CN113007590B - Quick-open type copper lining high-pressure hydrogen storage container - Google Patents
Quick-open type copper lining high-pressure hydrogen storage container Download PDFInfo
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- CN113007590B CN113007590B CN202110248141.5A CN202110248141A CN113007590B CN 113007590 B CN113007590 B CN 113007590B CN 202110248141 A CN202110248141 A CN 202110248141A CN 113007590 B CN113007590 B CN 113007590B
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- hydrogen storage
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- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 80
- 239000001257 hydrogen Substances 0.000 title claims abstract description 80
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 238000003860 storage Methods 0.000 title claims abstract description 43
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 22
- 239000010949 copper Substances 0.000 title claims abstract description 22
- 238000007789 sealing Methods 0.000 claims description 12
- 150000002431 hydrogen Chemical class 0.000 claims description 6
- 230000002708 enhancing effect Effects 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 238000009987 spinning Methods 0.000 abstract description 3
- 238000013461 design Methods 0.000 abstract description 2
- 238000004146 energy storage Methods 0.000 abstract description 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 20
- 229910000831 Steel Inorganic materials 0.000 description 13
- 239000010959 steel Substances 0.000 description 13
- VNTLIPZTSJSULJ-UHFFFAOYSA-N chromium molybdenum Chemical compound [Cr].[Mo] VNTLIPZTSJSULJ-UHFFFAOYSA-N 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 210000002445 nipple Anatomy 0.000 description 1
- 238000009659 non-destructive testing Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C1/00—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
- F17C1/02—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge involving reinforcing arrangements
- F17C1/04—Protecting sheathings
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C1/00—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
- F17C1/005—Storage of gas or gaseous mixture at high pressure and at high density condition, e.g. in the single state phase
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C1/00—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
- F17C1/10—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge with provision for protection against corrosion, e.g. due to gaseous acid
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/002—Details of vessels or of the filling or discharging of vessels for vessels under pressure
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/06—Closures, e.g. cap, breakable member
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
- F17C2201/0104—Shape cylindrical
- F17C2201/0119—Shape cylindrical with flat end-piece
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/01—Reinforcing or suspension means
- F17C2203/011—Reinforcing means
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0602—Wall structures; Special features thereof
- F17C2203/0612—Wall structures
- F17C2203/0626—Multiple walls
- F17C2203/0629—Two walls
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0634—Materials for walls or layers thereof
- F17C2203/0636—Metals
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0634—Materials for walls or layers thereof
- F17C2203/0636—Metals
- F17C2203/0648—Alloys or compositions of metals
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/01—Mounting arrangements
- F17C2205/0123—Mounting arrangements characterised by number of vessels
- F17C2205/0126—One vessel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2209/00—Vessel construction, in particular methods of manufacturing
- F17C2209/22—Assembling processes
- F17C2209/221—Welding
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2209/00—Vessel construction, in particular methods of manufacturing
- F17C2209/22—Assembling processes
- F17C2209/228—Assembling processes by screws, bolts or rivets
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/012—Hydrogen
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
- Y02P90/45—Hydrogen technologies in production processes
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
The invention relates to hydrogen energy storage equipment, and aims to provide a quick-opening copper lining high-pressure hydrogen storage container. Comprises a copper lining arranged in a hollow tubular outer cylinder, and the copper lining and the hollow tubular outer cylinder are in clearance fit; at least one end part of the outer cylinder is provided with a quick-opening end enclosure which is cylindrical and is sleeved in the outer cylinder in a threaded connection mode; a through hole is formed in the axial center of the quick-opening end enclosure, and the end part of the lining is sleeved in the through hole; the flange-bolt assembly is used for fixing the end joint of the connecting pipe on the quick-opening head, the end joint of the connecting pipe is tubular, the middle part of the end joint of the connecting pipe is provided with a radial boss for positioning and transferring load, and one side of the end joint of the connecting pipe extends into the end part of the lining, and the other side of the end joint of the connecting pipe is connected with an external hydrogen conveying pipe. The copper lining can effectively prevent high-pressure hydrogen from contacting with the outer cylinder, and performance degradation of the outer cylinder due to high-pressure hydrogen embrittlement is avoided. The strength of the outer barrel is not limited, and the light-weight design of the container is facilitated. Because the quick-opening end enclosure is adopted, the outer cylinder does not need to be formed by spinning, and the heat treatment is easy, so that the hydrogen storage pressure of the container is high, and the volume is large.
Description
Technical Field
The invention belongs to the field of hydrogen energy storage equipment development, and particularly relates to a quick-open type copper lining high-pressure hydrogen storage container.
Background
The storage of hydrogen is one of the core links of the hydrogen energy industry chain. High-pressure hydrogen storage is a mainstream hydrogen storage mode of hydrogen fuel cell automobiles, tube trailers, hydrogen filling stations and the like at present, and a high-pressure hydrogen storage container is a carrier for high-pressure hydrogen storage. Different from the conventional pressure vessel, the hydrogen storage vessel may face the material performance deterioration phenomenon caused by high-pressure hydrogen embrittlement in a high-pressure hydrogen environment, and great threat is caused to the safe operation of the vessel. Currently, the types of high pressure hydrogen storage vessels mainly include large volume seamless hydrogen storage vessels, austenitic stainless steel lined hydrogen storage vessels, and fiber wound composite bottle type hydrogen storage vessels.
The large-volume seamless hydrogen storage container is formed by spinning a seamless steel tube, has simple structure and low cost, can be produced in batches, but the hydrogen-contacting material is low alloy steel such as chromium-molybdenum steel and the like, and the material shows hydrogen embrittlement phenomena such as obvious ductility reduction, accelerated fatigue crack propagation rate, reduced fracture toughness and the like in a high-pressure hydrogen environment, thereby threatening the operation safety of the container. Meanwhile, as the strength of the material is higher and the hydrogen embrittlement is more serious, the upper limit of the tensile strength of the chromium-molybdenum steel material for the hydrogen storage container is regulated by the relevant standards at home and abroad (880 MPa at home and 950MPa at abroad generally), which causes that the potential of the mechanical properties of the material can not be fully exerted. Furthermore, when the hydrogen storage pressure is increased, the wall thickness of such a vessel increases, which makes spinning difficult and easily causes a phenomenon of quenching during heat treatment, which has an extremely adverse effect on the uniformity of the vessel along the wall thickness. At present, the container is often used in the situation that the pressure is less than 50 MPa.
The hydro-material of the austenitic stainless steel lining hydrogen storage container is austenitic stainless steel with good hydrogen embrittlement resistance such as 316L, and the like, and the container has high hydrogen storage pressure and large volume, but has complex structure (common steel belt winding type, laminate binding type and the like), long manufacturing period and high cost, and usually needs welding forming, and has very high requirement on welding process. In addition, the nondestructive testing of such containers is difficult due to the structural influence.
The bottle-type hydrogen storage container made of the fiber winding composite material is formed by winding a seamless steel pipe, an aluminum liner or a plastic liner and the like by carbon fibers and the like, has high hydrogen storage pressure, small hydrogen storage volume and higher cost of the materials such as the carbon fibers and the like, so the container is mainly used for hydrogen storage of hydrogen fuel cell automobiles at present and is not used for occasions of large-scale hydrogen storage such as a hydrogen refueling station and the like.
In view of the above, the present invention is proposed based on the current situation that the hydrogen embrittlement resistance, the use performance (storage pressure, storage volume, etc.), the manufacturing cost, etc. of the conventional high-pressure hydrogen storage container often cannot satisfy the requirements at the same time.
Disclosure of Invention
The invention aims to solve the technical problem of overcoming the defects in the prior art and provides a quick-opening copper lining high-pressure hydrogen storage container which has the advantages of good hydrogen brittleness resistance, high hydrogen storage pressure, large volume, relatively simple structure, convenience in manufacturing and low cost.
In order to solve the technical problem, the solution of the invention is as follows:
the quick-opening copper lining high-pressure hydrogen storage container comprises a hollow tubular copper lining for storing hydrogen, wherein the lining is sleeved in an outer cylinder of a hollow tubular structure and is in clearance fit with the outer cylinder; at least one end part of the outer cylinder is provided with a quick-opening end enclosure which is cylindrical and is sleeved in the outer cylinder in a threaded connection mode; a through hole is formed in the axial center of the quick-opening end socket, and the end part of the lining is sleeved in the through hole; on the outer end face of the quick-opening end socket, a joint at the end part of the connecting pipe is fixed on the quick-opening end socket through a component consisting of a flange and a bolt; the adapter end joint is tubular, the middle part of the adapter end joint is provided with a radial boss for positioning and transferring load, one side of the adapter end joint extends into the end part of the lining and is tightly matched with the end part of the lining, and the other side of the adapter end joint penetrates through an axial central through hole of the flange and is used for connecting an external hydrogen conveying pipe.
In the invention, two end parts of the outer cylinder are respectively provided with a quick-opening end socket, a connecting pipe end joint and a flange-bolt assembly, and have the same structure; or only one end part of the outer cylinder is provided with the quick-opening end socket, and the other end part is provided with a blind flange for plugging.
In the invention, the radial size of the end part of the lining sleeved on the central through hole of the quick-opening end socket is smaller than that of the main structure of the lining, namely, the reduced end part of the lining extends into the central through hole of the quick-opening end socket.
In the invention, the end surface of the inner side of the quick-opening end socket is in a shape matched with the end part of the lining, and the quick-opening end socket and the lining are in clearance fit.
In the invention, the outer part of the quick-opening end enclosure is provided with external threads, and the inner side of the outer cylinder is provided with internal threads; the tail end of the thread of the outer cylinder is provided with a step structure for positioning when the quick-opening end enclosure is installed.
In the invention, O-shaped sealing rings are respectively arranged between the quick-opening end socket and the outer cylinder and between the joint at the end part of the connecting pipe and the lining for strengthening sealing.
In the invention, one side of the adapter at the end part of the adapter extending into the end part of the lining has larger radial dimension, and the side surface is provided with a circumferential groove for installing an O-shaped sealing ring.
In the invention, a plurality of threaded holes are uniformly arranged on the end surface of the outer side of the quick-opening end socket along the circumferential direction, and the end joint of the connecting pipe is fixed on the quick-opening end socket by using a stud, a bolt and a flange.
Compared with the prior art, the invention has the beneficial effects that:
1. the lining of the high-pressure hydrogen storage container adopts oxygen-free copper and other materials with good ductility and hydrogen embrittlement resistance, and when the container is filled with high-pressure hydrogen, the copper lining can effectively prevent the high-pressure hydrogen from contacting the outer cylinder, so that the material performance deterioration of the outer cylinder caused by high-pressure hydrogen embrittlement is avoided. Meanwhile, the lining material has good ductility, so that the lining can be tightly attached to the inner wall of the outer barrel when being pressed, and the stress can be fully transferred to the outer barrel, so that the outer barrel mainly bears the pressure of hydrogen.
2. Because of the obstruction of the copper lining, the outer cylinder of the container can be made of the prior chromium-molybdenum steel material. As the chromium-molybdenum steel material belongs to a non-hydrogen material, the strength of the chromium-molybdenum steel material is not limited any more, the regulation of the existing standard on the strength of the chromium-molybdenum steel material for the hydrogen storage container can be broken through, the potential of the mechanical property of the chromium-molybdenum steel material is fully exerted, and the lightweight design of the container is facilitated.
3. Because the quick-opening end enclosure is adopted, the outer cylinder of the container does not need spin forming and is easy to carry out heat treatment in a double-sided quenching mode, so that the thickness of the outer cylinder is mainly calculated and determined by hydrogen storage pressure and is not limited by manufacturing processes such as spin forming, heat treatment and the like, and the container is high in hydrogen storage pressure and large in volume.
4. The quick-opening end enclosure is adopted, so that the inner cylinder and the outer cylinder can be conveniently installed, the container is simple to manufacture, batch production can be realized, and the container is low in cost because the adopted materials such as oxygen-free copper, chromium-molybdenum steel and the like are common metal materials. The vessel is therefore able to meet the requirements for large-scale hydrogen storage.
Drawings
FIG. 1 is a schematic diagram of the general structure of the present invention;
FIG. 2 is a schematic view of the outer barrel;
FIG. 3 is a schematic view of a liner;
FIG. 4 is a schematic view of a quick-opening closure;
FIG. 5 is a schematic view of a flange assembly;
figure 6 is a schematic view of a nipple end fitting.
The reference numbers in the figures are: the quick-opening sealing head comprises a quick-opening sealing head 1, a stud 2, a flange 3, a connecting pipe end joint 4, an O-shaped sealing ring 5, an outer cylinder 6 and an inner lining 7.
Detailed Description
The following describes embodiments of the present invention in detail by way of specific embodiments.
The quick-open copper lining high-pressure hydrogen storage container comprises a hollow tubular copper lining 7 for storing hydrogen, wherein the lining 7 is sleeved in an outer cylinder 6 with a hollow tubular structure, and the lining and the outer cylinder are in clearance fit; two ends of the outer cylinder 6 are respectively provided with a quick-opening end socket 1 which is cylindrical and is sleeved in the outer cylinder 6 in a threaded connection mode; the outer part of the quick-opening end enclosure 1 is provided with an external thread, and the inner side of the outer cylinder 6 is provided with an internal thread; the tail end of the thread of the outer cylinder 6 is provided with a step structure for positioning when the quick-opening end enclosure 1 is installed. A through hole is formed in the axial center of the quick-opening end socket 1, and the end part of the lining 7 is sleeved in the through hole; the end part of the lining 7 sleeved in the central through hole of the quick-opening end socket 1 has a radial size smaller than that of the main body structure of the lining 7, namely, the diameter-reduced end part of the lining 7 extends into the central through hole of the quick-opening end socket 1. The end surface of the inner side of the quick-opening end socket 1 is in a shape matched with the end part of the lining 7, and the quick-opening end socket and the lining are in clearance fit. On the outer end face of the quick-opening end socket 1, a connecting pipe end joint 4 is fixed on the quick-opening end socket 1 through an assembly consisting of a flange 3 and a bolt; the adapter end joint 4 is tubular, the middle part of the adapter end joint is provided with a radial boss for positioning and load transfer, one side of the adapter end joint extends into the end part of the lining and is tightly matched, the other side of the adapter end joint passes through an axial central through hole of the flange 3 and is used for connecting one side of the adapter end joint 4 of the external hydrogen conveying pipe, which extends into the end part of the lining 7, and the other side of the adapter end joint has larger radial size, and the side surface is provided with a circumferential groove for installing an O-shaped sealing ring 5. And O-shaped sealing rings 5 are respectively arranged between the quick-opening end socket 1 and the outer cylinder 6 and between the joint 4 at the end part of the connecting pipe and the lining 7 for enhancing sealing. A plurality of threaded holes are uniformly arranged on the end face of the outer side of the quick-opening end socket 1 along the circumferential direction, and a joint 4 at the end part of the connecting pipe is fixed on the quick-opening end socket 1 through a stud 2, a bolt and a flange 3.
As another embodiment, the quick-opening end enclosure 1 may be provided only at one end of the outer cylinder 6, and a blind flange for plugging may be provided at the other end.
Installation and use instructions of the invention:
during installation, the quick-opening end socket 1 is opened firstly, the lining 7 is placed in the outer cylinder 6, the lining and the outer cylinder are in clearance fit, and then the quick-opening end socket 1 is connected with the outer cylinder 6 through a thread structure. The outer cylinder 6 is used for bearing the pressure of compressed hydrogen, the material of the outer cylinder is high-strength steel such as chromium molybdenum steel, and the thickness of the outer cylinder is determined according to the calculation of hydrogen pressure. The cavity of the liner 7 is used as a container for containing high-pressure hydrogen, and the end part of the liner passes through the opening in the middle of the quick-opening end socket 1 to be connected with the joint 4 at the end part of the connecting pipe. The liner 7 is made of oxygen-free copper with good ductility and good hydrogen embrittlement resistance, and the shape of the liner is consistent with that of the inner cavity of the outer cylinder 6. The end part of the inner cavity of the outer cylinder 6 is provided with a thread structure and is matched with the external thread of the quick-opening end socket 1. A step structure is arranged behind the thread and used for positioning the quick-opening end socket 1 during installation. The quick-opening end socket 1 realizes quick disassembly by utilizing a thread structure and provides a load for balancing the internal pressure of hydrogen. The middle of the quick-opening end socket 1 is provided with a hole for penetrating the reducing end part of the lining 6. The adapter end joint 4 is used for connecting the hydrogen conveying pipe outside the container and the lining cavity, and the outer surface of the adapter end joint extending into the diameter-reducing end part of the lining is provided with a groove, so that the thickness of the adapter end joint is greater than that of the inner wall of the lining cavity. An O-shaped sealing ring 5 is arranged in the groove and is used for forming sealing with the reducing end part of the lining 6 and preventing hydrogen from leaking. The middle of the adapter end fitting 4 is provided with a boss by welding or other means for limiting the length of the reduced diameter end portion extending into the liner 7 and for transmitting the axial force of the hydrogen internal pressure acting on the adapter end fitting 4 to the bolt-flange assembly. The material of the joint 4 is S31603 with good hydrogen embrittlement resistance. The flange 3, the stud 2 and the nut form a flange assembly for providing pressure for balancing internal pressure acting on the connecting pipe end joint 4 and limiting the position of the connecting pipe end joint 4.
Claims (6)
1. A quick-open type copper lining high-pressure hydrogen storage container is characterized by comprising a hollow tubular copper lining for storing hydrogen, wherein the lining is sleeved in an outer barrel of a hollow tubular structure, the shape of the lining is consistent with that of an inner cavity of the outer barrel, and the lining and the outer barrel are in clearance fit; at least one end part of the outer cylinder is provided with a quick-opening end enclosure which is cylindrical and is sleeved in the outer cylinder in a threaded connection mode;
a through hole is formed in the axial center of the quick-opening end socket, and the end part of the lining is sleeved in the through hole; the radial dimension of the end part of the lining is smaller than that of the main structure of the lining, namely the diameter-reduced end part of the lining extends into the through hole at the center of the quick-opening end socket; the end surface of the inner side of the quick-opening end socket is in a shape matched with the end part of the lining, and the quick-opening end socket and the lining are in clearance fit;
on the outer end face of the quick-opening end socket, a joint at the end part of the connecting pipe is fixed on the quick-opening end socket through a component consisting of a flange and a bolt; the adapter end joint is tubular, the middle part of the adapter end joint is provided with a radial boss for positioning and transferring axial load, one side of the adapter end joint extends into the end part of the lining and is tightly matched with the end part of the lining, and the other side of the adapter end joint penetrates through an axial central through hole of the flange and is used for connecting an external hydrogen conveying pipe.
2. The quick-open copper-lined high-pressure hydrogen storage container according to claim 1, wherein the two ends of the outer cylinder are respectively provided with a quick-open end socket, a connecting pipe end joint and a flange-bolt assembly, and have the same structure; or only one end part of the outer cylinder is provided with the quick-opening end socket, and the other end part is provided with a blind flange for plugging.
3. The quick-open copper lining high-pressure hydrogen storage container according to claim 1, wherein the quick-open end enclosure is externally provided with external threads, and the inner side of the outer cylinder is provided with internal threads; the tail end of the thread of the outer cylinder is provided with a step structure for positioning when the quick-opening end enclosure is installed.
4. The quick-opening copper lining high-pressure hydrogen storage container as claimed in claim 1, wherein O-ring seals are respectively disposed between the quick-opening end closure and the outer cylinder and between the joint at the end of the connecting pipe and the lining for enhancing sealing.
5. The quick open copper lined high pressure hydrogen storage vessel of claim 1 wherein the adapter end fitting has a greater radial dimension on the side extending into the liner end, and a circumferential groove is provided in the side surface for receiving an O-ring seal.
6. The quick-opening copper-lined high-pressure hydrogen storage container as claimed in claim 1, wherein a plurality of threaded holes are uniformly formed in the circumferential direction on the outer end surface of the quick-opening closure, and the end fitting of the adapter is fixed to the quick-opening closure by means of a stud, a bolt and a flange.
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US20100059528A1 (en) * | 2008-09-11 | 2010-03-11 | C. En. Limited | Apparatus for gas storage |
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CN111022912A (en) * | 2020-02-18 | 2020-04-17 | 扬州大学 | Metal hydride hydrogen storage tank with low cost, high hydrogen absorption and desorption speed and high safety |
CN112178446B (en) * | 2020-09-14 | 2022-02-18 | 华东理工大学 | Jacket type high-pressure hydrogen storage device for hydrogenation station |
CN112212205B (en) * | 2020-10-19 | 2022-03-11 | 华东理工大学 | Anti-fatigue high-pressure hydrogen storage container for hydrogenation station |
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