CN112812465B - Optical camouflage compatible laser protection material and preparation method and application thereof - Google Patents

Optical camouflage compatible laser protection material and preparation method and application thereof Download PDF

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CN112812465B
CN112812465B CN202011639057.8A CN202011639057A CN112812465B CN 112812465 B CN112812465 B CN 112812465B CN 202011639057 A CN202011639057 A CN 202011639057A CN 112812465 B CN112812465 B CN 112812465B
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laser
mass
protection material
auxiliary agent
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CN112812465A (en
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陶益杰
张朝阳
袁源
郑欣
周建伟
闫佳
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Shanghai Rong Special Equipment Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041Optical brightening agents, organic pigments
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/48Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride

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  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
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Abstract

The invention discloses an optical camouflage compatible laser protection material and a preparation method and application thereof, wherein the novel laser protection material comprises the following components in parts by mass: 0.5-5 parts of laser absorbing material, 40-50 parts of organic solvent, 40-60 parts of transparent resin, 5-30 parts of toning pigment and 0.3-0.5 part of auxiliary agent. The protective material provided by the invention can be compatible with optical camouflage and laser stealth protection, has a wide wavelength range of laser protection, and can meet the protection requirements of laser detection with various different wavelengths; the preparation method of the protective material has simple process, can be used for mass production, can be indirectly used for processing camouflage fibers and the like, and the prepared product can be widely applied to laser reconnaissance prevention, laser eavesdropping prevention, military camouflage and the like.

Description

Optical camouflage compatible laser protection material and preparation method and application thereof
Technical Field
The invention relates to the technical field of camouflage protection, in particular to an optical camouflage compatible laser protection material and a preparation method and application thereof.
Background
With the rapid development of military technology, laser-guided weapons become the leading role of modern information-based combat, and the existing camouflage stealth protection technology does not consider laser protection performance, so that military equipment and fighters are seriously threatened by the laser-guided weapons. How to improve the laser protection technology is also the key point of the development of the military protection technology in the future. It should be noted that, because the reflection of near-infrared light needs to be greatly reduced in laser protection, it is difficult to make the laser protection compatible with optical camouflage, and this difficulty also greatly limits the application of laser protection materials.
At present, the approach for realizing laser stealth protection mainly comprises an appearance laser stealth technology or a laser stealth coating technology, so that the intensity of a target laser reflection signal is weakened. The stealth coating technology has the advantages of obvious effect, simple process, good economy and the like, but still has the problems of insufficient compatibility, poor mechanical property, inconvenience in use and the like.
Disclosure of Invention
The invention provides an optical camouflage compatible laser protection material, and a preparation method and application thereof, which are used for overcoming the defects that the optical camouflage and the laser protection are difficult to be compatible, the wavelength range of the laser protection is narrow, the aging performance is poor, the use is inconvenient and the like in the prior art.
In order to achieve the purpose, the invention provides an optical camouflage compatible laser protection material, which comprises the following components in parts by mass: 0.5-5 parts of laser absorbing material, 40-50 parts of organic solvent, 40-60 parts of transparent resin, 5-30 parts of toning pigment and 0.3-0.5 part of auxiliary agent.
In order to achieve the above object, the present invention further provides a method for preparing the above optical camouflage compatible laser protection material, comprising the following steps:
s1: weighing square phthalocyanine dyes, phthalocyanine dyes and methyl cyanine dyes according to the mass parts, stirring for 3-5 min by using a glass rod, and uniformly mixing to obtain a laser absorbing material;
s2: weighing the dispersing agent, the coupling agent, the ultraviolet aging aid, the light stabilizer and the antioxidant according to the mass parts, stirring for 3-5 min by using a glass rod, and uniformly mixing to obtain a mixed aid;
s3: weighing the laser absorbing material, the organic solvent, the transparent resin, the toning pigment and the auxiliary agent according to the mass parts of 0.5-5, 40-50, 40-60, 5-30 and 0.3-0.5, and sealing and drying the transparent resin at 60 ℃ for 4 hours;
s4: mixing a laser absorption material, an organic solvent, the transparent resin after drying treatment, a toning pigment and an auxiliary agent, stirring for 1-2 hours at a rotating speed of 300-500 r/min, and uniformly mixing to obtain a liquid laser protection material;
s5: and baking the liquid laser protection material at the temperature of 100-120 ℃ for 1-2 hours to obtain the laser protection material.
In order to achieve the purpose, the invention also provides an application of the optical camouflage compatible laser protection film, wherein the laser protection material or the laser protection material prepared by the preparation method is applied to laser reconnaissance prevention, laser eavesdropping prevention and military camouflage.
Compared with the prior art, the invention has the beneficial effects that:
1. the novel laser protection material provided by the invention comprises the following components in parts by mass: 0.5-5 parts of laser absorbing material, 40-50 parts of organic solvent, 40-60 parts of transparent resin, 5-30 parts of toning pigment and 0.3-0.5 part of auxiliary agent. The novel laser protection material has the advantages that the components are controlled, so that the novel laser protection material can effectively absorb laser emitted by weapons with laser wave bands of 810nm, 850nm, 905nm, 980nm and 1064nm, and the absorption coefficients of the laser wave bands of 810nm, 850nm, 905nm, 980nm and 1064nm are above 0.98 by using an ultraviolet/visible/near-infrared spectrophotometer and a Fourier infrared spectrometer, so that the novel laser protection material can effectively cope with the reconnaissance detection of the laser wave bands to achieve the stealth purpose. In addition, the novel laser protection material has an optical camouflage function, and the spectral camouflage performance meets the optical camouflage requirement in GJB 798-90.
2. The preparation method of the novel laser protection material provided by the invention is simple in process, can be used for mass production, has a wide application range of the prepared product, and can be applied to laser reconnaissance prevention, laser eavesdropping prevention, military camouflage and the like.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the structures shown in the drawings without creative efforts.
FIG. 1 is a graph of spectral reflectance of YG1560 yellow-green laser protection film in example 1;
FIG. 2 is a graph of spectral reflectance of a DG0730 dark green laser protection film in example 2;
FIG. 3 is a graph of spectral reflectance of the EG1456 emerald laser protection film of example 3;
FIG. 4 is a spectral reflectance curve of SE2635 sand-soil laser protective film in example 4;
FIG. 5 is a graph of the spectral reflectance of YE2344 loess laser protective film in example 5;
the implementation, functional features and advantages of the objects of the present invention will be further explained with reference to the accompanying drawings.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without inventive step based on the embodiments of the present invention, are within the scope of protection of the present invention.
In addition, the technical solutions in the embodiments of the present invention may be combined with each other, but it must be based on the realization of the technical solutions by those skilled in the art, and when the technical solutions are contradictory to each other or cannot be realized, such a combination of the technical solutions should not be considered to exist, and is not within the protection scope of the present invention.
The drugs/reagents used are all commercially available without specific mention.
The invention provides an optical camouflage compatible laser protection material, which comprises the following components in parts by mass: 0.5-5 parts of laser absorbing material, 40-50 parts of organic solvent, 40-60 parts of transparent resin, 5-30 parts of toning pigment and 0.3-0.5 part of auxiliary agent.
Aiming at the defects of the prior art, the invention provides an optical camouflage compatible laser protection material, which is formed by adding a laser absorption material, optical camouflage pigment, an auxiliary agent and the like into plastic matrixes such as polymethyl methacrylate, polyvinyl chloride, polyethylene terephthalate and the like to form a self-supporting structure. Due to the permeability of the laser absorption material in a visible light wavelength region, the material not only has laser protection effect, but also has optical camouflage and good aging resistance, mechanical property and other properties by adding the optical camouflage pigment and the auxiliary agent. When the material is used, a product made of the material is attached to or covered on the surfaces of equipment and personnel, so that the protection effect can be achieved, and the material can be granulated and spun to prepare cloth fibers with optical and laser camouflage protection functions, so that the cloth integrated camouflage protection effect is achieved.
Preferably, the laser light absorbing material is at least one of a dye of the squaraine type, a dye of the phthalocyanine type, and a dye of the methyl cyanine type. The combination of different laser absorbing materials can obtain laser absorbing effects with different wavelengths.
Preferably, the laser absorption material comprises the following components in parts by mass: 0-20 parts of a squaraine dye, 0-10 parts of a phthalocyanine dye and 0-20 parts of a methyl cyanine dye.
Such as: 20 parts of a squaraine dye, 10 parts of a phthalocyanine dye and 20 parts of a methyl cyanine dye.
Preferably, the organic solvent is at least one of dimethylformamide, n-butyl acetate, xylene and ethanol. These solvents are readily available and have strong versatility and can be applied to a variety of resin systems.
Preferably, the transparent resin substrate is at least one of polypropylene, polyethylene, polyvinyl chloride, polystyrene, polycarbonate, polymethyl methacrylate, polyimide, and polyamide. The transparent resin mainly functions as a base material for fixing the internal pigment and the like.
Preferably, the toning pigment is at least one of phthalocyanine blue, chrome green, permanent red, cobalt blue, permanent yellow, titanium white and carbon black. Different pigments to suit the optical camouflage requirements of the background.
Preferably, the auxiliary agent is at least one of a dispersant, a coupling agent, an ultraviolet aging auxiliary agent, a light stabilizer and an antioxidant. After the addition of the auxiliary agents, the laser pigment is more uniformly dispersed in the transparent resin, and the service life of various devices manufactured by the method can be prolonged to different degrees.
Preferably, the auxiliary agent comprises the following components in parts by mass: 5-30 parts of a dispersing agent, 2-10 parts of a coupling agent, 6-20 parts of an ultraviolet aging aid, 6-20 parts of a light stabilizer and 3-10 parts of an antioxidant.
The invention also provides a preparation method of the novel laser protection material, which comprises the following steps:
s1: weighing square phthalocyanine dyes, phthalocyanine dyes and methyl cyanine dyes according to the mass parts, stirring for 3-5 min by using a glass rod, and uniformly mixing to obtain a laser absorbing material;
s2: weighing the dispersing agent, the coupling agent, the ultraviolet aging aid, the light stabilizer and the antioxidant according to the mass parts, stirring for 3-5 min by using a glass rod, and uniformly mixing to obtain a mixed aid;
s3: weighing the laser absorbing material, the organic solvent, the transparent resin, the color matching pigment and the auxiliary agent according to the mass parts of 0.5-5, 40-50, 40-60, 5-30 and 0.3-0.5, and sealing and drying the transparent resin at 60 ℃ for 4 hours;
s4: mixing a laser absorption material, an organic solvent, transparent resin after drying treatment, a color mixing pigment and an auxiliary agent, stirring at a rotating speed of 300-500 r/min for 1-2 hours, and uniformly mixing to obtain a liquid laser protection material;
s5: baking the liquid laser protection material at the temperature of 100-120 ℃ for 1-2 hours to obtain a laser protection material;
s6: and (3) preparing the laser protection material into a novel laser protection film with the thickness of 0.1-1.0 mm at the mold temperature of 150-180 ℃ by adopting a calendaring molding process.
The invention also provides application of the optical camouflage compatible laser protection material, and the protection film or the protection film prepared by the preparation method is applied to laser reconnaissance prevention, laser eavesdropping prevention and military camouflage.
Example 1
The embodiment provides an optical camouflage compatible laser protection material, and the protection film comprises the following components in parts by mass: 2 parts by mass of laser absorbing material, 50 parts by mass of organic solvent, 50 parts by mass of transparent resin, 10.5 parts by mass of toning pigment and 0.4 part by mass of auxiliary agent.
The invention also provides a preparation method of the laser protection material, which comprises the following steps:
s1: weighing 20 parts by mass of a squaraine dye, 10 parts by mass of a cyanine dye and 20 parts by mass of a methyl cyanine dye, stirring for 3-5 min by using a glass rod, and uniformly mixing to obtain a laser absorbing material;
s2: weighing 30 parts by mass of a dispersing agent, 10 parts by mass of a coupling agent, 20 parts by mass of an ultraviolet aging aid, 20 parts by mass of a light stabilizer and 10 parts by mass of an antioxidant, stirring for 3-5 min by using a glass rod, and uniformly mixing to obtain a mixed aid;
s3: weighing 2 parts by mass of a laser absorbing material, 50 parts by mass of dimethylformamide, 50 parts by mass of transparent polyvinyl chloride, toning pigments (8 parts by mass of chrome green, 2 parts by mass of permanent yellow, 0.2 part by mass of permanent red, 0.2 part by mass of titanium white and 0.1 part by mass of carbon black) and 0.4 part by mass of an auxiliary agent according to the requirement of yellow green YG1560 laser stealth, and sealing and drying the transparent polyvinyl chloride for 4 hours at 60 ℃;
s4: mixing a laser absorption material, dimethylformamide, dried transparent polyvinyl chloride, a toning pigment and an auxiliary agent, stirring at a rotating speed of 400-500 r/min for 1-2 hours, and uniformly mixing to obtain a liquid laser protection material;
s5: baking the liquid laser protection material at the temperature of 100-120 ℃ for 1-2 hours, and drying to obtain a laser protection material;
s6: and (3) preparing the laser protection material into a novel laser protection film with the thickness of 0.5mm at the mold temperature of 150-180 ℃ by adopting a calendaring process.
The laser protective film of the present embodiment was subjected to actual measurement of color difference data and measurement of absorption value of laser band, and the results are shown in table 1.
Example 2
The embodiment provides an optical camouflage compatible laser protection material, and the protection film comprises the following components in parts by mass: 2 parts by mass of laser absorbing material, 50 parts by mass of organic solvent, 40 parts by mass of transparent resin, 18 parts by mass of toning pigment and 0.4 part by mass of auxiliary agent.
The invention also provides a preparation method of the protective film, which comprises the following steps:
s1: the same as example 1;
s2: the same as example 2;
s3: weighing 2 parts by mass of a laser absorbing material, 50 parts by mass of dimethylformamide, 40 parts by mass of transparent polyvinyl chloride, 10 parts by mass of color mixing pigment (chrome green, 4 parts by mass of permanent yellow, 2 parts by mass of permanent red and 2 parts by mass of carbon black) and 0.4 part by mass of auxiliary agent according to the requirement of laser stealth of dark green DG0730, and sealing and drying the transparent polyvinyl chloride at 60 ℃ for 4 hours;
s4: mixing a laser absorption material, dimethylformamide, dried transparent polyvinyl chloride, a toning pigment and an auxiliary agent, stirring at a rotating speed of 400-500 r/min for 1-2 h, and uniformly mixing to obtain a liquid laser protection material;
S5-S6: the same as in example 1.
The laser protective film of the present embodiment was subjected to actual measurement of color difference data and measurement of absorption value of laser band, and the results are shown in table 1.
Example 3
The embodiment provides an optical camouflage compatible laser protection material, and the protection film comprises the following components in parts by mass: 2 parts by mass of laser absorbing material, 50 parts by mass of organic solvent, 40 parts by mass of transparent resin, 11.3 parts by mass of toning pigment and 0.4 part by mass of auxiliary agent.
The invention also provides a preparation method of the protective film, which comprises the following steps:
s1: the same as example 1;
s2: same as example 2
S3: weighing 2 parts by mass of a laser absorbing material, 50 parts by mass of dimethylformamide, 40 parts by mass of transparent polyvinyl chloride, toning pigments (6 parts by mass of chromium green, 1 part by mass of titanium dioxide, 4 parts by mass of permanent yellow and 0.3 part by mass of phthalocyanine blue red) and 0.4 part by mass of an auxiliary agent according to the requirement of emerald EG1456 laser stealth, and sealing and drying the transparent polyvinyl chloride for 4 hours at 60 ℃;
s4: mixing a laser absorption material, dimethylformamide, dried transparent polyvinyl chloride, a toning pigment and an auxiliary agent, stirring at a rotating speed of 400-450 r/min for 1-2 h, and uniformly mixing to obtain a liquid laser protection material;
S5-S6: the same as in example 1.
The laser protective film of the present embodiment was subjected to actual measurement of color difference data and measurement of absorption value of laser band, and the results are shown in table 1.
Example 4
The embodiment provides an optical camouflage compatible laser protective film, which comprises the following components in parts by mass: 2 parts by mass of laser absorbing material, 50 parts by mass of organic solvent, 40 parts by mass of transparent resin, 22.5 parts by mass of toning pigment and 0.4 part by mass of auxiliary agent.
The invention also provides a preparation method of the protective film, which comprises the following steps:
s1: the same as example 1;
s2: same as example 2
S3: weighing 2 parts by mass of a laser absorbing material, 50 parts by mass of dimethylformamide, 40 parts by mass of transparent polyvinyl chloride, toning pigments (15 parts by mass of titanium dioxide, 6 parts by mass of permanent yellow, 1 part by mass of permanent red, 0.4 part by mass of phthalocyanine blue and 0.1 part by mass of carbon black) and 0.4 part by mass of an auxiliary agent according to the requirement of sand color SE2635 on laser stealth, and sealing and drying the transparent polyvinyl chloride for 4 hours at 60 ℃;
s4: mixing a laser absorption material, dimethylformamide, dried transparent polyvinyl chloride, a toning pigment and an auxiliary agent, stirring at a rotating speed of 400-500 r/min for 1-2 h, and uniformly mixing to obtain a liquid laser protection material;
S5-S6: the same as in example 1.
The laser protective film of the present embodiment was subjected to actual measurement of color difference data and measurement of absorption value of laser band, and the results are shown in table 1.
Example 5
The embodiment provides an optical camouflage compatible laser protective film, which comprises the following components in parts by mass: 2 parts by mass of laser absorbing material, 50 parts by mass of organic solvent, 40 parts by mass of transparent resin, 21 parts by mass of toning pigment and 0.4 part by mass of auxiliary agent.
The invention also provides a preparation method of the protective film, which comprises the following steps:
s1: the same as example 1;
s2: the same as example 2;
s3: weighing 2 parts by mass of a laser absorbing material, 50 parts by mass of dimethylformamide, 40 parts by mass of transparent polyvinyl chloride, toning pigment (8 parts by mass of titanium dioxide, 10 parts by mass of permanent yellow, 1.5 parts by mass of permanent red, 1.4 parts by mass of phthalocyanine blue and 0.1 part by mass of carbon black powder) and 0.4 part by mass of an auxiliary agent according to the mass parts, and sealing and drying the transparent polyvinyl chloride at 60 ℃ for 4 hours;
s4: mixing a laser absorption material, dimethylformamide, dried transparent polyvinyl chloride, a toning pigment and an auxiliary agent, stirring at a rotating speed of 400-450 r/min for 1-2 hours, and uniformly mixing to obtain a liquid laser protection material;
S5-S6: the same as in example 1.
The laser protective film of the present embodiment was subjected to actual measurement of color difference data and measurement of absorption value of laser band, and the results are shown in table 1.
Example 6
The embodiment provides an application of an optical camouflage compatible laser protection material, which comprises the following steps:
S1-S4: the same as in example 1.
S5: baking the liquid laser protection material at the temperature of 100-120 ℃ for 1-2 h, and drying to obtain a laser protection material to be melt-spun;
s6: and carrying out melt spinning on the laser protection material to be subjected to melt spinning at the temperature of 200 ℃ to obtain the polyester fiber with laser protection, and spinning the polyester fiber into the fabric with laser protection and optical camouflage.
The laser protection cloth of the embodiment is subjected to actual measurement of color difference data and measurement of laser waveband absorption values, and the results are shown in table 1; meanwhile, the physical properties of the laser protective fabric of this example were measured, and the results are shown in table 2.
And (3) performance detection:
1. spectral reflection tests were performed on the laser protective films prepared in examples 1 to 6, and the results are shown in fig. 1 to 5. The figure shows that the absorptivity of the five laser protective films in the laser wave band between 800 nm and 1100nm reaches more than 80%, particularly the absorptivity of the five laser protective films in the laser wave bands of 810nm, 850nm, 905nm, 980nm and 1064nm is more than 90%, the chromatic aberration meets the national military standard requirement through chromatic aberration calculation according to the tested L, a, b and the like, and the laser protective films have optical camouflage performance, and meanwhile can effectively resist the reconnaissance detection of the laser wave band, so that the stealth purpose is achieved.
TABLE 1 Standard value, actually measured value, chromatic aberration data, and laser band absorption value of cloth of five colors and YG1560 color in examples 1 to 6
Figure BDA0002879444790000111
TABLE 2 physical Properties of the YG1560 colored cloth of example
Figure BDA0002879444790000112
The above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, and all applications of the inventive concept of the present invention include, but are not limited to, the preparation of laser protective film by hot-pressing and calendering, the production of various product accessories by injection molding, and the application of processing techniques such as melt spinning and weaving cloth; the present invention also includes the method of using the same, and the method of using the same to perform the method of the present invention.

Claims (3)

1. The application of the optical camouflage compatible laser protection material is characterized in that the protection material is woven into cloth with laser protection and optical camouflage; the protective material comprises the following components in parts by mass: 0.5-5 parts by mass of a laser absorbing material, 40-50 parts by mass of an organic solvent, 40-60 parts by mass of a transparent resin, 5-30 parts by mass of a toning pigment and 0.3-0.5 part by mass of an auxiliary agent; the organic solvent is dimethylformamide; the transparent resin is polyvinyl chloride;
the laser absorption material comprises, by mass, 20 parts of a squaraine dye, 10 parts of a phthalocyanine dye and 20 parts of a methyl cyanine dye;
the auxiliary agent comprises the following components in parts by mass: 5-30 parts of dispersing agent, 2-10 parts of coupling agent, 6-20 parts of ultraviolet aging auxiliary agent, 6-20 parts of light stabilizer and 3-10 parts of antioxidant.
2. The use of an optically camouflaged compatible laser protective material according to claim 1, wherein the color-adjusting pigment is at least one of phthalocyanine blue, chrome green, permanent red, cobalt blue, permanent yellow, titanium white and carbon black.
3. The use of the optical camouflage compatible laser protection material as recited in claim 1, wherein the method of making the optical camouflage compatible laser protection material comprises the steps of:
s1: weighing square phthalocyanine dyes, phthalocyanine dyes and methyl cyanine dyes according to the mass parts, stirring for 3-5 min by using a glass rod, and uniformly mixing to obtain a laser absorbing material;
s2: weighing the dispersing agent, the coupling agent, the ultraviolet aging aid, the light stabilizer and the antioxidant according to the mass parts, stirring for 3-5 min by using a glass rod, and uniformly mixing to obtain a mixed aid;
s3: weighing the laser absorbing material, the organic solvent, the transparent resin, the color matching pigment and the auxiliary agent according to the mass parts of 0.5-5, 40-50, 40-60, 5-30 and 0.3-0.5, and sealing and drying the transparent resin at 60 ℃ for 4 hours;
s4: mixing a laser absorption material, an organic solvent, transparent resin after drying treatment, a color mixing pigment and an auxiliary agent, stirring at a rotating speed of 300-500 r/min for 1-2 hours, and uniformly mixing to obtain a liquid laser protection material;
s5: and baking the liquid laser protection material at the temperature of 100-120 ℃ for 1-2 hours to obtain the laser protection material.
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