CN113103767B - Method for performing mixed printing and thermal transfer printing by adopting multiple jet printing materials - Google Patents
Method for performing mixed printing and thermal transfer printing by adopting multiple jet printing materials Download PDFInfo
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- CN113103767B CN113103767B CN202110403045.3A CN202110403045A CN113103767B CN 113103767 B CN113103767 B CN 113103767B CN 202110403045 A CN202110403045 A CN 202110403045A CN 113103767 B CN113103767 B CN 113103767B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/21—Ink jet for multi-colour printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J3/00—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed
- B41J3/407—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material
- B41J3/4078—Printing on textile
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
Abstract
The invention discloses a method for performing mixed printing and thermal transfer printing by adopting various jet printing materials, which comprises the following steps: step one, loading an ink-jet thermal transfer medium on a multi-row ink-jet head printer; step two, loading corresponding jet printing materials in each row of nozzles of a multi-row ink-jet head printer by using an image decomposition channel to be printed; thirdly, the multi-row ink-jet head printer positions and jet prints various jet printing materials on the surface of the ink-jet thermal transfer medium according to the image channel; drying the jet printing material for jet printing the pictures and texts on the ink-jet thermal transfer printing medium, thermally transferring the pictures and texts on the ink-jet thermal transfer printing medium to a transferred material in a thermal transfer printing machine, cooling, and stripping the ink-jet thermal transfer printing medium to obtain an image on the transferred material; the relative position of the jet printing material can be accurately corresponded by the multi-row ink-jet head printer according to the image requirement, the accuracy is improved, the visual sense and the hand feeling of the fabric are improved, and the multi-row ink-jet head printer has great significance for the development of fabric printing.
Description
Technical Field
The invention relates to the technical field of textile printing, in particular to a method for carrying out mixed printing and thermal transfer printing by adopting various jet printing materials.
Background
At present, the polyester fiber fabric printing widely uses a thermal sublimation transfer printing method, which specifically comprises the following steps: printing an image on transfer paper by using disperse dye ink in an inkjet way, carrying out thermal sublimation transfer printing at about 200 ℃ on the transfer paper printing image facing the polyester fiber fabric, carrying out thermal sublimation of the disperse dye into polyester fiber molecules which expand by heating, and cooling to obtain a colorful image on the polyester fiber fabric; although the disperse dye ink can transfer the image and text to the polyester fiber fabric after thermal sublimation and has soft hand feeling, the effects of bright spots, color spots, metallic color, gold stamping and the like with hand feeling cannot be realized on the polyester fiber fabric.
A digital heat transfer printing positioning gold stamping method (CN110641173A) comprises the steps of firstly coating a layer of printing slurry on the surface of a gold stamping foil, then printing hot melt adhesive slurry on the surface of the gold stamping foil coated with the printing slurry, then printing disperse dye ink on the gold stamping foil with hot melt adhesive patterns on the surface in a nesting manner, finally attaching the gold stamping foil to a polyester fabric to be printed, and carrying out hot pressing to obtain a positioning gold stamping printed fabric; the method can print color and metal color on the fabric, but the process is complex, and simultaneously a plurality of devices such as a coating machine, a screen printing machine, an ink-jet printer and the like are used, so that the requirement on the same positioning precision among the devices is very high, and defective printed fabric can be obtained if errors or errors occur.
Disclosure of Invention
The invention aims to solve the problems and designs a method for performing mixed printing and thermal transfer printing by adopting a plurality of jet printing materials.
The technical scheme of the invention is that the method for performing mixed printing and thermal transfer printing by adopting a plurality of jet printing materials comprises the following steps:
step one, loading an ink-jet thermal transfer medium on a multi-row ink-jet head printer;
step two, loading corresponding jet printing materials in each row of nozzles of a multi-row ink-jet head printer by using an image decomposition channel to be printed;
thirdly, the multi-row ink-jet head printer positions and jet prints the corresponding jet printing material on the surface of the ink-jet thermal transfer medium according to the image channel;
and step four, drying the jet printing material for jet printing the pictures and texts on the ink-jet thermal transfer printing medium, thermally transferring the pictures and texts on the ink-jet thermal transfer printing medium to the transferred material in a thermal transfer printing machine, cooling, and stripping the ink-jet thermal transfer printing medium to obtain an image on the transferred material.
As a further explanation of the present invention, the multi-row inkjet head printing at least includes three rows of nozzles, wherein the inkjet material loaded by the first row of nozzles is cationic water, the inkjet material loaded by the second row of nozzles is disperse dye ink, paint ink or inkjet glue, and the inkjet material loaded by the third row of nozzles is disperse dye ink, paint ink or inkjet glue.
As a further illustration of the invention, the disperse dye ink or the coating ink is anionic ink, and the jet printing glue is anionic material, wherein the printing precision can be maintained by combining the cationic water with the anionic ink and the anionic material.
As a further illustration of the invention, the composition of the cationic water comprises 20-55% of quaternary ammonium salt, 5-20% of wetting agent, 0.2-2% of surfactant, 0.2-1% of bactericide, 0.2-2% of PH regulator and deionized water.
As a further illustration of the invention, the components of the spray printing glue comprise 15-40% of aqueous PU, 5-20% of wetting agent, 0.2-2% of surfactant, 0.2-1% of bactericide, 0.2-2% of PH regulator and deionized water.
As a further illustration of the invention, the temperature in the thermal transfer machine is 100-210 ℃, and the pressure is 0.05-20kg/cm 2 The thermal transfer time is 10-40 s.
As a further illustration of the invention, the ink-jet thermal transfer medium comprises release paper, a release film, a peelable gold stamping release film and a peelable laser film.
As a further explanation of the present invention, the transferred material includes a fiber fabric, leather, and a flat plate surface.
The multi-row ink gun printer has the advantages that 1, the multi-row spray heads are arranged on the multi-row ink gun printer, so that various jet printing materials can be loaded, the relative positions of the jet printing materials can be accurately corresponded according to the image requirements, and the accuracy is improved;
2. the spray printing material adopted by the invention comprises cationic water, disperse dye ink, coating ink and spray printing glue, the cationic water is firstly spray printed according to pictures and texts, and then the anionic ink or the spray printing glue is spray printed, and the anionic disperse dye ink, the coating ink or the spray printing glue cannot be dissolved due to the combination of the cations and the anions, so that the printing precision is kept;
3. the method has simple process, can thermally transfer images to various transferred materials such as fiber fabrics, leather, flat surfaces and the like, and has wide applicability;
4. the method of the invention can not only obtain the color image, but also accurately position and present the color spot image, the bright spot image, the laser image, the gold stamping image and other effects on the color image, thereby improving the visual sense and the hand feeling of the fabric and having great significance for the development of fabric printing.
Drawings
FIG. 1 is a schematic view of a multi-line ink-jet head printer according to the present invention;
FIG. 2 is a schematic structural diagram of an inkjet gold stamping release film medium according to embodiment 1 of the present invention;
FIG. 3 is a schematic diagram of a real object of a gold stamping image in embodiment 1 of the present invention;
FIG. 4 is a schematic illustration of an inkjet release paper or release film media according to example 2 of the present invention;
FIG. 5 is a schematic representation of color image entities according to example 2 of the present invention;
FIG. 6 is a schematic illustration of an inkjet release paper or release film media according to example 3 of the present invention;
fig. 7 is a schematic diagram of a high lizard skin-imitated image entity in accordance with example 3 of the present invention;
in the figure, firstly, a spray printing trolley is arranged; a first row of spray heads; the second row of spray heads; fourthly, a third row of spray heads; ink-jet thermal transfer medium; sixthly, a cationic water layer; seventhly, spraying and printing a glue layer; eighty disperse dye ink layer; ninthly coating the ink layer.
Detailed Description
The disperse dye ink in the printing of the polyester fiber fabric can be used for transferring the polyester fiber fabric after thermal sublimation and has soft hand feeling, but the effects of bright spots, color spots, metallic colors, gold stamping and the like with hand feeling can not be realized on the polyester fiber fabric; the digital thermal transfer printing positioning gold stamping method has a complex process, a plurality of devices need to be linked, the requirement on the same positioning precision among the devices is high, and if a mistake occurs, the printed fabric of defective products can be obtained; therefore, a method for performing mixed printing and thermal transfer printing by adopting a plurality of jet printing materials is designed, and the technical scheme of the invention is explained in detail according to the attached drawings;
the method of the invention comprises the following steps:
loading an ink-jet thermal transfer medium on a multi-row ink-jet head printer;
step two, loading corresponding jet printing materials in each row of nozzles of a multi-row ink-jet head printer by using an image decomposition channel to be printed;
step three, the multi-row ink gun printer performs positioning jet printing on the surface of the ink jet thermal transfer medium (fifth) according to the image channel to form a plurality of jet printing materials;
step four, drying the spray printing material for spraying and printing the pictures and texts on the ink-jet thermal transfer medium, and then drying the spray printing material at the temperature of 100 ℃ and 210 ℃ and under the pressure of 0.05-20kg/cm 2 The heat transfer machine transfers the pictures and texts on the ink-jet heat transfer medium to the material to be transferred for 10-40s, and after cooling, the ink-jet heat transfer medium is stripped off to obtain images (such as delicate and beautiful visual color images, paint ink images with hand feeling, colloid images, gold stamping images, laser images, etc.) on the material to be transferred.
As shown in fig. 1, the multi-row inkjet head printer used in the above steps includes a printing trolley, and the multi-row inkjet head printer mainly includes three rows of nozzles, all of which are located in the printing trolley, but the nozzles may be determined whether to be located in the printing trolley according to actual situations, for example, in high-speed printing, many nozzles may be separately installed in a plurality of printing trolleys.
The ink-jet heat transfer medium used in the step (c) comprises release paper, a release film, a peelable gold stamping release film and a peelable laser film; the transferred material includes fabric, leather and a flat surface.
The jet printing materials used in the steps comprise cationic water, disperse dye ink, coating ink and jet printing glue, the first row of spray heads of the multi-row ink-jet head printer in the step two are loaded with the cationic water, the second row of spray heads are loaded with the disperse dye ink, the coating ink or the jet printing glue, and the third row of spray heads are loaded with the disperse dye ink, the coating ink or the jet printing glue;
the jet printed material of the present invention is important and will be described below:
1. the cationic water is almost transparent water, and does not cover the image and text after thermal transfer printing, so that the cationic water is a bottom layer for printing all images; the composition of the cationic water is shown in the following table:
| composition (I) | In percentage by weight |
| Quaternary ammonium salts | 20－55 |
| Wetting agent | 5－20 |
| Surface active agent | 0.2－2 |
| Bactericide | 0.2－1 |
| PH regulator | 0.2－2 |
| Deionized water | The rest(s) |
The cationic water to be described with respect to the above components is a resin-free quaternary ammonium salt, which is a salt of quaternary ammonium cation having the characteristics of high cation concentration and low viscosity after 4 hydrogen ions in the ammonium ion are substituted by hydrocarbon groups, and the addition of deionized water in the cationic water can prevent anions in the water from combining with the cations of the quaternary ammonium salt to produce particles to block the micropores of the spray head; meanwhile, as the disperse dye ink or the coating ink is anionic ink, and the spray printing glue is an anionic material, cations can be combined with anions, and the disperse dye ink, the coating ink or the spray printing glue is not splashed by the cationic water, so that the printing precision is maintained.
2. The spray printing glue is used for printing pictures and texts in the special channel, a glue image is displayed at the appointed position of the ink-jet thermal transfer medium, and the composition components of the spray printing glue are shown in the following table:
| composition (I) | In percentage by weight |
| Aqueous PU | 15－40 |
| Wetting agent | 5－20 |
| Surface active agent | 0.2－2 |
| Bactericide | 0.2－1 |
| PH regulator | 0.2－2 |
| Deionized water | The rest(s) |
The glue is different from the conventional glue and is used for spray printing, the ink-jet thermal transfer printing medium can be peeled off in the thermal transfer printing process, meanwhile, the water is volatilized or dried after the spray printing process, the water-based PU becomes a solid film, and the solid film is melted and bonded with a transfer printing material in the thermal transfer printing process to transfer the pattern to the transfer printing material.
3. The disperse dye ink and the paint ink are both coloring agents, like spray printing glue, the disperse dye ink and the paint ink are both used for printing pictures and texts in a special channel, a disperse dye ink image or a paint ink image is presented at a designated position of the ink-jet thermal transfer medium, the disperse dye ink can be gasified or thermally migrated at about 200 ℃ to enter polyester fiber molecules which are expanded by heating for dyeing, and the paint ink is combined with the fibers in a bonding mode for dyeing.
In order to facilitate those skilled in the art to understand the technical solution of the present invention, the following description will be made by way of example with reference to the above contents:
example 1 bronzing image (as shown in FIG. 3)
Loading a release film (hereinafter referred to as a gold stamping release film) of a strippable gold stamping foil on a multi-row ink-jet head printer, wherein the release film is a film capable of separating a metal aluminum plating layer, and is formed by coating a strippable release agent on a polyester film, printing a color layer on the surface of the release agent, and electroplating aluminum on the color layer;
secondly, decomposing the image to be printed into channels, and loading cationic water, printing glue and disperse dye ink on a first row of nozzles, a second row of nozzles and a third row of nozzles of a multi-row ink-jet head printer;
thirdly, accurately positioning and spray-printing a spray-printing material on the electroplated aluminum surface of the gold stamping release film according to an image channel by a multi-row ink-jet head printer to obtain an ink-jet gold stamping release film medium (shown in figure 2) comprising a cationic water layer, a spray-printing glue layer and a dispersed dye ink layer;
step four, drying the printing surface of the ink-jet gold stamping release film medium, and then performing hot stamping at the temperature of 210 ℃ and under the pressure of about 0.05kg/cm 2 The thermal transfer printing machine thermally transfers the pictures and texts onto the polyester fabric, the thermal transfer printing time is 10s, the electroplated aluminum and the color thereof on the gold stamping release film can be adhered to the polyester fabric together with the jet printing glue, the gold stamping release film is peeled off after cooling, and bright color is obtained on the polyester fabricBeautiful and bright gold stamping images.
Example 2 color image (as shown in FIG. 5)
Loading release paper or release film on a multi-row ink-jet head printer;
secondly, decomposing the image to be printed into channels, and loading cationic water, coating ink and spray printing glue on a first row of nozzles, a second row of nozzles and a third row of nozzles of a multi-row ink-jet head printer;
thirdly, accurately positioning, spraying and printing a jet printing material on the release paper or the release film by a multi-row ink-jet head printer according to an image channel to obtain ink-jet release paper or release film medium (shown in figure 4) comprising a cationic water layer, a coating ink layer and a jet printing glue layer;
step four, drying the ink-jet release paper or the release film medium, and then, controlling the temperature at 100 ℃ and the pressure at 20kg/cm 2 The thermal transfer printing machine transfers the pictures and texts onto the leather in a thermal transfer printing mode for 20s, the spray printing glue is attached to the printing surface of the leather during thermal transfer printing, and the release paper or the release film is peeled after cooling to obtain a color image on the leather.
At present, with the improvement of consumption requirements, leather printed products are more and more, and leather is generally dyed and not printed, because the conditions of the long size, the thickness size and the leather surface of each piece of natural leather are different, the natural leather is difficult to be placed in a printer for printing in register precision, if printing is needed, a screen printer can only be used for printing in register with insufficient precision, and the traditional printing and dyeing method is limited by a printing machine and is not suitable for printing too large or too small leather.
The traditional ink-jet printing of leather or prints is to fix the printed matter on the flat plate of a special ink-jet printer, and directly ink-jet print the printed matter on the surface of the leather or prints by using UV ink or oily ink under insufficient hygienic conditions, so that the printing of very small leather or prints can be carried out, but the printing is not suitable for large sizes, because the large-size flat plate ink-jet printing machine is expensive in manufacturing cost, and in addition, the printed matter has toxicity and is prohibited to be used in the occasions of contacting skin and poor air circulation; the embodiment can print in a roll, and is convenient for cutting and manufacturing transfer paper with various sizes after printing so as to be positioned and thermally transferred on leather or woodcut with various sizes and manufacture a thermal transfer product which meets sanitary conditions and is exquisite.
The color pattern of the embodiment 2 can be thermally transferred on a board made of PU, PVC, PE or wood, and the color ink can be kept fadeless in the sun for a long time due to the pigment serving as a coloring agent, so that the color pattern can be used for making outdoor pictures.
Example 3 high lizard skin simulation image (as shown in FIG. 7)
Loading release paper or release film on a multi-row ink-jet head printer;
secondly, decomposing the image to be printed into channels, and loading cationic water, coating ink and disperse dye ink on a first row of nozzles, a second row of nozzles and a third row of nozzles of a multi-row ink-jet head printer;
thirdly, accurately positioning and jet-printing materials on release paper or a release film by a multi-row ink-jet head printer according to an image channel to obtain ink-jet release paper or release film media (shown in figure 6) comprising a cationic water layer (c), a coating ink layer (c) and a disperse dye ink layer (b);
step four, drying the ink-jet release paper or the release film medium, and then, controlling the temperature at 200 ℃ and the pressure at 1kg/cm 2 The thermal transfer printer thermally transfers the pictures and texts onto the polyester fabric (or a flat plate sprayed with a polyester layer), the thermal transfer printing time is 40s, the release paper or the release film is peeled off after cooling, the polyester fabric is dyed by the disperse dye ink to present a color image to form a ground color, and the coating ink presents color glue spots on the polyester fabric to obtain a high lizard-imitated skin image.
The high-imitation lizard skin fabric prepared by the method is only an example of high-imitation animal skin, and products such as crocodile skin, fish skin, snake skin, pangolin skin and the like can be imitated by color expression and matching of hard bright spots; the disperse dye ink and the coating ink are printed in a mixed mode, after heat transfer printing is carried out on polyester fabrics, the characteristics of high strength, beautiful color of disperse dyes and bright specks of polyester fabrics can be integrated, the polyester fabric is very similar to animal leathers in terms of color and hand feeling, and the polyester fabric can be used for manufacturing clothing articles and ornaments such as handbags, belts, leather shoes and clothes, so that the catching and killing of wild animals are reduced, and the ecological environment is protected.
It should be noted that the embodiments of the present invention are not limited to the above-mentioned embodiments, and structural, method, or functional changes made by those skilled in the art according to the embodiments are included in the scope of the present invention; the spray printing materials can be selected and combined as required, and then are thermally transferred to the corresponding transferred materials, so that the color image can be obtained, and the effects of color spot images, bright spot images, laser images, gold stamping images and the like can be accurately positioned and presented on the color image.
The technical solutions described above only represent the preferred technical solutions of the present invention, and some possible modifications to some parts of the technical solutions by those skilled in the art all represent the principles of the present invention, and fall within the protection scope of the present invention.
Claims (3)
1. A method for performing mixed printing and thermal transfer printing by adopting a plurality of jet printing materials is characterized by comprising the following steps:
step one, loading an ink-jet thermal transfer medium on a multi-row ink-jet head printer;
step two, loading corresponding jet printing materials in each row of nozzles of a multi-row ink-jet head printer by using an image decomposition channel to be printed;
thirdly, the multi-row ink-jet head printer positions and jet prints the corresponding jet printing material on the surface of the ink-jet thermal transfer medium according to the image channel;
drying the jet printing material for jet printing the pictures and texts on the ink-jet thermal transfer printing medium, thermally transferring the pictures and texts on the ink-jet thermal transfer printing medium to a transferred material in a thermal transfer printing machine, cooling, and stripping the ink-jet thermal transfer printing medium to obtain an image on the transferred material;
the multi-row ink gun printing at least comprises three rows of spray heads, wherein the spray printing material loaded by the first row of spray heads is cationic water, the spray printing material loaded by the second row of spray heads is disperse dye ink, coating ink or spray printing glue, and the spray printing material loaded by the third row of spray heads is disperse dye ink, coating ink or spray printing glue;
the disperse dye ink or the paint ink is anionic ink, and the spray printing glue is an anionic material, wherein the printing precision can be kept by combining the cationic water with the anionic ink and the anionic material;
the cationic water comprises 20-55% of quaternary ammonium salt, 5-20% of wetting agent, 0.2-2% of surfactant, 0.2-1% of bactericide, 0.2-2% of PH regulator and deionized water;
the components of the spray printing glue comprise 15-40% of aqueous PU, 5-20% of wetting agent, 0.2-2% of surfactant, 0.2-1% of bactericide, 0.2-2% of PH regulator and deionized water;
the temperature in the thermal transfer printer is 100-210 ℃, and the pressure is 0.05-20kg/cm 2 The thermal transfer time is 10-40 s.
2. The method of claim 1, wherein the inkjet thermal transfer medium comprises release paper, peelable bronzing release film, and peelable laser film.
3. The method of claim 1, wherein the transferred material comprises fabric, leather, and flat surfaces.
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