CN112853648A - Textile cloth ozone finishing method - Google Patents

Textile cloth ozone finishing method Download PDF

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Publication number
CN112853648A
CN112853648A CN202011534241.6A CN202011534241A CN112853648A CN 112853648 A CN112853648 A CN 112853648A CN 202011534241 A CN202011534241 A CN 202011534241A CN 112853648 A CN112853648 A CN 112853648A
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China
Prior art keywords
ozone
finishing
cloth
textile cloth
assembly
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011534241.6A
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Chinese (zh)
Inventor
林金标
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Borgman Jiangsu Textile Technology Co ltd
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Borgman Jiangsu Textile Technology Co ltd
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Priority to CN202011534241.6A priority Critical patent/CN112853648A/en
Publication of CN112853648A publication Critical patent/CN112853648A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/34Driving arrangements of machines or apparatus
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/34Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxygen, ozone or ozonides

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

The invention provides an ozone finishing method for textile cloth, which comprises the following steps: step 1, the textile cloth enters a prewashing device assembly through a cloth feeding device to be prewashed; step 2, the textile cloth enters the ozone finishing assembly from the prewashing device assembly through the traction of the ozone finishing assembly; step 3, the ozone production device continuously supplies ozone gas to the ozone finishing assembly, and the textile cloth of the ozone finishing assembly is subjected to ozone finishing; step 4, the textile cloth enters the washing device assembly from the ozone finishing assembly to be washed through the traction of the washing device assembly; and 5, under the traction of the cloth discharging device, the washed textile cloth enters the cloth discharging device to be discharged and arranged. According to the ozone finishing method, the textile cloth enters the ozone finishing assembly for ozone finishing, so that a rinsing mode of adopting a water washing matching preparation in the traditional technology is replaced, a large amount of rinsing water is saved, and meanwhile, the discharge of a large amount of textile wastewater is reduced; the process flow of weaving the cloth is simplified.

Description

Textile cloth ozone finishing method
Technical Field
The invention relates to the technical field of textile printing and dyeing, in particular to an ozone finishing method for textile cloth.
Background
The traditional textile cloth pretreatment is mainly completed by the treatment steps of desizing, scouring, bleaching, printing and washing, and the like, in the treatment process, a large amount of water and auxiliaries are needed to be consumed, so that a large amount of textile printing and dyeing wastewater is generated, has the characteristics of large water volume, high organic pollutant content, high alkalinity, large water quality change and the like, belongs to one of industrial wastewater difficult to treat, and contains dye, sizing agent, auxiliaries, oil agent, acid and alkali, fiber impurities, sand substances, inorganic salt and the like. The main methods for treating the printing and dyeing wastewater comprise a physical and chemical method, a biochemical method, a chemical method and a treatment method combining a plurality of processes, and the pretreatment in the wastewater treatment is mainly to improve the quality of the wastewater, remove suspended matters and impurities capable of directly settling, adjust the quality and quantity of the wastewater, reduce the temperature of the wastewater and the like, improve the overall effect of the wastewater treatment and ensure the stability of the whole treatment system, so the pretreatment has an extremely important position in the printing and dyeing wastewater treatment, and the actual treatment process often has the condition that the wastewater treatment is not complete, which causes the problems of environmental pollution and water pollution.
For example, chinese patent application No. CN201310568434.7 discloses a new environment-friendly rinsing process for knitted fabric, which specifically includes the following steps:
(1) the process flow of the cylinder grey cloth continuous pretreatment process is as follows: the method comprises the following steps of circular-cylinder knitting wool grey cloth → sewing machine seam joint → stripping and scutching → padding penetrant, degreasing agent, chelating agent → entering a stacking box for reaction → warm water washing → padding oxygen bleaching agent → steaming in a steaming box → hot water washing five grooves → padding softener (whitening product) and squeezing → cloth discharging → dyeing;
(2) the process flow of the continuous washing post-treatment of the dyed cylindrical gray fabric comprises the following steps: the dyed grey cloth → the washing in the dyeing machine once → the machine is discharged → the machine enters a continuous cylinder inflation open width washing machine → the warm water washing (acid neutralization) → hot water washing → soaping → color fixing → softening → squeezing → drying;
(3) designing a mercerizing process route of cylindrical gray fabric: mercerizing grey cloth: cylindrical grey cloth → cylindrical mercerizing → hot water washing → acid neutralization → water washing → oxygen bleaching in a continuous oxygen bleaching production line → dyeing → continuous water washing post-treatment;
(4) cutting open width and warp knitting product basic process route: the method comprises the steps of slitting open-width knitted grey cloth, warp-knitted grey cloth → presetting (ammonia-containing knitted grey cloth) → slitting open-width continuous oxygen bleaching production line oxygen bleaching.
In the actual application process of the prior art, a large amount of water is consumed and a large amount of auxiliaries are used in the rinsing process of knitted fabrics, so that a large amount of water is wasted, and the problems of environmental pollution and water pollution are easily caused.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide the textile cloth ozone finishing method, the textile cloth is treated in an ozone finishing mode, the processes of desizing, bleaching, washing, neutralizing and the like in the traditional process are replaced, the effect of saving a large amount of water is achieved, no auxiliary agent is added in the ozone finishing process, the pollution to the environment and water is reduced, and the process flow is simplified.
In order to solve the technical problems, the invention adopts the following technical scheme:
the invention provides an ozone finishing method for textile cloth, which comprises the following steps:
step 1, the textile cloth enters a prewashing device assembly through a cloth feeding device to be prewashed;
step 2, the textile cloth enters the ozone finishing assembly from the prewashing device assembly through the traction of the ozone finishing assembly;
step 3, the ozone production device continuously supplies ozone gas to the ozone finishing assembly, and the textile cloth of the ozone finishing assembly is subjected to ozone finishing;
step 4, the textile cloth enters the washing device assembly from the ozone finishing assembly to be washed through the traction of the washing device assembly;
and 5, under the traction of the cloth discharging device, the washed textile cloth enters the cloth discharging device to be discharged and arranged.
Preferably, a step of drying the textile cloth is included between the step 4 and the step 5.
Further, step 2 comprises:
step 2.1, the textile cloth is soaked in water and is rolled to remove water after passing through a water inlet water seal roller and a water seal groove padder;
step 2.2, the textile cloth is subjected to cloth scutching through a scutching roller;
step 2.3, the textile cloth is fully soaked by ozone after passing through the cloth conveying roller group;
and 2.4, outputting the textile cloth from the ozone finishing assembly through a cloth discharging water seal roller.
Further, in step 2.1, the textile cloth enters a water seal roller and a water seal groove padder after being subjected to prewashing and swelling treatment.
Further, step 3 comprises:
step 3.1, compressing the air;
step 3.2, filtering the compressed air and treating the compressed air by a dry cooling machine to generate mixed gas with the oxygen content of 93 percent;
3.3, conveying the mixed gas into a discharge type ozone generator to generate ozone gas;
and 3.4, inputting the ozone gas into an ozone finishing assembly to treat the textile cloth.
Further, in step 3, after the ozone finishing assembly is shut down, the tail gas treatment of ozone is carried out by filtering, destroying and eliminating reduction modes on part of ozone left in the ozone finishing assembly box body.
Preferably, step 3 further comprises controlling the circulation speed and concentration of the gas flow of ozone gas in the ozone finishing assembly.
Preferably, in step 3, the concentration of ozone is adjusted according to the gram weight of the cloth, the process requirements and the vehicle speed.
Further, the concentration of ozone is 0-70 g/m 3.
Further, in step 1, a drum-shaped prewashing device is adopted in the prewashing device assembly.
Preferably, step 2.3 further comprises the step of tensioning the textile piece goods on the set of piece goods feed rollers.
Compared with the prior art, the invention has the beneficial effects that:
1. according to the textile cloth ozone finishing method, the textile cloth enters the ozone finishing assembly for ozone finishing, a rinsing mode that a water washing matched preparation is adopted in the traditional technology is replaced, a large amount of rinsing water is saved, and meanwhile, the discharge of a large amount of textile wastewater is reduced; the process flow of weaving the cloth is simplified;
2. according to the ozone finishing method for the textile cloth, the textile cloth is conveyed in the conveying roller set, so that the conveying speed of the textile cloth in conveying is convenient to adjust, and the textile cloth can be ensured to be fully contacted with ozone;
3. according to the textile cloth ozone finishing method, the treatment effect of ozone on textile cloth is better by controlling the airflow circulation speed and the concentration of ozone gas in the ozone finishing assembly;
4. according to the textile cloth ozone finishing method, the drum-shaped prewashing device is used for prewashing the textile cloth, so that the prewashing effect is better, and the subsequent ozone finishing is convenient.
Detailed Description
In order that the above objects, features and advantages of the present invention may be more clearly understood, the present invention is described in further detail below with reference to specific embodiments, it should be noted that the embodiments and features of the embodiments of the present application may be combined with each other without conflict.
Example 1
The textile cloth ozone finishing method comprises the following steps:
step 1, the textile cloth enters a prewashing device assembly through a cloth feeding device to be prewashed;
step 2, the textile cloth enters the ozone finishing assembly from the prewashing device assembly through the traction of the ozone finishing assembly;
step 3, the ozone production device continuously supplies ozone gas to the ozone finishing assembly, and the textile cloth of the ozone finishing assembly is subjected to ozone finishing;
step 4, the textile cloth enters the washing device assembly from the ozone finishing assembly to be washed through the traction of the washing device assembly;
and 5, under the traction of the cloth discharging device, the washed textile cloth enters the cloth discharging device to be discharged and arranged.
In step 1 of the above example, the effect of the prewash was: cleaning some water-soluble dirt on the surface of the cloth in the early stage, soaking the cloth simultaneously to enable the dirt to be puffed, so that the ozone finishing in the later stage is more sufficient, and the finishing efficiency is higher;
in the practical application process, control parameters such as pressure and temperature in the prewashing tank body need to be controlled, when the pressure is normal pressure and the water temperature is 35-45 ℃, the cloth soaking effect is better, and dirt is more thoroughly puffed;
it should be noted that, as the pre-washing proceeds, the concentration of the water-soluble dirt in the water increases, in order to control the concentration of the water-soluble dirt in the water, the pre-washing wastewater needs to be discharged, and at the same time, new water is supplemented to reduce the concentration of the water-soluble dirt, so as to continuously clean the water-soluble dirt on the surface of the cloth.
In step 1 of the above embodiment, a drum-shaped prewashing device is adopted in the prewashing device assembly, the upper row of the drum-shaped prewashing device is all active smooth rollers, the lower row of the drum-shaped prewashing device is all passive multi-edge rollers, and when the textile cloth passes through the washing tank, the multi-edge rollers rotate in water to generate a beating effect, and beat the coated textile cloth to generate a cleaning effect.
In step 3 of the above embodiment, the concentration of ozone in the ozone finishing assembly is in the range of 0 to 70g/m3The adjustment of the ozone concentration is mainly adjusted according to the actual conditions of the gram weight of the cloth, the process requirement and the vehicle speed, for example, the gram weight of the cloth is relatively heavy, and the ozone concentration is relatively high;
in the ozone arrangement assembly, the pressure is kept at normal pressure, and therefore, a pressure adjusting device is required to be connected between the ozone arrangement assembly and the atmosphere to keep the normal pressure state;
in the ozone finishing assembly, the temperature is kept at normal temperature;
in the practical application process, the ozone concentration in the ozone finishing assembly is set according to specific textile cloth, the ozone concentration detector is adopted to monitor the concentration change of ozone in real time and carry out real-time ozone compensation according to concentration data, for example, the cloth containing amount of the ozone finishing assembly is 50m, two 1kg/h ozone generators are arranged to generate ozone in real time, the output of one ozone generator is constant, the output of the other ozone generator is adjustable, and the adjustment of the ozone concentration is realized through the adjustable ozone generators.
In step 4 of the above embodiment, the water washing in the water washing device assembly functions as: cleaning the product of the reaction of the dirt on the surface of the cloth and the ozone;
in the water washing device assembly, the temperature is controlled to be 25-90 ℃;
in the water washing device assembly, the product obtained after the reaction of the dirt on the surface of the cloth and the ozone is washed in a spraying mode, and the spraying pressure can be adjusted according to the actual spraying removal condition;
in the water washing device assembly, the spraying water is filtered and then circularly sprayed again.
As a modification of the above embodiment, a step of drying the textile piece goods is included between the step 4 and the step 5.
Example 2
The step 2 comprises the following steps:
step 2.1, the textile cloth is soaked in water and is rolled to remove water after passing through a water inlet water seal roller and a water seal groove padder;
step 2.2, the textile cloth is subjected to cloth scutching through a scutching roller;
step 2.3, the textile cloth is fully soaked by ozone after passing through the cloth conveying roller group;
and 2.4, outputting the textile cloth from the ozone finishing assembly through a cloth discharging water seal roller.
In the step 2.1 in the above embodiment, the textile cloth passes through the water inlet sealing roller to be fully soaked; in addition, the water seal roller is also used as a sealing device to prevent ozone from leaking; after the textile cloth passes through a water seal tank padder, rolling off redundant water in the textile cloth, so that ozone can more fully finish the textile cloth;
in step 2.2 of the above embodiment, before the textile cloth passes through the conveying roller group, the textile cloth passes through the high-speed reverse-rotating scutching roller, and the scutching roller enables the textile cloth to be fully opened, so that the problem of edge curling of the elastic cloth is solved, and meanwhile, the processing of the textile cloth by ozone is facilitated;
in step 2.3 of the above embodiment, the textile cloth is hung in the finishing box in a zigzag manner by a large number of cloth guide rollers, so that the textile cloth can be ensured to contact ozone in a larger area in a limited space, the pause time of the cloth in the finishing box is shortened, the effect of increasing the productivity is achieved, and in order to prevent the textile cloth from being excessively oxidized, the ozone concentration in the finishing box and the time of the cloth passing through the box body are adjusted;
in step 2.3 of the above embodiment, the textile cloth on the cloth conveying roller set is tension-adjusted, the cloth conveying roller set comprises a plurality of driving guide rollers and driven guide rollers with the same number as the driving guide rollers, the driving guide rollers are used for providing conveying power for conveying the textile cloth, a pneumatic elastic frame device is arranged between every two adjacent driving guide rollers, when the speed difference is generated between two adjacent driving guide rollers, the pneumatic elastic frame device rotates and swings, thereby relieving the tension change to prevent the textile cloth from wrinkling and further generating the condition of uneven ozone finishing, when the speed difference is overlarge, the pneumatic elastic frame device outputs a signal to the control system, the control system adjusts the driving guide roller with overlarge speed to eliminate the tension, in the actual working process, if the swing angle of the angle gauge on the pneumatic elastic frame device exceeds a set value, the situation is determined as that the speed difference is too large.
Example 3
The step 3 comprises the following steps:
step 3.1, compressing the air;
step 3.2, filtering the compressed air and treating the compressed air by a dry cooling machine to generate mixed gas with the oxygen content of 93 percent;
3.3, conveying the mixed gas into a discharge type ozone generator to generate ozone gas;
and 3.4, inputting the ozone gas into an ozone finishing assembly to treat the textile cloth.
As a preferred mode of the above embodiment, in step 3, after the ozone finishing assembly is shut down, the ozone tail gas treatment is performed by filtering, destroying, and eliminating reduction on part of the ozone left in the ozone finishing assembly box.
As another preferred embodiment of the above embodiment, step 3 further comprises controlling the circulation speed and concentration of the gas flow of ozone gas in the ozone finishing assembly.
In step 3.4 of the above embodiment, the ozone concentration in the ozone arrangement assembly and the ozone delivery pipe is detected simultaneously, and in the process of treating the textile cloth by the ozone arrangement assembly, ozone is continuously consumed, and waste gas is continuously discharged, so that the ozone needs to be supplemented according to the detected ozone concentration in the ozone arrangement assembly, and the ozone inlet valve is controlled according to the ozone concentration in the ozone delivery pipe to adjust the amount of gas supplement, thereby achieving the balance of supplement and consumption.
The above examples are further illustrated by comparing the conventional rinsing process with the ozone finishing process for textile pieces in the above examples.
The traditional rinsing method mainly comprises the modes of cleaning and soaping working washing liquor and washing acid-base waste water, wherein 48 kilograms of water, 1.8 kilograms of steam and a large amount of auxiliaries are consumed when 1 kilogram of textile cloth is produced in the treatment process;
in the embodiment, the traditional technology is replaced by adopting the modes of prewashing, ozone finishing and water washing, and 3-4 kg of water and 0.1-0.2 kg of steam are consumed for producing 1kg of textile cloth in the ozone finishing process, wherein the steam is mainly used for improving the water temperature of prewashing and water washing.
The present invention is not limited to the above-described embodiments, which are described in the specification and illustrated only for illustrating the principle of the present invention, but various changes and modifications may be made within the scope of the present invention as claimed without departing from the spirit and scope of the present invention. The scope of the invention is defined by the appended claims.

Claims (8)

1. An ozone finishing method for textile cloth is characterized by comprising the following steps:
step 1, the textile cloth enters a prewashing device assembly through a cloth feeding device to be prewashed;
step 2, the textile cloth enters the ozone finishing assembly from the prewashing device assembly through the traction of the ozone finishing assembly;
step 3, the ozone production device continuously supplies ozone gas to the ozone finishing assembly, and the textile cloth of the ozone finishing assembly is subjected to ozone finishing;
step 4, the textile cloth enters the washing device assembly from the ozone finishing assembly to be washed through the traction of the washing device assembly;
and 5, under the traction of the cloth discharging device, the washed textile cloth enters the cloth discharging device to be discharged and arranged.
2. The textile piece goods ozone finishing method according to the claim 1, characterized in that, the step of drying the textile piece goods is included between the step 4 and the step 5.
3. The textile cloth ozone finishing method of claim 1, characterized in that step 2 comprises:
step 2.1, the textile cloth is soaked in water and is rolled to remove water after passing through a water inlet water seal roller and a water seal groove padder;
step 2.2, the textile cloth is subjected to cloth scutching through a scutching roller;
step 2.3, the textile cloth is fully soaked by ozone after passing through the cloth conveying roller group;
and 2.4, outputting the textile cloth from the ozone finishing assembly through a cloth discharging water seal roller.
4. The textile cloth ozone finishing method of claim 1, characterized in that step 3 comprises:
step 3.1, compressing the air;
step 3.2, filtering the compressed air and treating the compressed air by a dry cooling machine to generate mixed gas with the oxygen content of 93 percent;
3.3, conveying the mixed gas into a discharge type ozone generator to generate ozone gas;
and 3.4, inputting the ozone gas into an ozone finishing assembly to treat the textile cloth.
5. The textile cloth ozone finishing method according to claim 1, characterized in that in step 3, after the ozone finishing assembly is shut down, the tail gas treatment of ozone is carried out by filtering, destroying and eliminating reduction ways on part of ozone left in the box body of the ozone finishing assembly.
6. The textile cloth piece ozone finishing method of claim 1, further comprising controlling the circulating speed and the concentration of the gas flow of the ozone gas in the ozone finishing assembly in step 3.
7. The textile cloth ozone finishing method of claim 1, characterized in that in the step 1, a drum-shaped prewashing device is included in the prewashing device assembly.
8. The textile piece goods ozone finishing method of claim 3, characterized in that in the step 2.3, the method further comprises the step of adjusting the tension of the textile piece goods on the piece goods conveying roller group.
CN202011534241.6A 2020-12-22 2020-12-22 Textile cloth ozone finishing method Pending CN112853648A (en)

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Application Number Priority Date Filing Date Title
CN202011534241.6A CN112853648A (en) 2020-12-22 2020-12-22 Textile cloth ozone finishing method

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Application Number Priority Date Filing Date Title
CN202011534241.6A CN112853648A (en) 2020-12-22 2020-12-22 Textile cloth ozone finishing method

Publications (1)

Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113322694A (en) * 2021-07-09 2021-08-31 东华大学 Pre-oxidation treatment method for cellulose-based textile active oxygen gradient fibril voids

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CN103215775A (en) * 2013-04-12 2013-07-24 王林伟 Ozone bleaching device and method
CN106661793A (en) * 2014-04-24 2017-05-10 广典制造公司 Methods and systems for bleaching textiles
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CN208884142U (en) * 2018-07-30 2019-05-21 上海森浩机械科技有限公司 Denim loose colour removes system
CN209353094U (en) * 2018-10-08 2019-09-06 诺唯格机械制造(江苏)有限公司 A kind of vibration drum device
WO2020025840A1 (en) * 2018-07-30 2020-02-06 Jeanologia, S. L. System and method for treating textile material with ozone
EP3718576A2 (en) * 2019-04-05 2020-10-07 Icos Pharma S.p.A. Method to treat loose objects

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101415874A (en) * 2007-02-27 2009-04-22 青野茂则 Process for producing bleached fiber product, apparatus for use therein, and thus obtained bleached fiber product
CN103215775A (en) * 2013-04-12 2013-07-24 王林伟 Ozone bleaching device and method
CN106661793A (en) * 2014-04-24 2017-05-10 广典制造公司 Methods and systems for bleaching textiles
CN208884142U (en) * 2018-07-30 2019-05-21 上海森浩机械科技有限公司 Denim loose colour removes system
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CN108950949A (en) * 2018-09-30 2018-12-07 嘉兴市吉荣纺织品有限公司 A kind of ultrasonic ozone habilimentation machine
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EP3718576A2 (en) * 2019-04-05 2020-10-07 Icos Pharma S.p.A. Method to treat loose objects

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113322694A (en) * 2021-07-09 2021-08-31 东华大学 Pre-oxidation treatment method for cellulose-based textile active oxygen gradient fibril voids

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