CN112874125A - Hot-melt paint decorative panel and preparation method and application thereof - Google Patents

Hot-melt paint decorative panel and preparation method and application thereof Download PDF

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Publication number
CN112874125A
CN112874125A CN202110105786.3A CN202110105786A CN112874125A CN 112874125 A CN112874125 A CN 112874125A CN 202110105786 A CN202110105786 A CN 202110105786A CN 112874125 A CN112874125 A CN 112874125A
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CN
China
Prior art keywords
hot
melt
hot melt
paint
melt paint
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Pending
Application number
CN202110105786.3A
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Chinese (zh)
Inventor
孙洪彦
杨显涛
霍韵辉
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Foshan Shunde Purete Mechanical Co ltd
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Foshan Shunde Purete Mechanical Co ltd
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Application filed by Foshan Shunde Purete Mechanical Co ltd filed Critical Foshan Shunde Purete Mechanical Co ltd
Priority to CN202110105786.3A priority Critical patent/CN112874125A/en
Publication of CN112874125A publication Critical patent/CN112874125A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/16Drying; Softening; Cleaning
    • B32B38/162Cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0004Cutting, tearing or severing, e.g. bursting; Cutter details
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/16Drying; Softening; Cleaning
    • B32B38/164Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/072Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • B32B2037/1215Hot-melt adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/243Coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a hot-melt paint decorative panel and a preparation method and application thereof. The preparation method comprises the following steps: (1) cleaning a base material, rolling polyurethane hot-melt paint on the base material in a rolling way, and drying to obtain a polyurethane hot-melt paint layer; (2) and (3) rolling a polyurethane hot melt adhesive layer with a PUR hot melt adhesive, and then pressing and pasting a surface material in an infrared heat preservation environment to obtain the hot melt adhesive decorative panel. The hot-melt paint belongs to air reaction type polyurethane hot-melt paint, is safe and environment-friendly, has no viscosity, has good filling property, and can effectively fill all conduits and pinholes on a substrate, so that the surface of the substrate is smoother; the preparation method can realize continuous production, and has the advantages of high efficiency, short period, high yield and lower cost.

Description

Hot-melt paint decorative panel and preparation method and application thereof
Technical Field
The invention belongs to the technical field of decorative materials, and particularly relates to a hot-melt paint decorative panel and a preparation method and application thereof.
Background
The current process route of the traditional melamine veneer comprises two steps: 1. adhering melamine paper on the surface of the base material; 2. the surface of the melamine paper is pasted with a high-gloss transparent material. The step 1 comprises three procedures of coating the base material with the triamine glue, pasting the melamine paper and hot-pressing and bonding at high temperature, and the step 2 comprises three procedures of waiting for the melamine paper to be firmly bonded, coating the surface of the melamine paper with the hot melt glue and pasting the highlight transparent PVC/PET surface material. However, the above process has the following disadvantages: because the hot-press bonding generally needs 1 minute, each produced plate needs at least 1 minute to wait, and the high-gloss transparent material can be pasted after the triamine glue is completely cured, so the production period is long; continuous production cannot be realized, and the traditional process has the defects that the steps 1 and 2 are finished by two production lines, so that the efficiency is low; the cost of the melamine paper is high; the roughness of substrate is not high, and melamine paper can reach the effect of veneer, but still can't solve the problem of substrate surface unevenness after having pasted melamine paper, and paste the pursuit to panel veneer effect on the market alone one melamine paper can't be satisfied, so need add highlight plane materiel membrane behind the back and carry out highlight veneer effect, nevertheless because the substrate surface after traditional pasting melamine paper is the unevenness still, does the highlight product and has the flaw easily, orange peel appears easily, the yields is low.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art described above. Therefore, the hot-melt paint decorative panel and the preparation method thereof provided by the invention have the advantages of continuous production, high efficiency, short period, high yield and lower cost.
The invention provides a hot-melt paint decorative panel which comprises a base material, a polyurethane hot-melt paint layer, a PUR hot-melt adhesive layer and a surface material which are sequentially arranged from bottom to top.
In some embodiments of the invention, the face stock is also coated with a protective film. The protective film is preferably PVC protective film with thickness of 60-70 μm.
In some embodiments of the invention, the facestock is a clear color or clear color highlight PVC or PET film. Because the surface of the base material is not prepared after the polyurethane hot-melt paint is coated on the base material, a pure-color or pure-color high-brightness PVC or PET film material needs to be pasted for decoration.
The invention also provides a preparation method of the hot-melt paint decorative panel, which comprises the following steps:
(1) cleaning a base material, rolling polyurethane hot-melt paint on the base material in a rolling way, and drying to obtain a polyurethane hot-melt paint layer;
(2) and rolling a PUR hot melt adhesive on the polyurethane hot melt paint layer, and then pressing and pasting a surface material in an infrared heat preservation environment to obtain the hot melt paint decorative panel.
The base material is cleaned by a dust removing process on the surface of the base material by using a dust remover, so that the adhesion after the glue paint is coated is ensured to have good adhesive force. The polyurethane hot-melt paint is an air reaction type polyurethane hot-melt paint, is safe and environment-friendly, has no viscosity, and has good filling property. The PUR hot melt adhesive is a moisture reaction type polyurethane hot melt adhesive, is safe and environment-friendly, and has good initial viscosity and good adhesive strength. The infrared heat preservation is to prolong the opening time of the glue, which is beneficial to better bonding and the preservation of the initial bonding property of the glue.
In some embodiments of the present invention, the method further comprises a step of rolling the surface of the plate to cover the protective film after the surface material is laminated. The protective film is used for protecting the surface of the product, and the surface of the product cannot be scratched after the product is off-line or in the transportation process.
In some embodiments of the present invention, after the surface material is pressed or the protective film is pressed, the process of trimming and beveling is further included, which is to trim the surface material and the protective film on the surface of the substrate to make the contour of four sides of the product completely consistent with the specification and shape of the substrate, so as to make the product more beautiful.
In some embodiments of the present invention, in the step (1), the roller temperature of the roller coating polyurethane hot melt paint is 120-130 ℃, and the coating weight is 30-40g/m2
In some embodiments of the present invention, in the step (1), the temperature of the drying is 40 to 60 ℃.
In some embodiments of the invention, in the step (2), the temperature of the roller for rolling the PUR hot melt adhesive is 120-130 ℃, and the coating weight is 35-40g/m2
In some embodiments of the invention, in step (2), the temperature of the infrared incubation is in the range of 55-65 ℃.
In some embodiments of the invention, in step (2), the pressing height of the press face material is the thickness of the sheet minus 0.3-0.5 mm.
In some embodiments of the invention, when the facestock is a patch, the step of pressing the facestock is: firstly, pasting the sheet and then rolling the sheet. When the surface material is a coiled material, the step of pressing and pasting the surface material is as follows: the coiled material is directly pressed on the plate by a roller press. No matter the sheet material or the coiled material is pasted, rolling and pressing can be carried out, so that the bonding effect is more compact and firm.
The invention also provides application of the hot-melt paint decorative panel in home decoration and buildings.
Has the advantages that:
1. the hot-melt paint disclosed by the invention belongs to air reaction type polyurethane hot-melt paint, is safe and environment-friendly, has no viscosity, has good filling property, can be used for effectively filling all guide tubes and needle holes on a base material, so that the surface of the base material is smoother, and the flatness of a hot-melt paint decorative panel detected by a feeler gauge measuring method reaches 0.02-0.04 mm.
2. The polyurethane hot-melt paint belongs to an environment-friendly quick-drying type, and can be quickly dried 3 seconds after the hot-melt paint is coated by a roller.
3. The production line is directly coated with the PUR hot melt adhesive in the next process after hot melt paint is coated in a roller mode, the traditional melamine paper pasting preparation method is optimized, two production lines are changed into one production line for online production, the melamine paper pasting procedures are reduced, continuous production can be achieved, the efficiency is high, the period is short, the yield is high, and the cost is lower.
Drawings
The invention is further described with reference to the following figures and examples, in which:
FIG. 1 is a schematic flow diagram of a conventional process for the preparation of melamine;
fig. 2 is a schematic flow chart of a method for manufacturing a hot-melt paint decorative panel according to an embodiment of the invention.
Detailed Description
The concept and technical effects of the present invention will be clearly and completely described below in conjunction with the embodiments to fully understand the objects, features and effects of the present invention. It is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments, and those skilled in the art can obtain other embodiments without inventive effort based on the embodiments of the present invention, and all embodiments are within the protection scope of the present invention.
Examples
The embodiment prepares a hot-melt paint decorative panel, and the specific process comprises the following steps:
(1) cleaning the surface of the substrate by using a dust remover;
(2) the spreading machine is used for roller coating the polyurethane hot-melt paint, the used polyurethane hot-melt paint is produced by acrylic adhesive limited company, and the coating weight is 30g/m2The surface temperature of the roller needs to be heated to 120 ℃ for painting, and a one-meter drying tunnel is arranged behind the glue spreader, and the temperature isAfter passing through the drying tunnel, the hot-melt paint is dried at 40 ℃, the surface of the hot-melt paint is not sticky, and the pores of the base material are filled, so that the board surface is smoother;
(3) coating PUR hot melt adhesive on a polyurethane hot melt paint layer by using a glue coating machine, wherein the glue is acrylic polyurethane hot melt adhesive, and the coating weight is 35g/m2The surface temperature of the roller needs to be heated to 120 ℃ for gluing;
(4) an infrared leveling machine with a surface mounting function is used, the infrared heat is preserved at 60 ℃, and a pure-color high-brightness PVC membrane is attached to the plate during discharging;
(5) pressing the plate with the surface material attached by using a roller press, wherein the pressing height is the thickness of the plate minus 0.3mm, so that the surface material and the PUR hot melt adhesive are firmly attached to the plate, and when the wire drawing phenomenon occurs on the plate surface, heating the pressing roller to 120 ℃;
(6) an automatic film laminating and cutting machine is used for laminating a protective film on the surface of a plate to protect the surface effect of the plate, a protective film is attached to the surface of a conventional PVC or PET plane material when a product is manufactured, and the embodiment is to carry out surface protection treatment on plane materials such as wood veneers, fireproof plates, acrylic plates and the like;
(7) and (3) trimming and beveling the board by using a beveling machine, and cutting and trimming the surface material and the protective film on the surface of the board to obtain the hot-melt paint decorative panel.
Comparative example
The comparative example is used for preparing a traditional melamine veneer, and is different from the embodiment in that the roller coating polyurethane hot melt paint is replaced by the melamine paper, and the specific process comprises the following steps:
(1) cleaning the surface of the substrate by using a dust remover;
(2) substrate sizing: coating triamine glue on the surface of the substrate;
(3) pasting paper on a base material: adhering melamine paper on the surface of the base material;
(4) high-temperature hot pressing: the base material after the melamine paper is pasted enters a hot press for high-temperature hot pressing for 1 minute;
(5) the production line 1 for plate material off-line waits for glue solidification, and the production line 2 is changed;
(6) surface cleaning: carrying out line change production on a melamine board (a board with melamine paper stuck on a base material), and cleaning surface dust;
(7) preheating and heating the plate: the melamine board enters a preheating and heating device, and glue is placed on the surface of the base material to be coated on the board for rapid aging in order to make the surface of the base material have temperature;
(8) coating PUR hot melt adhesive on a melamine plate by using a glue coating machine, wherein the glue is acrylic polyurethane hot melt adhesive, and the coating weight is 35g/m2The surface temperature of the roller needs to be heated to 120 ℃ for gluing;
(9) an infrared leveling machine with a surface mounting function is used, the infrared heat is preserved at 60 ℃, and a pure-color high-brightness PVC membrane is attached to the plate during discharging;
(10) pressing the plate with the surface material attached by using a roller press, wherein the pressing height is the thickness of the plate minus 0.3mm, so that the surface material and the PUR hot melt adhesive are firmly attached to the melamine board;
(11) coating a protective film on the surface of the plate by using an automatic film coating and cutting machine to protect the surface effect of the plate;
(12) and (3) trimming and beveling the board by using a beveling machine, and cutting and trimming the surface material and the protective film on the surface of the board to obtain the melamine veneer.
The cost, production efficiency and flatness of the product of the examples and comparative examples are compared as shown in table 1.
TABLE 1
Figure BDA0002917343920000051
As can be seen from Table 1, the embodiment cost is 8-10 yuan/piece, the efficiency is 5-6 sheets/min, the comparative example of the traditional process is 2-3 sheets per minute in the period of hot-pressing the melamine paper by the conventional base material, glue curing is carried out after hot pressing, highlight face material pasting decoration is carried out, blanking is needed to be carried out on a flat pasting line again, if the flat pasting line speed is 18m/min, 6-7 sheets are pasted for one minute, the whole process is long, continuous production cannot be carried out, and the process efficiency is higher, the cost is lower, and the flatness is better.
The embodiments of the present invention have been described in detail with reference to the accompanying drawings, but the present invention is not limited to the above embodiments, and various changes can be made within the knowledge of those skilled in the art without departing from the gist of the present invention. Furthermore, the embodiments of the present invention and the features of the embodiments may be combined with each other without conflict.

Claims (10)

1. The hot-melt paint decorative panel is characterized by comprising a base material, a polyurethane hot-melt paint layer, a PUR hot-melt adhesive layer and a surface material which are sequentially arranged from bottom to top.
2. The hot melt painted panel of claim 1 wherein the face stock is further coated with a protective film.
3. The hot melt painted panel of claim 1 wherein the facestock is a clear color or clear color high gloss PVC or PET film.
4. A method of making a hot melt painted panel as claimed in any one of claims 1 to 3, comprising the steps of:
(1) cleaning a base material, rolling polyurethane hot-melt paint on the base material in a rolling way, and drying to obtain a polyurethane hot-melt paint layer;
(2) and rolling a PUR hot melt adhesive on the polyurethane hot melt paint layer, and then pressing and pasting a surface material in an infrared heat preservation environment to obtain the hot melt paint decorative panel.
5. The method according to claim 4, further comprising a step of roll-coating the surface of the sheet with a protective film after the surface material is laminated.
6. The preparation method as claimed in claim 4, wherein in the step (1), the roller temperature of the roller coating polyurethane hot melt paint is 120-130 ℃, and the coating amount is 30-40g/m2
7. The method according to claim 4, wherein the temperature of the drying in the step (1) is 40 to 60 ℃.
8. The preparation method as claimed in claim 4, wherein in step (2), the roll temperature of the roll coating PUR hot melt adhesive is 120-130 ℃, and the coating amount is 35-40g/m2
9. The preparation method according to claim 4, wherein in the step (2), the temperature of the infrared ray heat preservation is 55-65 ℃; in the step (2), the pressing height of the pressing surface material is the thickness of the plate minus 0.3-0.5 mm.
10. Use of the hot melt paint decorative panel according to any one of claims 1 to 3 in home decoration and construction.
CN202110105786.3A 2021-01-26 2021-01-26 Hot-melt paint decorative panel and preparation method and application thereof Pending CN112874125A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050154109A1 (en) * 2004-01-12 2005-07-14 Minyu Li Floor finish with lightening agent
WO2010003960A1 (en) * 2008-07-07 2010-01-14 Klebchemie M. G. Becker Gmbh & Co. Kg Method for laminating high-gloss surfaces
CN102602085A (en) * 2012-03-02 2012-07-25 浙江临亚股份有限公司 Weatherproof flexible veneer and manufacturing method thereof
CN103429357A (en) * 2010-12-20 2013-12-04 粘合化学M.G.贝克尔有限及两合公司 High-gloss surface by means of hot-coating
EP2799155A1 (en) * 2013-05-03 2014-11-05 Klebchemie M.G. Becker GmbH & Co. KG Method for generating of seamless high gloss surfaces as well as objects with such a surface

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050154109A1 (en) * 2004-01-12 2005-07-14 Minyu Li Floor finish with lightening agent
WO2010003960A1 (en) * 2008-07-07 2010-01-14 Klebchemie M. G. Becker Gmbh & Co. Kg Method for laminating high-gloss surfaces
CN103429357A (en) * 2010-12-20 2013-12-04 粘合化学M.G.贝克尔有限及两合公司 High-gloss surface by means of hot-coating
CN102602085A (en) * 2012-03-02 2012-07-25 浙江临亚股份有限公司 Weatherproof flexible veneer and manufacturing method thereof
EP2799155A1 (en) * 2013-05-03 2014-11-05 Klebchemie M.G. Becker GmbH & Co. KG Method for generating of seamless high gloss surfaces as well as objects with such a surface

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Application publication date: 20210601