CN112661245A - Water body sterilization device and manufacturing method of photovoltaic power generation unit - Google Patents

Water body sterilization device and manufacturing method of photovoltaic power generation unit Download PDF

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Publication number
CN112661245A
CN112661245A CN201910983474.5A CN201910983474A CN112661245A CN 112661245 A CN112661245 A CN 112661245A CN 201910983474 A CN201910983474 A CN 201910983474A CN 112661245 A CN112661245 A CN 112661245A
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China
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power generation
water pipe
self
supporting power
substrate
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CN201910983474.5A
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Chinese (zh)
Inventor
刘朝红
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Hisense Guangdong Kitchen and Bath System Co Ltd
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Hisense Guangdong Kitchen and Bath System Co Ltd
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Priority to CN201910983474.5A priority Critical patent/CN112661245A/en
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Abstract

The invention discloses a water sterilizing device, which comprises a branch water pipe, a photovoltaic power generation unit and a sterilizing unit, wherein the branch water pipe is connected with the photovoltaic power generation unit; the photovoltaic power generation unit comprises a self-supporting power generation film and at least one pair of connecting electrodes; the pair of connecting electrodes are respectively connected with two ends of the self-supporting power generation film; the self-supporting power generation membrane is embedded on the branch water pipe, one part of the self-supporting power generation membrane is positioned in the branch water pipe, and the other part of the self-supporting power generation membrane is positioned outside the branch water pipe; the sterilization unit comprises barbed electrodes which are parallel to each other in pairs and are arranged at intervals, and the barbed electrodes are electrically connected with the paired connecting electrodes respectively; when sterilizing, the prickle electrode is fixedly arranged in the water body. Also discloses a manufacturing method of the hydroelectric generation unit, which comprises the steps of spraying layered double-metal hydroxide material slurry on a substrate; after solidification, the paired connecting electrodes are respectively placed at two ends of the substrate, layered double-metal hydroxide material slurry is continuously sprayed, the connecting electrodes are embedded, and the self-supporting power generation membrane is formed through solidification. The invention has the advantages of no energy consumption, good sterilization effect and no safety risk.

Description

Water body sterilization device and manufacturing method of photovoltaic power generation unit
Technical Field
The invention belongs to the technical field of water sterilization equipment, and particularly relates to a water sterilization device and a manufacturing method of a photovoltaic power generation unit.
Background
Microorganisms in the water body can bring harm to the health of human bodies. Many household electrical appliances that wade with water all have the problem of microorganism breeding such as bacterium. For example, in water storage type water heaters such as heat pump water heaters and electric water heaters, bacteria are bred due to the fact that a part of dead water exists in the inner container, and water quality is discolored and smells; the water outlets of the water dispenser and the water purifier product are kept moist for a long time and are communicated with the air, so that bacteria in the air reversely enter the water pipe from the water outlets, the total number of bacterial colonies in drinking water flowing out of the water outlets reaches more than 1000 CFU/mL, and the bacterial colonies far exceed the relevant regulations of the health department on water quality; the inside of the dish washer and the washing machine is also subjected to microorganism breeding due to the existence of a damp and humid environment. Therefore, it is necessary to provide a sterilizing apparatus in the water body of the wading home appliance.
At present, common sterilization technical means in wading household appliances mainly include high-temperature sterilization, micro-nano metal particle/ion sterilization, ultraviolet sterilization and the like. However, the existing high-temperature sterilization in the water-related household appliances has the problems of unsatisfactory killing effect, high energy consumption and high-temperature safety due to insufficient temperature and short heat preservation time. The micro-nano metal particle/ion sterilization generally selects silver, copper and the like, but the nano silver, the nano copper and the like only act on microorganisms such as bacteria and the like which are in contact with the surfaces of the micro-nano metal particle/ion sterilization and are ineffective to the microorganisms floating in the water body, and the metal ion sterilization technology requires that metal ions must reach a certain concentration to effectively inhibit bacteria/sterilize. In addition, ultraviolet sterilization generally adopts ultraviolet light in a UVC wave band, and has short wavelength and limited penetration effect. Therefore, the problems of high energy consumption, limited sterilization effect, safety risk and the like generally exist in various conventional sterilization means.
Disclosure of Invention
The invention provides a water body sterilization device and a manufacturing method of a photovoltaic power generation unit, which can reduce energy consumption and improve sterilization effect without safety risk.
In order to solve the technical problems, the invention adopts the following technical scheme:
a water sterilization device comprises a branch water pipe, a photovoltaic power generation unit and a sterilization unit;
when the branch water pipe is communicated with the water body, a branch water body is formed;
the photovoltaic power generation unit comprises a self-supporting power generation film and at least one pair of connecting electrodes; the paired connecting electrodes are respectively connected with two ends of the self-supporting power generation film; the self-supporting power generation film is embedded on the branch water pipe; when the branch water pipe is communicated with the water body, one end of the self-supporting power generation film is immersed into the branch water body, and the other end of the self-supporting power generation film is exposed in the air;
the sterilization unit comprises at least one pair of prickle electrodes which are parallel to each other and are arranged at intervals; the paired barbed electrodes are electrically connected with the paired connecting electrodes respectively; when sterilization is carried out, the prickle electrode is fixedly arranged in the water body.
Preferably, the connecting electrodes are ITO electrodes, are long, and are transversely disposed at both ends of the self-supporting power generation film.
As a specific structural design of the water sterilizing device, the water sterilizing device also comprises a main water pipe, and the branch water pipe is fixedly connected and communicated with the main water pipe; each prickle electrode is vertically arranged on the inner wall of the main water pipe.
As another specific structural design of the water sterilizing device, the water sterilizing device also comprises a main water pipe, and the branch water pipe is fixedly connected and communicated with the main water pipe; the sterilization unit further comprises at least one pair of first substrates made of a conductive material; each prickle electrode is fixedly arranged on each first substrate respectively; a plurality of through holes are formed in the first substrate; each first substrate is transversely arranged in the main water pipe.
Preferably, the branch water pipe is a U-shaped water pipe, and two ends of the branch water pipe are respectively communicated with the main water pipe.
Further, the two ends of the main water pipe are provided with connecting joints which are 1/2 or 3/4 taps.
Further, the self-supporting electricity generating membrane is made of a layered double hydroxide material, which includes pores; the size of the pore canal is not more than 2 times the debye length of the water in the body of water.
Preferably, the photovoltaic power generation unit further comprises a second substrate; the self-supporting electricity generating film is disposed on one side or both sides of the second substrate.
A manufacturing method of a photovoltaic power generation unit comprises the following steps:
spraying layered double-metal hydroxide material slurry on a substrate;
after the layered double hydroxide material slurry is solidified, connecting electrodes connected with leads are respectively placed on the outer sides of the layered double hydroxide material slurry at the two ends of the substrate; continuously spraying the layered double hydroxide material slurry on the outer side of the layered double hydroxide material slurry, embedding the connecting electrode, and curing to form a self-supporting power generation film;
and embedding the self-supporting power generation membrane on the branch water pipe, so that one part of the self-supporting power generation membrane is positioned in the branch water pipe, and the other part of the self-supporting power generation membrane is exposed to the air outside the branch water pipe.
Preferably, the method further comprises the following steps:
separating the substrate of the self-supporting electrical generation membrane to form a substrate-free self-supporting electrical generation membrane;
and embedding the self-supporting power generation film without a substrate on the branch water pipe, so that one part of the self-supporting power generation film is positioned in the branch water pipe, and the other part of the self-supporting power generation film is exposed to the air outside the branch water pipe.
Compared with the prior art, the invention has the advantages and positive effects that: the water body sterilization device comprises a photovoltaic power generation unit manufactured by utilizing a photovoltaic power generation principle, and can generate voltage level voltage without energy consumption. The water body to be sterilized is provided with the prickle electrodes connected with the photovoltaic power generation unit to form a strong electric field, so that the cell membrane of microorganisms such as bacteria and the like in the electric field is deformed to be broken due to the mechanical compression effect generated by the electric field, and the microorganisms die, thereby achieving the sterilization effect. The water sterilization device is not connected with an external power supply, so that no energy is consumed; the electric field water body has good penetrating power and good sterilization effect; low voltage, no safety problems such as high voltage and high temperature. The manufacturing method of the photovoltaic power generation unit is simple in process and high in efficiency.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings needed to be used in the embodiments are briefly introduced below, and it is obvious that the drawings in the following description are some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without creative efforts.
Fig. 1 is a schematic longitudinal sectional view of an embodiment of a water sterilization device according to the present invention;
fig. 2 is a schematic longitudinal sectional structural view of another embodiment of a water sterilization device in accordance with the present invention.
In the figure, the position of the upper end of the main shaft,
1. a branched water pipe; 2. a photovoltaic power generation unit; 3. a sterilization unit; 4. a main water pipe; 21. a self-supporting power generation membrane; 22. connecting the electrodes; 31. a through hole; 32. and (4) a bur electrode.
Detailed Description
Reference will now be made in detail to embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to the same or similar elements or elements having the same or similar functions throughout. The embodiments described below with reference to the drawings are illustrative and intended to be illustrative of the invention and are not to be construed as limiting the invention.
Referring to fig. 1 and 2, the water sterilizing apparatus of the present invention includes a branch water pipe 1, a photovoltaic power generation unit 2, and a sterilizing unit 3. The branch water pipe 1 is used for being communicated with a water body to form a branch water body. The photovoltaic power generation unit 2 comprises a self-supporting power generation membrane 21 which is fixedly connected with the branch water pipe 1. When the branch water pipe 1 is communicated with the water body, one end of the self-supporting power generation film 21 is immersed in the branch water body, and the other end is exposed to the air. The sterilization unit 3 comprises at least one pair of prickle electrodes 32 which are parallel to each other and are arranged in the water body channel or the water body container at intervals; the paired bur electrodes 32 are respectively connected with two ends of the self-supporting power generation film 21 correspondingly through leads. When the branch water pipe 1 is communicated with a water body channel or a water body container, the photovoltaic power generation unit 2 generates voltage by using the photovoltaic power generation principle and transmits the voltage to the sterilization unit 3 through a lead. Form the electric field between the parallel and spaced arrangement's prickle electrode 32, and because the prickle electrode 32 that corresponds includes a plurality of pointed ends end that correspond, make and form the strong electric field between the prickle electrode 32 that corresponds, make microorganism such as bacterium take place irreversible deformation to decomposition, fracture under the mechanical compression effect of electric field cell membrane to kill microorganism such as bacterium, play the effect of disinfecting for the water body. Because the photovoltaic power generation unit 2 generates flowing potential difference through water body evaporation, no energy is consumed, the invention can reduce energy consumption; because the voltage generated by the photovoltaic power generation unit 2 is voltage level voltage, safety risks such as high voltage and high temperature do not exist, and the safety of the sterilization device is improved; an electric field is formed in the water body channel or the container, and the water body is sterilized when flowing through the electric field, so that the penetrating power is good, and the sterilizing effect is good.
The following describes the detailed structure and principle of the water sterilizing device according to the present invention with reference to the specific embodiments.
In a first embodiment, referring to fig. 1, the photovoltaic power generation unit 2 further includes at least one pair of connection electrodes 22 respectively located at two ends of the self-supporting power generation membrane 21, and fixedly connected and electrically communicated with the self-supporting power generation membrane 21. The paired connecting electrodes 22 are respectively connected with the paired bur electrodes 32 correspondingly through leads, so that a voltage level generated by the self-supporting power generation film 21 is conducted to the bur electrodes 32 through the leads by the connecting electrodes 22, the paired bur electrodes 32 are respectively charged with positive electricity and negative electricity, and a strong electric field is formed between the paired bur electrodes 32. Preferably, the photovoltaic power generation unit 2 includes a pair of connection electrodes 22 respectively disposed at both ends of the self-supporting power generation membrane 21. Preferably, the sterilization unit 3 includes a pair of barbed electrodes 32.
Referring to fig. 1, the water sterilizing apparatus further includes a main water pipe 4 for communicating with the water body or for the water to flow through. The branch water pipe 1 is fixedly connected and communicated with the main water pipe 4. The paired prickle electrodes 32 are respectively fixedly disposed in the main water pipe 4, and sterilize the water flowing in the main water pipe 4. Preferably, the pair of barbed electrodes 32 are longitudinally disposed on the inner wall of the main water tube 4 such that water flows between the pair of barbed electrodes 32 and is sterilized in the electric field formed by the barbed electrodes 32.
Referring to fig. 1, preferably, the connection electrodes 22 are ITO electrodes, and have a long shape and are laterally disposed at both ends of the self-supporting power generation film 21. Preferably, the branch water pipe 1 is a U-shaped pipe, and both ends thereof are fixedly connected and communicated with the main water pipe 4. Preferably, the main water pipe 4 and the branch water pipe 1 are made of a non-conductive material. Preferably, the main water pipe 4 and the branch water pipe 1 are made of plastic or glass and are connected by welding. Preferably, the two ends of the main water pipe 4 are provided with connection joints for facilitating connection with a delivery water pipe. Preferably, the connecting joint is 1/2 or 3/4 taps. Of course, the branch water pipe 1 may also be an "I" pipe or other conveniently installed water pipe, one end of which is fixedly connected and communicated with the main water pipe 4 and the other end is closed. And the connection mode of the branch water pipe 1 and the main water pipe 4 can also adopt the connection mode of screw thread connection and the like.
Preferably, the self-supporting power generation membrane 21 is made of a layered double hydroxide material, which includes pores having a size not greater than 2 times the debye length of water in the water body, so that the water in the water body moves from one end to the other end of the self-supporting power generation membrane 21 and evaporates into the air, generating a volt-level voltage.
Preferably, the photovoltaic power generation unit 2 further includes a second substrate, and the self-supporting power generation film 21 is disposed on one side or both sides of the second substrate to increase the strength of the self-supporting power generation film 21. The second substrate and the self-supporting electricity generating film 21 or the self-supporting electricity generating film 21 are connected with the branch water pipe 1 in a sealing mode through a sealing device. The preferred sealing device is a sealing sleeve or a sealing gasket.
Preferably, an electrode switching device is provided between the connection electrode 22 and the barbed electrode 32, so that the voltage polarity of the barbed electrode 32 is periodically switched, i.e., the two barbed electrodes 32 in a pair are periodically switched between positive and negative and positive. Preferably, the electrode switching device may be implemented by providing a rotating brush.
In the second embodiment, referring to fig. 2, the photovoltaic power generation unit 2 further includes at least one pair of connection electrodes, which are respectively located at two ends of the self-supporting power generation film 21, and are fixedly connected and electrically communicated with the self-supporting power generation film 21. The paired connecting electrodes 22 are respectively connected with the paired bur electrodes 32 correspondingly through leads, so that a voltage level generated by the self-supporting power generation film 21 is conducted to the bur electrodes 32 through the connecting electrodes 22 and the leads, the paired bur electrodes 32 are respectively charged with positive electricity and negative electricity, and a strong electric field is formed between the paired bur electrodes 32. Preferably, the photovoltaic power generation unit 2 includes a pair of connection electrodes 22 respectively disposed at both ends of the self-supporting power generation membrane 21. Preferably, the sterilization unit 3 includes a pair of barbed electrodes 32.
Referring to fig. 2, the water sterilizing apparatus further includes a main water pipe 4 for communicating with the water body or for the water to flow through. The branch water pipe 1 is fixedly connected and communicated with the main water pipe 4. The paired prickle electrodes 32 are respectively fixedly disposed in the main water pipe 4, and sterilize the water flowing in the main water pipe 4. Preferably, the photovoltaic power generation unit 2 further includes two first substrates, and a plurality of through holes 31 through which water flows are provided on each of the first substrates. The paired prickle electrodes 32 are respectively fixedly connected with the two first substrates, and each first substrate is transversely arranged in the main water pipe, so that water flows through each through hole 31 and flows through the sterilization device to perform sterilization treatment in an electric field formed by the paired prickle electrodes 32.
Referring to fig. 1, preferably, the connection electrode 22 is an ITO electrode, and it is a long strip shape, and is laterally disposed at both ends of the self-supporting power generation film 21. Preferably, the branch water pipe 1 is a U-shaped pipe, and both ends thereof are fixedly connected and communicated with the main water pipe 4. Preferably, the main water pipe 4 and the branch water pipe 1 are made of a non-conductive material. Preferably, the main water pipe 4 and the branch water pipe 1 are made of plastic or glass and are connected by welding. Preferably, the two ends of the main water pipe 4 are provided with connection joints for facilitating connection with a delivery water pipe. Preferably, the connecting joint is 1/2 or 3/4 taps. Of course, the branch water pipe 1 may also be an "I" pipe or other shape convenient to install, one end of which is fixedly connected and communicated with the main water pipe 4, and the other end is closed. And the connection mode of the branch water pipe 1 and the main water pipe 4 can also adopt the connection mode of screw thread connection and the like.
Preferably, the self-supporting power generation membrane 21 is made of a layered double hydroxide material, which includes pores having a size not greater than 2 times the debye length of water in the water body, so that the water in the water body moves from one end to the other end of the self-supporting power generation membrane 21 and evaporates into the air, generating a volt-level voltage.
Preferably, the photovoltaic power generation unit 2 further comprises a second substrate, and the self-supporting power generation film 21 is disposed on one side or both sides of the second substrate to improve the strength of the self-supporting power generation film 21. The second substrate and the self-supporting electricity generating film 21 or the self-supporting electricity generating film 21 are connected with the branch water pipe 1 in a sealing mode through a sealing device. Preferably, the sealing device is a sealing sleeve or a sealing gasket.
Preferably, an electrode switching device is provided between the connection electrode 22 and the barbed electrode 32, so that the voltage polarity of the barbed electrode 32 is periodically switched, i.e., the two barbed electrodes 32 in a pair are periodically switched between positive and negative and positive. Preferably, the electrode switching device may be implemented by providing a brush that rotates autonomously.
Referring to fig. 1 and 2, a photovoltaic power generation unit 2 of the water sterilization device according to the first and second embodiments is prepared by the following method. Spraying layered double-metal hydroxide material slurry with a certain thickness on a clean glass substrate and the like; after solidification, respectively placing connecting electrodes connected with leads on the outer sides of the layered double-metal hydroxide material slurry at the two ends of the substrate, continuously spraying the layered double-metal hydroxide material slurry with a certain thickness, and embedding the connecting electrodes; curing forms the self-supporting electricity generating film 21. The same spraying process can be used to spray the layered double hydroxide material slurry on the other side of the substrate, and the double-sided self-supporting power generation film 21 is formed after curing. The substrate of the self-supporting electricity generating membrane 21 may also be separated to form a substrate-free self-supporting electricity generating membrane 21, which also works as a double-sided pore channel. The self-supporting power generation membrane 21 is fitted to the branch water pipe 1 by a sealing means so that a part thereof is positioned in the branch water pipe 1 and a part thereof is positioned in the air outside the branch water pipe. When the branch water pipe 1 is communicated with the water body, one part of the self-supporting power generation membrane 21 is always wetted by water, and the other part is exposed to the air.
In the description of the present invention, it is to be understood that the terms "first", "second" and the like are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implying any number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one such feature. In the description of the present invention, "a plurality" means at least two, e.g., two, three, etc., unless specifically limited otherwise.
In the present invention, unless otherwise expressly stated or limited, the terms "mounted," "connected," "secured," and the like are to be construed broadly and can, for example, be fixedly connected, detachably connected, or integrally formed; can be mechanically or electrically connected; they may be directly connected or indirectly connected through intervening media, or they may be connected internally or in any other suitable relationship, unless expressly stated otherwise. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
In the description herein, a particular feature, structure, material, or characteristic is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
Although embodiments of the present invention have been shown and described above, it is understood that the above embodiments are exemplary and should not be construed as limiting the present invention, and that variations, modifications, substitutions and alterations can be made to the above embodiments by those of ordinary skill in the art within the scope of the present invention.

Claims (10)

1. A water sterilization device, comprising:
a branch water pipe which forms a branch water body when communicating with the water body;
a photovoltaic power generation unit including a self-supporting power generation film, at least one pair of connection electrodes; the paired connecting electrodes are respectively connected with two ends of the self-supporting power generation film; the self-supporting power generation film is embedded on the branch water pipe; when the branch water pipe is communicated with the water body, one end of the self-supporting power generation film is immersed into the branch water body, and the other end of the self-supporting power generation film is exposed in the air;
the sterilization unit comprises at least one pair of prickle electrodes which are parallel to each other and are arranged at intervals; the paired barbed electrodes are electrically connected with the paired connecting electrodes respectively; when sterilization is carried out, the prickle electrode is fixedly arranged in the water body.
2. The water sterilizing device of claim 1, wherein the connecting electrodes are ITO electrodes and are strip-shaped and arranged transversely at two ends of the self-supporting power generating film.
3. The water sterilizing device of claim 1, further comprising a main water pipe, wherein the branch water pipe is fixedly connected and communicated with the main water pipe; each prickle electrode is vertically arranged on the inner wall of the main water pipe.
4. The water sterilizing device of claim 1, further comprising a main water pipe, wherein the branch water pipe is fixedly connected and communicated with the main water pipe; the sterilization unit further comprises at least one pair of first substrates made of a conductive material; each prickle electrode is fixedly arranged on each first substrate respectively; a plurality of through holes are formed in the first substrate; each first substrate is transversely arranged in the main water pipe.
5. The water sterilizing device of claim 3 or 4, wherein the branch water pipe is a U-shaped water pipe, and two ends of the branch water pipe are respectively communicated with the main water pipe.
6. The water sterilization device as claimed in claim 5, wherein the main water pipe is provided at both ends thereof with connection joints which are 1/2 or 3/4 taps.
7. The water sterilization device of claim 1, wherein the self-supporting power generation membrane is made of a layered double hydroxide material comprising pores; the size of the pore canal is not more than 2 times the debye length of the water in the body of water.
8. The water sterilization device of claim 7, wherein the photovoltaic power generation unit further comprises a second substrate; the self-supporting electricity generating film is disposed on one side or both sides of the second substrate.
9. The manufacturing method of the photovoltaic power generation unit is characterized by comprising the following steps:
spraying layered double-metal hydroxide material slurry on a substrate;
after the layered double-metal hydroxide material slurry is solidified, connecting electrodes connected with leads are respectively placed on the outer sides of the layered double-metal hydroxide material slurry at the two ends of the substrate; continuously spraying the layered double hydroxide material slurry on the outer side of the layered double hydroxide material slurry, embedding the connecting electrode, and curing to form a self-supporting power generation film;
and embedding the self-supporting power generation membrane on the branch water pipe, so that one part of the self-supporting power generation membrane is positioned in the branch water pipe, and the other part of the self-supporting power generation membrane is exposed to the air outside the branch water pipe.
10. The method of making a photovoltaic cell of claim 9, further comprising the steps of:
separating the substrate of the self-supporting electrical generation membrane to form a substrate-free self-supporting electrical generation membrane;
and embedding the self-supporting power generation film without a substrate on the branch water pipe, so that one part of the self-supporting power generation film is positioned in the branch water pipe, and the other part of the self-supporting power generation film is exposed to the air outside the branch water pipe.
CN201910983474.5A 2019-10-16 2019-10-16 Water body sterilization device and manufacturing method of photovoltaic power generation unit Pending CN112661245A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910983474.5A CN112661245A (en) 2019-10-16 2019-10-16 Water body sterilization device and manufacturing method of photovoltaic power generation unit

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910983474.5A CN112661245A (en) 2019-10-16 2019-10-16 Water body sterilization device and manufacturing method of photovoltaic power generation unit

Publications (1)

Publication Number Publication Date
CN112661245A true CN112661245A (en) 2021-04-16

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