CN112831229A - Multifunctional environment-friendly exterior wall paint - Google Patents
Multifunctional environment-friendly exterior wall paint Download PDFInfo
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- CN112831229A CN112831229A CN202110132882.7A CN202110132882A CN112831229A CN 112831229 A CN112831229 A CN 112831229A CN 202110132882 A CN202110132882 A CN 202110132882A CN 112831229 A CN112831229 A CN 112831229A
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- silicon oxide
- artificial zeolite
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a multifunctional environment-friendly exterior wall paint, and relates to the technical field of building materials. The multifunctional environment-friendly exterior wall paint comprises the following raw materials: 44 to 59 percent of water, 0.5 to 1 percent of quartz sand, 2.3 to 3.2 percent of epoxy resin, 20 to 24 percent of superfine calcium bicarbonate, 3.5 to 5 percent of barium sulfate, 2.5 to 3.5 percent of calcined kaolin, 6.5 to 10 percent of styrene-acrylic emulsion, 5 to 6.5 percent of silicon dioxide colloid solution, 1.4 to 2.5 percent of ethylene glycol, 4.5 to 5.5 percent of calcium carbonate, 5 to 6 percent of silicon oxide, 3 to 4 percent of artificial zeolite, 2.5 to 3 percent of titanium dioxide, 0.2 to 0.4 percent of smoothing agent, wetting agent and defoaming agent and 0.08 to 1 percent of PH regulator. The artificial zeolite replaces H + ions generated by the moss blastospores, so that the H + ions generated by the moss blastospores cannot react with the wall, the nutrient source of the moss blastospores is eliminated, the moss blastospores have no nutrients to grow, the high water absorption characteristics of calcium carbonate and silicon oxide eliminate the germination environment of the moss blastospores, the moss blastospores are prevented from growing too harshly on the wall, the attractiveness of the wall is influenced, and the artificial zeolite wall is worthy of great popularization.
Description
Technical Field
The invention relates to the technical field of building materials, in particular to a multifunctional environment-friendly exterior wall paint.
Background
The multifunctional environment-friendly exterior wall paint belongs to a building material, is usually used in a decoration stage, and can be waterproof, crack-resistant, environment-friendly, odorless and colorful.
After the house is used for many years, moss blastospores are attached to corners of shady and cool backlight, after the moss blastocysts fly to be adhered to a wet wall, the roots of the moss blastocysts can secrete a trace amount of H + ions, the H + ions can convert metal ions in minerals to become nutrients of the Zhang Sheng moss, the moss is in a sponge shape and absorbs moisture on the surface of the wall for a long time, so that the underlying wall is wetted for a long time, deterioration, color change and wet and slippery are caused, when the moss gradually grows and spreads, the water-retaining property of the wall is gradually increased, the H + ions are converted, organic matters generate carbonic acid, humic acid and various organic acids, a colloidal clay film is generated on the surface to damage the surface of the wall, and the attractiveness of the wall is influenced.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a multifunctional environment-friendly exterior wall paint, which solves the problem of moss growth on exterior walls.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: a multifunctional environment-friendly exterior wall paint comprises the following raw materials: 44 to 59 percent of water, 0.5 to 1 percent of quartz sand, 2.3 to 3.2 percent of epoxy resin, 20 to 24 percent of superfine calcium bicarbonate, 3.5 to 5 percent of barium sulfate, 2.5 to 3.5 percent of calcined kaolin, 6.5 to 10 percent of styrene-acrylic emulsion, 5 to 6.5 percent of silicon dioxide colloid solution, 1.4 to 2.5 percent of ethylene glycol, 4.5 to 5.5 percent of calcium carbonate, 5 to 6 percent of silicon oxide, 3 to 4 percent of artificial zeolite, 2.5 to 3 percent of titanium dioxide, 0.2 to 0.4 percent of smoothing agent, wetting agent and defoaming agent and 0.08 to 1 percent of PH regulator.
A multifunctional environment-friendly exterior wall paint comprises the following preparation steps:
s1, adding 35-40% of water into a stirrer, then sequentially adding 0.5-1% of quartz sand, 22-27% of superfine calcium bicarbonate, 3.5-5% of barium sulfate, 2.5-3.5% of calcined kaolin and 2.5-3% of titanium dioxide, and stirring for 15-30 min;
s2, pumping the uniformly stirred water, quartz sand, superfine calcium bicarbonate, barium sulfate, calcined kaolin and titanium dioxide into a dispersing and grinding tank, and dispersing and grinding for 2-4 times, wherein each time lasts for 40-50 min;
s3, filtering the water, the quartz sand, the superfine calcium bicarbonate, the barium sulfate, the calcined kaolin and the titanium dioxide which are subjected to membrane grinding through a screen mesh, wherein the aperture of the screen mesh is 250-mesh and 300-mesh;
s4, adding 5-6.5% of silica colloid solution into 2.3-3.2% of epoxy resin, and stirring for 20-30min to enable the epoxy resin to be riveted on the surface of the silica;
s5, dripping 0.06% -0.08% of a PH regulator into the mixture of the epoxy resin and the silica colloid solution to enable the PH value to be between 8 and 9;
s6, mixing the ground raw materials with the mixed emulsion with the adjusted pH value, and fully stirring for 30-45 min;
s7, adding 6.5-11% of styrene-acrylic emulsion into the mixed substance in the S6, and fully stirring for 10-15 min;
s8, adding 9-10% of water into the stirrer, then sequentially adding 3-4% of artificial zeolite, 4.5-5.5% of calcium carbonate and 5-6% of silicon oxide, and stirring for 15-20 min;
s9, pumping the stirred water, the artificial zeolite, the calcium carbonate and the silicon oxide into a dispersion grinding tank, and carrying out dispersion grinding for 2-4 times, wherein each time lasts for 40-50 min;
s10, filtering the ground water, the artificial zeolite, the calcium carbonate and the silicon oxide through a screen mesh, wherein the aperture of the screen mesh is 200-300 meshes;
s11, adding 1.4-2.5% of glycol into the filtered water, the artificial zeolite, the calcium carbonate and the silicon oxide, and stirring for 15-20 min;
s12, mixing the mixture obtained in the S7 and the S11, adding a smoothing agent, a lubricant and a defoaming agent which account for 0.2-0.4% of the total amount, and then stirring for 1.5-2 h;
s13, sealing and canning.
(III) advantageous effects
The invention provides a multifunctional environment-friendly exterior wall paint. The method has the following beneficial effects:
1. according to the invention, the artificial zeolite is added in the multifunctional exterior wall paint, and the artificial zeolite replaces H + ions, so that H + can not generate replacement reaction on a wall, moss blastospores can not grow without nutrients, and calcium carbonate and silicon oxide are added, and have the characteristic of high water absorption, so that the wall is kept dry, the roots of the moss blastospores are reduced to secrete H + ions, the moss is prevented from growing on the surface of the wall, the attractiveness of the wall is kept, and the multifunctional exterior wall paint is worthy of great popularization.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the embodiment of the invention provides a multifunctional environment-friendly exterior wall paint which comprises the following raw materials: 44 to 59 percent of water, 0.5 to 1 percent of quartz sand, 2.3 to 3.2 percent of epoxy resin, 20 to 24 percent of superfine calcium bicarbonate, 3.5 to 5 percent of barium sulfate, 2.5 to 3.5 percent of calcined kaolin, 6.5 to 10 percent of styrene-acrylic emulsion, 5 to 6.5 percent of silicon dioxide colloid solution, 1.4 to 2.5 percent of ethylene glycol, 4.5 to 5.5 percent of calcium carbonate, 5 to 6 percent of silicon oxide, 3 to 4 percent of artificial zeolite, 2.5 to 3 percent of titanium dioxide, 0.2 to 0.4 percent of smoothing agent, wetting agent and defoaming agent and 0.08 to 1 percent of PH regulator.
Example two:
the embodiment of the invention provides a multifunctional environment-friendly exterior wall paint which comprises the following preparation steps:
s1, adding 40% of water into a stirrer, then sequentially adding 0.5% of quartz sand, 22% of superfine calcium bicarbonate, 3.5% of barium sulfate, 2.5% of calcined kaolin and 2.5% of titanium dioxide, and stirring for 15 min;
s2, pumping the uniformly stirred water, quartz sand, superfine calcium bicarbonate, barium sulfate, calcined kaolin and titanium dioxide into a dispersing and grinding tank, and dispersing and grinding for 2 times, wherein each time lasts for 50 min;
s3, filtering the water, the quartz sand, the superfine calcium bicarbonate, the barium sulfate, the calcined kaolin and the titanium dioxide which are subjected to membrane grinding through a screen mesh, wherein the aperture of the screen mesh is 250-mesh and 300-mesh;
s4, adding 5% of silicon dioxide colloidal solution into 3.2% of epoxy resin, and stirring for 20min to enable the epoxy resin to be riveted on the surface of the silicon dioxide;
s5, dropwise adding 0.06% of PH regulator into the mixture of the epoxy resin and the silica colloid solution to enable the PH value to be between 8 and 9;
s6, mixing the ground raw materials with the mixed emulsion with the adjusted pH value, and fully stirring for 30 min;
s7, adding 11% of styrene-acrylic emulsion into the mixed species in the S6, and fully stirring for 10-15 min;
s8, adding 10% of water into the stirrer, then sequentially adding 3% of artificial zeolite, 4.5% of calcium carbonate and 5% of silicon oxide, and stirring for 15 min;
s9, pumping the stirred water, the artificial zeolite, the calcium carbonate and the silicon oxide into a dispersion grinding tank, and dispersing and grinding for 2 times, 5 times
0min;
S10, filtering the ground water, the artificial zeolite, the calcium carbonate and the silicon oxide through a screen mesh, wherein the aperture of the screen mesh is 200-300 meshes;
s11, adding 2.5% of glycol into the filtered water, the artificial zeolite, the calcium carbonate and the silicon oxide, and stirring for 15 min;
s12, mixing the mixture obtained in the S7 and the S11, adding a smoothing agent, a lubricant and a defoaming agent which account for 0.2 percent of the total amount, and then stirring for 1.5 hours;
s13, sealing and canning.
Example three:
the embodiment of the invention provides a multifunctional environment-friendly exterior wall paint which comprises the following preparation steps:
s1, adding 36% of water into a stirrer, then sequentially adding 1% of quartz sand, 27% of superfine calcium bicarbonate, 5% of barium sulfate, 3.5% of calcined kaolin and 3% of titanium dioxide, and stirring for 30 min;
s2, pumping the uniformly stirred water, quartz sand, superfine calcium bicarbonate, barium sulfate, calcined kaolin and titanium dioxide into a dispersing and grinding tank, and dispersing and grinding for 4 times, wherein each time lasts for 40 min;
s3, filtering the water, the quartz sand, the superfine calcium bicarbonate, the barium sulfate, the calcined kaolin and the titanium dioxide which are subjected to membrane grinding through a screen mesh, wherein the aperture of the screen mesh is 250-mesh and 300-mesh;
s4, adding 6.5% of silicon dioxide colloidal solution into 2.3% of epoxy resin, and stirring for 30min to enable the epoxy resin to be riveted on the surface of the silicon dioxide;
s5, dropwise adding a 0.08% PH regulator into the mixture of the epoxy resin and the silica colloid solution to enable the PH value to be between 8 and 9;
s6, mixing the ground raw materials with the mixed emulsion with the adjusted pH value, and fully stirring for 45 min;
s7, adding 6.5% of styrene-acrylic emulsion into the mixed substance in the S6, and fully stirring for 10-15 min;
s8, adding 9% of water into the stirrer, then sequentially adding 4% of artificial zeolite, 5.5% of calcium carbonate and 6% of silicon oxide, and stirring for 20 min;
s9, pumping the stirred water, the artificial zeolite, the calcium carbonate and the silicon oxide into a dispersion grinding tank, and performing dispersion grinding for 4 times, wherein each time lasts for 40 min;
s10, filtering the ground water, the artificial zeolite, the calcium carbonate and the silicon oxide through a screen mesh, wherein the aperture of the screen mesh is 200-300 meshes;
s11, adding 1.4% of glycol into the filtered water, the artificial zeolite, the calcium carbonate and the silicon oxide, and stirring for 20 min;
s12, mixing the mixture obtained in the S7 and the S11, adding a smoothing agent, a lubricant and a defoaming agent which account for 0.4 percent of the total amount, and then stirring for 2 hours;
s13, sealing and canning.
Example four:
the embodiment of the invention provides a multifunctional environment-friendly exterior wall paint which comprises the following preparation steps:
s1, adding 38% of water into a stirrer, then sequentially adding 8% of quartz sand, 25% of superfine calcium bicarbonate, 4.2% of barium sulfate, 3% of calcined kaolin and 2.7% of titanium dioxide, and stirring for 15-30 min;
s2, pumping the uniformly stirred water, quartz sand, superfine calcium bicarbonate, barium sulfate, calcined kaolin and titanium dioxide into a dispersing and grinding tank, and dispersing and grinding for 3 times, wherein each time lasts for 45 inches;
s3, filtering the water, the quartz sand, the superfine calcium bicarbonate, the barium sulfate, the calcined kaolin and the titanium dioxide which are subjected to membrane grinding through a screen mesh, wherein the aperture of the screen mesh is 250-mesh and 300-mesh;
s4, adding 6.2% of silicon dioxide colloidal solution into 2.6% of epoxy resin, and stirring for 20-30min to enable the epoxy resin to be riveted on the surface of the silicon dioxide;
s5, dropwise adding 0.07% of PH regulator into the mixture of the epoxy resin and the silica colloid solution to enable the PH value to be between 8 and 9;
s6, mixing the ground raw materials with the mixed emulsion with the adjusted pH value, and fully stirring for 40 min;
s7, adding 8% of styrene-acrylic emulsion into the mixed species in the S6, and fully stirring for 12 min;
s8, adding 9.5% of water into the stirrer, then sequentially adding 3.5% of artificial zeolite, 4.5% -5.5% of calcium carbonate and 5.5% of silicon oxide, and stirring for 18 min;
s9, pumping the stirred water, the artificial zeolite, the calcium carbonate and the silicon oxide into a dispersion grinding tank, and performing dispersion grinding for 2-4 times, wherein each time lasts for 45 min;
s10, filtering the ground water, the artificial zeolite, the calcium carbonate and the silicon oxide through a screen mesh, wherein the aperture of the screen mesh is 200-300 meshes;
s11, adding 1.9% of glycol into the filtered water, the artificial zeolite, the calcium carbonate and the silicon oxide, and stirring for 15-20 min;
s12, mixing the mixture obtained in the S7 and the S11, adding a smoothing agent, a lubricant and a defoaming agent which account for 0.3 percent of the total amount, and then stirring for 1.8 hours;
s13, sealing and canning.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (2)
1. The utility model provides a multi-functional environmental protection exterior wall paint which characterized in that: the method comprises the following raw materials: 44 to 59 percent of water, 0.5 to 1 percent of quartz sand, 2.3 to 3.2 percent of epoxy resin, 20 to 24 percent of superfine calcium bicarbonate, 3.5 to 5 percent of barium sulfate, 2.5 to 3.5 percent of calcined kaolin, 6.5 to 10 percent of styrene-acrylic emulsion, 5 to 6.5 percent of silicon dioxide colloid solution, 1.4 to 2.5 percent of ethylene glycol, 4.5 to 5.5 percent of calcium carbonate, 5 to 6 percent of silicon oxide, 3 to 4 percent of artificial zeolite, 2.5 to 3 percent of titanium dioxide, 0.2 to 0.4 percent of smoothing agent, wetting agent and defoaming agent and 0.08 to 1 percent of PH regulator.
2. The multifunctional environment-friendly exterior wall paint as claimed in claim 1, wherein: the preparation method comprises the following steps:
s1, adding 35-40% of water into a stirrer, then sequentially adding 0.5-1% of quartz sand, 22-27% of superfine calcium bicarbonate, 3.5-5% of barium sulfate, 2.5-3.5% of calcined kaolin and 2.5-3% of titanium dioxide, and stirring for 15-30 min;
s2, pumping the uniformly stirred water, quartz sand, superfine calcium bicarbonate, barium sulfate, calcined kaolin and titanium dioxide into a dispersing and grinding tank, and dispersing and grinding for 2-4 times, wherein each time lasts for 40-50 min;
s3, filtering the water, the quartz sand, the superfine calcium bicarbonate, the barium sulfate, the calcined kaolin and the titanium dioxide which are subjected to membrane grinding through a screen mesh, wherein the aperture of the screen mesh is 250-mesh and 300-mesh;
s4, adding 5-6.5% of silica colloid solution into 2.3-3.2% of epoxy resin, and stirring for 20-30min to enable the epoxy resin to be riveted on the surface of the silica;
s5, dripping 0.06% -0.08% of a PH regulator into the mixture of the epoxy resin and the silica colloid solution to enable the PH value to be between 8 and 9;
s6, mixing the ground raw materials with the mixed emulsion with the adjusted pH value, and fully stirring for 30-45 min;
s7, adding 6.5-11% of styrene-acrylic emulsion into the mixed substance in the S6, and fully stirring for 10-15 min;
s8, adding 9-10% of water into the stirrer, then sequentially adding 3-4% of artificial zeolite, 4.5-5.5% of calcium carbonate and 5-6% of silicon oxide, and stirring for 15-20 min;
s9, pumping the stirred water, the artificial zeolite, the calcium carbonate and the silicon oxide into a dispersion grinding tank, and carrying out dispersion grinding for 2-4 times, wherein each time lasts for 40-50 min;
s10, filtering the ground water, the artificial zeolite, the calcium carbonate and the silicon oxide through a screen mesh, wherein the aperture of the screen mesh is 200-300 meshes;
s11, adding 1.4-2.5% of glycol into the filtered water, the artificial zeolite, the calcium carbonate and the silicon oxide, and stirring for 15-20 min;
s12, mixing the mixture obtained in the S7 and the S11, adding a smoothing agent, a lubricant and a defoaming agent which account for 0.2-0.4% of the total amount, and then stirring for 1.5-2 h;
s13, sealing and canning.
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CN202110132882.7A CN112831229A (en) | 2021-02-01 | 2021-02-01 | Multifunctional environment-friendly exterior wall paint |
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CN202110132882.7A CN112831229A (en) | 2021-02-01 | 2021-02-01 | Multifunctional environment-friendly exterior wall paint |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2103439T3 (en) * | 1992-01-13 | 1997-09-16 | Inst Francais Du Petrole | USE OF AN ANTI-SLIP AND ANTIFUNGAL PRODUCT FOR FLOORS AND FLOOR COATINGS. |
CN106007483A (en) * | 2016-05-13 | 2016-10-12 | 郝飞虎 | Exterior wall coating |
CN106118141A (en) * | 2016-06-20 | 2016-11-16 | 王聚会 | A kind of inorganic polymeric coating with zeolite as adsorbent and preparation method |
CN111747680A (en) * | 2019-03-26 | 2020-10-09 | 沈阳康亿环保科技有限公司 | Preparation method of environment-friendly liquid antibacterial diatom coating |
-
2021
- 2021-02-01 CN CN202110132882.7A patent/CN112831229A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2103439T3 (en) * | 1992-01-13 | 1997-09-16 | Inst Francais Du Petrole | USE OF AN ANTI-SLIP AND ANTIFUNGAL PRODUCT FOR FLOORS AND FLOOR COATINGS. |
CN106007483A (en) * | 2016-05-13 | 2016-10-12 | 郝飞虎 | Exterior wall coating |
CN106118141A (en) * | 2016-06-20 | 2016-11-16 | 王聚会 | A kind of inorganic polymeric coating with zeolite as adsorbent and preparation method |
CN111747680A (en) * | 2019-03-26 | 2020-10-09 | 沈阳康亿环保科技有限公司 | Preparation method of environment-friendly liquid antibacterial diatom coating |
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