CN112980263A - Artistic painted wall cloth and preparation method thereof - Google Patents

Artistic painted wall cloth and preparation method thereof Download PDF

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Publication number
CN112980263A
CN112980263A CN202110448051.0A CN202110448051A CN112980263A CN 112980263 A CN112980263 A CN 112980263A CN 202110448051 A CN202110448051 A CN 202110448051A CN 112980263 A CN112980263 A CN 112980263A
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layer
artistic
paint
parts
art
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CN112980263B (en
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张小琼
张海雄
陆勇新
黄少婷
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Guangdong Yulan Group Co ltd
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Guangdong Yulan Group Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/002—Priming paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

Abstract

The invention provides an art paint wall cloth and a preparation method thereof. The art paint wall cloth provided by the invention comprises the following components in sequential contact: the decorative paint comprises a base material layer, a reinforcing layer, an art paint layer, a pattern layer, a texture layer and a waterproof protective layer; the artistic paint layer is formed by artistic slurry comprising the following components in parts by mass: 15-50 parts of water-based acrylic emulsion; 6-9 parts of water; 3-10 parts of nano mica powder; 1-10 parts of nano titanium dioxide; 12-18 parts of calcium carbonate; 0.2-0.5 parts of chopped fiber filaments; 0.5-1 part of methoxysilane; 0.5-0.7 part of a film-forming assistant; 0.5-1.5 parts of a nonionic surfactant; 0.2-0.5 part of a dispersing agent; 0-1 part of gloss enhancer. The art paint wall cloth provided by the invention can achieve the decorative effect of art paint and has good adhesiveness, scratch resistance and flexing resistance.

Description

Artistic painted wall cloth and preparation method thereof
Technical Field
The invention relates to the field of decorative materials, in particular to an art paint wall cloth and a preparation method thereof.
Background
Interior decoration materials are important components in interior design and interior decoration. With the gradual improvement of the artistic appreciation capability and the artistic appreciation degree of people, better artistic requirements are required for indoor decoration, and particularly, the decoration of indoor wall surfaces often requires the addition of artistic elements so as to improve the artistic appreciation of decoration and decoration results.
The existing indoor wall surface decoration forms are various, such as wall paper/cloth decoration, painting of art paint and the like.
Wallpaper (wall cloth), also called wallpaper (wall cloth), is an interior decoration material for pasting wall surfaces, and is widely used for interior decoration of houses, offices and hotels. Because the wallpaper is produced in manufacturers, the decorative effect of the wall surface can be finished by sticking the wallpaper to the hands of consumers only by glue, and the wallpaper is popular among people.
The artistic painted wall surface is the indoor decoration which is made in recent years and is mainly finished according to the site construction of professional construction personnel. Specifically, the construction of art paint wall surfaces firstly needs to paint a closed clear primer on the wall surface, then paint a single-color paint, and then show the patterns of designers on the wall surface by means of scraping or rubbing by professional constructors. Due to the fact that the field construction speciality of the art paint is high, the effect difference of the pattern displayed on the same design drawing is large due to the fact that the manual skill levels of professional constructors are different; in addition, the construction area is large, more construction time and construction cost are needed, and more travel expenses are generated for professional constructors, so that the time cost and the cost of the art paint for field construction are high, and common consumers are difficult to bear. Therefore, the development of the indoor decoration product which has the decoration effect of the artistic paint and is combined with the advantages of wallpaper (wall cloth) has great significance.
Disclosure of Invention
In view of the above, the invention aims to provide an art paint wall cloth and a preparation method thereof. The art paint wall cloth provided by the invention has an art paint effect, the cost can be reduced compared with a painting mode, and the art paint wall cloth provided by the invention has excellent scratch resistance, adhesion and bending resistance.
The invention provides an art paint wall cloth, which comprises:
a substrate layer;
the reinforcing layer is compounded on the surface of the base material layer;
an artistic paint layer compounded on the surface of the reinforcing layer;
the pattern layer is compounded on the surface of the artistic paint layer;
the texture layer is compounded on the surface of the pattern layer;
a waterproof protective layer compounded on the surface of the texture layer;
the artistic paint layer is formed by artistic slurry comprising the following components in parts by mass:
Figure BDA0003037588530000021
preferably, the chopped fiber yarns are selected from one or more of polyester fiber yarns, viscose fiber yarns and spandex fiber yarns.
Preferably, the methoxysilane is selected from one or more of gamma- (methacryloyloxy) methyltriethoxysilane, vinyltrimethoxysilane and gamma-methacryloxypropyltrimethoxysilane.
Preferably, the nonionic surfactant is alkylphenol ethoxylates and/or high-carbon fatty alcohol polyoxyethylene ether;
the dispersing agent is selected from one or more of sodium dodecyl sulfate, methyl amyl alcohol, polyacrylamide, fatty acid polyglycol ester and methoxy ester propyl ester;
the film forming auxiliary agent is selected from one or more of propylene glycol methyl ether acetate, ethylene glycol butyl ether, benzyl alcohol, dodecyl alcohol ester and hexanediol butyl ether acetate;
the gloss enhancer comprises one or more of mica sheet, aluminum paste and glitter powder.
Preferably, the reinforcing layer is a primer layer;
or
The reinforcing layer is a check gauze layer; and the square gauze layer is bonded with the base material layer through an adhesive layer.
Preferably, the primer layer is formed by a primer including the following components in mass ratio:
Figure BDA0003037588530000031
the grid gauze layer is characterized in that the fineness of warp yarns is 16-40 inches, the density of the warp yarns is 15-30 yarns/inch, the fineness of weft yarns is 6-20 yarns/inch, and the density of the weft yarns is 10-20 yarns/inch.
Preferably, the resin emulsion is vinyl acetate-ethylene copolymer emulsion, styrene-acrylate copolymer emulsion and water-based fluorocarbon resin;
the epoxy silane is one or more of gamma-glycidyl ether oxygen propyl methyl diethoxy silane, beta- (3, 4-epoxy cyclohexyl) ethyl triethoxysilane and gamma-glycidyl ether propyl trimethylsilane.
Preferably, the mass ratio of the vinyl acetate-ethylene copolymer emulsion to the styrene-acrylate copolymer emulsion to the aqueous fluorocarbon resin is 5 to (3-5) to (1-3);
the wetting dispersant is BYK-190.
The invention also provides a preparation method of the art paint wall cloth in the technical scheme, which comprises the following steps:
s1, compounding a reinforcing layer on one surface of the base material layer;
s2, coating the art slurry on the reinforcing layer to form an art paint layer;
s3, rolling or rubbing a pattern on the artistic paint layer to form a pattern layer;
s4, making patterns on the pattern layer to form a texture layer;
and S5, compounding a waterproof protective layer on the surface of the texture layer to obtain the art paint wall cloth.
Preferably, the step S1 specifically includes:
after coating a primer on one surface of the substrate layer, drying to form a reinforcing layer;
or
And after an adhesive layer is coated on one surface of the base material layer, the square gauze is pressed on the adhesive layer and dried to form the reinforcing layer.
The art paint wall cloth provided by the invention comprises the following components in sequential contact: the decorative paint comprises a base material layer, a reinforcing layer, an art paint layer, a pattern layer, a texture layer and a waterproof protective layer; the artistic paint layer is formed by artistic slurry comprising the following components in parts by mass: 15-50 parts of water-based acrylic emulsion; 6-9 parts of water; 3-10 parts of nano mica powder; 1-10 parts of nano titanium dioxide; 12-18 parts of calcium carbonate; 0.2-0.5 parts of chopped fiber filaments; 0.5-1 part of methoxysilane; 0.5-0.7 part of a film-forming assistant; 0.5-1.5 parts of a nonionic surfactant; 0.2-0.5 part of a dispersing agent; 0-1 part of gloss enhancer. The invention adopts specific art slurry to form the art paint layer, and achieves the decorative effect of the art paint through the common arrangement of the pattern layer and the texture layer; moreover, through the arrangement of the reinforcing layer and the matching of the artistic paint layer, the adhesiveness, the scraping resistance and the bending resistance of the wall cloth can be effectively improved.
Experimental results show that the scratch resistance of the art painted wall cloth provided by the invention can reach 2H level, the adhesive force reaches 0 level, and the outward and inward bending properties are good.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the provided drawings without creative efforts.
FIG. 1 is a schematic structural view of an art painted wall covering provided by the present invention;
FIG. 2 is a schematic view of an art painted wall covering provided in accordance with one embodiment of the present invention;
fig. 3 is a schematic view of an art painted wall covering according to another embodiment of the present invention.
Detailed Description
The invention provides an art paint wall cloth, which comprises:
a substrate layer;
the reinforcing layer is compounded on the surface of the base material layer;
an artistic paint layer compounded on the surface of the reinforcing layer;
the pattern layer is compounded on the surface of the artistic paint layer;
the texture layer is compounded on the surface of the pattern layer;
a waterproof protective layer compounded on the surface of the texture layer;
the artistic paint layer is formed by artistic slurry comprising the following components in parts by mass:
Figure BDA0003037588530000051
referring to fig. 1, fig. 1 is a schematic structural view of an art painted wall cloth provided by the present invention; wherein, 1 is the substrate layer, 2 is the enhancement layer, 3 is art paint layer, 4 is the pattern layer, 5 is the texture layer, 6 is the waterproof layer.
The substrate layer 1 is a substrate of the whole wallpaper/wall cloth, the invention has no special limitation on the kind thereof, and the substrate is a conventional substrate known to those skilled in the art, such as a wood pulp paper layer, a non-woven fabric layer or a woven fabric layer. In the present invention, the source of the base material layer is not particularly limited, and may be a general commercially available product. In the invention, the thickness of the base material layer is preferably 0.08-2 mm.
The reinforcing layer 2 is compounded on the surface of the substrate layer 1, so that the adhesive force of the substrate layer can be effectively improved.
In some embodiments of the present invention, the strengthening layer 2 is a primer layer, which is an interface strengthening layer, and is a layer structure formed after the primer is cured, so as to improve the adhesion between the substrate layer and the art paint layer, and make the art paint layer not easy to fall off. Referring to fig. 2, fig. 2 is a schematic view of an art painted wall cloth according to an embodiment of the present invention, in which 1 is a substrate layer, 21 is a primer layer, 3 is an art paint layer, 4 is a pattern layer, 5 is a texture layer, and 6 is a waterproof protective layer.
In the present invention, the primer layer is preferably formed of a primer including the following components in mass ratio:
Figure BDA0003037588530000052
wherein:
the resin emulsion is preferably vinyl acetate-ethylene copolymer emulsion, styrene-acrylate copolymer emulsion and water-based fluorocarbon resin. The mass ratio of the vinyl acetate-ethylene copolymer emulsion to the styrene-acrylate copolymer emulsion to the aqueous fluorocarbon resin is preferably 5: 3-5: 1-3, and more preferably 5: 2. Wherein, the vinyl acetate-ethylene copolymer emulsion and the styrene-acrylate copolymer emulsion are soft resin, and the aqueous fluorocarbon resin is hard resin; the soft resin can be matched with zeolite powder well, and a coating film with a rough surface can be formed after the coating; the hard resin has good bonding force with the substrate layer, but is easy to break; by matching the soft resin and the hard resin, the advantages of the soft resin and the hard resin are inherited, and a rough primer coating with good flexibility can be obtained in the subsequent production steps. The using amount of the resin emulsion is 20-30 parts; in some embodiments of the invention, the resin emulsion is used in an amount of 20 parts or 30 parts.
The fineness of the zeolite powder is preferably 600-1500 meshes. Taking the amount of the resin emulsion as a reference of 20-30 parts, and the amount of the zeolite powder is 0.5-1 part; in some embodiments of the invention, the zeolite powder is used in an amount of 0.5 parts or 1 part.
The using amount of the water is 30-60 parts; in some embodiments of the invention, water is used in an amount of 30 parts or 60 parts.
The wetting and dispersing agent is preferably BYK-190, available from Pico. The dosage of the wetting dispersant is 0.1-0.5 part based on 20-30 parts of the dosage of the resin emulsion; in some embodiments of the invention, the wetting dispersant is used in an amount of 0.1 parts or 0.5 parts.
The epoxy silane is preferably one or more of gamma-glycidyl ether oxygen propyl methyl diethoxy silane, beta- (3, 4-epoxy cyclohexyl) ethyl triethoxysilane and gamma-glycidyl ether propyl trimethylsilane. In some embodiments of the invention, the epoxysilane is gamma-glycidoxypropylmethyldiethoxysilane. In other embodiments of the invention, the epoxysilane is gamma-glycidoxypropylmethyldiethoxysilane and beta- (3, 4-epoxycyclohexyl) ethyltriethoxysilane. In some embodiments of the invention, the epoxysilane is gamma-glycidoxypropylmethyldiethoxysilane and beta- (3, 4-epoxycyclohexyl) ethyltriethoxysilane in a 1: 1 mass ratio. The dosage of the wetting dispersant is 0.5-1 part based on 20-30 parts of the dosage of the resin emulsion; in some embodiments of the invention, the wetting dispersant is used in an amount of 0.5 parts or 1 part.
The preparation method of the primer is not particularly limited, and the components are uniformly mixed. In the primer formula, the selection and matching of the resin emulsion and the epoxy silane are particularly critical for improving the performance of the wall cloth.
In the invention, the thickness of the primer layer is preferably 0.05-0.1 mm. Because the final effect that needs to present the texture of art lacquer layer, the viscosity of so thick liquids is big, if art lacquer thick liquids and substrate layer direct contact, the moist effect of art lacquer thick liquids on the substrate layer is relatively poor, through the priming paint layer, can effectually realize substrate layer and the adhering to of art thick liquids. After the priming paint is coated, the self-made art slurry is coated, because the priming paint contains epoxy silane, acrylic resin in the self-made art slurry contains carboxyl, the carboxyl in the resin reacts with epoxy group in the epoxy silane, hydrolyzable silane oxygen group is introduced, and then Si-O-Si crosslinking is formed through hydrolysis and condensation of silicon alkoxy, so that excellent adhesion effect is realized.
In some embodiments of the invention, the reinforcing layer 2 is a checkered scrim layer; the square gauze layer is bonded with the base material layer 1 through an adhesive layer. Referring to fig. 3, fig. 3 is a schematic view of an art painted wall cloth according to another embodiment of the present invention, wherein 1 is a substrate layer, 22 is a square gauze layer, 23 is an adhesive layer, 3 is an art paint layer, 4 is a pattern layer, 5 is a texture layer, and 6 is a waterproof protective layer. The grid gauze layer is arranged, so that the thickness of the wallpaper can be increased, the bending and folding resistance of the wallpaper can be improved, the contact area between the artistic sizing agent for forming the artistic paint layer and a semi-finished wallpaper product can be effectively increased, the fastness of the artistic paint layer is increased, and the artistic paint layer is not easy to fall off.
In the present invention, the specification of the square gauze layer is preferably: the fineness of the warp yarn is 16-40 inches, the density of the warp yarn is 15-30 pieces/inch, the fineness of the weft yarn is 6-20 pieces, and the density of the weft yarn is 10-20 pieces/inch. The smaller the number of the yarns is, the thicker the corresponding yarns are, the larger the density of the warps and the density of the wefts are, the smaller the corresponding grids are, and the grid gauze layer is controlled under the specifications to enable the artistic paint layer to achieve a good adhesion effect.
In the invention, the square gauze layer and the base material layer 1 are bonded through the adhesive layer. The adhesive type of the adhesive layer is not particularly limited, and the adhesive layer is an adhesive between conventional composite layers in the field, and specifically can be a polyurethane adhesive.
The artistic paint layer 3 is compounded on the surface of the reinforced layer 2, and the wallpaper/wall cloth achieves the decorative effect of the artistic paint by arranging the artistic paint layer.
In the invention, the art paint layer 3 is formed by art slurry comprising the following components in parts by mass:
Figure BDA0003037588530000071
Figure BDA0003037588530000081
wherein:
the aqueous acrylic emulsion is used in an amount of 15 to 50 parts, and in some embodiments of the present invention, 15 parts, 18 parts, or 20 parts.
The water is used in an amount of 6 to 9 parts, and in some embodiments of the invention, 6, 7, or 9 parts.
The fineness of the nano mica powder is preferably 5000-10000 meshes. Taking 15-50 parts of the water-based acrylic emulsion as a reference, and taking 3-10 parts of nano mica powder; in some embodiments of the present invention, the nano mica powder is used in an amount of 3 parts, 4 parts or 5 parts.
The fineness of the nano titanium dioxide is preferably 4000-8000 meshes. Taking 15-50 parts of the water-based acrylic emulsion as a reference, and taking 1-10 parts of nano titanium dioxide; in some embodiments of the invention, the amount of the nano titanium dioxide is 1 part, 1.5 parts, or 2 parts.
The fineness of the calcium carbonate is preferably 800-1200 meshes. Taking 15-50 parts of the water-based acrylic emulsion as a reference, and taking 12-18 parts of calcium carbonate; in some embodiments of the invention, the calcium carbonate is used in an amount of 12 parts, 15 parts, or 18 parts.
The nano mica powder, the nano titanium dioxide and the calcium carbonate are used as the filler together, and can be matched with other components in the slurry, so that the adhesiveness of the artistic paint layer is improved, and the flexing resistance of the wall cloth is not influenced; in addition, the nano mica powder can provide cool touch feeling for the artistic paint layer; the nanometer titanium dioxide can provide a certain antibacterial effect, a large amount of superoxide anions and hydroxyl free radicals are generated under the illumination condition, and the products can promote the decomposition of microbial esters and the variation of proteins, so that the antibacterial effect is realized.
The chopped fiber yarns are preferably one or more of polyester fiber yarns, viscose fiber yarns and spandex fiber yarns. The chopped fiber yarns are added into the sizing agent, so that the mechanical property of the art paint layer can be enhanced, when cracks appear on the art paint layer due to external force, the art paint layer is pulled tightly under the action of the chopped fiber yarns, and fine lines are not easy to expand and expose. Based on 15-50 parts of the water-based acrylic emulsion, the chopped fiber filaments are 0.2-0.5 part; in some embodiments of the present invention, the chopped strand is used in an amount of 0.2 parts, 0.4 parts, or 0.5 parts.
The methoxysilane is preferably one or more of gamma- (methacryloyloxy) methyltriethoxysilane, vinyltriethoxysilane and gamma-methacryloxypropyltrimethoxysilane. Methoxy silane is introduced to be used as an adhesion promoter, so that the adhesion between fibers and slurry and the adhesion between the slurry and gauze can be enhanced. Taking 15-50 parts of the water-based acrylic emulsion as a reference, and taking 0.5-1 part of methoxysilane; in some embodiments of the invention, the methoxysilane is used in an amount of 0.5 parts, 0.8 parts, or 1 part.
The film-forming auxiliary agent is preferably one or more of propylene glycol methyl ether acetate, ethylene glycol butyl ether, benzyl alcohol, dodecyl alcohol ester and hexanediol butyl ether acetate. Taking 15-50 parts of the water-based acrylic emulsion as a reference, and taking 0.5-0.7 part of the film-forming assistant; in some embodiments of the invention, the coalescent is used in an amount of 0.5 parts, 0.6 parts, or 0.7 parts.
The nonionic surfactant is preferably alkylphenol ethoxylates and/or higher fatty alcohol ethoxylates. The nonionic surfactant can achieve good dispersion, emulsification and solubilization effects of the slurry. Taking 15-50 parts of the water-based acrylic emulsion as a reference, and taking 0.5-1.5 parts of the nonionic surfactant; in some embodiments of the invention, the nonionic surfactant is used in an amount of 0.5 parts, 1 part, or 1.5 parts.
The dispersant is preferably one or more of sodium dodecyl sulfate, methyl amyl alcohol, polyacrylamide, fatty acid polyglycol ester and methoxy ester propyl ester. Taking 15-50 parts of the water-based acrylic emulsion as a reference, and taking 0.2-0.5 part of a dispersing agent; in some embodiments of the invention, the dispersant is used in an amount of 0.2 parts, 0.3 parts, or 0.5 parts.
The gloss enhancer preferably comprises one or more of mica sheet, aluminum paste and glitter powder. In the present invention, the source of the gloss enhancer is not particularly limited, and may be any commercially available product. Taking 15-50 parts of the water-based acrylic emulsion as a reference, and taking 0-1 part of the gloss enhancer; in some embodiments of the present invention, the gloss enhancer is used in an amount of 0 parts, 0.5 parts, or 1 part.
The preparation method of the art slurry is not particularly limited, and the components are uniformly mixed. The invention enables the wallpaper/wall cloth to have the decorative effect of the artistic paint surface of the wallpaper by arranging the artistic paint layer, and meanwhile, the artistic paint layer has better flexibility and can be bent into a coil. In the invention, the thickness of the art paint layer 3 is preferably 0.5-3 mm.
The pattern layer 4 is formed by applying a pattern to the surface of the artistic paint layer 3 by roll coating or rubbing. In the present invention, the thickness of the pattern layer 4 is preferably 0.5 to 1 mm.
The texture layer 5 is compounded on the surface of the pattern layer 4, and patterns can be formed on the surface of the pattern layer 4 by scraping, pressing or contacting with fluffy objects, so that the texture layer is formed. Wherein, the fluffy articles can be sponge, cotton, thread balls and other articles. In the invention, the thickness of the texture layer 5 is preferably 0.5-5 mm.
The waterproof protective layer 6 is compounded on the surface of the texture layer 5 and can be prepared by painting waterproof paint. The invention has no special limitation on the type of waterproof paint, and the waterproof paint is the conventional waterproof paint in the field. In the invention, the thickness of the waterproof protective layer is preferably 0.1-0.3 mm.
The invention also provides a preparation method of the art paint wall cloth in the technical scheme, which comprises the following steps:
s1, compounding a reinforcing layer on one surface of the base material layer;
s2, coating the art slurry on the reinforcing layer to form an art paint layer;
s3, rolling or rubbing a pattern on the artistic paint layer to form a pattern layer;
s4, making patterns on the pattern layer to form a texture layer;
and S5, compounding a waterproof protective layer on the surface of the texture layer to obtain the art paint wall cloth.
The types, sizes and the like of the substrate layer, the artistic paint layer, the pattern layer, the texture layer and the waterproof protective layer are consistent with those in the technical scheme, and are not repeated one by one.
Regarding step S1:
the first mode of compounding the reinforcing layer on the base material layer specifically is as follows: and (3) coating a primer on one surface of the substrate layer, and drying to form the reinforcing layer. Wherein the coating amount of the primer is preferably 100-200 g/m2. The drying temperature is preferably 80-100 ℃, and the drying time is preferably 1-3 min.
The second mode of compounding the reinforcing layer on the base material layer specifically is as follows: and after an adhesive layer is coated on one surface of the base material layer, the square gauze is pressed on the adhesive layer and dried to form the reinforcing layer. Wherein the coating amount of the adhesive is preferably 50-150 g/m2. The pressure for pressing the check gauze is preferably 0.8-1.2 MPa. The drying temperature is preferably 80-100 ℃, and the drying time is preferably 1-3 min.
Regarding step S2: the manner of coating the artistic slurry is preferably knife coating or spray coating. The coating amount of the art slurry is preferably 300-1000 g/m2。
Regarding step S3: the manner of rolling or rubbing the pattern on the artistic paint layer is not particularly limited and may be performed according to the conventional operation in the art.
Regarding step S4: the texture layer is preferably manufactured by the following method: the pattern layer 4 is scratched or pressed on the surface thereof or brought into contact with the bulky article to form a pattern, thereby forming a texture layer. Wherein, the fluffy articles can be sponge, cotton, thread balls and other articles.
Regarding step S5: the mode of compounding the waterproof protective layer is preferably as follows: and rolling or spraying waterproof paint on the texture layer, and drying to form the waterproof protective layer. The invention has no special limitation on the type of waterproof paint, and the waterproof paint is the conventional waterproof paint in the field. The drying temperature is preferably 100-150 ℃, and the drying time is preferably 1-3 min.
In the invention, after the artistic painted wall cloth is prepared by the steps, the artistic painted wall cloth is cut, and the artistic painted wall cloth is bent outwards to be packaged into a roll for standby.
The art paint wall cloth provided by the invention has the following beneficial effects:
1. in actual use, the decorative effect of the art paint can be realized only by the wallpaper construction mode without complex operation and excessive waiting time; when wallpaper/cloth is replaced, the wallpaper/cloth can be replaced according to the wallpaper dismounting method, the art paint does not need to be scraped off for construction again, and dust in the replacement process does not need to be endured. Relatively speaking, the art paint wallpaper/cloth is convenient to install, convenient to replace and high in practicability.
2. The art paint wallpaper provided by the invention has excellent scratch resistance, adhesion and bending resistance.
3. The artistic paint wallpaper provided by the invention has good pattern stability, namely good reproducibility, can realize batch production, and has lower cost.
For a further understanding of the invention, reference will now be made to the preferred embodiments of the invention by way of example, and it is to be understood that the description is intended to further illustrate features and advantages of the invention, and not to limit the scope of the claims. In the following examples, the zeolite powder particle size in the primer was as described above. The particle sizes of the nano mica powder, the nano titanium dioxide and the calcium carbonate in the art slurry are as described above. The room temperature is specifically 25 ℃. The base material layer in the wallpaper is a non-woven fabric layer. A waterproof paint for forming a waterproof protective layer when preparing wall cloth was AG-E082 available from AGC corporation.
Example 1: preparation of the primer
1. The formula is as follows:
Figure BDA0003037588530000111
wherein:
the resin emulsion is as follows: a composition formed by mixing vinyl acetate-ethylene copolymer emulsion, styrene-acrylate copolymer emulsion and aqueous fluorocarbon resin according to the mass ratio of 5: 2;
the wetting dispersant is BYK-190;
the epoxy silane is gamma-glycidoxypropyl methyldiethoxysilane.
2. Preparation: and mixing and stirring the resin emulsion, water, zeolite powder, wetting dispersant and epoxy silane uniformly at room temperature to obtain the primer.
Example 2: preparation of the primer
1. The formula is as follows:
Figure BDA0003037588530000121
wherein:
the resin emulsion is as follows: a composition formed by mixing vinyl acetate-ethylene copolymer emulsion, styrene-acrylate copolymer emulsion and aqueous fluorocarbon resin according to the mass ratio of 5: 2;
the wetting dispersant is BYK-190;
the epoxy silane is: a composition in which gamma-glycidoxypropylmethyldiethoxysilane and beta- (3, 4-epoxycyclohexyl) ethyltriethoxysilane are mixed in a mass ratio of 1: 1; .
2. Preparation: and mixing and stirring the resin emulsion, water, zeolite powder, wetting dispersant and epoxy silane uniformly at room temperature to obtain the primer.
Example 3: preparation of art size
1. The formula is as follows:
Figure BDA0003037588530000122
Figure BDA0003037588530000131
2. preparation: the raw materials are mixed and stirred evenly at room temperature to obtain the art paste.
Example 4: preparation of art size
1. The formula is as follows:
Figure BDA0003037588530000132
2. preparation: the raw materials are mixed and stirred evenly at room temperature to obtain the art paste.
Example 5: preparation of art size
1. The formula is as follows:
Figure BDA0003037588530000133
Figure BDA0003037588530000141
2. preparation: the raw materials are mixed and stirred evenly at room temperature to obtain the art paste.
Example 6: preparation of art size
1. The formula is as follows:
Figure BDA0003037588530000142
wherein the methoxysilane is gamma- (methacryloyloxy) methyltriethoxysilane and gamma-methacryloxypropyltrimethoxysilane (mass ratio is 1: 1).
2. Preparation: the raw materials are mixed and stirred evenly at room temperature to obtain the art paste.
Example 7: preparing artistic paint wallpaper
S1, spreading the substrate layer (with the thickness of 1 mm).
S2, coating the primer of the example 1 on one side of the substrate layer, wherein the coating amount is 150g/m2And after painting, drying at 80 ℃ for 3min to form the reinforcing layer.
S3, the art size of example 3 was knife coated on the reinforcing layer with a coating weight of 500g/m2；
S4, rolling and coating the semi-finished product of the step S3 with patterns to form a pattern layer.
And S5, forming patterns on the surface of the pattern layer by batch scraping and sponge contact, and drying at 80 ℃ for 40min to form the texture layer.
S6, spraying waterproof paint on the texture layer, wherein the spraying amount is 50g/m2And drying at 100 ℃ for 3min to obtain the art wall cloth.
And S7, cutting, and bending the artistic paint layer outwards to form a roll package.
Example 8: preparing artistic paint wallpaper
S1, spreading the substrate layer (same thickness as example 7).
S2, coating the primer of the example 2 on one side of the substrate layer, wherein the coating amount is 100g/m2And after painting, drying at 80 ℃ for 3min to form the reinforcing layer.
S3, the art size of example 4 is knife-coated on the reinforcing layer with a coating weight of 500g/m2；
S4, rolling and coating the semi-finished product of the step S3 with patterns to form a pattern layer.
And S5, forming patterns on the surface of the pattern layer by batch scraping and sponge contact, and drying at 80 ℃ for 40min to form the texture layer.
S6, spraying waterproof paint on the texture layer, and drying at 100 ℃ for 3min to obtain the artistic wallpaper.
And S7, cutting, and bending the artistic paint layer outwards to form a roll package.
Example 9: preparing artistic paint wallpaper
S1, spreading the substrate layer (same thickness as example 7).
S2, coating an adhesive (type is PU-803, purchased from En chemical Co., Ltd., Anhui) on one side of the substrate layer, wherein the coating amount is 150g/m2Pressing the check gauze on the adhesive layer under the pressure of 1.2 MPa; after pressing, the layers were dried at 100 ℃ for 2min to form a reinforcing layer.
S3, the art size of example 3 is knife-coated on the reinforcing layer with the amount of 800g/m2；
S4, rubbing the pattern on the semi-finished product of the step S3 to form a pattern layer.
And S5, pressing the pattern layer surface to form patterns, and drying at 100 ℃ for 30min to form the texture layer.
S6, roll-coating waterproof paint on the texture layer, and drying at 150 ℃ for 2min to obtain the artistic wallpaper.
And S7, cutting, and bending the artistic paint layer outwards to form a roll package.
Example 10: preparing artistic paint wallpaper
S1, spreading the substrate layer (same thickness as example 7).
S2, coating an adhesive (type PU-7108, available from Shanghai Berter New Material science and technology Co., Ltd.) on one side of the substrate layer with a coating amount of 150g/m2Pressing the check gauze on the adhesive layer under the pressure of 1.2 MPa; after pressing, the layers were dried at 100 ℃ for 2min to form a reinforcing layer.
S3, the art size of example 4 is knife-coated on the reinforcing layer with the amount of 800g/m2；
S4, rubbing the pattern on the semi-finished product of the step S3 to form a pattern layer.
And S5, pressing the pattern layer surface to form patterns, and drying at 100 ℃ for 30min to form the texture layer.
S6, roll-coating waterproof paint on the texture layer, and drying at 150 ℃ for 2min to obtain the artistic wallpaper.
And S7, cutting, and bending the artistic paint layer outwards to form a roll package.
Example 11: preparing artistic paint wallpaper
S1, spreading the substrate layer (same thickness as example 7).
S2, coating an adhesive (model KL-100F, available from Korea adhesive Co., Ltd., Dongguan) on one side of the substrate layer, wherein the coating amount is 150g/m2Pressing the check gauze on the adhesive layer under the pressure of 1.2 MPa; after pressing, the layers were dried at 100 ℃ for 2min to form a reinforcing layer.
S3, the art size of example 5 is knife-coated on the reinforcing layer with the amount of 800g/m2；
S4, rubbing the pattern on the semi-finished product of the step S3 to form a pattern layer.
And S5, pressing the pattern layer surface to form patterns, and drying at 100 ℃ for 30min to form the texture layer.
S6, roll-coating waterproof paint on the texture layer, and drying at 150 ℃ for 2min to obtain the artistic wallpaper.
And S7, cutting, and bending the artistic paint layer outwards to form a roll package.
Example 12: preparing artistic paint wallpaper
S1, spreading the substrate layer (same thickness as example 7).
S2, coating an adhesive (type is PU-803, purchased from En chemical Co., Ltd., Anhui) on one side of the substrate layer, wherein the coating amount is 150g/m2Pressing the check gauze on the adhesive layer under the pressure of 1.2 MPa; after pressing, the layers were dried at 100 ℃ for 2min to form a reinforcing layer.
S3, the art paste of example 6 was knife-coated on the reinforcing layer at a coating weight of 800g/m2；
S4, rubbing the pattern on the semi-finished product of the step S3 to form a pattern layer.
And S5, pressing the pattern layer surface to form patterns, and drying at 100 ℃ for 30min to form the texture layer.
S6, roll-coating waterproof paint on the texture layer, and drying at 150 ℃ for 2min to obtain the artistic wallpaper.
And S7, cutting, and bending the artistic paint layer outwards to form a roll package.
Comparative example 1
The procedure of example 7 was followed except that the art size of the art paint layer was replaced with the paint of example 1 in CN 201811105098.1.
Comparative example 2
The procedure of example 7 was followed except that the base coat was not applied and the artistic paint layer was applied directly to the substrate.
Comparative example 3
The procedure of example 9 was followed, except that the reinforcing layer was not provided and the base material was directly coated with an art paint layer.
Example 13: performance testing
The wallpapers of examples 7-12 and comparative examples 1-3 were tested for scratch resistance, adhesion, and flex resistance, respectively.
Scratch resistance: testing is carried out according to GB/T6739-2006;
adhesion force: the test is carried out according to GB/T9286-1998, and the rest test processes are carried out according to the standard except for different thicknesses;
bending resistance: taking a part without crease marks, discoloration or other damages in a sample, inwards bending a coating layer of the sample, placing 500g of an article at a bending position, taking out the sample after 5min, and detecting the damage condition by visual inspection and a magnifying glass under the light of not less than 600 lx; and taking another sample, bending the coating surface of the sample outwards, placing the sample at a bending position by using 500g of articles, taking out the sample after 5min, and detecting the damage condition of the coating by visual inspection and using a magnifying glass under the light of not less than 600 lx.
The test results are shown in table 1:
TABLE 1 Properties of wallpapers obtained in examples 7 to 12 and comparative examples 1 to 3
Figure BDA0003037588530000171
As can be seen from the test results in Table 1, the artistic wall cloth provided by the invention has good scratch resistance, adhesive force and flexing resistance. The comparison with the effect of the comparative example 1 proves that the scratch resistance, the adhesion and the bending resistance of the wall cloth can be effectively improved by adopting the art paint disclosed by the invention. Compared with the effects of comparative examples 2-3, the reinforcing layer is set, so that the adhesiveness of the wall cloth can be effectively improved.
The foregoing examples are provided to facilitate an understanding of the principles of the invention and their core concepts, including the best mode, and also to enable any person skilled in the art to practice the invention, including making and using any devices or systems and performing any incorporated methods. It should be noted that, for those skilled in the art, it is possible to make various improvements and modifications to the present invention without departing from the principle of the present invention, and those improvements and modifications also fall within the scope of the claims of the present invention. The scope of the invention is defined by the claims and may include other embodiments that occur to those skilled in the art. Such other embodiments are intended to be within the scope of the claims if they have structural elements that approximate the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal languages of the claims.

Claims (10)

1. An artistic painted wall covering, comprising:
a substrate layer;
the reinforcing layer is compounded on the surface of the base material layer;
an artistic paint layer compounded on the surface of the reinforcing layer;
the pattern layer is compounded on the surface of the artistic paint layer;
the texture layer is compounded on the surface of the pattern layer;
a waterproof protective layer compounded on the surface of the texture layer;
the artistic paint layer is formed by artistic slurry comprising the following components in parts by mass:
Figure FDA0003037588520000011
2. the artistic painted wall cloth according to claim 1, wherein the chopped fiber yarns are selected from one or more of polyester fiber yarns, viscose fiber yarns and spandex fiber yarns.
3. The artistic painted wall covering of claim 1, wherein the methoxysilane is selected from one or more of γ - (methacryloyloxy) methyltriethoxysilane, vinyltrimethoxysilane, and γ -methacryloxypropyltrimethoxysilane.
4. The art paint wall cloth of claim 1, wherein the nonionic surfactant is alkylphenol ethoxylate and/or higher fatty alcohol ethoxylate;
the dispersing agent is selected from one or more of sodium dodecyl sulfate, methyl amyl alcohol, polyacrylamide, fatty acid polyglycol ester and methoxy ester propyl ester;
the film forming auxiliary agent is selected from one or more of propylene glycol methyl ether acetate, ethylene glycol butyl ether, benzyl alcohol, dodecyl alcohol ester and hexanediol butyl ether acetate;
the gloss enhancer comprises one or more of mica sheet, aluminum paste and glitter powder.
5. The artistic painted wall covering of claim 1, wherein the reinforcing layer is a primer layer;
or
The reinforcing layer is a check gauze layer; and the square gauze layer is bonded with the base material layer through an adhesive layer.
6. The artistic painted wall cloth according to claim 5, wherein the primer layer is formed by a primer including the following components in mass ratio:
Figure FDA0003037588520000021
the grid gauze layer is characterized in that the fineness of warp yarns is 16-40 inches, the density of the warp yarns is 15-30 yarns/inch, the fineness of weft yarns is 6-20 yarns/inch, and the density of the weft yarns is 10-20 yarns/inch.
7. The artistic painted wall cloth of claim 6, wherein the resin emulsion is a vinyl acetate-ethylene copolymer emulsion, a styrene-acrylate copolymer emulsion and a water-based fluorocarbon resin;
the epoxy silane is one or more of gamma-glycidyl ether oxygen propyl methyl diethoxy silane, beta- (3, 4-epoxy cyclohexyl) ethyl triethoxysilane and gamma-glycidyl ether propyl trimethylsilane.
8. The art paint wall cloth according to claim 7, wherein the mass ratio of the vinyl acetate-ethylene copolymer emulsion to the styrene-acrylate copolymer emulsion to the aqueous fluorocarbon resin is 5 to (3-5) to (1-3);
the wetting dispersant is BYK-190.
9. A preparation method of the art painted wall cloth of any one of claims 1 to 8, which is characterized by comprising the following steps:
s1, compounding a reinforcing layer on one surface of the base material layer;
s2, coating the art slurry on the reinforcing layer to form an art paint layer;
s3, rolling or rubbing a pattern on the artistic paint layer to form a pattern layer;
s4, making patterns on the pattern layer to form a texture layer;
and S5, compounding a waterproof protective layer on the surface of the texture layer to obtain the art paint wall cloth.
10. The method according to claim 1, wherein the step S1 specifically includes:
after coating a primer on one surface of the substrate layer, drying to form a reinforcing layer;
or
And after an adhesive layer is coated on one surface of the base material layer, the square gauze is pressed on the adhesive layer and dried to form the reinforcing layer.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113463858A (en) * 2021-07-15 2021-10-01 绍兴恒高新材料科技股份有限公司 Artistic painted wall cloth and its production process
CN114541157A (en) * 2022-02-28 2022-05-27 华文煜 Manufacturing process of non-woven all-cotton wall cloth

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11115111A (en) * 1997-10-16 1999-04-27 Dainippon Printing Co Ltd Formaldehyde scavenging wall paper
JP2009242970A (en) * 2008-03-31 2009-10-22 Dainippon Printing Co Ltd Foamed wallpaper
CN104479270A (en) * 2014-12-31 2015-04-01 广东玉兰装饰材料有限公司 Water-based environment-protective resin, preparation method and application
CN107012744A (en) * 2017-05-05 2017-08-04 全南县智护力工业产品设计有限公司 A kind of wallpaper with water resistance
CN108442624A (en) * 2018-02-05 2018-08-24 凯诺（青岛）新型建材有限公司 A kind of wall decoration material and application with rice paper skin texture
CN211106032U (en) * 2019-11-07 2020-07-28 绍兴梓迈纺织有限公司 Antibacterial wall cloth
CN112680035A (en) * 2021-03-16 2021-04-20 广东博智林机器人有限公司 Artistic paint and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11115111A (en) * 1997-10-16 1999-04-27 Dainippon Printing Co Ltd Formaldehyde scavenging wall paper
JP2009242970A (en) * 2008-03-31 2009-10-22 Dainippon Printing Co Ltd Foamed wallpaper
CN104479270A (en) * 2014-12-31 2015-04-01 广东玉兰装饰材料有限公司 Water-based environment-protective resin, preparation method and application
CN107012744A (en) * 2017-05-05 2017-08-04 全南县智护力工业产品设计有限公司 A kind of wallpaper with water resistance
CN108442624A (en) * 2018-02-05 2018-08-24 凯诺（青岛）新型建材有限公司 A kind of wall decoration material and application with rice paper skin texture
CN211106032U (en) * 2019-11-07 2020-07-28 绍兴梓迈纺织有限公司 Antibacterial wall cloth
CN112680035A (en) * 2021-03-16 2021-04-20 广东博智林机器人有限公司 Artistic paint and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄文润: "《硅烷偶联剂及硅树脂》", 31 August 2010, 四川科学技术出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113463858A (en) * 2021-07-15 2021-10-01 绍兴恒高新材料科技股份有限公司 Artistic painted wall cloth and its production process
CN114541157A (en) * 2022-02-28 2022-05-27 华文煜 Manufacturing process of non-woven all-cotton wall cloth

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