CN112609461A - Cellulose-based goat milk protein fiber and preparation method thereof - Google Patents
Cellulose-based goat milk protein fiber and preparation method thereof Download PDFInfo
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- CN112609461A CN112609461A CN202011495547.5A CN202011495547A CN112609461A CN 112609461 A CN112609461 A CN 112609461A CN 202011495547 A CN202011495547 A CN 202011495547A CN 112609461 A CN112609461 A CN 112609461A
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- 235000020251 goat milk Nutrition 0.000 title claims abstract description 59
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- 229920002678 cellulose Polymers 0.000 title claims abstract description 34
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- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 229920003043 Cellulose fiber Polymers 0.000 claims abstract description 22
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004627 regenerated cellulose Substances 0.000 claims abstract description 7
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- 239000000843 powder Substances 0.000 claims description 12
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- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 claims description 3
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- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- OMRXVBREYFZQHU-UHFFFAOYSA-N 2,4-dichloro-1,3,5-triazine Chemical compound ClC1=NC=NC(Cl)=N1 OMRXVBREYFZQHU-UHFFFAOYSA-N 0.000 description 1
- ZKHQWZAMYRWXGA-KQYNXXCUSA-N Adenosine triphosphate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OP(O)(=O)OP(O)(O)=O)[C@@H](O)[C@H]1O ZKHQWZAMYRWXGA-KQYNXXCUSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 208000010201 Exanthema Diseases 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- 108060003951 Immunoglobulin Proteins 0.000 description 1
- 208000019693 Lung disease Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
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- 230000005784 autoimmunity Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 201000005884 exanthem Diseases 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 102000018358 immunoglobulin Human genes 0.000 description 1
- 230000006651 lactation Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 1
- 239000002773 nucleotide Substances 0.000 description 1
- 125000003729 nucleotide group Chemical group 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000035935 pregnancy Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
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- 230000009759 skin aging Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/01—Stain or soil resistance
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a cellulose-based goat milk protein fiber and a preparation method thereof, wherein the goat milk protein is grafted onto cellulose fiber by utilizing cyanuric chloride, the obtained goat milk protein fiber is milk white and is warm and moist like jade, the goat milk protein fiber is rich in polar groups such as amino, carboxyl and the like, has good acid-base neutralization effect, can quickly eliminate sweat odor, has the characteristics of moisture absorption and moisture retention, moist heat regulation, antistatic and dustproof, and cannot stimulate skin or cause allergy; meanwhile, the textile prepared from the goat milk protein fiber has good resilience, smooth and glutinous touch, velvet-like touch feeling, obviously superior size stability to regenerated cellulose fiber, no oppression to skin when worn, skin friendliness and no skin adhesion.
Description
Technical Field
The invention relates to the field of new textile materials, and particularly relates to a cellulose-based goat milk protein fiber and a preparation method thereof.
Background
Goat milk is regarded as a fine product in dairy products with the advantages of rich nutrition, easy absorption and the like, is called as 'king of milk', and is recognized in the world as the dairy product closest to human milk. It has the following characteristics: 1. the nutrition is rich: abundant nucleic acid, nucleotide and ATP, can enhance the function of the organism, abundant phospholipid, DNA and choline are excellent for brainworkers and students, and abundant potassium and magnesium can prevent stroke caused by hypertension of middle-aged and old people; 2. the absorption is faster: because the milk protein in the goat milk is higher than the casein, the protein clot is fine and soft, and the emulsified state is good. In the fat structure, the carbon chain is short, and the fat ball is small, so that the direct utilization and absorption of the organism are facilitated; 3. the calcium content is higher: goat milk is also high in calcium and phosphorus. The calcium content of the milk is 5 times of that of human milk and is 15 percent more than that of milk, which is particularly needed for adolescents with vigorous development, growing infants and women in pregnancy lactation; 4. no allergy: the proportion of amino acid is easy to be digested and absorbed by human body and is close to breast milk. Does not contain gamma-casein, and does not produce rash and eczema; 5. and (3) face care and beauty maintenance: like breast milk, goat milk contains EGF (epidermal growth factor), so that it has effects of delaying skin aging, preventing mottle, removing wrinkle, and making skin glossy, tender and elastic; 6. and (3) enhancing immunity: the goat milk is rich in immunoglobulin and natural antibiotics, and can enhance the autoimmunity of human bodies and prevent lung and respiratory diseases after long-term drinking. For a long time, the goat milk is only used as a nutrient for beverages, other purposes are rarely reported, and the goat milk is not used for manufacturing textile fibers.
Disclosure of Invention
Aiming at the defects in the prior art, the cellulose-based goat milk protein fiber provided by the invention is rich in polar groups such as amino groups and carboxyl groups, has a good acid-base neutralization effect, can quickly eliminate sweat odor, is good in resilience, smooth and glutinous, has a velvet touch feeling, and is obviously superior to regenerated cellulose fibers in dimensional stability; simultaneously, the production process technology of the cellulose-based goat milk protein fiber is also provided, the goat milk grafting technology of the cellulose fiber is realized, and the goat milk protein fiber can be grafted and manufactured in a dye vat.
The invention is realized by the following technical scheme:
a sheep milk protein fiber is prepared by grafting sheep milk protein onto cellulose fiber to form cellulose-based sheep milk protein fiber.
The cellulose fibers include natural cellulose fibers and regenerated cellulose fibers.
The natural cellulose fiber includes cotton and hemp.
The regenerated cellulose fiber comprises modal, tencel, viscose filament and staple fiber.
The goat milk protein fiber is milk white, is warm and moist like jade, is rich in polar groups such as amino groups, carboxyl groups and the like, has a good acid-base neutralization effect, can quickly remove sweat odor, has the characteristics of moisture absorption, moisture retention, humidity and heat regulation, static resistance and dust prevention, cannot stimulate the skin, causes allergy, and has a more prominent effect after dyeing.
A preparation method of cellulose-based goat milk protein fiber comprises the following steps: 1) dissolving goat milk protein powder in alkali liquor, stirring and dissolving to obtain solution A; placing the solution A in a reaction kettle, stirring, adding cyanuric chloride, controlling the temperature at 10-18 ℃, reacting for 2-4 hours, and filtering to remove solid matters to obtain a goat milk protein modified solution I; 2) putting cellulose fibers into a container, adding soft water, adding NaOH, raising the temperature of the system to 60-100 ℃, preserving the heat for 0.5-3 hours, and then washing the fibers to be neutral by using the soft water to obtain a product II; 3) placing the product II in a container, adding soft water, then respectively adding sodium hydroxide alkali liquor and cationic modifier 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride, raising the temperature of the system to 60-90 ℃, preserving the heat for 0.5-3 hours, and washing the soft water to be neutral to obtain a product III; 4) putting the fiber modified product III obtained in the step 3) into a container, adding soft water, adding the goat milk protein modified liquid I obtained in the step 1), uniformly stirring for 20 minutes, heating to 60-90 ℃, preserving heat for 1-3 hours, washing with soft water to be neutral to obtain a product, and dehydrating and drying to obtain a finished product.
In the step 1), the concentration of the sodium hydroxide solution is 0.5-2%, the solid weight of the goat milk protein powder and the sodium hydroxide is 10-20:1, and the dosage of the cyanuric chloride is 10-20% of that of the goat milk protein powder.
The mass (kg) of the cellulose in the step 4): 10-20 parts of goat milk protein powder (kg): 1.
the principle of the goat milk protein grafted cellulose fiber is as follows: in an alkaline solution, an amino terminal in the protein can insert cyanuric chloride which is a substance with high reaction activity into the protein through nucleophilic substitution reaction to generate dichloro-s-triazine protein, and the second chlorine and the third chlorine on the triazine ring can react with hydroxyl on cellulose, so that the aim of grafting the whole goat milk protein molecule onto the fiber is fulfilled; in addition, cellulose is subjected to cation modification, so that the carboxyl end of protein can be combined with the cellulose in an ion mode, the affinity of the protein and the fiber is enhanced, and the grafting reaction of the protein and the cellulose is facilitated.
The textile prepared from the goat milk protein fiber has good resilience, smooth and glutinous touch feeling like silk velvet, obviously superior dimensional stability to regenerated cellulose fiber, no oppression to skin when worn, skin friendliness and no skin adhesion.
Compared with the prior art, the invention has the following advantages and beneficial effects:
1. the cellulose-based goat milk protein fiber is milk white, is warm and moist like jade, is rich in polar groups such as amino groups, carboxyl groups and the like, has good acid-base neutralization effect, and can quickly eliminate sweat odor;
2. the cellulose-based goat milk protein fiber has the characteristics of moisture absorption and preservation, moisture and heat regulation, static resistance and dust prevention, and cannot irritate skin or cause allergy;
3. according to the preparation method of the cellulose-based goat milk protein fiber, the grafting of goat milk protein and cellulose is realized by using cyanuric chloride as a grafting active substance, and the cellulose is subjected to cationic modification, so that the carboxyl end of protein can be combined with the cellulose in an ion manner, the affinity of the protein and the fiber is enhanced, and the grafting reaction of the protein and the cellulose is facilitated.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail below with reference to examples, and the exemplary embodiments and descriptions thereof are only used for explaining the present invention and are not used as limitations of the present invention.
Examples
A preparation method of cellulose-based goat milk protein fiber comprises the following steps:
step 1) preparation of goat milk protein modified solution:
weighing goat milk protein powder and sodium hydroxide according to the solid weight ratio of 10-20:1, dissolving the sodium hydroxide in water to prepare 0.5-2% sodium hydroxide solution, dissolving the goat milk protein powder in alkali liquor, and stirring for dissolving for 0.5-6 hours to obtain solution A; placing the solution A in a reaction kettle, stirring and adding cyanuric chloride, wherein the dosage of the cyanuric chloride is 10-20% of that of the protein powder, controlling the temperature at 10-18 ℃, reacting for 2-4 hours, and filtering to remove solid matters to obtain goat milk protein modified solution I;
step 2) pretreatment of cellulose fibers:
placing the fiber into a container, and mixing the fiber with a cellulose mass (kg): adding soft water with the volume (L) of 1:6-1:15, adding NaOH according to 1-4g/L, heating the system to 60-100 ℃, preserving heat for 0.5-3 hours, and washing the fibers with the soft water to be neutral to obtain a product II;
step 3) cellulose fiber cation modification:
the product II was placed in a vessel, in mass on a cellulose dry basis (kg): adding soft water with the volume (L) of 1:6-15, then respectively adding 5-20g/L sodium hydroxide alkali liquor and 10-30g/L cationic modifier 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride, raising the temperature of the system to 60-90 ℃, preserving the temperature for 0.5-3 hours, and washing the soft water to be neutral to obtain a product III;
step 4), compounding of fibers and protein liquid:
placing the fiber modification III obtained in the step 3 into a container, wherein the mass (kg) of cellulose is as follows: adding soft water with the volume (L) of 1:6-15, and adding the soft water according to the mass (kg) of cellulose: 10-20 parts of protein powder (kg): 1, adding the goat milk protein modified solution I obtained in the step 1), uniformly stirring for 20 minutes, heating to 60-90 ℃, preserving heat for 1-3 hours, washing with soft water to be neutral to obtain a product, dehydrating and drying to obtain a finished product.
The strength of the goat milk protein fiber prepared by the invention is reduced by 10-20% compared with that of the corresponding untreated white blank fiber, and the protein content reaches 2-5%, so that the goat milk protein fiber not only can embody the functions thereof, but also can meet the textile requirements.
The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are merely exemplary embodiments of the present invention, and are not intended to limit the scope of the present invention, and any modifications, equivalent substitutions, improvements and the like made within the spirit and principle of the present invention should be included in the scope of the present invention.
Claims (8)
1. The goat milk protein fiber is characterized in that goat milk protein is grafted to the surface of cellulose fiber to form the cellulose-based goat milk protein fiber.
2. The goat milk protein fiber as claimed in claim 1, wherein said cellulose fiber comprises natural cellulose fiber and regenerated cellulose fiber.
3. The cellulose-based goat milk protein fiber as claimed in claim 1, wherein the natural cellulose fiber comprises cotton, hemp.
4. The cellulose-based goat milk protein fiber as claimed in claim 1, wherein the regenerated cellulose fiber comprises modal, tencel, viscose filament and staple fiber.
5. A preparation method of cellulose-based goat milk protein fiber is characterized by comprising the following steps: 1) dissolving goat milk protein powder in alkali liquor, stirring and dissolving to obtain solution A; placing the solution A in a reaction kettle, stirring, adding cyanuric chloride, controlling the temperature at 10-18 ℃, reacting for 2-4 hours, and filtering to remove solid matters to obtain a goat milk protein modified solution I; 2) putting cellulose fibers into a container, adding soft water, adding NaOH, raising the temperature of the system to 60-100 ℃, preserving the heat for 0.5-3 hours, and then washing the fibers to be neutral by using the soft water to obtain a product II; 3) placing the product II in a container, adding soft water, then respectively adding sodium hydroxide alkali liquor and cationic modifier 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride, raising the temperature of the system to 60-90 ℃, preserving the heat for 0.5-3 hours, and washing the soft water to be neutral to obtain a product III; 4) putting the fiber modified product III obtained in the step 3) into a container, adding soft water, adding the goat milk protein modified liquid I obtained in the step 1), uniformly stirring for 20 minutes, heating to 60-90 ℃, preserving heat for 1-3 hours, washing with soft water to be neutral to obtain a product, and dehydrating and drying to obtain a finished product.
6. The method for preparing cellulose-based goat milk protein fiber as claimed in claim 5, wherein the concentration of the sodium hydroxide solution in step 1) is 0.5-2%, the weight ratio of the goat milk protein powder to the sodium hydroxide is 10-20:1, and the dosage of the cyanuric chloride is 10-20% of that of the goat milk protein powder.
7. The method for preparing cellulose-based goat milk protein fiber according to claim 5, wherein the mass ratio of the cellulose to the goat milk protein powder in the step 4) is 10-20: 1.
8. the application of the cellulose-based goat milk protein fiber is characterized in that the cellulose-based goat milk protein fiber is used for preparing textiles.
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| CN111021053A (en) * | 2019-11-26 | 2020-04-17 | 杭州优标科技有限公司 | Fiber containing artemisia annua composite extract and preparation method thereof |
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| JP2003239175A (en) * | 2002-02-14 | 2003-08-27 | Shohi Kagaku Kenkyusho:Kk | Method for modifying cellulosic fiber material with vegetable protein |
| CN108708169A (en) * | 2018-05-28 | 2018-10-26 | 深圳市零度智控科技有限公司 | A kind of viscose face fabric finishing agent and its application method |
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Application publication date: 20210406 |