CN112626877A - Infrared-reflection PVC artificial leather - Google Patents
Infrared-reflection PVC artificial leather Download PDFInfo
- Publication number
- CN112626877A CN112626877A CN201910953405.XA CN201910953405A CN112626877A CN 112626877 A CN112626877 A CN 112626877A CN 201910953405 A CN201910953405 A CN 201910953405A CN 112626877 A CN112626877 A CN 112626877A
- Authority
- CN
- China
- Prior art keywords
- layer
- infrared
- artificial leather
- pvc
- color paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002649 leather substitute Substances 0.000 title claims abstract description 54
- 239000010410 layer Substances 0.000 claims abstract description 82
- 238000005187 foaming Methods 0.000 claims abstract description 23
- 239000002344 surface layer Substances 0.000 claims abstract description 16
- HEQBUZNAOJCRSL-UHFFFAOYSA-N iron(ii) chromite Chemical compound [O-2].[O-2].[O-2].[Cr+3].[Fe+3] HEQBUZNAOJCRSL-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004744 fabric Substances 0.000 claims description 17
- 239000003381 stabilizer Substances 0.000 claims description 14
- 239000003973 paint Substances 0.000 claims description 13
- 239000004014 plasticizer Substances 0.000 claims description 11
- 239000003292 glue Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 claims description 2
- 239000004088 foaming agent Substances 0.000 claims description 2
- 238000007731 hot pressing Methods 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 33
- 238000001816 cooling Methods 0.000 abstract description 21
- 230000000694 effects Effects 0.000 abstract description 15
- 229920000915 polyvinyl chloride Polymers 0.000 description 66
- 239000004800 polyvinyl chloride Substances 0.000 description 66
- 239000010985 leather Substances 0.000 description 12
- 238000000576 coating method Methods 0.000 description 11
- 239000000049 pigment Substances 0.000 description 11
- 238000002310 reflectometry Methods 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 238000004049 embossing Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 230000005855 radiation Effects 0.000 description 7
- 238000009472 formulation Methods 0.000 description 6
- 239000006229 carbon black Substances 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 239000004604 Blowing Agent Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011265 semifinished product Substances 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 239000012463 white pigment Substances 0.000 description 4
- QEFDIAQGSDRHQW-UHFFFAOYSA-N [O-2].[Cr+3].[Fe+2] Chemical compound [O-2].[Cr+3].[Fe+2] QEFDIAQGSDRHQW-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229910000604 Ferrochrome Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000002666 chemical blowing agent Substances 0.000 description 1
- 239000001031 chromium pigment Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000036561 sun exposure Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0036—Polyester fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
- D06N3/005—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by blowing or swelling agent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
- D06N3/0097—Release surface, e.g. separation sheets; Silicone papers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
- D06N3/08—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products with a finishing layer consisting of polyacrylates, polyamides or polyurethanes or polyester
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/068—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/08—Properties of the materials having optical properties
- D06N2209/0807—Coloured
- D06N2209/0823—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/08—Properties of the materials having optical properties
- D06N2209/0876—Reflective
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/26—Vehicles, transportation
- D06N2211/261—Body finishing, e.g. headliners
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to infrared-reflective PVC artificial leather which comprises a surface layer and a foaming layer, wherein infrared-reflective color paste is added into the surface layer and the foaming layer, and the infrared-reflective color paste is made of chromium iron oxide. The PVC artificial leather according to the present invention can be applied to automotive interiors, and has significantly improved cooling effects compared to conventional materials.
Description
Technical Field
The invention relates to infrared-reflective PVC artificial leather which can be applied to automotive interior and has a cooling effect under solar radiation.
Background
Polyvinyl chloride (i.e., PVC) is an important raw material in the production and development of artificial leather, and is widely used in automotive interiors. For artificial leather, sufficient color hiding power is generally required to improve the conventional demands of leather such as light fastness, heat resistance, and stain resistance. For this reason, conventional PVC interior materials mostly use conventional black pigments such as carbon black to achieve color hiding of leather. Especially in summer, the interior of the automobile may reach high temperatures of up to 75 to 85 ℃ under the sun exposure, and in such high temperature conditions, the conventional PVC interior material has disadvantages in that: the body feels uncomfortable when being in direct contact with the PVC interior material; the smell in the car is relatively bad, and harmful emission substances are increased; the aging of the PVC interior material is accelerated at high temperature.
In order to improve the heating problem of the PVC leather, a plurality of researches are carried out in the prior art.
Korean patent application KR20180091173 discloses artificial leather for automotive interiors, in which it is mentioned that glass bubbles, which have near-infrared reflectivity and low heat capacity, are added in surface treatment of the outermost layer, and near-infrared reflection type pigments are added in the PVC skin layer.
Patent application WO2018012691 discloses artificial leather for automotive interiors, comprising an infrared-transmitting upper layer and an infrared-reflecting lower layer, wherein inorganic reflective pigments, such as titanium dioxide, iron oxide and the like, are added to the infrared-reflecting lower layer.
Chinese patent CN101624783B discloses a PVC artificial leather with high infrared reflectivity, comprising: a transmissive surface layer comprising a black pigment mixture of a perylene black pigment and a carbon black pigment; a reflective foam layer comprising a white titanium dioxide pigment and a PVC resin; a reflective substrate layer comprising polyester fibers, the polyester fibers comprising white titanium dioxide pigment.
Chinese patent CN102275348B discloses an automobile interior decoration material in which a skin material has an infrared ray reflective layer as a lower layer and a thin appearance layer coated on the infrared ray reflective layer as an upper layer. A black pigment having infrared transmittance is added to the appearance layer, and incident infrared rays are transmitted through the appearance layer, reflected by the infrared reflection layer, and diffused.
The cooling type automobile interior decoration field has the potential of further research and development and improvement, and particularly, the color requirement of leather must be met while the cooling effect is ensured, and the adverse effect of white pigment such as titanium dioxide on the color of the leather is avoided. It is also necessary to ensure the mechanical performance requirements for the interior of the vehicle.
Disclosure of Invention
Based on the prior art, the invention aims to provide the infrared-reflective PVC artificial leather. The PVC artificial leather can be applied to automotive interiors, meets the requirement that the leather has an expected dark color, and has a good cooling effect at a high temperature of solar radiation.
In order to achieve the technical purpose, the invention provides infrared-reflective PVC artificial leather which comprises a surface layer and a foaming layer, wherein infrared-reflective color paste is added into the surface layer and the foaming layer, and the infrared-reflective color paste is made of iron oxide chromium.
The temperature change of the surface of the material depends on the reflectivity of the material. The higher the reflectivity of the material, the more solar radiant energy is reflected and the smaller the magnitude of the surface temperature increase. The invention uses infrared reflection color paste to replace the traditional color paste added in the skin layer and the foaming layer, such as carbon black. Taking a black material as an example, in a visible light region of 350nm to 750nm, the reflection spectrogram of the infrared reflection color paste is similar to that of the traditional color paste, and the appearance of the material has no macroscopic change; and in the near infrared region of 750nm to 2500nm, compared with the traditional color paste, the infrared reflection color paste has smaller absorption and slower temperature increase. Because the heat energy carried by the near infrared region accounts for more than 53% of the total solar heat energy radiation amount, the key for realizing the cooling is to improve the heat energy radiation of the near infrared region. Therefore, the infrared reflection color paste is used for replacing the traditional black color paste, so that the low-temperature effect of the PVC material under the high-temperature solar radiation can be well achieved.
The invention adopts iron oxide chromium pigment as the material of infrared reflection color paste, which belongs to black color paste. In the near infrared region, conventional black pigments such as carbon black maintain a low reflectance of about 5%, and thus reflect less solar radiation, resulting in a sharp rise in temperature; although the white pigment has very high reflectivity and strong reflectivity, the temperature rise is little, however, the white pigment can not meet the covering requirement of the automobile interior leather for the color; the black infrared reflection color paste well balances two requirements of reflectivity and color covering, can realize high reflectivity of more than 45 percent which is close to that of the conventional white pigment in a near infrared region, and simultaneously ensures good leather color covering. Compared with other conventionally known infrared reflection additives, for example, the manganese ferrite (manganese iron black) has an infrared reflectivity of 12%, and the ferrochrome nickel (black) has an infrared reflectivity of 13%, the iron chromium oxide adopted by the invention has a higher infrared reflectivity, and thus a significantly more excellent reflection effect can be realized. It is critical that the chromium iron oxide be able to achieve a satisfactory colour while ensuring high reflectance.
According to one embodiment of the present invention, the skin layer comprises, in addition to the infrared-reflective color pastes, other color pastes in which the infrared-reflective color paste comprises 80% to 90% of the total weight of the color pastes in the skin layer, for example 80%, 81%, 82%, 83%, 84%, 85%, 86%, 87%, 88%, 89%, 90% or a specific gravity in the range between any two of these values. Accordingly, the other color pastes constitute from 10% to 20% of the total weight of color pastes in the skin layer, for example 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18%, 19%, 20% or a specific gravity within a range between any two of these values. Other color pastes, such as phthalocyanine blue, red iron oxide, etc., are used to adjust the overall color paste color to match the target color. When the infrared reflection color paste in the surface layer accounts for less than 80 percent of the total weight of the color paste, the cooling effect is poor, and the expected black color cannot be blended; when the infrared reflecting color paste in the skin layer comprises more than 90% of the total color paste weight, the desired different colors may not be achieved. Based on the content range, the target color can be blended on the basis of improving the use proportion of the reflection color paste as much as possible. This makes it possible to improve the surface reflection performance of leather and to satisfy the conventional requirements of leather, such as the desired deep color, light fastness, heat resistance, and stain resistance.
According to one embodiment of the present invention, the infrared-reflective color paste in the foamed layer comprises at least 80%, such as 80%, 85%, 90%, 95%, 100% or a range between any two of these values, of the total weight of the color paste in the foamed layer. Preferably, the infrared reflection color paste in the foaming layer accounts for at least 90 percent of the total weight of the color paste in the foaming layer, and more preferably 100 percent. The foaming layer has little influence on the color of the surface of the leather, so that when all the color paste in the foaming layer is infrared reflection color paste, the optimal cooling effect can be achieved.
According to one embodiment of the present invention, the skin layers comprise, based on the total weight of the skin layers:
42% -57% PVC powder, e.g., 42%, 43%, 44%, 45%, 46%, 47%, 48%, 49%, 50%, 51%, 52%, 53%, 54%, 55%, 56%, 57% or a PVC powder in a range between any two of these values,
35% -52% plasticizer, e.g., 35%, 36%, 37%, 38%, 39%, 40%, 41%, 42%, 43%, 44%, 45%, 46%, 47%, 48%, 49%, 50%, 51%, 52% plasticizer or a range between any two of these values,
0.1% to 3.5% of a stabilizer, e.g., 0.1%, 0.5%, 1.0%, 2.0%, 3.0%, 3.1%, 3.2%, 3.3%, 3.4%, 3.5% or a stabilizer within a range between any two of these values,
2% -15% of an infrared-reflecting color paste, e.g., 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, or a range between any two of these values, and
0-5% of other color pastes, for example 0%, 1%, 2%, 3%, 4%, 5% or other color pastes in a range between any two of these values.
When the content of the infrared reflection color paste is too low, the expected cooling effect cannot be realized. When the content of the infrared reflection color paste is too high, other mechanical properties of the PVC artificial leather, such as abrasion resistance and flexing resistance, may be reduced, thereby failing to satisfy the mechanical requirements of the automotive interior.
According to one embodiment of the present invention, the foamed layer comprises, based on the total weight of the foamed layer:
37% -55% PVC powder, e.g. 37%, 38%, 39%, 40%, 41%, 42%, 43%, 44%, 45%, 46%, 47%, 48%, 49%, 50%, 51%, 52%, 53%, 54%, 55% or a PVC powder in a range between any two of these values,
32% -52% plasticizer, e.g., 32%, 33%, 34%, 35%, 36%, 37%, 38%, 39%, 40%, 41%, 42%, 43%, 44%, 45%, 46%, 47%, 48%, 49%, 50%, 51%, 52% or a range between any two of these values,
0.07% to 3.3% stabilizer, e.g., 0.07%, 0.1%, 0.5%, 1.0%, 1.5%, 2.0%, 2.5%, 3.0%, 3.3% or a stabilizer within a range between any two of these values,
0% to 6% of an infrared-reflecting color paste, for example 0%, 1%, 2%, 3%, 4%, 5%, 6% or an infrared-reflecting color paste in the range between any two of these values,
0.8% -4.5% of a blowing agent, e.g., 0.8%, 1.0%, 2.0%, 3.0%, 4.0%, 4.5% or a range between any two of these values, and
1% to 5% flame retardant, e.g., 1%, 2%, 3%, 4%, 5% or a range between any two of these values.
According to one embodiment of the invention, the PVC artificial leather has a base fabric, preferably a white polyester base fabric or a polyester cotton base fabric, on the other side of the foamed layer facing away from the skin layer. The color of the base cloth is preferably white because dark colors tend to absorb heat and white base cloth helps to enhance reflection. In addition, due to the existence of the base cloth, the PVC artificial leather has better mechanical property when being applied to automobile interiors, particularly automobile seats, is more suitable for sewing and can be used for manual cladding, so that the artificial leather is attached to an automobile interior framework, and the operation is more convenient.
According to one embodiment of the invention, the foamed layer and the base fabric are bonded together by glue or are laminated together by hot pressing. According to one embodiment of the invention, the glue comprises 47% -69% of PVC powder, 28% -49% of plasticizer and 1.9% -5.9% of stabilizer based on the total weight of the glue. The glue is favorable for firm adhesion of the foaming layer and the base cloth.
According to the invention, the plasticizers in the skin layer, the foam layer and the glue may be selected from long-chain alkane or aromatic ring plasticizers, such as dialkyl phthalates; the stabilizer in the skin layer, the foam layer and the glue may be selected from light and heat resistant stabilizers, such as organic epoxy stabilizers and calcium and zinc stabilizers.
Here, the PVC resins in the skin layer, the foam layer, and the glue may be the same or different; the plasticizers in the skin layer, the foaming layer and the glue can be the same or different; the stabilizers in the skin layer, the foam layer and the glue may be the same or different. The blowing agent may be selected from a variety of chemical blowing agents known to those skilled in the art, such as azo-based blowing agents, or physical blowing agents, such as microspheres formed from a polymer shell encapsulating an alkane gas.
In addition, other auxiliary agents may be contained in the skin layer and the foamed layer of the PVC artificial leather, and conventional materials well known to those skilled in the art may be selected as needed.
The thickness of the skin layer in the PVC artificial leather according to the present invention is generally 0.25-0.3 mm; the thickness of the foamed layer is generally 0.3 to 0.5 mm.
According to one embodiment of the present invention, a paint layer is coated on the surface of the skin layer. The surface coating may be carried out using conventional paints known in the art. In the present invention, the coating is preferably performed using an aqueous polyurethane paint. The gloss, hand feeling, and light, heat, dirt, abrasion, scratch, and other functionalities of the surface of the PVC artificial leather can be advantageously improved by performing the surface treatment by printing paint on the surface of the material.
According to a preferred embodiment of the invention, a pattern is provided on the paint layer. The high temperature embossing is performed on the paint layer in order to make the final PVC artificial leather have the same appearance pattern and feel as genuine leather.
In order to prepare the infrared-reflective PVC artificial leather according to the present invention, a preparation method comprising the steps of:
(A) preparing color pastes of the skin layer and the foaming layer in advance, wherein the color pastes comprise infrared reflection color pastes;
(B) preparing a surface layer and a foaming layer, wherein the surface layer contains PVC resin, a plasticizer, a stabilizer and pre-prepared surface layer color paste, and the foaming layer contains the PVC resin, the plasticizer, the stabilizer, a foaming agent and pre-prepared foaming layer color paste;
(C) printing a paint layer on the surface layer;
(D) high temperature embossing is performed on the paint layer.
The infrared-reflective PVC artificial leather can be applied to automotive interiors such as automobile door panels, instrument panels, control consoles, stand columns, seat back panels, seat fabrics and the like, and is particularly used as an automobile seat fabric.
In addition, according to another embodiment of the present invention, in order to improve the cooling effect of the PVC artificial leather at high temperature of solar radiation, instead of the infrared reflection color paste, an infrared transmission color paste, preferably a polycyclic perylene pigment, may be added to the skin layer and/or the foamed layer.
The invention has the advantages that:
in direct sunlight in summer, the temperature of the cooling type PVC material according to the invention is raised less and has better temperature feeling compared with the traditional PVC material. Meanwhile, the cost of the cooling PVC is not obviously increased, and the field process parameters are not changed;
compared with the traditional PVC material, the cooling PVC material has better environmental durability under high-temperature exposure;
compared with the traditional PVC material, the cooling PVC material has better smell and diffusion under high-temperature insolation;
the cooling PVC material according to the invention has good color covering power and desirable mechanical properties while ensuring cooling effect.
Detailed Description
In order to make those skilled in the art better understand the technical solution of the present invention, the following description will be made for clarity and completeness in combination with examples and comparative examples, and it is obvious that the described examples are a part of the examples of the present invention, but not all of the examples. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the infrared-reflective PVC artificial leather was prepared according to the following procedure.
(1) Mixing materials: the raw materials were placed in a mixing tank according to the raw material ratios given in the formulation in table 1, then mechanically stirred and vacuumed until well mixed. Thus, a PVC paste was obtained.
(2) Coating: the indirect coating method is adopted, the PVC slurry of the surface layer is coated on the release paper, and the release paper is sent into a first section drying oven at 180 ℃ for plasticizing and shaping. And then coating the PVC slurry of the foaming layer on the plasticized and shaped surface layer, and continuously sending the PVC slurry into a second section of drying oven at 180 ℃ for plasticizing and shaping. And then roll gluing water on the plasticized and shaped foaming layer, compounding the base fabric, and sending the base fabric into a third-section drying oven at 200 ℃ for final shaping to obtain the PVC artificial leather coating material. And (4) after the PVC artificial leather coating material is taken out of the oven, separating the PVC artificial leather coating material from release paper, and respectively rolling. The rolled PVC artificial leather coating material is sent to the printing stage.
(3) Printing: in the printing stage, after the rolled PVC artificial leather coating material is unreeled, paint is printed on the surface layer of the PVC artificial leather coating material. And (3) after printing the paint by a printing machine, sending the paint into an oven at 140 ℃ for drying, and then cooling and rolling to obtain a rolled PVC artificial leather printing semi-finished product. The printed semi-finished product of the PVC artificial leather is sent to an embossing stage.
(4) Embossing: and in the embossing stage, unreeling the rolled printing semi-finished product of the PVC artificial leather. After softening the surface of the printed semi-finished product of the PVC artificial leather by heating, the embossing roller is used to endow the patterns on the surface of the embossing roller on the surface of the PVC artificial leather by pressure at the embossing temperature of 200 ℃. And cooling to obtain the final finished product of the PVC artificial leather with patterns on the surface.
(5) Cutting: and cutting and packaging the prepared PVC artificial leather coiled material according to the required size.
Table 1: formulation of example 1
The mechanical properties, such as tensile strength, abrasion resistance, flexing resistance, of the PVC artificial leather obtained from the above example 1 were measured, and the results are shown in the following table 2:
table 2: mechanical Properties of PVC Artificial leather obtained according to example 1
The results of the above mechanical properties all meet the mechanical requirements for automotive interior materials.
Comparative example 1:
PVC artificial leather was prepared according to the formulation in table 3 in the same manner as in example 1.
Table 3: formulation of comparative example 1
Comparative example 2:
PVC artificial leather was prepared according to the formulation in table 4 in the same manner as in example 1.
Table 4: formulation of comparative example 2
Testing and comparing cooling effect：
The PVC artificial leather obtained in example 1 and comparative examples 1 and 2 were respectively placed under an infrared lamp for irradiation (opper brand bathroom lamp, power 275W, irradiation distance 25cm), and then the temperature of the surface of the material was measured for a certain period of time. The results are shown in table 5 below.
Table 5: comparison of Cooling Effect of Artificial leather (Unit:. degree. C.)
| Example 1 | Comparative example 1 | Comparative example 2 | |
| 0 minute | 18.4 | 19.2 | 19.0 |
| 20 minutes | 36.1 | 50.9 | 47.4 |
| 40 minutes | 40.6 | 54.4 | 50.5 |
| 60 minutes | 40.5 | 56 | 51.8 |
As can be seen from the comparison of the data in table 5, the PVC artificial leather obtained according to example 1 of the present invention has significantly improved cooling effect compared to comparative examples 1 and 2, i.e., compared to the use of the conventional carbon black color paste and the use of other conventional infrared reflection color pastes.
It will be understood that the above embodiments are merely exemplary embodiments taken to illustrate the principles of the present invention, which is not limited thereto. It will be apparent to those skilled in the art that various modifications and improvements can be made without departing from the spirit and substance of the invention, and these modifications and improvements are also considered to be within the scope of the invention.
Claims (8)
1. The infrared-reflection PVC artificial leather comprises a surface layer and a foaming layer and is characterized in that infrared-reflection color paste is added into the surface layer and the foaming layer, and the infrared-reflection color paste is made of chromium iron oxide.
2. The PVC artificial leather according to claim 1, wherein the skin layer further comprises other color pastes besides the infrared-reflective color paste, wherein the content of the infrared-reflective color paste is 80 to 90 percent of the total weight of the color pastes in the skin layer.
3. The PVC artificial leather according to claim 1, wherein the infrared-reflecting color paste in the foamed layer accounts for at least 80%, preferably at least 90%, most preferably 100% of the total weight of the color paste in the foamed layer.
4. The PVC artificial leather according to claim 1, wherein the skin layer comprises 42-57% of PVC powder, 35-52% of plasticizer, 0.1-3.5% of stabilizer, 2-15% of infrared reflective color paste, and 0-5% of other color pastes, based on the total weight of the skin layer.
5. The PVC artificial leather according to claim 1, wherein the foaming layer comprises 37-55% of PVC powder, 32-52% of plasticizer, 0.07-3.3% of stabilizer, 0-6% of infrared reflection color paste, 0.8-4.5% of foaming agent, and 1-5% of flame retardant, based on the total weight of the foaming layer.
6. The PVC artificial leather according to claim 1, wherein the PVC artificial leather is provided with a base fabric on the other side of the foaming layer, which is away from the surface layer, and the base fabric is preferably a white polyester base fabric or a polyester cotton base fabric.
7. The PVC artificial leather according to claim 6, wherein the foaming layer and the base fabric are bonded together by glue or are laminated together by hot pressing.
8. The PVC artificial leather according to any one of claims 1 to 7, wherein the surface of the skin layer is coated with a paint layer, preferably an aqueous polyurethane paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910953405.XA CN112626877A (en) | 2019-10-09 | 2019-10-09 | Infrared-reflection PVC artificial leather |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910953405.XA CN112626877A (en) | 2019-10-09 | 2019-10-09 | Infrared-reflection PVC artificial leather |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112626877A true CN112626877A (en) | 2021-04-09 |
Family
ID=75283597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910953405.XA Pending CN112626877A (en) | 2019-10-09 | 2019-10-09 | Infrared-reflection PVC artificial leather |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112626877A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113774672A (en) * | 2021-05-26 | 2021-12-10 | 加通汽车内饰(常熟)有限公司 | Novel physical foaming agent and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101624783A (en) * | 2008-07-10 | 2010-01-13 | 现代自动车株式会社 | Polyvinylchloride artificial leather having high reflecting infrared ray |
| CN107237163A (en) * | 2017-06-21 | 2017-10-10 | 福建宝利特科技股份有限公司 | A kind of heat reflection artificial leather |
-
2019
- 2019-10-09 CN CN201910953405.XA patent/CN112626877A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101624783A (en) * | 2008-07-10 | 2010-01-13 | 现代自动车株式会社 | Polyvinylchloride artificial leather having high reflecting infrared ray |
| CN107237163A (en) * | 2017-06-21 | 2017-10-10 | 福建宝利特科技股份有限公司 | A kind of heat reflection artificial leather |
Non-Patent Citations (1)
| Title |
|---|
| 郑公劭: "红外反射颜料及其应用", 《上海涂料》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113774672A (en) * | 2021-05-26 | 2021-12-10 | 加通汽车内饰(常熟)有限公司 | Novel physical foaming agent and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2020233027A1 (en) | Coating composite material and manufacturing method therefor | |
| KR100992734B1 (en) | Polyvinylchloride artificial leather having high reflecting infrared ray | |
| CN101472738B (en) | Dark color sheet-shaped material having light reflective properties in near infrared range | |
| TWI441877B (en) | Substrates and articles of manufacture coated with a waterborne 2k coating composition | |
| CN111040612A (en) | Preparation method of carbon nano tube modified light-resistant waterborne polyurethane coating and adhesive | |
| CN108104414A (en) | A kind of suspension floor and preparation method and application | |
| CN109293969A (en) | A kind of polyurethane TPU curtain liner layer and preparation method thereof | |
| WO2020244449A1 (en) | Tpo composition with light transmission properties and tpo artificial leather containing same | |
| CN107746590A (en) | A kind of organo-mineral complexing insulating moulding coating and preparation method thereof | |
| CN112824591B (en) | Production process of wear-resistant transfer coating umbrella fabric | |
| CN101633816A (en) | Glass heat insulation paint of water-based hydroxyl polyurethane resin and preparation method thereof | |
| CN112626877A (en) | Infrared-reflection PVC artificial leather | |
| CN111607980A (en) | Artificial leather with ice-cold air permeability and preparation method and application thereof | |
| CN105755800A (en) | A thermal reflective coating cloth | |
| CN112626881A (en) | Outdoor tent fabric with efficient uvioresistant heat-insulating coating | |
| CN113524814A (en) | Automobile suede fabric ceiling and preparation method and application thereof | |
| KR101635001B1 (en) | Superior See-Through and Energy Saving Sunscreen Fabrics with Coated Yarn Containing Organic/Inorganic Hybrid Coating Layer and The Preparation Method Thereof | |
| CN112030571A (en) | Skin layer composition and uniformly light-transmitting PVC artificial leather prepared from same | |
| CN107434950A (en) | A kind of colored steel coil coating polyurethane primer | |
| CN107237163B (en) | A kind of heat reflection artificial leather | |
| CN111016355A (en) | Low-temperature-rise automobile interior material and preparation method thereof | |
| KR101312609B1 (en) | Film for magnet attachment and manufacturing method thereof and sheet for magnet attachment | |
| JP2016222135A (en) | Vehicle interior component and skin material for vehicle interior component | |
| CN1844560A (en) | Process for making reflective fabric | |
| CN106589907A (en) | Automobile sun visor composite materialand preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Country or region after: China Address after: No. 108 Jianghai South Road, Jingang Town, Zhangjiagang City, Suzhou City, Jiangsu Province, 215632 Applicant after: Benecke Changshun automotive interior materials (Zhangjiagang) Co.,Ltd. Address before: 215632 No.1 Jianghai South Road, Jingang town, Zhangjiagang City, Jiangsu Province Applicant before: BENECKE-CHANGSHUN AUTO TRIM (ZHANGJIAGANG) Co.,Ltd. Country or region before: China |