JP5265301B2 - Transfer sheet and printing method using the transfer sheet - Google Patents
Transfer sheet and printing method using the transfer sheet Download PDFInfo
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- JP5265301B2 JP5265301B2 JP2008273717A JP2008273717A JP5265301B2 JP 5265301 B2 JP5265301 B2 JP 5265301B2 JP 2008273717 A JP2008273717 A JP 2008273717A JP 2008273717 A JP2008273717 A JP 2008273717A JP 5265301 B2 JP5265301 B2 JP 5265301B2
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- 238000007639 printing Methods 0.000 title claims description 27
- 238000000034 method Methods 0.000 title claims description 12
- 238000009966 trimming Methods 0.000 claims description 55
- 239000004840 adhesive resin Substances 0.000 claims description 43
- 229920006223 adhesive resin Polymers 0.000 claims description 43
- 229920005989 resin Polymers 0.000 claims description 31
- 239000011347 resin Substances 0.000 claims description 31
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 21
- 239000000758 substrate Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 238000007731 hot pressing Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000000088 plastic resin Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 50
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000012943 hotmelt Substances 0.000 description 6
- 229910052814 silicon oxide Inorganic materials 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 229920005749 polyurethane resin Polymers 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 4
- 238000005406 washing Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000013518 transcription Methods 0.000 description 1
- 230000035897 transcription Effects 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
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- Decoration By Transfer Pictures (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Description
本発明はTシャツやジャンパー等の衣類に図形、文字、模様等をプリントする方法、及びその際に使用する転写シートに関するものである。 The present invention relates to a method for printing figures, characters, patterns and the like on clothing such as T-shirts and jumpers, and a transfer sheet used at that time.
Tシャツやジャンパーなど衣類表面に図形や文字、模様等をプリントすることは従来から行われている。その1つの方法として、剥離性のある紙やフイルム基材上に色を付けたホットメルト樹脂がコーティングされたカラー転写シートを使用し、このカラー転写シートをコンピューターよりデーターを出力してカッター刃の付いたカッティングプロッターで、基材上の色の付いたホットメルト樹脂をトリミングし、次に手作業で不要部分を取り除き、残った部分の絵紋様を、Tシャツやジャンパー等の衣類に当てて熱圧を加えプリントしている。 Printing a figure, a character, a pattern, etc. on the clothes surface, such as a T-shirt and a jumper, has been performed conventionally. One method is to use a color transfer sheet coated with a colored hot melt resin on a peelable paper or film substrate, and then output data from the color transfer sheet from the computer to the cutter blade. Use the attached cutting plotter to trim the colored hot melt resin on the base material, then remove the unnecessary parts by hand, and apply the remaining pattern to clothing such as T-shirts and jumpers. Printing is applied with pressure.
しかし、この方法では転写シートのカラー色が決まってしまう。その為に、各色多数のカラー転写シートの在庫が必要になってしまい、又フルカラーの絵紋様をプリントすることは出来ない。何よりも、カッティングプロッターでトリミングされたカラー転写シートの不要部分を除去しなくてはならず、デザインによっては小さな漢字のように入り組んだ繊細で小さな絵紋様の場合、カットすることが困難であり、不要部分の除去は手作業のため多大なる時間がかかり過ぎてコスト高になってしまうなどの欠点がある。 However, this method determines the color color of the transfer sheet. Therefore, it is necessary to stock a large number of color transfer sheets for each color, and it is impossible to print a full-color picture pattern. Above all, it is necessary to remove unnecessary parts of the color transfer sheet trimmed with a cutting plotter, and depending on the design, it is difficult to cut in the case of delicate and small picture patterns that are intricate like small kanji, Removal of unnecessary parts has a drawback that it takes a lot of time because of manual work, resulting in high costs.
すなわち、この方法だと絵紋様のサイズ(外観的な大きさ)が同じであってもデザインやその複雑さによっては、カッティングされた不要部分の除去などの手作業による時間が異なることで、製作コストが違ってしまい、製造原価の見積もりも出来ない。 In other words, even if the pattern size (appearance size) is the same with this method, depending on the design and its complexity, the time required for manual operations such as removal of cut unnecessary parts will vary. The cost is different, and the manufacturing cost cannot be estimated.
このように従来のプリント方法には上記のごとき問題がある。本発明が解決しようとする課題はこの問題点であり、絵紋様が如何に複雑であってもTシャツなどの衣類に簡単にプリントすることが出来るプリント方法、及びその際に使用する転写シートを提供する。 Thus, the conventional printing method has the above-described problems. The problem to be solved by the present invention is this problem. A printing method capable of easily printing on clothing such as a T-shirt, and a transfer sheet used at that time, regardless of how complex the pattern is. provide.
本発明に係るプリント方法は、転写シートを用いてTシャツなどの衣類表面に転写するものである。すなわち、カラープリンターで好きな色や絵紋様を描いた転写シートをレーザープリンタやインクジェットプリンタなどの色材に混合されている樹脂トナーに、熱圧を加えて引き剥がすことによって、トリミングと同時に不要部分の除去を行うことで、Tシャツなどに好みの色で表現でき、繊細な絵紋様であってもトリミングされ、同じ時間とコストでプリント出来ることを可能としたプリント方法である。 The printing method according to the present invention is to transfer onto a clothing surface such as a T-shirt using a transfer sheet. In other words, a transfer sheet depicting a favorite color or picture pattern with a color printer is removed by applying thermal pressure to the resin toner mixed with the color material of a laser printer or ink jet printer, etc. This is a printing method that can be expressed in a favorite color on a T-shirt or the like by trimming and trimming even a delicate picture pattern and can be printed at the same time and cost.
剥離層を支持した紙又はフイルムから成る基材の上に透明な接着樹脂層と無機鉱物接着樹脂層が積層したA転写シート、又は剥離層を支持した紙又はフイルムから成る基材の上に透明な無機鉱物接着樹脂層と接着樹脂層が積層したB転写シートのどちらか一方にインクジェットプリンタ又はレーザープリンタで絵柄を印刷する。 A transfer sheet in which a transparent adhesive resin layer and an inorganic mineral adhesive resin layer are laminated on a substrate made of paper or film supporting a release layer, or transparent on a substrate made of paper or film supporting a release layer A pattern is printed by an inkjet printer or a laser printer on one of the B transfer sheets in which the inorganic mineral adhesive resin layer and the adhesive resin layer are laminated.
そして該絵柄を間にしてA転写シートにB転写シートを貼り合わして熱プレスし、次にB転写シート側の基材を剥がし、A転写シート上にB転写シートの樹脂層を移したトリミング転写シートを作成し、該トリミング転写シートのB転写樹脂層側に、トナーでネガポジの絵紋様を印刷した普通紙の印刷面を、トリミング転写シートに重ね合わせて上から熱プレスを加える。 Then, the B transfer sheet is bonded to the A transfer sheet with the pattern in between and heat-pressed, then the base material on the B transfer sheet side is peeled off, and the resin layer of the B transfer sheet is transferred onto the A transfer sheet. A sheet is prepared, and a printing surface of plain paper on which a negative / positive image pattern is printed with toner is superimposed on the trimming transfer sheet on the B transfer resin layer side of the trimming transfer sheet, and a hot press is applied from above.
そして、普通紙を引き剥がすことによりトリミング転写シートの絵柄はトリミング転写シート基材上の樹脂と共にネガポジの絵紋様に切り抜き取られ、同時に不要部分が除去され、次にトリミング転写シート上に残った絵柄を剥がして接着樹脂面を被転写体に宛てがい、上部より熱プレスしてプリントすることが出来る。 Then, by peeling off the plain paper, the pattern on the trimming transfer sheet is cut out in a negative-positive pattern together with the resin on the trimming transfer sheet substrate. At the same time, unnecessary portions are removed, and then the pattern remaining on the trimming transfer sheet Is peeled off, the adhesive resin surface is directed to the transfer target, and printing can be performed by hot pressing from above.
一方、剥離層を支持した紙又はフイルムから成る基材の上に透明な接着樹脂層と無機鉱物接着樹脂層が積層したA転写シート、又は剥離層を支持した紙又はフイルムから成る基材の上に透明な無機鉱物接着樹脂層と接着樹脂層が積層したB転写シートのどちらか一方にインクジェットプリンタ又はレーザープリンタで絵柄を印刷する。 On the other hand, an A transfer sheet in which a transparent adhesive resin layer and an inorganic mineral adhesive resin layer are laminated on a base material made of paper or film supporting a release layer, or a base material made of paper or film supporting a release layer. A pattern is printed on either one of the B transfer sheets on which the transparent inorganic mineral adhesive resin layer and the adhesive resin layer are laminated with an inkjet printer or a laser printer.
そして、該絵柄を間にしてA転写シートにB転写シートを貼り合わして熱プレスし、次にB転写シート側の基材を剥がし、A転写シート上にB転写シートの樹脂層を移したトリミング転写シートを作成し、該トリミング転写シートのB転写樹脂層側に、トナーでネガポジの絵紋様を印刷した普通紙の印刷面を、トリミング転写シートに重ね合わせて上から熱プレスを行う。 Then, the B transfer sheet is bonded to the A transfer sheet with the pattern in between and heat-pressed, then the base material on the B transfer sheet side is peeled off, and the resin layer of the B transfer sheet is transferred onto the A transfer sheet A transfer sheet is prepared, and a printing surface of plain paper on which a negative / positive image pattern is printed with toner is superimposed on the trimming transfer sheet on the B transfer resin layer side of the trimming transfer sheet, and hot pressing is performed from above.
そして、普通紙を引き剥がすことによりトリミング転写シートの絵柄はトリミング転写シート基材上の樹脂と共にネガポジの絵紋様に切り抜き取られ、同時に不要部分が除去され、次にトリミング転写シート上に残った絵柄を被転写体に宛がい、トリミング転写シートの上部より熱プレスしてプリントすることが出来る。 Then, by peeling off the plain paper, the pattern on the trimming transfer sheet is cut out in a negative-positive pattern together with the resin on the trimming transfer sheet substrate. At the same time, unnecessary portions are removed, and then the pattern remaining on the trimming transfer sheet Can be applied to a transfer medium and printed by hot pressing from above the trimming transfer sheet.
本発明に係るプリント方法は、A転写シートとB転写シートの2枚を1組として使用し、細かく繊細な絵紋様であってもTシャツなどの衣類表面に正確にプリントすることが出来、しかもこのプリントに際してかかるコストは絵紋様の複雑さや繊細さに影響されることはなく、一定である。勿論、低コストでプリントすることが出来る。しかも、カラープリンターがあれば誰でも手軽にプリントすることが出来る。そして、プリントされた絵紋様は何回洗濯しても剥がれ落ちることはなく、耐洗濯性に優れている。 The printing method according to the present invention uses two sheets of an A transfer sheet and a B transfer sheet as a set, and even a fine and delicate picture pattern can be printed accurately on the surface of clothing such as a T-shirt. The cost for this printing is not affected by the complexity and delicacy of the picture pattern and is constant. Of course, it can be printed at low cost. Moreover, anyone with a color printer can easily print. And the printed picture pattern does not peel off even if it is washed many times, and is excellent in washing resistance.
(実施例1)
ここでは、シルクスクリーン印刷機を用いてコーティング機として説明するが、勿論、ロールコーターなど他のコーティング装置を用いても同様な結果が得られる。
図1はA転写シートの断面拡大図を示し、その製作方法は次の通りである。
普通紙にクレーなどで目止めコートされた用紙1に信越化学社製シリコーンKS3502樹脂溶液をシルクスクリーン印刷機で、乾燥膜厚2μ程度を均一に塗工し、剥離層2を支持した基材1,2を製作した。
Example 1
Here, a silk screen printing machine is used as the coating machine, but it goes without saying that similar results can be obtained using other coating apparatuses such as a roll coater.
FIG. 1 shows an enlarged cross-sectional view of the A transfer sheet, and the manufacturing method thereof is as follows.
A base material 1 that supports a release layer 2 by uniformly applying a silicone KS3502 resin solution manufactured by Shin-Etsu Chemical Co., Ltd. on a plain paper 1 with a clay or the like with a silk screen printer to a dry film thickness of about 2 μm. , 2 was produced.
上記、基材剥離層2の上に大日本インキ社製ホットメルト系のポリウレタン樹脂クリスボン(商品名4407)をシルクスクリーン印刷機で、乾燥膜厚30〜40μになるように均一に塗工して接着樹脂層3を形成した。 On the base material release layer 2, Dainippon Ink Co., Ltd. hot-melt polyurethane resin Crisbon (trade name 4407) was applied uniformly with a silk screen printer to a dry film thickness of 30 to 40 μm. An adhesive resin layer 3 was formed.
上記、接着樹脂層3の上に酸化ケイ素中にポリエステル/ポリエーテル系ウレタン樹脂を30部混入して信越化学社製シリコーンKS603を3%と油化産業社製エレガンワックス樹脂3%を溶かしたシクロヘキサノン溶液と1:2の割合でミキサーで混合攪拌し、シルクスクリーン印刷機で乾燥膜厚5μの無機鉱物接着樹脂層4を表層面に形成したA転写シートと成る。 Cyclohexanone in which 30 parts of polyester / polyether urethane resin is mixed in silicon oxide on the adhesive resin layer 3 and 3% of silicone KS603 manufactured by Shin-Etsu Chemical Co., Ltd. and 3% of elegance wax resin manufactured by Yuka Sangyo Co., Ltd. are dissolved. The mixture is stirred with a mixer at a ratio of 1: 2 with the solution, and an A transfer sheet is obtained in which an inorganic mineral adhesive resin layer 4 having a dry film thickness of 5 μm is formed on the surface by a silk screen printer.
又、図2にB転写シートの断面拡大図を示しているが、このB転写シートは次のように製作される。すなわち、上記A転写シートの場合と同じように、普通紙にクレーなどで目止めコートされた用紙1に信越化学社製シリコーンKS3502樹脂溶液をシルクスクリーン印刷機で、乾燥膜厚2μ程度を均一に塗工し、剥離層2を支持した基材1,2を製作した。ここで、無機鉱物接着樹脂層とは、無機鉱物の微粉末の中にプラスチック樹脂を混入したものである。 FIG. 2 shows an enlarged cross-sectional view of the B transfer sheet. The B transfer sheet is manufactured as follows. That is, as in the case of the above A transfer sheet, a silicone KS3502 resin solution manufactured by Shin-Etsu Chemical Co., Ltd. is applied to paper 1 coated with clay or the like on plain paper using a silk screen printer, and a dry film thickness of about 2 μm is uniformly formed. The substrates 1 and 2 supporting the release layer 2 were manufactured by coating. Here, the inorganic mineral adhesive resin layer is obtained by mixing a plastic resin in a fine powder of inorganic mineral.
そして、上記基材剥離層2の上に酸化ケイ素中にポリエステル/ポリエーテル系ウレタン樹脂を60部混入して信越化学社製シリコーンKS603を3%溶かしたシクロヘキサノン溶液と1:3の割合でミキサーで混合攪拌し、シルクスクリーン印刷機で乾燥膜厚5μの無機鉱物接着樹脂層4を形成した。 Then, 60 parts of a polyester / polyether urethane resin is mixed in silicon oxide on the substrate peeling layer 2 and a cyclohexanone solution in which 3% of silicone KS603 manufactured by Shin-Etsu Chemical Co., Ltd. is dissolved in a mixer at a ratio of 1: 3. After mixing and stirring, an inorganic mineral adhesive resin layer 4 having a dry film thickness of 5 μm was formed by a silk screen printer.
その上に、大日本インキ社製ホットメルト性のポリウレタン樹脂クリスボン(商品名4407)に酸化ケイ素を1%加えミキサー攪拌後、さらに大日精化社製ダイアロマー2501ポリウレタン樹脂を50部加え、トナー及びインクの受容性を持たせた樹脂を、シルクスクリーン印刷機で、乾燥膜厚15〜20μになるように均一に塗工し、接着樹脂層3を表層面に形成してB転写シートを作成した。 On top of that, 1% silicon oxide was added to a hot melt polyurethane resin Chrisbon (trade name 4407) manufactured by Dainippon Ink Co., Ltd., and the mixture was stirred. The resin having the receptivity was applied uniformly with a silk screen printer so as to have a dry film thickness of 15 to 20 μm, and an adhesive resin layer 3 was formed on the surface layer to prepare a B transfer sheet.
上記、A転写シートにエプソン社製PM−G800インクジェットプリンタで絵柄5を印刷し、そして図3に示すように該A転写シートにB転写シートを太陽精機社製TP600Aの熱プレス機で、温度130℃、圧力250g/cm2で15秒間、熱プレスを行い、絵柄5を間にして貼り合わせた。
次にB転写シート側の基材1,2を剥がし、図4に示すように、A転写シート上にB転写シートの樹脂層を移しトリミング転写シートを作成した。
The pattern 5 is printed on the A transfer sheet by an Epson PM-G800 inkjet printer, and the B transfer sheet is applied to the A transfer sheet as shown in FIG. Hot pressing was performed at a temperature of 250 ° C./cm 2 for 15 seconds, and the patterns 5 were bonded together.
Next, the base materials 1 and 2 on the B transfer sheet side were peeled off, and as shown in FIG. 4, a resin layer of the B transfer sheet was transferred onto the A transfer sheet to prepare a trimming transfer sheet.
そして、図5に示すように、トリミング転写シートのB転写樹脂層側に、リコー社製 imagio MP2500のトナー6でネガポジの絵紋様を印刷した普通紙7の印刷面を、トリミング転写シートに重ね合わせる。
そして、上から熱プレス機で、温度130℃、圧力250g/cm2で15秒間、熱プレスを行う。
Then, as shown in FIG. 5, the printing surface of plain paper 7 on which the negative positive pattern is printed with the toner 6 of Ricoh imgio MP2500 is superimposed on the trimming transfer sheet on the B transfer resin layer side of the trimming transfer sheet. .
Then, hot pressing is performed for 15 seconds at a temperature of 130 ° C. and a pressure of 250 g / cm 2 with a hot press machine from above.
そこで、図6に示すように、熱いうちに普通紙7を引き剥がすと、トリミング転写シートの絵柄5はトリミング転写シート基材1,2上の樹脂と共に残る。すなわち、ネガポジのトナー6部分のところが普通紙7に貼り付き、トナー6の載っていない部分はトリミング転写シート上に残こされ、不要部分は瞬時に切り抜き取ることが出来た。 Therefore, as shown in FIG. 6, when the plain paper 7 is peeled off while it is hot, the pattern 5 of the trimming transfer sheet remains together with the resin on the trimming transfer sheet bases 1 and 2. That is, the negative-positive toner 6 portion stuck to the plain paper 7, the portion where the toner 6 was not placed was left on the trimming transfer sheet, and the unnecessary portion could be cut out instantly.
次に図8に示すように、トリミング転写シート上に残ったトリミングされた絵柄5を白Tシャツ9に宛てがい、上部より温度180℃で同様の圧力(250g/cm2)と時間(15秒)を加え、冷めてからトリミング転写シートの基材1,2を剥がすならば、図10のように白Tシャツ9に鮮明なプリントを施すことが出来た。ここで、表面層を形成している接着樹脂層3と無機鉱物接着樹脂層4は透明である為に、絵柄5は透けて見える。 Next, as shown in FIG. 8, the trimmed pattern 5 remaining on the trimming transfer sheet is directed to the white T-shirt 9, and the same pressure (250 g / cm 2 ) and time (15 seconds) at a temperature of 180 ° C. from above. If the base materials 1 and 2 of the trimming transfer sheet are peeled off after cooling, the white T-shirt 9 can be clearly printed as shown in FIG. Here, since the adhesive resin layer 3 and the inorganic mineral adhesive resin layer 4 forming the surface layer are transparent, the pattern 5 can be seen through.
一方、図2に示すB転写シートにエプソン社製MP−G800インクジェットプリンタで絵柄5を印刷し、図3に示すようにA転写シートにB転写シートを太陽精機社製TP600A熱プレス機で、温度130℃、15秒間、圧力250g/cm2で熱プレスを加え、絵柄5を間にして貼り合わせる場合もある。
次に図4に示すように、B転写シート側の基材を剥がし、A転写シート上にB転写シートの樹脂層を移しトリミング転写シートを作成した。
On the other hand, the pattern 5 was printed on the B transfer sheet shown in FIG. 2 using an Epson MP-G800 inkjet printer, and the B transfer sheet was transferred to the A transfer sheet as shown in FIG. 3 using a TP600A hot press manufactured by Taiyo Seiki Co., Ltd. In some cases, a hot press is applied at 130 ° C. for 15 seconds at a pressure of 250 g / cm 2 , and the pattern 5 is put together.
Next, as shown in FIG. 4, the base material on the B transfer sheet side was peeled off, and the resin layer of the B transfer sheet was transferred onto the A transfer sheet to prepare a trimming transfer sheet.
そして、図5に示すように、トリミング転写シートのB転写樹脂層側に、リコー社製 imagio MP2500のトナー6でネガポジの絵紋様を印刷した普通紙7の印刷面を、トリミング転写シートに重ね合わせ、上から熱プレス機で温度130℃、15秒間、圧力250g/cm2の熱プレスを行う。 Then, as shown in FIG. 5, the printing surface of plain paper 7 on which the negative positive pattern is printed with the toner 6 of imgio MP2500 made by Ricoh is superimposed on the trimming transfer sheet on the B transfer resin layer side of the trimming transfer sheet. From above, hot pressing is performed at a temperature of 130 ° C. for 15 seconds with a pressure of 250 g / cm 2 using a hot press machine.
そこで、図6に示すように、熱いうちに普通紙7を引き剥がすと、トリミング転写シートの絵柄5はトリミング転写シート基材1,2上の樹脂と共に残る。すなわち、ネガポジのトナー6部分のところが普通紙7に貼り付き、トナー6の載っていない部分はトリミング転写シート上に残こされ、不要部分は瞬時に切り抜き取ることが出来た。 Therefore, as shown in FIG. 6, when the plain paper 7 is peeled off while it is hot, the pattern 5 of the trimming transfer sheet remains together with the resin on the trimming transfer sheet bases 1 and 2. That is, the negative-positive toner 6 portion stuck to the plain paper 7, the portion where the toner 6 was not placed was left on the trimming transfer sheet, and the unnecessary portion could be cut out instantly.
次に図8に示すように、トリミング転写シート上に残ったトリミングされた絵柄5を白Tシャツ9に宛てがい、上部より温度180℃で同様の圧力(250g/cm2)と時間(15秒)を加え、冷めてからトリミング転写シートの基材1,2を剥がすならば、図10のように白Tシャツ9に鮮明なプリントを施すことが出来た。ここで、表面層を形成している接着樹脂層3と無機鉱物接着樹脂層4は透明である為に、絵柄5は透けて見える。 Next, as shown in FIG. 8, the trimmed pattern 5 remaining on the trimming transfer sheet is directed to the white T-shirt 9, and the same pressure (250 g / cm 2 ) and time (15 seconds) at a temperature of 180 ° C. from above. If the base materials 1 and 2 of the trimming transfer sheet are peeled off after cooling, the white T-shirt 9 can be clearly printed as shown in FIG. Here, since the adhesive resin layer 3 and the inorganic mineral adhesive resin layer 4 forming the surface layer are transparent, the pattern 5 can be seen through.
上記A転写シート、B転写シートのどちらもリコー社製 imagio MP2500のカラーレーザープリンタのトナーで絵柄5を印刷しても、上記同様のトリミング転写シートが作成出来、Tシャツ9にプリントすることが出来た。
そして、プリントして得たそれぞれのTシャツ9をTOSHIBA社製洗濯機 Ginga2.2 にて、15分間水温50℃で洗い、すすぎ15分、脱水5分を3回行ったが、色落ち、剥がれ、浮きが無いことを確認した。
(実施例2)
図1はA転写シートの断面拡大図であり、普通紙にクレーなどで目止めコートされた用紙1に信越化学社製シリコーンKS3502樹脂溶液をシルクスクリーン印刷機で、乾燥膜厚2μ程度を均一に塗工し、剥離層2を支持した基材1,2を製作した。
そして、上記基材1,2の剥離層2の上に大日本インキ社製ホットメルト系のポリウレタン樹脂クリスボン(商品名4407)をシルクスクリーン印刷機で、乾燥膜厚30〜40μになるように均一に塗工し接着樹脂層3を形成した。
Both the A transfer sheet and the B transfer sheet can be printed on the T-shirt 9 even if the pattern 5 is printed with the toner of the color laser printer of imgio MP2500 manufactured by Ricoh. It was.
Each T-shirt 9 obtained by printing was washed with a washing machine Ginga2.2 manufactured by TOSHIBA for 15 minutes at a water temperature of 50 ° C., rinsed for 15 minutes, and dehydrated for 5 minutes three times. It was confirmed that there was no lift.
(Example 2)
FIG. 1 is an enlarged cross-sectional view of a transfer sheet A. A silicone KS3502 resin solution made by Shin-Etsu Chemical Co., Ltd. is applied to plain paper 1 with a clay coating, etc., and a dry film thickness of about 2 μm is uniformly formed. The substrates 1 and 2 supporting the release layer 2 were manufactured by coating.
Then, a hot melt polyurethane resin made by Dainippon Ink Co., Ltd. (trade name 4407) is uniformly applied on the release layer 2 of the substrates 1 and 2 with a silk screen printer so as to have a dry film thickness of 30 to 40 μm. The adhesive resin layer 3 was formed by coating.
上記接着樹脂層3の上に白色顔料となる酸化チタン中に酸化ケイ素5部とにポリエステル/ポリエーテル系ウレタン樹脂を60部混入して信越化学社製シリコーンKS603を3%と油化産業社製エレガンワックス樹脂3%を溶かしたシクロヘキサノン溶液と1:2の割合でミキサーで混合攪拌し、シルクスクリーン印刷機で乾燥膜厚5μの無機鉱物接着樹脂層4を表層面に形成してA転写シートが作成される。 60% of polyester / polyether urethane resin is mixed with 5 parts of silicon oxide in titanium oxide serving as a white pigment on the adhesive resin layer 3 and 3% of silicone KS603 manufactured by Shin-Etsu Chemical Co., Ltd. Mix and stir with a cyclohexanone solution containing 3% elegan wax resin at a ratio of 1: 2 with a mixer, and form an inorganic mineral adhesive resin layer 4 having a dry film thickness of 5 μm on the surface with a silk screen printer. Created.
又、図2にB転写シートの断面拡大図を示しているが、このB転写シートは次のように製作される。すなわち、上記A転写シートの場合と同じように、普通紙にクレーなどで目止めコートされた用紙1に信越化学社製シリコーンKS3502樹脂溶液をシルクスクリーン印刷機で、乾燥膜厚2μ程度を均一に塗工し、剥離層2を支持した基材1,2を製作した。 FIG. 2 shows an enlarged cross-sectional view of the B transfer sheet. The B transfer sheet is manufactured as follows. That is, as in the case of the above A transfer sheet, a silicone KS3502 resin solution manufactured by Shin-Etsu Chemical Co., Ltd. is applied to paper 1 coated with clay or the like on plain paper using a silk screen printer, and a dry film thickness of about 2 μm is uniformly formed. The substrates 1 and 2 supporting the release layer 2 were manufactured by coating.
上記、基材1,2の剥離層2の上に酸化ケイ素中にポリエステル/ポリエーテル系ウレタン樹脂を60部混入して信越化学社製シリコーンKS603を3%溶かしたシクロヘキサノン溶液と1:3の割合でミキサーで混合攪拌し、シルクスクリーン印刷機で乾燥膜厚5μの無機鉱物接着樹脂層4を形成した。 A ratio of 1: 3 to a cyclohexanone solution in which 60 parts of a polyester / polyether urethane resin is mixed in silicon oxide on the release layer 2 of the substrates 1 and 2 and 3% of silicone KS603 manufactured by Shin-Etsu Chemical Co., Ltd. is dissolved. The mixture was stirred with a mixer, and an inorganic mineral adhesive resin layer 4 having a dry film thickness of 5 μm was formed with a silk screen printer.
その上に、大日本インキ社製ホットメルト性のポリウレタン樹脂クリスボン(商品名4407)に酸化ケイ素を1%加えミキサー攪拌後、さらに大日精化社製ダイアロマー2501ポリウレタン樹脂を50部加えてトナー及びインクの受容性を持たせた樹脂を、シルクスクリーン印刷機で、乾燥膜厚15〜20μになるように均一に塗工し、接着樹脂層3を表層面に形成してB転写シートを作成した。 On top of that, 1% silicon oxide was added to a hot-melt polyurethane resin Chrisbon (trade name 4407) manufactured by Dainippon Ink Co., Ltd. The resin having the receptivity was applied uniformly with a silk screen printer so as to have a dry film thickness of 15 to 20 μm, and an adhesive resin layer 3 was formed on the surface layer to prepare a B transfer sheet.
図3に示すように、A転写シートにリコー社製 imagio MP2500のカラーレーザープリンタのトナーで絵柄5を印刷し、A転写シートにB転写シートを太陽精機社製TP600A熱プレス機で、温度130℃、15秒間、圧力250g/cm2で熱プレスを加え、絵柄5を間にして貼り合わせた。
次にB転写シート側の基材1,2を剥がし、図4に示すようにA転写シート上にB転写シートの樹脂層を移しトリミング転写シートを作成した。
As shown in FIG. 3, a pattern 5 is printed on the A transfer sheet with the toner of an imgio MP2500 color laser printer manufactured by Ricoh, and the B transfer sheet is printed on the A transfer sheet with a TP600A hot press manufactured by Taiyo Seiki Co. Then, a heat press was applied at a pressure of 250 g / cm 2 for 15 seconds, and the images were bonded together with the pattern 5 in between.
Next, the base materials 1 and 2 on the B transfer sheet side were peeled off, and the resin layer of the B transfer sheet was transferred onto the A transfer sheet as shown in FIG. 4 to prepare a trimming transfer sheet.
図5に示すように、トリミング転写シートのB転写樹脂層側に、リコー社製 imagio MP2500のトナー6でネガポジの絵紋様を印刷した普通紙7の印刷面を、トリミング転写シートに重ね合わせる。そして、上から熱プレス機で温度130℃、15秒間、250g/cm2の熱プレスを行う。 As shown in FIG. 5, the printing surface of plain paper 7 on which the negative positive pattern is printed with the toner 6 of imgio MP2500 manufactured by Ricoh is superimposed on the trimming transfer sheet on the B transfer resin layer side of the trimming transfer sheet. Then, hot pressing is performed at a temperature of 130 ° C. for 15 seconds from the top at 250 g / cm 2 .
そこで、図6に示すように、熱いうちに普通紙7を引き剥がすと、トリミング転写シートの絵柄5はトリミング転写シート基材1,2上の樹脂と共に残る。すなわち、ネガポジのトナー6部分のところが普通紙7に貼り付き、トナー6の載っていない部分はトリミング転写シート上に残こされ、不要部分は瞬時に切り抜き取ることが出来た。 Therefore, as shown in FIG. 6, when the plain paper 7 is peeled off while it is hot, the pattern 5 of the trimming transfer sheet remains together with the resin on the trimming transfer sheet bases 1 and 2. That is, the negative-positive toner 6 portion stuck to the plain paper 7, the portion where the toner 6 was not placed was left on the trimming transfer sheet, and the unnecessary portion could be cut out instantly.
次に、図7に示すごとくトリミング転写シート上に残ったトリミングされた絵柄をリンテック社製のリタック粘着シール8でトリミング転写シートより受け取り、これを図9に示すように黒Tシャツ9に宛てがい、上部より温度130℃、15秒間、圧力250g/cm2で熱プレスを加えた。そして、少し冷めてからリタック粘着シール8を剥がしてみると、図11のように黒Tシャツ9にトリミングされた鮮明な絵柄をプリントすることが出来た。 Next, the trimmed pattern remaining on the trimming transfer sheet as shown in FIG. 7 is received from the trimming transfer sheet by the retack adhesive seal 8 manufactured by Lintec, and this is applied to the black T-shirt 9 as shown in FIG. A hot press was applied from the top at a temperature of 130 ° C. for 15 seconds at a pressure of 250 g / cm 2 . When the retuck adhesive seal 8 was peeled off after being slightly cooled, it was possible to print a clear picture trimmed on the black T-shirt 9 as shown in FIG.
ところで、トナー6で絵柄を印刷する転写シートをA転写シートではなく、B転写シートとすることも出来る。すなわち、B転写シートにリコー社製 imagio MP2500のカラーレーザープリンタのトナー6で絵柄を印刷し、図3に示すようにA転写シートにB転写シートを太陽精機社製TP600A熱プレス機で温度130℃、15秒間、圧力250g/cm2で熱プレスを加え、絵柄を間にして貼り合わせる場合もある。 By the way, the transfer sheet on which the image is printed with the toner 6 can be a B transfer sheet instead of the A transfer sheet. That is, a pattern is printed on the B transfer sheet with toner 6 of an imgio MP2500 color laser printer manufactured by Ricoh, and the B transfer sheet is applied to the A transfer sheet at a temperature of 130 ° C. using a TP600A hot press manufactured by Taiyo Seiki Co. In some cases, a heat press is applied at a pressure of 250 g / cm 2 for 15 seconds, and the images are bonded together with a pattern in between.
その後の工程は前記実施例と同じであり、図4のように、B転写シート側の基材1,2を剥がし、A転写シート上にB転写シートの樹脂層を移しトリミング転写シートを作成する。そして、図5のようにトリミング転写シートのB転写樹脂層側に、リコー社製 imagio MP2500のトナーでネガポジの絵紋様を印刷した普通紙の印刷面を、トリミング転写シートに重ね合わせ、上から熱プレス機で温度130℃、15秒間、250g/cm2の熱プレスを行い、熱いうちに普通紙7を引き剥がすと、図6のようにネガポジのトナー6部分のところが普通紙7に貼り付き、トナー6の載っていない部分はトリミング転写シート上に残こされ、不要部分は瞬時に切り抜き取ることが出来た。 The subsequent steps are the same as in the previous embodiment. As shown in FIG. 4, the base materials 1 and 2 on the B transfer sheet side are peeled off, and the resin layer of the B transfer sheet is transferred onto the A transfer sheet to create a trimming transfer sheet. . Then, as shown in FIG. 5, on the B transfer resin layer side of the trimming transfer sheet, the printing surface of plain paper on which a negative-positive pattern is printed with the toner of imgio MP2500 manufactured by Ricoh is superimposed on the trimming transfer sheet, and heat is applied from above. Performing a hot press at 250 ° C./cm 2 at a temperature of 130 ° C. for 15 seconds with a press machine, and peeling off the plain paper 7 while it is hot, the negative positive toner 6 part sticks to the plain paper 7 as shown in FIG. The portion where the toner 6 was not placed was left on the trimming transfer sheet, and the unnecessary portion could be cut out instantly.
次に、図7に示すごとくトリミング転写シート上に残ったトリミングされた絵柄をリンテック社製のリタック粘着シール8でトリミング転写シートより受け取り、これを図9に示すように黒Tシャツ9に宛てがい、上部より温度130℃、15秒間、圧力250g/cm2で熱プレスを加えた。そして、少し冷めてからリタック粘着シール8を剥がしてみると、図11のように黒Tシャツ9にトリミングされた鮮明な絵柄をプリントすることが出来た。 Next, the trimmed pattern remaining on the trimming transfer sheet as shown in FIG. 7 is received from the trimming transfer sheet by the retack adhesive seal 8 manufactured by Lintec, and this is applied to the black T-shirt 9 as shown in FIG. A hot press was applied from the top at a temperature of 130 ° C. for 15 seconds at a pressure of 250 g / cm 2 . When the retuck adhesive seal 8 was peeled off after being slightly cooled, it was possible to print a clear picture trimmed on the black T-shirt 9 as shown in FIG.
ところで、プリントして得たそれぞれのTシャツ9をTOSHIBA社製洗濯機 Ginga2.2 にて、水温50℃で15分洗い すすぎ15分 脱水5分を3回行ったが、色落ち、剥がれ、浮きが無いことを確認した。 By the way, each T-shirt 9 obtained by printing was washed with a washing machine Ginga2.2 manufactured by TOSHIBA for 15 minutes at a water temperature of 50 ° C., rinsed for 15 minutes and dehydrated for 5 minutes three times. It was confirmed that there was no.
1 目止めコートした用紙
2 剥離層
3 接着樹脂層
4 無機鉱物接着樹脂層
5 トナーインク色材で印刷された絵柄
6 トナー
7 普通紙
8 リタック粘着シール
9 Tシャツ
DESCRIPTION OF SYMBOLS 1 Paper which coat-coated 2 Release layer 3 Adhesive resin layer 4 Inorganic mineral adhesive resin layer 5 Picture printed with toner ink coloring material 6 Toner 7 Plain paper 8 Retack adhesive seal 9 T-shirt
Claims (3)
The release layer has a base material comprising a support and a paper or film, the adhesive resin layer on the base material, A transfer made of inorganic mineral adhesive resin layer obtained by mixing plastic resins in fine powder inorganic minerals thereon A B transfer sheet comprising a sheet, a base made of paper or film supporting a release layer, an inorganic mineral adhesive resin layer in which a plastic resin is mixed in an inorganic mineral fine powder, and an adhesive resin layer laminated thereon. A transfer sheet comprising a set of two sheets.
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