CN112896833A - Storage tank exhaust emission reduction system and method - Google Patents

Storage tank exhaust emission reduction system and method Download PDF

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Publication number
CN112896833A
CN112896833A CN201911229623.5A CN201911229623A CN112896833A CN 112896833 A CN112896833 A CN 112896833A CN 201911229623 A CN201911229623 A CN 201911229623A CN 112896833 A CN112896833 A CN 112896833A
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CN
China
Prior art keywords
storage tank
gas
tank
pressure
working liquid
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Pending
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CN201911229623.5A
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Chinese (zh)
Inventor
刘忠生
廖昌建
王海波
朴勇
戴金玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Dalian Petrochemical Research Institute Co ltd
China Petroleum and Chemical Corp
Original Assignee
China Petroleum and Chemical Corp
Sinopec Dalian Research Institute of Petroleum and Petrochemicals
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Application filed by China Petroleum and Chemical Corp, Sinopec Dalian Research Institute of Petroleum and Petrochemicals filed Critical China Petroleum and Chemical Corp
Priority to CN201911229623.5A priority Critical patent/CN112896833A/en
Publication of CN112896833A publication Critical patent/CN112896833A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00Component parts, details or accessories for large containers
    • B65D90/48Arrangements of indicating or measuring devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D88/00Large containers
    • B65D88/74Large containers having means for heating, cooling, aerating or other conditioning of contents
    • B65D88/744Large containers having means for heating, cooling, aerating or other conditioning of contents heating or cooling through the walls or internal parts of the container, e.g. circulation of fluid inside the walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00Component parts, details or accessories for large containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00Component parts, details or accessories for large containers
    • B65D90/22Safety features
    • B65D90/28Means for preventing or minimising the escape of vapours

Abstract

The invention discloses an exhaust emission reduction system for waste gas discharged by a storage tank. The waste gas emission reduction system comprises an oil product storage tank, a gas storage tank, a working solution storage tank, a first working solution pump, a second working solution pump and a related detection control instrument. The tank top of the oil product storage tank is communicated with the tank top of the gas storage tank through a gas connecting pipe, and meanwhile, the tank top of the gas storage tank is provided with a waste gas discharge pipeline; gaseous holding vessel bottom sets up liquid outlet and liquid inlet, and gaseous holding vessel liquid outlet passes through first working fluid pump and working solution holding vessel liquid inlet intercommunication, and gaseous holding vessel liquid inlet passes through second working fluid pump and working solution holding vessel liquid outlet intercommunication. The emission reduction system provided by the invention realizes the adjustment of the pressure of the gas storage tank by adjusting the liquid level of the gas storage tank, thereby realizing the emission reduction of the waste gas in the storage tank. The system has the characteristics of safety, reliability, simple equipment operation, low operation cost, obvious energy-saving effect and the like.

Description

Storage tank exhaust emission reduction system and method
Technical Field
The invention relates to the technical field of environmental protection and energy conservation, in particular to a method and a system for reducing emission of waste gas discharged by a storage tank.
Background
During storage and transportation of oil and chemicals, large amounts of oil and gas or Volatile Organic Compounds (VOCs) are lost. According to statistics, the oil loss caused by the loss of light oil products accounts for about 0.5 percent of the light oil products each year, on one hand, a large amount of oil gas or volatile organic compounds are wasted, the economic benefit of enterprises is reduced, and on the other hand, serious environmental pollution is caused. In addition, as the oil gas and the air are easy to form an explosive mixture (the lower explosion limit is generally 1% -6%), the oil gas dissipation can cause the concentration of the oil gas around corresponding facilities to easily reach the explosion limit, and the oil gas gathered on the ground brings great potential safety hazards to enterprises and consumers, thereby endangering the safety production of the enterprises and directly influencing the health of operators and surrounding environment personnel. Therefore, it is necessary to recover the dissipated oil gas.
The traditional oil gas recovery treatment mode has three kinds: firstly, the fuel is directly used as fuel; oil gas is returned to the oil tank gas-liquid balance system, so that the oil gas partial pressure is increased, and the evaporation loss of oil products is reduced; thirdly, recovery devices and technologies are adopted, such as a condensation method, an absorption method, an adsorption method, a combined process thereof and the like.
CN101342427A discloses a method for recovering oil gas by a condensation-adsorption combined process, wherein, the oil gas is cooled and condensed to realize the condensation and separation of part of oil gas components, the uncondensed oil gas is recovered by adsorption-pressure swing desorption, the adsorbed tail gas reaches the standard and is discharged, and the desorbed oil gas returns to a cooling device to be mixed with the collected oil gas and enters a condenser. The recommended oil gas condensation temperature is-80-30 ℃, and the optimal temperature is-70-40 ℃. Oil gas components are recovered mainly by means of condensation and liquefaction, the condensation temperature is low, crystallization occurs in a condenser, and crystallization and condensation oil of water need to be removed periodically, so that two series of condensers are required to be switched for use; the total energy consumption of the device is larger, and the failure rate of the refrigeration equipment is higher. In addition, crystallization also occurs in the subsequent adsorption tanks, significantly reducing the service life of the adsorbent.
CN 105737517A discloses an oil storage tank exhaust gas purification method and device, and in this patent the oil storage tank exhaust gas is through compression condensation with heavy component oil gas condensation recovery in the exhaust gas, and noncondensable gas returns low pressure gas pipe network, has realized that the oil storage tank is when normal operation, and no pollutant is arranged outward, has avoided the discharge of tank field atmospheric pollutants. CN108069155A discloses a storage tank discharge gas emission reduction and recovery system, and in this patent, the oil storage space of the storage tank is strictly separated from the air space by using a floating disc, an edge seal, a seal film and a fixed ring plate, and the oil product is closely separated from the air, so that the oil gas generated by the evaporation of the oil product is pure oil gas, the gas itself has no explosiveness, and the evaporated oil gas can be safely controlled and recovered. Meanwhile, the floating disc is contacted with the oil product, so that the evaporation space of the oil product is reduced, and the loss of the oil product is reduced to the maximum extent. The oil gas evaporated by the storage tank can enter a low-pressure gas system after being subjected to desulfurization treatment by the absorption tower, so that no pollutant is discharged from the storage tank. However, in the methods disclosed in patent CN 105737517A and patent CN108069155A, an oil gas recovery system needs to be arranged and communicated with a gas pipe network, the system is complex, and the device investment is high.
The existing storage tank is mainly a vault tank, an inner floating roof tank and an outer floating roof tank, the storage tank has air suction and exhaust processes in the breathing process, the storage tank has the phenomenon of pollutant discharge, the exhaust gas needs to be treated up to the standard, and the problems of more complex treatment process, high treatment cost and the like exist.
Disclosure of Invention
Aiming at the problems in the prior art, the invention aims to provide a method and a system for reducing the emission of waste gas discharged by a storage tank.
The invention provides an emission reduction system for waste gas discharged from a storage tank.
A storage tank emission abatement system, the system comprising:
the oil storage tank comprises a pressure detection instrument arranged on the tank top and a gas connecting pipeline arranged on the tank top;
the gas storage tank comprises a gas connecting pipe arranged on the tank top, a waste gas discharge pipeline arranged on the tank top, a pressure detection instrument arranged on the tank top, a liquid inlet arranged at the bottom of the tank and a liquid outlet; the gas storage tank is communicated with the oil product storage tank through a gas connecting pipeline on the tank top;
the working liquid storage tank comprises a working liquid outlet arranged at the bottom of the tank and a working liquid inlet arranged in the middle of the tank body;
the inlet and the outlet of the first working liquid pump are respectively communicated with the liquid outlet of the gas storage tank and the liquid inlet of the working liquid storage tank;
and the inlet and the outlet of the second working liquid pump are respectively communicated with the liquid outlet of the working liquid storage tank and the liquid inlet of the gas storage tank.
Further, a thermometer is arranged in the upper space of the gas storage tank. Furthermore, the outer tank wall of the gas storage tank is provided with a plurality of groups of cooling water spray nozzles which are communicated with the cooling water pipe. The multiple groups refer to more than two groups.
The oil product storage tank can be an inner floating roof tank or a vault tank. The oil product storage tank can be a single storage tank or a tank group. The oil product storage tank can be a normal temperature storage tank or a high temperature storage tank.
The gas storage tank is a vault tank. The tank top of the gas storage tank is provided with a temperature and pressure detection instrument, the tank bottom of the gas storage tank is provided with a liquid level detection instrument, and working liquid is stored in the tank.
The working solution storage tank is a vault tank and an inner floating roof tank. The volume of the working liquid storage tank is not less than that of the gas storage tank, and working liquid is stored in the tank. A liquid level detection instrument is arranged in the working liquid storage tank.
In the present invention, the working fluid may be water, diesel oil, hydrogenated tail oil, or the like, and water is preferred.
In a second aspect, the invention provides a method for reducing emission of waste gas from a storage tank, wherein the emission reduction system is applied.
The method comprises the following steps:
when the gas pressure of the oil product storage tank is higher than a first pressure (namely the high value of the exhaust pressure of the storage tank, wherein the high value of the exhaust pressure can be any value in the pressure range of 1-2 kPa), starting a first working liquid pump to discharge the working liquid in the gas storage tank to a working liquid storage tank through the first working liquid pump; the gas in the oil product storage tank enters the gas storage tank through the gas connecting pipe;
when the gas pressure of the oil product storage tank is reduced to a second pressure (namely the exhaust pressure of the storage tank is low, and the exhaust pressure low can be any value in a pressure range of 0.2-0.5 kPa), stopping the first working liquid pump;
when the tank top pressure in the oil product storage tank is lower than a third pressure (namely the low value of the suction pressure of the storage tank, which can be any value in the pressure range of 0-0.2 kPa) and air suction is required, starting a second working liquid pump to enable working liquid in the working liquid storage tank to enter a gas storage tank through the second working liquid pump, increasing the liquid level in the gas storage tank, and discharging waste gas in the gas storage tank into the oil product storage tank to realize air suction;
and when the gas pressure in the oil product storage tank reaches a fourth pressure (namely the air suction pressure of the storage tank is high, and the air suction pressure can be any value in the pressure range of 0.6-1.0 kPa), stopping the second working liquid pump.
Furthermore, when the temperature of the gas in the gas storage tank is higher than 45 ℃, cooling water is sprayed on the wall of the outer tank of the gas storage tank through the cooling water spraying nozzle, so that the temperature of the gas in the gas storage tank is kept lower than the first temperature.
Further, when the gas pressure in the gas storage tank is higher than the high value (1.5-2.0 kPa) of the exhaust pressure of the storage tank, the gas storage tank discharges the waste gas to the waste gas treatment device for treatment through the waste gas discharge pipeline.
In the invention, the technologies of the storage tank top communication, the tank spraying cooling and the like are well known by the technical personnel in the field.
Compared with the prior art, the system and the method for reducing the emission of the waste gas discharged by the storage tank have the following advantages:
1. in the system for reducing the emission of the waste gas discharged by the storage tank, the waste gas emission of the storage tank can be reduced by adjusting the pressure of the storage tank, changing the liquid level of the gas storage tank, cooling the sprayed water outside the gas storage tank and other measures, and when the effective gas storage volume of the gas storage tank is larger than the gas phase space volume of the oil product storage tank, the system can realize no waste gas emission.
2. In the method for reducing the emission of the waste gas discharged by the storage tank, the gas storage tank is adopted to buffer the oil gas, the oil gas emission reduction of the oil product storage tank is realized, the scale of a waste gas treatment device in the tank area can be greatly reduced, and the device investment is saved.
Drawings
FIG. 1 is a schematic diagram of a storage tank emission abatement method and system of the present invention.
In fig. 1: 1-an oil product storage tank, 2-a gas storage tank, 3-a gas communicating pipe, 4-a waste gas discharge pipeline, 5-a first working liquid pump, 6-a second working liquid pump, 7-a working liquid storage tank, 8-a cooling water spray nozzle, 9, 12-a liquid outlet, 10, 11-a liquid inlet, 13, 14-a pressure detection instrument and 15-a temperature detection instrument.
Detailed Description
The following examples further illustrate specific aspects of the present invention, but are not limited to the following examples.
Example 1
As shown in fig. 1, the system for reducing emission of exhaust gas from a storage tank of the present invention includes an oil product storage tank 1, a gas storage tank 2, a working fluid storage tank 7, a first working fluid pump 5, a second working fluid pump 6, and a related detection control instrument. The tank top of the oil product storage tank 1 is communicated with the tank top of the gas storage tank 2 through a gas connecting pipe 3. The tank top of the gas storage tank 2 is provided with a waste gas discharge pipeline 4, and the bottom of the gas storage tank 2 is provided with a liquid outlet 9 and a liquid inlet 10. The bottom and the middle part of the working fluid storage tank 7 are respectively provided with a fluid outlet 12 and a fluid inlet 11. The inlet and outlet of the first working-fluid pump 5 communicate with the fluid outlet 9 of the gas storage tank and the fluid inlet 11 of the working-fluid storage tank, respectively. The inlet and outlet of the second working fluid pump 6 communicate with a liquid outlet 12 of the working fluid storage tank and a liquid inlet 10 of the gas storage tank, respectively.
The tank tops of the oil storage tank and the gas storage tank are provided with pressure detection instruments 13 and 14. A temperature detection instrument 15 is provided in the gas storage tank. Furthermore, the outer tank wall of the gas storage tank is provided with a plurality of groups of cooling water spray nozzles 8, and the cooling water spray nozzles 8 are communicated with the cooling water pipe.
Example 2
With reference to fig. 1, the method for reducing emission of the tank farm exhaust gas according to the present invention comprises the following steps: when the oil storage tank 1 generates waste gas and the tank top pressure is higher than the exhaust pressure (namely the high value of the exhaust pressure of the storage tank, the high value of the exhaust pressure can be any value in the pressure range of 1-2 kPa), the first working liquid pump 5 is started, the liquid level in the gas storage tank 2 is reduced, part of working liquid is conveyed to the working liquid storage tank 7, and the waste gas (oil gas) generated by the oil storage tank 1 enters the gas storage tank 2 through the gas connecting pipe 3. When the tank top pressure of the oil product storage tank 1 is reduced to 0.2-05 kPa, stopping the first working fluid pump 5; when the tank top pressure of the oil product storage tank 1 is lower than 0-0.2 kPa and needs to suck air, the second working liquid pump 6 is started, working liquid in the working liquid storage tank 7 is discharged to the gas storage tank 2, the liquid level in the gas storage tank 2 is increased, and waste gas in the gas storage tank 2 is discharged into the oil product storage tank 1. And when the gas pressure in the oil product storage tank 1 reaches 0.6-1.0 kPa, stopping the second working fluid pump 6. When the temperature of the gas in the gas storage tank 2 is higher than 45 ℃, spraying cooling water on the outer surface of the gas storage tank 2 through a cooling water spraying nozzle 8, and keeping the temperature of the gas in the gas storage tank 2 lower than 45 ℃; when the gas pressure in the gas storage tank 2 is higher than 1.5-2.0 kPa, the gas storage tank 2 discharges the waste gas to the waste gas treatment device for treatment through the waste gas discharge pipe 4 line.

Claims (14)

1. A storage tank emission abatement system, the system comprising:
the oil storage tank comprises a pressure detection instrument arranged on the tank top and a gas connecting pipeline arranged on the tank top;
the gas storage tank comprises a gas connecting pipe arranged on the tank top, a waste gas discharge pipeline arranged on the tank top, a pressure detection instrument arranged on the tank top, a liquid inlet arranged at the bottom of the tank and a liquid outlet; the gas storage tank is communicated with the oil product storage tank through a gas connecting pipeline on the tank top;
the working liquid storage tank comprises a working liquid outlet arranged at the bottom of the tank and a working liquid inlet arranged in the middle of the tank body;
the inlet and the outlet of the first working liquid pump are respectively communicated with the liquid outlet of the gas storage tank and the liquid inlet of the working liquid storage tank;
the inlet and the outlet of the second working liquid pump are respectively communicated with the liquid outlet of the working liquid storage tank and the liquid inlet of the gas storage tank;
wherein, working liquid is stored in the gas storage tank and the working liquid storage tank.
2. The system of claim 1, wherein a thermometer is disposed at an upper portion of the gas storage tank.
3. The system of claim 2, wherein the outer wall of the gas storage tank is provided with a plurality of sets of cooling water spray headers, the cooling water spray headers being in communication with the cooling water pipes.
4. The system of claim 1, wherein the oil storage tank is an internal floating roof tank or a dome tank.
5. The system of claim 1, wherein the oil storage tank is a single storage tank or a group of tanks.
6. The system of claim 1, wherein the gas storage tank is a dome tank.
7. The system of claim 1, wherein the gas storage tank and the working fluid storage tank are provided with level detectors.
8. The system of claim 1, wherein the working fluid storage tank has a volume not less than a volume of the gas storage tank, and the working fluid is stored in the tank.
9. A method for reducing emission of exhaust gas from a storage tank, using the emission reduction system of any one of claims 1 to 9.
10. The method of claim 9, wherein the method comprises the following:
when the gas pressure of the oil product storage tank is higher than the exhaust pressure of the storage tank, starting a first working liquid pump to discharge the working liquid in the gas storage tank to a working liquid storage tank through the first working liquid pump; the gas in the oil product storage tank enters the gas storage tank through the gas connecting pipe;
when the gas pressure of the oil product storage tank is reduced to a low value of the storage tank exhaust pressure, the first working liquid pump is stopped;
when the tank top pressure in the oil product storage tank is lower than the low value of the storage tank suction pressure and the suction is needed, starting a second working liquid pump to enable the working liquid in the working liquid storage tank to enter a gas storage tank through the second working liquid pump, increasing the liquid level in the gas storage tank, and discharging the waste gas in the gas storage tank into the oil product storage tank to realize the suction;
and when the gas pressure in the oil product storage tank reaches the high value of the air suction pressure of the storage tank, stopping the second working liquid pump.
11. The method according to claim 10, wherein the exhaust pressure is high at any value in the pressure range of 1 to 2 kPa; the low value of the exhaust pressure of the storage tank is any value in the pressure range of 0.2-0.5 kPa; the low value of the suction pressure of the storage tank is any value in the pressure range of 0-0.2 kPa; the air suction pressure of the storage tank is 0.6-1.0 kPa.
12. The method of claim 10, wherein when the gas pressure in the gas storage tank is higher than any value of 1.5 to 2.0kPa higher than the tank discharge pressure, the gas storage tank discharges the waste gas through a waste gas discharge line to a waste gas treatment device for treatment.
13. The method of claim 10, wherein the temperature of the gas in the gas storage tank is maintained below the first temperature by spraying cooling water on the wall of the gas storage tank outside the gas storage tank through a cooling water spray head when the temperature of the gas in the gas storage tank is above 45 ℃.
14. The method of claim 10, wherein the working fluid is one of water, diesel fuel, or hydrogenated tail oil.
CN201911229623.5A 2019-12-04 2019-12-04 Storage tank exhaust emission reduction system and method Pending CN112896833A (en)

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Application Number Priority Date Filing Date Title
CN201911229623.5A CN112896833A (en) 2019-12-04 2019-12-04 Storage tank exhaust emission reduction system and method

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Application Number Priority Date Filing Date Title
CN201911229623.5A CN112896833A (en) 2019-12-04 2019-12-04 Storage tank exhaust emission reduction system and method

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Publication Number Publication Date
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101306259A (en) * 2008-01-24 2008-11-19 戴伦华 High-pressure and low-temperature condensing recovery method of volatile organic steam in oil gas
CN102309914A (en) * 2010-07-07 2012-01-11 中国石油化工股份有限公司 Treatment method for stinky waste gas discharged by storage tank
CN103768914A (en) * 2012-10-23 2014-05-07 中国石油化工股份有限公司 Treatment method of dissipative exhaust gas from acidic water storage tank
CN205478198U (en) * 2016-04-10 2016-08-17 万建雄 Liquor pump formula air compressor
CN107353955A (en) * 2017-06-28 2017-11-17 滁州新奥燃气工程有限公司 CNG gas stations blowdown gas recovering device
CN108043062A (en) * 2017-12-06 2018-05-18 陆勇 A kind of processing system of storage tank breathing discharge escaping gas
CN209100273U (en) * 2018-11-30 2019-07-12 寿光市荣晟新材料有限公司 Vacuum pump fluid cyclic utilization system
KR20190090675A (en) * 2018-01-25 2019-08-02 한국조선해양 주식회사 Volatile organic compounds treatment system and ship having the same

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101306259A (en) * 2008-01-24 2008-11-19 戴伦华 High-pressure and low-temperature condensing recovery method of volatile organic steam in oil gas
CN102309914A (en) * 2010-07-07 2012-01-11 中国石油化工股份有限公司 Treatment method for stinky waste gas discharged by storage tank
CN103768914A (en) * 2012-10-23 2014-05-07 中国石油化工股份有限公司 Treatment method of dissipative exhaust gas from acidic water storage tank
CN205478198U (en) * 2016-04-10 2016-08-17 万建雄 Liquor pump formula air compressor
CN107353955A (en) * 2017-06-28 2017-11-17 滁州新奥燃气工程有限公司 CNG gas stations blowdown gas recovering device
CN108043062A (en) * 2017-12-06 2018-05-18 陆勇 A kind of processing system of storage tank breathing discharge escaping gas
KR20190090675A (en) * 2018-01-25 2019-08-02 한국조선해양 주식회사 Volatile organic compounds treatment system and ship having the same
CN209100273U (en) * 2018-11-30 2019-07-12 寿光市荣晟新材料有限公司 Vacuum pump fluid cyclic utilization system

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