CN112753707A - Weeding composition containing bensulfuron methyl, butachlor and clomazone - Google Patents

Weeding composition containing bensulfuron methyl, butachlor and clomazone Download PDF

Info

Publication number
CN112753707A
CN112753707A CN202110036314.7A CN202110036314A CN112753707A CN 112753707 A CN112753707 A CN 112753707A CN 202110036314 A CN202110036314 A CN 202110036314A CN 112753707 A CN112753707 A CN 112753707A
Authority
CN
China
Prior art keywords
butachlor
clomazone
methyl
bensulfuron
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202110036314.7A
Other languages
Chinese (zh)
Other versions
CN112753707B (en
Inventor
李玉洁
李冰清
李多才
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongtu Chemical Anhui Co ltd
Original Assignee
Zhongtu Chemical Anhui Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhongtu Chemical Anhui Co ltd filed Critical Zhongtu Chemical Anhui Co ltd
Priority to CN202110036314.7A priority Critical patent/CN112753707B/en
Publication of CN112753707A publication Critical patent/CN112753707A/en
Application granted granted Critical
Publication of CN112753707B publication Critical patent/CN112753707B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

Abstract

The invention provides a weeding composition containing bensulfuron-methyl, butachlor and clomazone, wherein the active ingredients comprise the bensulfuron-methyl, the butachlor and the clomazone, and the mass ratio of the bensulfuron-methyl, the butachlor and the clomazone is 1-10:1-30: 1-20. The weeding composition can be used for preventing and removing annual weeds in the paddy field and has obvious synergistic effect.

Description

Weeding composition containing bensulfuron methyl, butachlor and clomazone
Technical Field
The invention belongs to the field of herbicides, and particularly relates to a weeding composition containing bensulfuron methyl, butachlor and clomazone and application thereof.
Background
Bensulfuron-methyl belongs to sulfonylurea systemic conduction selective herbicide, and can prevent and kill annual broad leaf weeds and sedge weeds, such as common burreed rhizome, monochoria vaginalis, rhizoma alismatis, short arrowhead, Japanese eclipta, felt of cattle, potamogeton indica, spirodela tetraphylla, cyperus heterophylla, mozucca pubescens, allium fistulosum linn, pipewort and Chinese cabbage.
Butachlor belongs to amide selective preemergence herbicides, and is mainly absorbed by weed sprouts and young secondary roots to inhibit in-vivo protein synthesis, so that the weed sprouts are enlarged and deformed to finally cause death, and various annual weeds in transplanted paddy fields can be effectively prevented and removed.
Clomazone is a high-efficiency selective pre-emergence herbicide, can inhibit various enzyme activities, prevent chlorophyll from generating, generate albinism to kill, and can prevent and kill various annual gramineous weeds and broadleaf weeds, such as wild oat, barnyard grass, green bristlegrass, amaranthus retroflexus, black nightshade and the like.
After the herbicides are mixed for use, three different combined actions of synergism, addition and antagonism occur, the weeding composition with synergism can effectively reduce the using dosage of active ingredients, slow down the generation of drug resistance of weeds and reduce environmental pollution, and a plurality of domestic pesticide enterprises pay attention to the compounding of medicaments to screen out the weeding composition with excellent synergism for registration. The previous investigation finds that no report is available in the prior art about the compound use of bensulfuron-methyl, butachlor and clomazone.
Disclosure of Invention
The weeding composition containing bensulfuron methyl, butachlor and clomazone and the application thereof have obvious synergistic effect. The specific technical scheme is as follows:
a weeding composition containing bensulfuron-methyl, butachlor and clomazone is characterized in that the mass ratio of the bensulfuron-methyl, the butachlor and the clomazone is 0.1-10:1-30: 1-20.
The weeding composition is characterized in that the mass ratio of the bensulfuron methyl, the butachlor and the clomazone is 0.1-1:5-30: 5-20. The preferable mass ratio of the bensulfuron methyl, the butachlor and the clomazone is 1:5-30: 5-20.
The weeding composition is mixed with common auxiliary materials on pesticides to prepare any preparation suitable for agriculture; the weeding composition is characterized in that the mass percentage of the active ingredients is 1-95%. .
The preparation is dispersible oil suspending agent, suspending emulsion, water dispersible granule, large granule, wettable powder, suspending agent and missible oil.
The weeding composition is used for preventing and removing crop weeds. The crop is rice; the weeds are annual grassy, broad-leaved and sedge weeds.
Compared with the prior art, the invention has the following beneficial effects:
1. the composition of the invention has obvious synergistic effect: when the mass ratio of the bensulfuron methyl to the butachlor to the clomazone is 0.1:5:10, 0.5:5:5, 0.5:15:10, 1.0:15:5, 1.0:30:10 and 1.0:5:20, the composition has a synergistic effect on the barnyard grass; when the mass ratio of the bensulfuron methyl to the butachlor to the clomazone is 0.1:5:10, 0.5:5:5, 0.5:15:10, 1.0:15:5, 1.0:30:10 and 1.0:5:20, the composition has a synergistic effect on the monochoria vaginalis. 2. The composition of the invention can effectively reduce the dosage of active ingredients, slow down the generation of drug resistance of weeds and reduce environmental pollution.
Detailed Description
Example 1: indoor bioassay of barnyard grass by using compound medicament
Testing weeds: barnyard grass.
The test method comprises the following steps: a greenhouse potting method is adopted. The test soil is special soil for the test, and no medicament is applied to the collected soil plots. Filling soil special for the test into a flowerpot; the flowerpot is placed in a basin for containing water, and soil is kept moist by adopting an infiltrating irrigation mode at the bottom of the basin. Sowing 35 barnyard grass seeds in a flowerpot, covering soil of 0.5cm after sowing, and performing soil spraying treatment 24 hours after sowing, wherein the treatment is repeated for 4 times. After treatment, the barnyard grass is placed in a greenhouse for normal management, the growth condition of the barnyard grass is regularly observed, the fresh weight of the overground part of the barnyard grass is weighed after 30 days, and the fresh weight inhibition rate is calculated. The combined effect of the herbicidal compositions was evaluated using the Gowing method.
And (3) testing results:
TABLE 1 indoor bioassay results for barnyard grass with compounded agent
Figure BDA0002893308000000031
Figure BDA0002893308000000041
As can be seen from Table 1, the combination of bensulfuron methyl, butachlor and clomazone exhibited different combined effects on barnyard grass. When the mass ratio of the bensulfuron methyl, the butachlor and the clomazone is 0.5:15:10, 1.0:15:5, 1.0:30:10 and 1.0:5:20, the synergistic effect is shown, and the other mass ratios are additive effects, particularly, when the mass ratio of the bensulfuron methyl, the butachlor and the clomazone is 0.1:5:10, 0.5:5:5 and 0.5:30:20, the E-E0 is more than 9.5, the using dosage of active ingredients can be effectively reduced, and the generation of drug resistance is slowed down.
Example 2: indoor determination of herba monochoriae vaginalis by using compound medicament
Testing weeds: herba Monochoriae; the test method comprises the following steps: reference is made to example 1.
And (4) analyzing results:
TABLE 2 indoor determination of the combination of the agents on the herba Otteliae Alismoidis
Figure BDA0002893308000000051
Figure BDA0002893308000000061
As can be seen from Table 2, the combination of bensulfuron methyl, butachlor and clomazone exhibited different combined effects on Monochoria. When the mass ratio of the bensulfuron methyl, the butachlor and the clomazone is 0.1:5:10, 0.5:5:5, 0.5:15:10, 1.0:15:5, 1.0:30:10 and 1.0:5:20, the synergistic effect is shown, and the other ratios are additive effects, particularly, when the mass ratio of the bensulfuron methyl, the butachlor and the clomazone is 0.1:15:20, 0.1:30:5 and 0.5:30:20, the E-E0 is more than 9.0, the using dosage of active ingredients can be effectively reduced, and the generation of drug resistance is slowed down.
Example 3
42% bensulfuron methyl butachlor clomazone water dispersible granule
2% of bensulfuron-methyl, 30% of butachlor, 10% of clomazone, 6% of polycarboxylate, 8% of calcium lignosulfonate, 3% of urea, 2% of xanthan gum, 1% of sodium carboxymethylcellulose, 2% of white carbon black and 100% of kaolin.
26% bensulfuron methyl butachlor clomazone wettable powder
1% of bensulfuron methyl, 5% of butachlor, 20% of clomazone, 5% of sodium dodecyl benzene sulfonate, 4% of polycarboxylate, 4% of calcium lignosulfonate, 2% of white carbon black and the balance of bentonite to 100%.
10.5% bensulfuron methyl butachlor clomazone missible oil
Bensulfuron-methyl 0.5%, butachlor 5%, clomazone 5%, castor oil polyoxyethylene ether 5%, agricultural milk 5005%, agricultural milk 160110%, methyl oleate make up to 100%.
Example 4 determination of the drug Effect of the compounded agent on weeds in Rice field
Weeds in rice fields: barnyard grass, moleplant seed, herba arthrodii, herba monochoriae vaginalis, rhizoma alismatis, morningglory, and cyperus heterophyllus.
The application method comprises the following steps: 3 drug treatments were set, 1 blank control, repeated 3 times; the area per cell was 20m2, and the random arrangement was made. And (4) carrying out soil spraying treatment by adopting a sprayer. And (5) investigating the weed fresh weight control effect 21d after the application.
And (4) analyzing results: the compound composition of bensulfuron methyl, butachlor and clomazone has good control effect on weeds in rice fields.
Table 3 herbicidal Effect of the compounded preparations on paddy fields
Figure BDA0002893308000000071
Figure BDA0002893308000000081
The foregoing is only a preferred embodiment of the present invention, and it will be apparent to those skilled in the art that modifications may be made without departing from the invention as claimed in the invention and these modifications are within the scope of the invention.

Claims (8)

1. A weeding composition containing bensulfuron-methyl, butachlor and clomazone is characterized in that the mass ratio of the bensulfuron-methyl, the butachlor and the clomazone is 0.1-10:1-30: 1-20.
2. A herbicidal composition according to claim 1, characterized in that the mass ratio of bensulfuron-methyl, butachlor and clomazone is 0.1-1:5-30: 5-20.
3. A herbicidal composition according to claim 1, wherein the mass ratio of bensulfuron methyl, butachlor and clomazone is 1:5-30: 5-20.
4. A herbicidal composition according to any one of claims 1 to 3, characterized in that the active ingredient is present in an amount of 1 to 95% by weight.
5. The weeding composition according to claim 4, wherein the weeding composition is mixed with the common auxiliary materials on the pesticides to prepare any preparation suitable for agriculture.
6. A herbicidal composition according to claim 5, wherein said formulation is a dispersible oil suspension, suspoemulsion, water dispersible granule, macrogranule, wettable powder, suspension, emulsifiable concentrate.
7. Use of the herbicidal composition according to any one of claims 1 to 6 for controlling crop weeds.
8. Use of a herbicidal composition according to claim 7, characterized in that the crop is rice; the weeds are annual grassy, broad-leaved and sedge weeds.
CN202110036314.7A 2021-01-12 2021-01-12 Weeding composition containing bensulfuron methyl, butachlor and clomazone Expired - Fee Related CN112753707B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110036314.7A CN112753707B (en) 2021-01-12 2021-01-12 Weeding composition containing bensulfuron methyl, butachlor and clomazone

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110036314.7A CN112753707B (en) 2021-01-12 2021-01-12 Weeding composition containing bensulfuron methyl, butachlor and clomazone

Publications (2)

Publication Number Publication Date
CN112753707A true CN112753707A (en) 2021-05-07
CN112753707B CN112753707B (en) 2022-08-02

Family

ID=75701612

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110036314.7A Expired - Fee Related CN112753707B (en) 2021-01-12 2021-01-12 Weeding composition containing bensulfuron methyl, butachlor and clomazone

Country Status (1)

Country Link
CN (1) CN112753707B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113197205A (en) * 2021-04-27 2021-08-03 中土化工(安徽)有限公司 Weeding composition containing butachlor, clomazone and bensulfuron methyl
CN115336589A (en) * 2022-08-19 2022-11-15 南通江山农药化工股份有限公司 High-efficiency weeding composition for preventing and removing weeds in paddy fields and preparation thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102845446A (en) * 2011-06-30 2013-01-02 浙江天丰化学有限公司 Herbicidal composition containing bensulfuron methyl and butachlorfor for paddy field
CN104430460A (en) * 2014-12-03 2015-03-25 安徽美兰农业发展股份有限公司 Pyrazosulfuron-ethyl, clomazone and butachlor compound dispersible oil suspension concentrate and preparation method thereof
CN106954631A (en) * 2017-03-02 2017-07-18 安徽金培因科技有限公司 A kind of careless agent of hybrid rice compounding suppression and its production method
CN107027795A (en) * 2017-04-27 2017-08-11 安徽喜洋洋农业科技有限公司 A kind of winter wheat field annual grassy weeds herbicide and its collocation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102845446A (en) * 2011-06-30 2013-01-02 浙江天丰化学有限公司 Herbicidal composition containing bensulfuron methyl and butachlorfor for paddy field
CN104430460A (en) * 2014-12-03 2015-03-25 安徽美兰农业发展股份有限公司 Pyrazosulfuron-ethyl, clomazone and butachlor compound dispersible oil suspension concentrate and preparation method thereof
CN106954631A (en) * 2017-03-02 2017-07-18 安徽金培因科技有限公司 A kind of careless agent of hybrid rice compounding suppression and its production method
CN107027795A (en) * 2017-04-27 2017-08-11 安徽喜洋洋农业科技有限公司 A kind of winter wheat field annual grassy weeds herbicide and its collocation method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113197205A (en) * 2021-04-27 2021-08-03 中土化工(安徽)有限公司 Weeding composition containing butachlor, clomazone and bensulfuron methyl
CN115336589A (en) * 2022-08-19 2022-11-15 南通江山农药化工股份有限公司 High-efficiency weeding composition for preventing and removing weeds in paddy fields and preparation thereof

Also Published As

Publication number Publication date
CN112753707B (en) 2022-08-02

Similar Documents

Publication Publication Date Title
CN112753707B (en) Weeding composition containing bensulfuron methyl, butachlor and clomazone
CN102265861A (en) Mixed herbicide containing bentazone, cyhalofop-butyl and propanil and application thereof
CN113197205B (en) Weeding composition containing butachlor, clomazone and bensulfuron methyl
CN112471154A (en) Weeding composition containing clethodim and fluroxypyr meptyl
CN102265871A (en) Weeding composition containing bentazone and 2,4-dichlorophenoxyacetic acid and application thereof
CN109832268A (en) A kind of triazine Herbicidal combinations of brassinolide-containing class compound
CN112715571A (en) Ternary weeding composition and application thereof
CN102461527A (en) Mixed herbicide composition containing bispyribac-sodium and benthiocarb
CN112088890A (en) Weeding composition containing oxaziclomefone, bensulfuron methyl and penoxsulam
CN112753702A (en) Weeding composition containing oxaziclomefone, clomazone and pyrazosulfuron-ethyl
CN106665629A (en) Compound herbicide used before direct sowing of field seedlings on dry paddy field
CN102461558A (en) Mixed weeding composite containing bispyribac and aniloguard
CN112314610A (en) Weeding composition containing metamifop, halosulfuron-methyl and butachlor
CN111657284A (en) Weeding composition containing trifluralin, acetochlor and thifensulfuron methyl
CN111226943A (en) Weeding composition containing quinclorac, topramezone and terbuthylazine
CN104886159B (en) A kind of rice terrace herbicidal composition
CN108477183A (en) A kind of ternary weeding composition and its application
CN102461545B (en) Hybrid weeding composite containing Bispyribac-sodium and cyclosulfamuron
CN107801726A (en) A kind of built herbicide for rice field
CN112586501B (en) Weeding composition containing cyhalofop-butyl and imazamox
CN109452301B (en) Ternary weeding composition containing propyrisulfuron
CN102461530B (en) Mixed herbicide containing cinosulfuron, bensulfuron-methyl and pendimethalin and application thereof
CN106973909A (en) A kind of ternary built rice weeding composition
CN107347901B (en) Compound herbicide used after wheat field seedling emergence
CN112088891A (en) Weeding composition containing oxaziclomefone, pretilachlor and pyriminobac-methyl

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20220802