CN113004952A - M100 methanol fuel for vehicles and preparation method thereof - Google Patents
M100 methanol fuel for vehicles and preparation method thereof Download PDFInfo
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- CN113004952A CN113004952A CN202110244726.XA CN202110244726A CN113004952A CN 113004952 A CN113004952 A CN 113004952A CN 202110244726 A CN202110244726 A CN 202110244726A CN 113004952 A CN113004952 A CN 113004952A
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- preparation
- vehicles
- parts
- methanol
- methanol fuel
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 162
- 239000000446 fuel Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 239000000654 additive Substances 0.000 claims description 27
- 230000000996 additive effect Effects 0.000 claims description 27
- 239000002131 composite material Substances 0.000 claims description 23
- 238000002156 mixing Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 230000007797 corrosion Effects 0.000 claims description 20
- 238000005260 corrosion Methods 0.000 claims description 20
- 239000003963 antioxidant agent Substances 0.000 claims description 19
- 230000003078 antioxidant effect Effects 0.000 claims description 19
- 239000003112 inhibitor Substances 0.000 claims description 19
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 18
- 239000006079 antiknock agent Substances 0.000 claims description 18
- 239000006184 cosolvent Substances 0.000 claims description 18
- 239000002455 scale inhibitor Substances 0.000 claims description 15
- 239000012459 cleaning agent Substances 0.000 claims description 14
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 10
- NUMQCACRALPSHD-UHFFFAOYSA-N tert-butyl ethyl ether Chemical compound CCOC(C)(C)C NUMQCACRALPSHD-UHFFFAOYSA-N 0.000 claims description 10
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 8
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims description 8
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 claims description 8
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 8
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 8
- -1 alkenyl succinate Chemical compound 0.000 claims description 7
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 7
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 6
- 230000000087 stabilizing effect Effects 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 5
- XTUVJUMINZSXGF-UHFFFAOYSA-N N-methylcyclohexylamine Chemical compound CNC1CCCCC1 XTUVJUMINZSXGF-UHFFFAOYSA-N 0.000 claims description 5
- PAMIQIKDUOTOBW-UHFFFAOYSA-N N-methylcyclohexylamine Natural products CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 claims description 5
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 5
- HVZJRWJGKQPSFL-UHFFFAOYSA-N tert-Amyl methyl ether Chemical compound CCC(C)(C)OC HVZJRWJGKQPSFL-UHFFFAOYSA-N 0.000 claims description 5
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 claims description 4
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 4
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 4
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 4
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 4
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 4
- PCSMJKASWLYICJ-UHFFFAOYSA-N Succinic aldehyde Chemical compound O=CCCC=O PCSMJKASWLYICJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 4
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 claims description 4
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims description 4
- PFEFOYRSMXVNEL-UHFFFAOYSA-N 2,4,6-tritert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 PFEFOYRSMXVNEL-UHFFFAOYSA-N 0.000 claims description 3
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 claims description 3
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 229940035429 isobutyl alcohol Drugs 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000003502 gasoline Substances 0.000 description 9
- 239000003245 coal Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 6
- 238000011161 development Methods 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 150000008054 sulfonate salts Chemical class 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- HUMNYLRZRPPJDN-KWCOIAHCSA-N benzaldehyde Chemical group O=[11CH]C1=CC=CC=C1 HUMNYLRZRPPJDN-KWCOIAHCSA-N 0.000 description 1
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000002816 fuel additive Substances 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
- C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1857—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
- C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
- C10L1/233—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/08—Inhibitors
- C10L2230/081—Anti-oxidants
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses an M100 methanol fuel for a vehicle and a preparation method thereof, wherein the M100 methanol fuel comprises a body, a plurality of box bodies are arranged in the body, the box bodies are movably matched and connected with the body, a plurality of trapezoidal bosses are arranged on the side wall of each box body and arranged at two sides of each box body; the lower end of the body is provided with a heating device which is fixedly connected with the body and fixedly connected with the box body; a driving device is arranged on one side of the heating device, the driving device is fixedly connected with the heating device, an ejection mechanism is arranged at the upper end of the driving device, the ejection mechanism is movably matched and connected with the driving device, and the ejection mechanism penetrates through the box body and extends to the bottom end of the box body; the invention has the advantages of simple structure, convenient use, higher working efficiency, more accurate positioning and higher manufacturing efficiency.
Description
Technical Field
The invention relates to the technical field of preparation of vehicle methanol fuel, in particular to vehicle M100 methanol fuel and a preparation method thereof.
Background
With the improvement of the living standard of people, all countries in the world pay more and more attention to the environmental problem, maintain the ecological environment, prevent and control pollution, and research on alternative fuels, particularly development and utilization of renewable resources to produce clean fuels, has become a major topic of all industrial countries in the world. The domestic development of methanol fuel and methanol fuel automobiles has various advantages and better development prospect. The developed fuel methanol meets the resource characteristics and environmental protection requirements of China. Most raw materials for producing methanol in China are high-sulfur high-ash low-grade coal, and the low-grade coal accounts for 40-50% of the national coal reserves and cannot be directly combusted. The coal-based fuel methanol is clean and reasonable utilization of inferior coal resources and conforms to the national conditions of 'rich coal and lean oil' in China.
Compared with gasoline vehicles, the methanol vehicle has the advantages of enhanced dynamic property, good acceleration performance, cleanness and environmental protection. The emission of carbon monoxide, hydrocarbon and nitrogen oxide of the methanol automobile can be reduced by 30-45%, and the emission of PM2.5 is reduced by times. The development of the methanol vehicle fuel has multiple advantages, the product has national recommendation standard, and the popularization is brought into the national strategy.
The methanol is used as a high-octane component, and after being mixed with the gasoline, the octane value of the methanol gasoline is improved by 3-5 units compared with that of national standard gasoline with the same grade, the octane value meets the regulation, the normal operation of an engine is ensured, no knocking occurs, and the power is fully exerted. However, since methanol and ethanol have great differences from the existing gasoline in the aspects of polarity, combustibility and the like, there are many problems in directly applying low-carbon alcohol to gasoline. Firstly, the heat value of low-carbon alcohol is low, the combustion speed is slow, and compared with the common gasoline, the theoretical air-fuel ratio of the alcohol-based gasoline for the automobile is low, so that the dynamic property of the automobile is reduced, the acceleration is poor, and the oil consumption of the automobile is increased; secondly, alcohols are easy to absorb water and generate liquid phase separation, and fuel oil stratification can occur when a vehicle is parked for a long time, so that the vehicle is not easy to start and has poor stability; thirdly, free water in the alcohol-based fuel has great harm to metal and can corrode various steel parts, such as steel oil tanks, oil drums, pipelines, valves and other parts. And fourthly, automobile parts such as internal combustion engines, spark plugs, oil nozzles and the like developed aiming at the hydrocarbon gasoline have obviously shortened service life when the alcohol-based fuel is used. Therefore, alcohol-based fuel suitable for vehicles needs to be developed, and for the problems, the problems of corrosivity, swelling property, stability and the like of the alcohol-based fuel are solved by adding a proper additive, however, at present, no additive capable of effectively solving all the problems of the alcohol-based fuel exists, so that an alcohol-based fuel additive with good stability, good intersolubility and strong universality needs to be urgently explored, and the alcohol-based fuel meeting different market requirements of vehicles, industries, even civil use and the like is prepared.
Disclosure of Invention
Aiming at the problems, the technical problem to be solved by the invention is to provide a preparation method of vehicle methanol with stable properties, and to explore a vehicle M100 methanol fuel with good stability, good intersolubility and wide application range and a preparation method thereof.
In order to solve the technical problem, the scheme of the invention is as follows:
an M100 methanol fuel for vehicles and a preparation method thereof are characterized in that methanol is mixed with a methanol mixture of 1: 0.03-0.09 part of composite additive is evenly mixed at normal temperature to obtain the product.
The purity of the methanol is more than 99.5%;
the composite additive comprises 6-8 parts of cosolvent, 20-50 parts of antiknock agent, 4-6 parts of corrosion inhibitor, 0.5-3 parts of antioxidant, 20-50 parts of scale inhibitor, 0-6 parts of pH regulator and 0.05-0.1 part of dispersed cleaning agent.
The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the cosolvent is one or more of ketones (cyclohexanone, cyclopentanone, methyl isobutyl ketone and methyl ethyl ketone), aldehydes (benzaldehyde, glutaraldehyde and succinaldehyde) and alcohols (n-butyl alcohol, isobutyl alcohol, n-propyl alcohol and isopropyl alcohol) mixed at any proportion.
The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the antiknock agent is one or a mixture of more of methyl tert-butyl ether, ethyl tert-butyl ether, methyl tert-amyl ether, diisopropyl ether, dimethyl carbonate, polyoxyethylene ether dicarboxylate, dimethyl malonate and butanol.
The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the corrosion inhibitor is one or a mixture of benzotriazole, mercapto benzothiazole, methyl benzotriazole, fatty alcohol-polyoxyethylene ether, N-disalicylidene-1, 3-diaminopropane and alkenyl succinate.
The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the antioxidant is one or a mixture of 2, 6-di-tert-butyl-4-methylphenol, 2, 4-dimethyl-6-tert-butylphenol and 2,4, 6-tri-tert-butylphenol.
The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the scale inhibitor is a polyetheramine compound with the molecular weight of 1000-2000.
The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the pH regulator is one or a mixture of more of cyclohexylamine, N-methylcyclohexylamine and N, N-dimethylcyclohexylamine.
The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the dispersed cleaning agent is petroleum sulfonate.
The preparation method of the alcohol-based fuel composite additive according to claim 1, characterized by comprising the steps of (1) mixing a cosolvent, a corrosion inhibitor and an antioxidant under normal temperature and pressure, and stirring and mixing for 10-20 min;
(2) then adding an antiknock agent, and uniformly mixing to obtain a uniform solution;
(3) stabilizing the mixed reagent at 25 ℃, and adding a scale inhibitor, a pH regulator and a dispersing cleaning agent to obtain the alcohol-based fuel composite additive.
Compared with the prior art, the invention has the beneficial effects that:
according to the M100 methanol fuel for the vehicle and the preparation method thereof, corrosion of polar dissolution on a fuel tank body is reduced by adding the corrosion inhibitor, and stability of fuel oil is improved by using the antioxidant. Because various inorganic or organic impurities are easily generated in the coal-based methanol, particularly various inorganic impurities are easy to scale in the automobile, the organic scale inhibitor is added in the additive to prevent scaling. Aiming at the problem that the methanol sources are different and the acidity of the methanol is greatly different, the pH regulator is added in the invention, so that the pH regulator not only can regulate the base number of a methanol product, but also can be used as a fuel oil stabilizer to improve the quality of an oil product.
Detailed Description
The following further describes the embodiments of the present invention.
It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
Example one
A vehicle M100 methanol fuel and a preparation method thereof are characterized by comprising the following steps,
(1) under the conditions of normal temperature and normal pressure, firstly mixing the cosolvent, the corrosion inhibitor and the antioxidant, and stirring and mixing for 10 min;
(2) then adding an antiknock agent, and uniformly mixing to obtain a uniform solution;
(3) stabilizing the mixed reagent at 25 ℃, and adding a compound of ether amine and molecular weight of 1000, a pH regulator and petroleum sulfonate to obtain the alcohol-based fuel composite additive.
(4) And mixing methanol with the concentration of more than 99.5 percent with the mixture of 1: 0.03 part of the composite additive is evenly mixed at normal temperature to obtain the composite additive.
The composite additive comprises 6 parts of cosolvent, 20 parts of antiknock agent, 4 parts of corrosion inhibitor, 0.5 part of antioxidant, 20 parts of scale inhibitor, 0 part of pH regulator and 0.05 part of dispersing cleaning agent.
The cosolvent is cyclohexanone, and can be one or a mixture of cyclopentanone, methyl isobutyl ketone and methyl ethyl ketone in any proportion or substituted.
Preferably, the antiknock agent is one or a mixture of several of methyl tert-butyl ether, ethyl tert-butyl ether, methyl tert-amyl ether, diisopropyl ether, dimethyl carbonate, polyoxyethylene ether dicarboxylate, dimethyl malonate and butanol. .
Preferably, the corrosion inhibitor is one or a mixture of benzotriazole, mercapto benzothiazole, methyl benzotriazole, fatty alcohol-polyoxyethylene ether, N-disalicylidene-1, 3-diaminopropane and alkenyl succinate. .
Preferably, the antioxidant is one or a mixture of 2, 6-di-tert-butyl-4-methylphenol, 2, 4-dimethyl-6-tert-butylphenol and 2,4, 6-tri-tert-butylphenol.
Preferably, the scale inhibitor is a polyetheramine compound with a molecular weight of 2000.
Preferably, the dispersed cleaning agent is a petroleum sulfonate salt.
Example two
A vehicle M100 methanol fuel and a preparation method thereof are characterized by comprising the following steps,
(1) under the conditions of normal temperature and normal pressure, firstly mixing the cosolvent, the corrosion inhibitor and the antioxidant, and stirring and mixing for 15 min;
(2) then adding an antiknock agent, and uniformly mixing to obtain a uniform solution;
(3) stabilizing the mixed reagent at 25 ℃, and adding a compound of ether amine and molecular weight of 1500, a pH regulator and petroleum sulfonate to obtain the alcohol-based fuel composite additive.
(4) And mixing methanol with the concentration of more than 99.5 percent with the mixture of 1: 0.06 part of the composite additive is uniformly mixed at normal temperature to obtain the composite additive.
The composite additive comprises 7 parts of cosolvent, 25 parts of antiknock agent, 5 parts of corrosion inhibitor, 1.5 parts of antioxidant, 35 parts of scale inhibitor, 3 parts of pH regulator and 0.08 part of dispersing cleaning agent.
The cosolvent is benzaldehyde, and one or more of glutaraldehyde and butanedialdehyde can be mixed or replaced at any proportion.
Preferably, the antiknock agent is ethyl tert-butyl ether.
Preferably, the corrosion inhibitor is mercaptobenzothiazole.
Preferably, the antioxidant is 2, 4-dimethyl-6-tert-butylphenol.
Preferably, the scale inhibitor is a polyetheramine, a compound with a molecular weight of 1500.
Preferably, the pH adjusting agent is N-methylcyclohexylamine.
Preferably, the dispersed cleaning agent is a petroleum sulfonate salt.
EXAMPLE III
A vehicle M100 methanol fuel and a preparation method thereof are characterized by comprising the following steps,
(1) under the conditions of normal temperature and normal pressure, firstly mixing the cosolvent, the corrosion inhibitor and the antioxidant, and stirring and mixing for 18 min;
(2) then adding an antiknock agent, and uniformly mixing to obtain a uniform solution;
(3) stabilizing the mixed reagent at 25 ℃, and adding a compound of ether amine and molecular weight of 1800, a pH regulator and petroleum sulfonate to obtain the alcohol-based fuel composite additive.
(4) And mixing methanol with the concentration of more than 99.5 percent with the mixture of 1: and 0.09 part of the composite additive is uniformly mixed at normal temperature to obtain the composite additive.
The composite additive comprises 8 parts of cosolvent, 40 parts of antiknock agent, 5 parts of corrosion inhibitor, 2 parts of antioxidant, 40 parts of scale inhibitor, 4 parts of pH regulator and 0.1 part of dispersing cleaning agent.
The cosolvent is n-butanol, and can be one or a mixture of isobutanol, n-propanol and isopropanol at any proportion or substituted.
Preferably, the antiknock agent is t-amyl methyl ether.
Preferably, the corrosion inhibitor is methyl benzotriazole.
Preferably, the antioxidant is 2, 6-di-tert-butyl-4-methylphenol.
Preferably, the scale inhibitor is a polyetheramine, a compound with a molecular weight of 2000.
Preferably, the pH adjusting agent is N-methylcyclohexylamine.
Preferably, the dispersed cleaning agent is a petroleum sulfonate salt.
Example four
A vehicle M100 methanol fuel and a preparation method thereof are characterized by comprising the following steps,
(1) under the conditions of normal temperature and normal pressure, firstly mixing the cosolvent, the corrosion inhibitor and the antioxidant, and stirring and mixing for 20 min;
(2) then adding an antiknock agent, and uniformly mixing to obtain a uniform solution;
(3) stabilizing the mixed reagent at 25 ℃, and adding a compound of ether amine and molecular weight of 2000, a pH regulator and petroleum sulfonate to obtain the alcohol-based fuel composite additive.
(4) And mixing methanol with the concentration of more than 99.5 percent with the mixture of 1: and 0.09 part of the composite additive is uniformly mixed at normal temperature to obtain the composite additive.
The composite additive comprises 8 parts of cosolvent, 50 parts of antiknock agent, 6 parts of corrosion inhibitor, 3 parts of antioxidant, 50 parts of scale inhibitor, 6 parts of pH regulator and 0.1 part of dispersing cleaning agent.
The cosolvent is one or more of methyl isobutyl ketone, glutaraldehyde and n-propanol, and can be one or more of ketones (cyclohexanone, cyclopentanone and methyl ethyl ketone), aldehydes (benzaldehyde and succinaldehyde) and alcohols (n-butanol, isobutanol and isopropanol) at any ratio or substituted.
Preferably, the antiknock agent is one or a mixture of methyl tert-butyl ether, ethyl tert-butyl ether, methyl tert-amyl ether, diisopropyl ether, dimethyl carbonate, polyoxyethylene ether dicarboxylate, dimethyl malonate and butanol or a substitute thereof.
Preferably, the corrosion inhibitor is benzotriazole.
Preferably, the antioxidant is 2, 6-di-tert-butyl-4-methylphenol.
Preferably, the scale inhibitor is a polyetheramine, a compound with a molecular weight of 1000.
Preferably, the pH regulator is one or a mixture of more of cyclohexylamine, N-methylcyclohexylamine and N, N-dimethylcyclohexylamine.
Preferably, the dispersed cleaning agent is a petroleum sulfonate salt.
The embodiments of the present invention have been described in detail above, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, and the scope of protection is still within the scope of the invention.
Claims (9)
1. An M100 methanol fuel for vehicles and a preparation method thereof are characterized in that methanol is mixed with a methanol mixture of 1: 0.03-0.09 part of composite additive is evenly mixed at normal temperature to obtain the product.
The purity of the methanol is more than 99.5%;
the composite additive comprises 6-10 parts of cosolvent, 20-40 parts of antiknock agent, 3-8 parts of corrosion inhibitor, 0.5-2 parts of antioxidant, 20-50 parts of scale inhibitor, 0-6 parts of pH regulator and 3-8 parts of dispersed cleaning agent.
2. The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the cosolvent is one or more of ketones (cyclohexanone, cyclopentanone, methyl isobutyl ketone and methyl ethyl ketone), aldehydes (benzaldehyde, glutaraldehyde and succinaldehyde) and alcohols (n-butyl alcohol, isobutyl alcohol, n-propyl alcohol and isopropyl alcohol) mixed at any proportion.
3. The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the antiknock agent is one or a mixture of more of methyl tert-butyl ether, ethyl tert-butyl ether, methyl tert-amyl ether, diisopropyl ether, dimethyl carbonate, polyoxyethylene ether dicarboxylate, dimethyl malonate and butanol.
4. The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the corrosion inhibitor is one or a mixture of benzotriazole, mercapto benzothiazole, methyl benzotriazole, fatty alcohol-polyoxyethylene ether, N-disalicylidene-1, 3-diaminopropane and alkenyl succinate.
5. The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the antioxidant is one or a mixture of 2, 6-di-tert-butyl-4-methylphenol, 2, 4-dimethyl-6-tert-butylphenol and 2,4, 6-tri-tert-butylphenol.
6. The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the scale inhibitor is a polyetheramine compound with the molecular weight of 1000-2000.
7. The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the pH regulator is one or a mixture of more of cyclohexylamine, N-methylcyclohexylamine and N, N-dimethylcyclohexylamine.
8. The M100 methanol fuel for vehicles and the preparation method thereof according to claim 1, wherein: the dispersed cleaning agent is petroleum sulfonate.
9. The method for preparing the alcohol-based fuel complex additive according to claim 1, comprising the steps of,
(1) under the conditions of normal temperature and normal pressure, firstly mixing the cosolvent, the corrosion inhibitor and the antioxidant, and stirring and mixing for 10-20 min;
(2) then adding an antiknock agent, and uniformly mixing to obtain a uniform solution;
(3) stabilizing the mixed reagent at 25 ℃, and adding a scale inhibitor, a pH regulator and a dispersing cleaning agent to obtain the alcohol-based fuel composite additive.
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