CN112644114A - 一种高保温高透气环保无味木胶板及其制备方法 - Google Patents
一种高保温高透气环保无味木胶板及其制备方法 Download PDFInfo
- Publication number
- CN112644114A CN112644114A CN202011466475.1A CN202011466475A CN112644114A CN 112644114 A CN112644114 A CN 112644114A CN 202011466475 A CN202011466475 A CN 202011466475A CN 112644114 A CN112644114 A CN 112644114A
- Authority
- CN
- China
- Prior art keywords
- wood
- glycol
- plastic composite
- fiber filler
- veneer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Abstract
本发明提供一种高保温高透气环保无味木胶板及其制备方法，木胶板包括多层单板与多层粘合薄膜交叉叠放组成，多层单板由透明木塑复合材料制备而成，多层粘合薄膜由高密度聚乙烯薄膜制备而成，透明木塑复合材料，包括脱木质素可回收木质纤维填料、聚甲基丙烯酸甲酯、多元醇或醚‑二醇、2,2'偶氮二(2‑甲基丙腈)、正硅酸四乙酯、环己烷、正戊醇、十六烷基三甲基溴化铵、尿素。本发明所使用的木塑复合材料通过脱木质素过程，然后通过用径向介孔二氧化硅负载聚乙二醇的相变蓄热材料接枝聚甲基丙烯酸甲酯共聚物渗透孔隙空间来减少光散射，进一步加强了对光能所带来的热能的吸收效率，能够在环境温度下降时释放更多的热能，起到了良好的保温效果。
Description
技术领域
本发明属于木胶板技术领域，具体涉及一种高保温高透气环保无味木胶板及其制备方法。
背景技术
我国建筑节能的核心就是对建筑物围护结构和采暖系统进行革新，其中墙体保温施工技术在建筑节能中发挥着越来越重要的作用。当今社会，发达国家都空前地重视节能问题，我国目前的单位建筑面积采暖用能耗相当于气候条件相近的发达国家的3倍～4倍，中国是一个能源比较贫瘠的国家，因此合理利用能源，提高能源利用率是我国社会发展的根本大计，而建筑物外墙围护结构节能技术的改进，保温材料的更新对社会及建筑能耗的降低具有极其重大的意义。
发明内容
本发明针对上述缺陷，提供一种能够减少光散射以及潮湿环境下的分层现象发生、克服固-液相变储能缺陷的高保温高透气环保无味木胶板及其制备方法。
本发明提供如下技术方案：一种高保温高透气环保无味木胶板，所述木胶板包括多层单板与多层粘合薄膜交叉叠放组成，所述多层单板由透明木塑复合材料制备而成，所述多层粘合薄膜由高密度聚乙烯薄膜制备而成，所述透明木塑复合材料，按重量组分，包括以下组分：
进一步地，所述木胶板中位于最外层的均为单板，相邻两层单板之间通过所述粘合薄膜粘接。
进一步地，所述单板的数量为3层～5层，所述粘合薄膜的数量为2 层～4层。
进一步地，所述多元醇为聚丙二醇或聚乙二醇中的一种或两种，所述醚-二醇为聚四亚甲基醚二醇、聚四氢呋喃醚二醇或聚亚丁基醚二醇中的一种或几种。
进一步地，所述脱木质素可回收木质纤维填料的制备方法，包括以下步骤：
1)将25份～35份亚氯酸钠溶于乙酸溶液中，形成亚氯酸钠乙酸溶液；
2)将可回收木质纤维填料粉碎至50目～80目，将所述步骤1)的亚氯酸钠乙酸溶液加热至75℃～85℃后，保持此温度下将60份～80份粉碎后的可回收木质纤维填料浸没于加热后的亚氯酸钠乙酸溶液中20min～ 30min；
3)当所述可回收木质纤维填料变白时，将所述可回收木质纤维填料用蒸馏水清洗3次～5次，然后浸没于3份～5份乙醇和5份～8份的丙酮脱水15min～30min，取出风干得到所述脱木质素可回收木质纤维填料。
进一步地，所述可回收木质纤维填料包括废弃木料、竹工艺品加工废弃边角料、花生壳、稻草或秸秆中的一种或几种。
进一步地，所述步骤1)中的所述乙酸溶液的pH为4～5，所述亚氯酸钠乙酸溶液的浓度为1％的质量分数。
进一步地，所述透明木塑复合材料的制备方法包括以下步骤：
S1：将所述重量组分的正硅酸四乙酯与所述重量组分的环己烷、所述重量组分的正戊醇混合；
S2：将所述重量组分的十六烷基三甲基溴化铵溶于水中，形成质量分数为10％～20％的十六烷基三甲基溴化铵水溶液，将所述重量组分的尿素加入所述十六烷基三甲基溴化铵水溶液中；
S3：将所述S2步骤得到的混合溶液与所述S1步骤得到的混合溶液混合，于1000rpm～1500rpm转速下快速激烈搅拌20min～25min；
S4：将所述S3步骤得到的混合溶液加入至聚四氟乙烯高压釜中于 140℃～160℃下高温加热2h～2.5h，然后冷却至25℃～28℃后，于 10000×g～12000×g转速下离心5min；
S5：取所述S4步骤的沉淀继续以与所述S4步骤离心条件相同转速和时间离心，重复该步骤2次；
S6：将所述S5步骤最终得到的沉淀于真空下、65℃～70℃下干燥 45min～60min，得到径向介孔二氧化硅；
S7：将所述S6步骤得到的径向介孔二氧化硅和所述重量组分的多元醇或醚-二醇置于过滤瓶中，采用真空浸渍装置浸渍混合后，将所述过滤瓶于70℃～100℃、70kPa～80kPa真空压力下加热20min～90min，得到具有径向介孔二氧化硅负载多元醇或醚-二醇的相变蓄热材料；
S8：将所述S7步骤得到的相变蓄热材料与所述重量组分的聚甲基丙烯酸甲酯混合后溶于200ml～500ml乙醇中，然后加入所述重量组分的2,2' 偶氮二(2-甲基丙腈)于50℃、200rpm转速下持续搅拌10min；
S9：将所述重量组分的脱木质素可回收木质纤维填料浸渍于所述S8 步骤得到的溶液中，于25℃～28℃、5bar～6bar真空压力下抽滤15min，得到所述透明木塑复合材料。
进一步地，所述步骤S6形成的径向介孔二氧化硅的孔径为40nm～ 70nm。
本发明还提供上述高保温高透气环保无味木胶板的制作方法，包括以下步骤：
将由透明木塑复合材料制备而成的单板与所述由高密度聚乙烯薄膜制备而成的粘合薄膜依次按照所需数量交叉重叠放置于模具中，于-20℃～ -10℃、30MPa～50MPa下冷压成型，然后于130℃～160℃下热固化1h～ 1.5h，得到所述高保温高透气环保无味木胶板。
本发明的有益效果为：
1、本发明提供的木胶板通过多层单板和多层高密度聚乙烯薄膜先于低温下冷压成型，能够在低温高压下加强单板与粘合薄膜之间的紧密度，释放空隙中的空气，以便于在高温加热时，使高密度聚乙烯薄膜于熔点下逐渐熔化过程中快速与上下两侧单板进行结合，粘结结合更紧密的同时，也降低了木胶板在潮湿空气下逐渐分层老化的现象的发生。
2、本发明通过正硅酸四乙酯作为硅源，加入环己烷与正戊醇的混合溶液后与含有尿素的十六烷基三甲基溴化铵进行混合后，通过自主装后形成具有外侧为疏水端和内侧为亲水端亲水端的径向介孔二氧化硅的微胶粒，通过外侧疏水端和内侧亲水端的静电作用力，当与多元醇或醚-二醇进行混合时，能够使其具有的40nm～70nm的纳米尺度和介孔限制以及表面吸附的共同作用阻碍了整个多元醇或醚-二醇链的晶体聚集，使最终形成的具有径向介孔二氧化硅负载多元醇或醚-二醇的相变蓄热材料在多元醇或醚-二醇的熔点以上具有稳定性，然后再与聚甲基丙烯酸甲酯混合，形成接枝共聚物克服固-液单一相变材料的缺点并提高其孔隙率，最终脱木质素可回收木质纤维填料浸渍后，形成最终的透明木塑复合材料可以与空气直接接触时，在温度高于室温时，将温度通过孔隙接触吸收至木塑复合材料中，在当环境温度降低至室温以下时，通过多元醇或醚-二醇的晶体结构改变释放所储存的热能，起到室内环境的保温和高透气效果。
3、由于所使用的木塑复合材料通过脱木质素过程，去除木材中主要的吸光成分木质素，然后通过用与木材折射率相匹配的聚合物(径向介孔二氧化硅负载多元醇或醚-二醇的相变蓄热材料接枝聚甲基丙烯酸甲酯共聚物)组分渗透孔隙空间来减少光散射，进一步加强了对光能所带来的热能的吸收效率，能够在环境温度下降时释放更多的热能，进一步加强了保温效果。
4、本发明所采用的相变储能材料为多元醇或醚-二醇，多元醇或醚- 二醇为环氧乙烷水解产物的聚合物，无毒、无刺激性，并且多元醇或醚- 二醇被自组装形成的径向介孔二氧化硅负载后与同样环保的聚甲基丙烯酸甲酯，因此，最终形成的木胶板不会在高温情况下释放有毒有害气体，同时还会储存环境改变所带来的热能，减少其他供暖所需要的能源，起到了双重环保的效果。
附图说明
图1为本发明实施例1提供的高保温高透气环保无味木胶板的剖面结构示意图；
图2为本发明实施例2提供的高保温高透气环保无味木胶板的剖面结构示意图；
图3为本发明实施例3提供的高保温高透气环保无味木胶板的剖面结构示意图。
具体实施例方式
下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
本发明所采用的真空浸渍装置购自上海拓精科技有限公司，其余化学原料均为市购。
实施例1
如图1所示，为本发明提供的一种高保温高透气环保无味木胶板，所述木胶板包括3层单板1与2层粘合薄膜2交叉叠放组成，位于最外层的均为单板，相邻两层单板之间通过所述粘合薄膜粘接，其中单板由透明木塑复合材料制备而成，粘合薄膜由高密度聚乙烯薄膜制备而成，透明木塑复合材料，按重量组分，包括以下组分：
其中，脱木质素回收废弃木料纤维填料的制备方法，包括以下步骤：
1)将25份亚氯酸钠溶于pH为4的乙酸溶液中，形成质量分数为1％的亚氯酸钠乙酸溶液；
2)将可回收废弃木料纤维填料粉碎至50目，将步骤1)的亚氯酸钠乙酸溶液加热至75℃后，保持此温度下将60份粉碎后的可回收废弃木料纤维填料浸没于加热后的亚氯酸钠乙酸溶液中20min；
3)当可回收废弃木料纤维填料变白时，将可回收废弃木料纤维填料用蒸馏水清洗3次，然后浸没于3份乙醇和5份的丙酮脱水15min，取出风干得到脱木质素回收废弃木料纤维填料。
透明木塑复合材料的制备方法包括以下步骤：
S1：将25份的正硅酸四乙酯与15份的环己烷、0.5份的正戊醇混合；
S2：将10份的十六烷基三甲基溴化铵溶于水中，形成质量分数为10％的十六烷基三甲基溴化铵水溶液，将所0.3份的尿素加入所述十六烷基三甲基溴化铵水溶液中；
S3：将S2步骤得到的混合溶液与S1步骤得到的混合溶液混合，于 1000rpm转速下快速激烈搅拌20min；
S4：将S3步骤得到的混合溶液加入至聚四氟乙烯高压釜中于140℃下高温加热2h，然后冷却至25℃后，于10000×g转速下离心5min；
S5：取S4步骤的沉淀继续以与S4步骤离心条件相同转速和时间离心，重复该步骤2次；
S6：将S5步骤最终得到的沉淀于真空下、65℃下干燥45min，得到孔径为40nm的径向介孔二氧化硅；
S7：将S6步骤得到的径向介孔二氧化硅和30份的聚丙二醇置于过滤瓶中，采用真空浸渍装置浸渍混合后，将过滤瓶于70℃、70kPa真空压力下加热20min，得到具有径向介孔二氧化硅负载聚乙二醇的相变蓄热材料；
S8：将S7步骤得到的相变蓄热材料与55份的聚甲基丙烯酸甲酯混合后溶于200ml乙醇中，然后加入8份的2,2'偶氮二(2-甲基丙腈)于50℃、 200rpm转速下持续搅拌10min；
S9：将75份的脱木质素可回收废弃木料纤维填料浸渍于S8步骤得到的溶液中，于25℃、5bar真空压力下抽滤15min，得到透明木塑复合材料。
本实施例还提供上述高保温高透气环保无味木胶板的制作方法，包括以下步骤：
将3层由透明木塑复合材料制备而成的单板与2层由高密度聚乙烯薄膜制备而成的粘合薄膜依次按照所需数量交叉重叠放置于模具中，于 -10℃、30MPa下冷压成型，然后于130℃下热固化1h，得到高保温高透气环保无味木胶板。
实施例2
如图2所示，为本实施例提供的一种高保温高透气环保无味木胶板，所述木胶板包括4层单板1与3层粘合薄膜2交叉叠放组成，位于最外层的均为单板，相邻两层单板之间通过所述粘合薄膜粘接，其中单板由透明木塑复合材料制备而成，粘合薄膜由高密度聚乙烯薄膜制备而成，所述透明木塑复合材料，按重量组分，包括以下组分：
其中，脱木质素可回收竹工艺品加工废弃边角料纤维填料的制备方法，包括以下步骤：
1)将30份亚氯酸钠溶于pH为4.5的乙酸溶液中，形成质量分数为 1％的亚氯酸钠乙酸溶液；
2)将可回收竹工艺品加工废弃边角料纤维填料粉碎至65目，将步骤 1)的亚氯酸钠乙酸溶液加热至80℃后，保持此温度下将70份粉碎后的可回收竹工艺品加工废弃边角料纤维填料浸没于加热后的亚氯酸钠乙酸溶液中25min；
3)当可回收竹工艺品加工废弃边角料纤维填料变白时，将可回收竹工艺品加工废弃边角料纤维填料用蒸馏水清洗4次，然后浸没于4份乙醇和6份的丙酮脱水22min，取出风干得到脱木质素可回收竹工艺品加工废弃边角料纤维填料。
透明木塑复合材料的制备方法包括以下步骤：
S1：将27份的正硅酸四乙酯与17.5份的环己烷、0.75份的正戊醇混合；
S2：将12.5份的十六烷基三甲基溴化铵溶于水中，形成质量分数为 15％的十六烷基三甲基溴化铵水溶液，将0.4份的尿素加入所述十六烷基三甲基溴化铵水溶液中；
S3：将S2步骤得到的混合溶液与S1步骤得到的混合溶液混合，于 1250rpm转速下快速激烈搅拌22min；
S4：将S3步骤得到的混合溶液加入至聚四氟乙烯高压釜中于150℃下高温加热2.25h，然后冷却至26℃后，于11000×g转速下离心5min；
S5：取S4步骤的沉淀继续以与S4步骤离心条件相同转速和时间离心，重复该步骤2次；
S6：将S5步骤最终得到的沉淀于真空下、68℃下干燥55min，得到孔径为55m的径向介孔二氧化硅；
S7：将S6步骤得到的径向介孔二氧化硅和20份的聚四亚甲基醚二醇、 15份的聚亚丁基醚二醇置于过滤瓶中，采用真空浸渍装置浸渍混合后，将所述过滤瓶于85℃、75kPa真空压力下加热55min，得到具有径向介孔二氧化硅负载聚乙二醇的相变蓄热材料；
S8：将S7步骤得到的相变蓄热材料与58份的聚甲基丙烯酸甲酯混合后溶于350ml乙醇中，然后加入10份的2,2'偶氮二(2-甲基丙腈)于50℃、 200rpm转速下持续搅拌10min；
S9：将80份的脱木质素可回收竹工艺品加工废弃边角料纤维填料浸渍于S8步骤得到的溶液中，于27℃、5.5bar真空压力下抽滤15min，得到透明木塑复合材料。
本实施例还提供上述高保温高透气环保无味木胶板的制作方法，包括以下步骤：
将4层由透明木塑复合材料制备而成的单板与3层由高密度聚乙烯薄膜制备而成的粘合薄膜依次按照所需数量交叉重叠放置于模具中，于 -15℃、40MPa下冷压成型，然后于125℃下热固化1.25h，得到高保温高透气环保无味木胶板。
实施例3
如图3所示，为本实施例提供的一种高保温高透气环保无味木胶板，所述木胶板包括5层单板1与4层粘合薄膜2交叉叠放组成，位于最外层的均为单板，相邻两层单板之间通过所述粘合薄膜粘接，其中单板由透明木塑复合材料制备而成，粘合薄膜由高密度聚乙烯薄膜制备而成，透明木塑复合材料，按重量组分，包括以下组分：
其中，脱木质素可回收花生壳与秸秆混合纤维填料的制备方法，包括以下步骤：
1)将35份亚氯酸钠溶于pH为5的乙酸溶液中，形成质量分数为1％的亚氯酸钠乙酸溶液；
2)将脱木质素可回收花生壳与秸秆混合纤维填料粉碎至80目，将所述步骤1)的亚氯酸钠乙酸溶液加热至85℃后，保持此温度下将80份粉碎后的脱木质素可回收花生壳与秸秆混合纤维填料浸没于加热后的亚氯酸钠乙酸溶液中30min；
3)当所述脱木质素可回收花生壳与秸秆混合纤维填料变白时，将脱木质素可回收花生壳与秸秆混合纤维填料用蒸馏水清洗5次，然后浸没于 5份乙醇和8份的丙酮脱水30min，取出风干得到脱木质素可回收花生壳与秸秆混合纤维填料。
透明木塑复合材料的制备方法包括以下步骤：
S1：将30份的正硅酸四乙酯与20份的环己烷、1的正戊醇混合；
S2：将15份的十六烷基三甲基溴化铵溶于水中，形成质量分数为20％的十六烷基三甲基溴化铵水溶液，将0.5份的尿素加入十六烷基三甲基溴化铵水溶液中；
S3：将S2步骤得到的混合溶液与S1步骤得到的混合溶液混合，于 1500rpm转速下快速激烈搅拌25min；
S4：将S3步骤得到的混合溶液加入至聚四氟乙烯高压釜中于160℃下高温加热2.5h，然后冷却至28℃后，于12000×g转速下离心5min；
S5：取S4步骤的沉淀继续以与所述S4步骤离心条件相同转速和时间离心，重复该步骤2次；
S6：将S5步骤最终得到的沉淀于真空下、70℃下干燥60min，得到孔径为70nm的径向介孔二氧化硅；
S7：将S6步骤得到的径向介孔二氧化硅和40份的聚乙二醇置于过滤瓶中，采用真空浸渍装置浸渍混合后，将所述过滤瓶于100℃、80kPa真空压力下加热90min，得到具有径向介孔二氧化硅负载聚乙二醇的相变蓄热材料；
S8：将S7步骤得到的相变蓄热材料与60份的聚甲基丙烯酸甲酯混合后溶于500ml乙醇中，然后12份的2,2'偶氮二(2-甲基丙腈)于50℃、200rpm 转速下持续搅拌10min；
S9：将85份的脱木质素可回收花生壳与秸秆混合纤维填料浸渍于所述S8步骤得到的溶液中，于28℃、6bar真空压力下抽滤15min，得到所述透明木塑复合材料。
本实施例还提供上述高保温高透气环保无味木胶板的制作方法，包括以下步骤：
将5层由透明木塑复合材料制备而成的单板与4层由高密度聚乙烯薄膜制备而成的粘合薄膜依次按照所需数量交叉重叠放置于模具中，于 -20℃、0MPa下冷压成型，然后于150℃下热固化1.5h，得到高保温高透气环保无味木胶板。
对比例1
本对比例与实施例1的区别在于，在3层单板之间不使用粘合薄膜进行粘结，在制备过程中采用普通的酚醛树脂胶在每层单板中进行涂覆后，直接于130℃下热固化1h，得到一种木胶板。
对比例2
本对比例与实施例1的区别在于，对比例2所使用的透明木塑复合材料中的可回收废弃木料纤维填料不经过脱木质素处理，透明木塑复合材料按重量组分，包括以下组分：
在制备过程的S9步骤中也使用的是未经脱木质素处理的可回收废弃木料纤维填料。
对比例3
本对比例与实施例1的区别仅在于，对比例3所使用的制备单板的透明木塑复合材料的制备中使用普通的粒径为40nm的纳米二氧化硅，透明木塑复合材料按重量组分，包括以下组分：
在制备透明木塑复合材料的过程中，省略S1步骤-S6步骤，从S7步骤开始，将普通的粒径为40nm的纳米二氧化硅和30份的聚丙二醇置于过滤瓶中，剩余步骤与实施例1相同。
测试例
对实施例1-3及对比例1-3制备的木胶板进行性能测试，测试每个实施例与对比例制备得到的单板材料的孔隙率；将各实施例与对比例得到的木胶板裁剪为长×宽为2cm×3cm的木块，各实施例与对比例的木块厚度不同，然后置于10cm×10cm×10cm的密闭空间内于30℃～40℃下高温加热，采用干燥器法测量甲醛释放量；并测试各密闭空间内于35℃下逐渐降温至0℃后的环境温度变化率，测试结果如表1所示。
表1
尽管已描述了本发明的优选实施例，但本领域内的技术人员一旦得知了基本创造性概念，则可对这些实施例做出另外的变更和修改。所以，所附权利要求意欲解释为包括优选实施例以及落入本发明范围的所有变更和修改。显然，本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样，倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内，则本发明也意图包含这些改动和变型在内。
Claims (10)
1.一种高保温高透气环保无味木胶板，其特征在于，所述木胶板包括多层单板(1)与多层粘合薄膜(2)交叉叠放组成，所述多层单板(1)由透明木塑复合材料制备而成，所述多层粘合薄膜(2)由高密度聚乙烯薄膜制备而成，所述透明木塑复合材料，按重量组分，包括以下组分：
2.根据权利要求1所述的一种高保温高透气环保无味木胶板，其特征在于，所述木胶板中位于最外层的均为单板(1)，相邻两层单板(1)之间通过所述粘合薄膜(2)粘接。
3.根据权利要求2所述的一种高保温高透气环保无味木胶板，其特征在于，所述单板(1)的数量为3层～5层，所述粘合薄膜(2)的数量为2层～4层。
4.根据权利要求1所述的一种一种高保温高透气环保无味木胶板，其特征在于，所述多元醇为聚丙二醇或聚乙二醇中的一种或两种，所述醚-二醇为聚四亚甲基醚二醇、聚四氢呋喃醚二醇或聚亚丁基醚二醇中的一种或几种。
5.根据权利要求1所述的一种高保温高透气环保无味木胶板，其特征在于，所述脱木质素可回收木质纤维填料的制备方法，包括以下步骤：
1)将25份～35份亚氯酸钠溶于乙酸溶液中，形成亚氯酸钠乙酸溶液；
2)将可回收木质纤维填料粉碎至50目～80目，将所述步骤1)的亚氯酸钠乙酸溶液加热至75℃～85℃后，保持此温度下将60份～80份粉碎后的可回收木质纤维填料浸没于加热后的亚氯酸钠乙酸溶液中20min～30min；
3)当所述可回收木质纤维填料变白时，将所述可回收木质纤维填料用蒸馏水清洗3次～5次，然后浸没于3份～5份乙醇和5份～8份的丙酮脱水15min～30min，取出风干得到所述脱木质素可回收木质纤维填料。
6.根据权利要求5所述的一种高保温高透气环保无味木胶板，其特征在于，所述可回收木质纤维填料包括废弃木料、竹工艺品加工废弃边角料、花生壳、稻草或秸秆中的一种或几种。
7.根据权利要求5所述的一种高保温高透气环保无味木胶板，其特征在于，所述步骤1)中的所述乙酸溶液的pH为4～5，所述亚氯酸钠乙酸溶液的浓度为1％的质量分数。
8.根据权利要求1～8所述的一种高保温高透气环保无味木胶板，其特征在于，所述透明木塑复合材料的制备方法包括以下步骤：
S1：将所述重量组分的正硅酸四乙酯与所述重量组分的环己烷、所述重量组分的正戊醇混合；
S2：将所述重量组分的十六烷基三甲基溴化铵溶于水中，形成质量分数为10％～20％的十六烷基三甲基溴化铵水溶液，将所述重量组分的尿素加入所述十六烷基三甲基溴化铵水溶液中；
S3：将所述S2步骤得到的混合溶液与所述S1步骤得到的混合溶液混合，于1000rpm～1500rpm转速下快速激烈搅拌20min～25min；
S4：将所述S3步骤得到的混合溶液加入至聚四氟乙烯高压釜中于140℃～160℃下高温加热2h～2.5h，然后冷却至25℃～28℃后，于10000×g～12000×g转速下离心5min；
S5：取所述S4步骤的沉淀继续以与所述S4步骤离心条件相同转速和时间离心，重复该步骤2次；
S6：将所述S5步骤最终得到的沉淀于真空下、65℃～70℃下干燥45min～60min，得到径向介孔二氧化硅；
S7：将所述S6步骤得到的径向介孔二氧化硅和所述重量组分的多元醇或醚-二醇置于过滤瓶中，采用真空浸渍装置浸渍混合后，将所述过滤瓶于70℃～100℃、70kPa～80kPa真空压力下加热20min～90min，得到具有径向介孔二氧化硅负载多元醇或醚-二醇的相变蓄热材料；
S8：将所述S7步骤得到的相变蓄热材料与所述重量组分的聚甲基丙烯酸甲酯混合后溶于200ml～500ml乙醇中，然后加入所述重量组分的2,2'偶氮二(2-甲基丙腈)于50℃、200rpm转速下持续搅拌10min；
S9：将所述重量组分的脱木质素可回收木质纤维填料浸渍于所述S8步骤得到的溶液中，于25℃～28℃、5bar～6bar真空压力下抽滤15min，得到所述透明木塑复合材料。
9.根据权利要求8所述的一种高保温高透气环保无味木胶板的制作方法，其特征在于，所述步骤S6形成的径向介孔二氧化硅的孔径为40nm～70nm。
10.根据权利要求1所述的一种高保温高透气环保无味木胶板的制作方法，其特征在于，包括以下步骤：
将由透明木塑复合材料制备而成的单板(1)与所述由高密度聚乙烯薄膜制备而成的粘合薄膜(2)依次按照所需数量交叉重叠放置于模具中，于-20℃～-10℃、30MPa～50MPa下冷压成型，然后于100℃～150℃下热固化1h～1.5h，得到所述高保温高透气环保无味木胶板。
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