35 nm.
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| CN102092996A (en) * | 2010-11-30 | 2011-06-15 | 南京理工大学 | Cement-based composite material with high-temperature resistance and superhigh performance and preparation method thereof |
| CN105294027B (en) * | 2015-12-04 | 2017-03-22 | 武汉理工大学 | Graphene oxide modified cement-based composite material and preparation method thereof |
| CN106278026B (en) * | 2016-08-09 | 2018-11-02 | 郑州大学 | A kind of cement-base composite material and preparation method thereof |
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| CN111377687A (en) * | 2020-03-24 | 2020-07-07 | 重庆高途新材料科技有限公司 | Graphene oxide low-cement-consumption ultrahigh-performance concrete and preparation method thereof |
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