CN112608080B - Color active mixed material and preparation method and application thereof - Google Patents

Color active mixed material and preparation method and application thereof Download PDF

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Publication number
CN112608080B
CN112608080B CN202011441399.9A CN202011441399A CN112608080B CN 112608080 B CN112608080 B CN 112608080B CN 202011441399 A CN202011441399 A CN 202011441399A CN 112608080 B CN112608080 B CN 112608080B
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active
inorganic substance
color
inorganic
powder
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CN112608080A (en
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石磊
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Guangdong Fumei Material Science And Technology Co ltd
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Guangdong Fumei Material Science And Technology Co ltd
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Publication of CN112608080A publication Critical patent/CN112608080A/en
Priority to PCT/CN2021/105727 priority patent/WO2022121307A1/en
Priority to DE202021004245.8U priority patent/DE202021004245U1/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/001—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26—Silicates of the alkali metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06—Acrylates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

The invention discloses a color active mixed material and a preparation method and application thereof, wherein the preparation method comprises the following steps: inactive inorganic substance, active inorganic substance, and surface coating agent. The color active mixed material simultaneously has an inactive inorganic substance and an active inorganic substance, the surface coating agent is coated on the outer surfaces of the inactive inorganic substance and the active inorganic substance, and the surfaces of the inactive inorganic substance and the active inorganic substance are homogenized and activated under the action of the surface coating agent, so that the using amount of the active inorganic substance is obviously reduced under the condition that the color active mixed material has stronger activity. Meanwhile, as the inactive inorganic matters and the active inorganic matters have colors, the color active mixed materials with the same color can be obtained by mixing the inactive inorganic matters and the active inorganic matters, and the color active mixed materials with different colors can be obtained by mixing the inactive inorganic matters and the active inorganic matters, so that the color active mixed materials with different primary colors from the inactive inorganic matters and the active inorganic matters are enriched.

Description

Color active mixed material and preparation method and application thereof
Technical Field
The invention belongs to the technical field of inorganic matters, and particularly relates to a color active mixed material as well as a preparation method and application thereof.
Background
Inactive inorganic substances such as natural soil, quartz, limestone and the like have natural colors such as red, yellow, white and black, and active materials such as sintered red brick waste, cement waste, volcanic ash, blast furnace slag, phosphate slag, fly ash and the like also have natural colors such as red, yellow, white and black, but the types of the colors are not abundant. The existing decorative materials generally show different colors by adding chemical pigments, and the color fixing property of the materials obtained by the method is poor. At the same time, in order to obtain a material with higher activity, the demand of active inorganic matters is generally larger, which results in higher cost of the whole material. Meanwhile, the existing building materials are multipurpose cement, so that the cost is high, and the problem of saltpetering exists; the plastic articles in daily life are wide and harmful to the environment.
Therefore, the inorganic mineral-based composite material is based on the existing inorganic substances, and more possibilities are searched through modification, so that more possibilities are provided for the fields of buildings, life and the like.
Disclosure of Invention
The present invention is directed to solving, at least in part, one of the technical problems in the related art. To this end, it is an object of the present invention to provide a color active hybrid material, a method for its production and its use. Under the condition of stronger activity, the use amount of active inorganic matters of the color active mixed material is obviously reduced. Meanwhile, the color is remarkably rich.
In one aspect of the invention, the invention proposes a color active hybrid material, according to an embodiment of the invention, comprising: inactive inorganic substance, active inorganic substance, and surface coating agent.
According to the colored active mixed material provided by the embodiment of the invention, the colored active mixed material simultaneously comprises the inactive inorganic substance and the active inorganic substance, the surface coating agent is coated on the outer surfaces of the inactive inorganic substance and the active inorganic substance, the surface coating agent simultaneously contains the inactive inorganic substance and the active inorganic substance, and the surfaces of the inactive inorganic substance and the active inorganic substance are homogenized and activated under the action of the surface coating agent, so that the using amount of the active inorganic substance is obviously reduced under the condition that the obtained colored active mixed material has stronger activity. Meanwhile, the inactive inorganic matters and the active inorganic matters have self colors, the color active mixed materials with the same color can be obtained by mixing the inactive inorganic matters with the same color and the active inorganic matters with the same color, and the color active mixed materials which are different from the primary colors of the inactive inorganic matters and the active inorganic matters can be obtained by mixing the inactive inorganic matters with different colors and the active inorganic matters, so that the colors of the color active mixed materials are obviously enriched.
In addition, the color active hybrid material according to the above embodiment of the present invention may also have the following additional technical features:
in some embodiments of the invention, the mass ratio of the inactive inorganic substance to the active inorganic substance is 1: (1-4).
In some embodiments of the invention, the ratio of the mass of the non-active mineral to the active mineral and the mass of the surface coating agent is 100:0.4-8.
In some embodiments of the invention, the color active blending material further comprises a mineral pigment.
In some embodiments of the present invention, the mass ratio of the sum of the masses of the inactive inorganic substance and the active inorganic substance to the mineral pigment is 100: (0-20).
In some embodiments of the present invention, the mass ratio of the sum of the masses of the inactive inorganic substance and the active inorganic substance, the mineral pigment to the surface coating agent is 100:0.2-5.
In some embodiments of the invention, the non-reactive inorganic substance is selected from at least one of natural earth, quartz, limestone.
In some embodiments of the invention, the active inorganic substance is selected from at least one of fired red brick clinker, cement clinker, pozzolan, blast furnace slag, phosphate slag, fly ash.
In some embodiments of the invention, the mineral pigment is selected from at least one of red iron oxide, yellow iron oxide, black iron oxide, carbon black, zinc oxide, titanium white.
In some embodiments of the invention, the surface coating agent is selected from at least one of a higher ammonium salt, octadecylamine, a fluorocarbon surfactant, gamma-aminopropyltriethoxysilane, glutathione, cysteine, acacia, gelatin, polypyrrolidone, 3-aminopropyltrimethoxysilane, dopamine, levodopa, dopamine hydrochloride, bovine serum albumin, polyethyleneimine, chitosan, tridecafluorooctyltrimethoxysilane, tridecafluorooctyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltrimethoxysilane, organoamine halide acids, oligopeptides.
In a further aspect of this aspect, the present invention proposes a method of preparing the above-mentioned color active hybrid material, according to an embodiment of the present invention, the method comprising:
respectively crushing the inactive inorganic matters to preset particle sizes according to colors so as to obtain inactive inorganic matter powder with different colors and preset particle sizes;
respectively crushing the active inorganic matters to preset particle sizes according to colors so as to obtain active inorganic matter powder with different colors and preset particle sizes;
mixing the non-active inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powders with different colors;
and mixing and coating the mixed inorganic substance powder and the surface coating agent to obtain the color active mixed material.
According to the method for preparing the colored active mixed material of the embodiment of the invention, the inactive inorganic matters with different colors and the active inorganic matters with different colors are respectively crushed into powders with preset particle sizes, and then the inactive inorganic matter powder is mixed with the active inorganic matter powder, so that mixed inorganic matter powder with preset particle size ranges, which is consistent with or inconsistent with the colors of the raw inactive inorganic matter powder or the active inorganic matter powder, can be obtained, and the colors of the finally obtained colored active mixed material are remarkably enriched. Further, since the color of the inactive inorganic substance powder and the active inorganic substance powder is the original color of the material itself, the color fastness of the obtained color active mixed material is much stronger than that of dyeing. By coating the mixed inorganic substance powder, the inactive inorganic substance powder and the active inorganic substance powder are both coated inside by the surface coating agent, so that the activity of the color active mixed material can be obviously improved, the using amount of the active inorganic substance is obviously reduced, and the economic value of the whole color active mixed material is obviously improved.
In addition, the color active hybrid material according to the above embodiment of the present invention may also have the following additional technical features:
in some embodiments of the invention, the mixed mineral powder and mineral pigment are mixed prior to subjecting the mixed mineral powder to the coating process.
In some embodiments of the invention, the inactive inorganic powder has a particle size of 80-12000 mesh.
In some embodiments of the invention, the active inorganic powder has a particle size of 80-12000 mesh.
In yet another aspect of the invention, the invention provides a cement member, which is prepared by adopting the colored active mixed material or the colored active mixed material prepared by adopting the method for preparing the colored active mixed material according to the embodiment of the invention. According to the cement member of the embodiment of the invention, the colored active mixed material can provide color blending for the cement member, meanwhile, due to the adoption of the colored active mixed material, the using amount of cement can be reduced by 30-100%, and the strength of the cement member can be increased by at least 20% due to the matching of the non-active inorganic substance and the active inorganic substance. Furthermore, in the aspect of saving and/or replacing cement, the color active mixed material can also be directly used as a pavement mixed material in rural areas and ecological scenic spots, and researches show that the color active mixed material has the characteristics of higher strength, more excellent color effect and more excellent rain wash resistance compared with a pavement paved by pure soil stones.
In a further aspect of the present invention, the present invention provides a coating material, which comprises 5-20wt% of a water-based high molecular polymer having a solid content of 50wt%, 2-17wt% of water, and 70-95wt% of a color active blending material, which is the above color active blending material, according to an embodiment of the present invention, or the color active blending material prepared by the above method for preparing a color active blending material. The coating provided by the embodiment of the invention has the advantages of good dispersibility, difficult agglomeration, long and stable gelling time, wind, sunlight and discoloration resistance after coating, and aging resistance experiment which can reach more than 3500 h. When the paint is used for an outer wall, the paint has the characteristics of no color change and no chalking for a long time, and has good air permeability, moisture resistance and environmental protection when used for an inner wall. When the material is directly made into sheets, plates or blocks for building exterior decoration, the material has the characteristics of no discoloration, no pulverization and durability like cement, stone and ceramic for a long time.
In a further aspect of the invention, the invention provides a building block, according to an embodiment of the invention, comprising: 8-16wt% of water, 0-10wt% of acrylic rubber powder, 0-15wt% of water glass and 80-92wt% of color active mixed material, wherein the color active mixed material is the color active mixed material or the color active mixed material prepared by the method for preparing the color active mixed material. According to the building brick provided by the embodiment of the invention, the color active mixed material in the building brick can replace clay, a sintering process is omitted, the strength of the obtained building brick exceeds that of a red brick sintered at 800 ℃, meanwhile, the color of the building brick is completely controllable, and different colors can be selected according to requirements.
In another aspect of the present invention, the present invention provides a sheet or a plate, wherein the sheet or the plate is prepared from the above-mentioned color active mixed material, or prepared from the above-mentioned color active mixed material. According to the sheet or the plate provided by the embodiment of the invention, the sheet or the plate is prepared by adopting the color active mixed material, a new possibility is provided for the field of the existing architectural decoration, the flexibility of the obtained sheet or the plate can reach 40 ℃, the tensile strength and the elongation at break at the standard temperature can respectively reach 5MPa and 80%, and the fire-proof grade is A1 grade.
In another aspect of the present invention, the present invention provides a profile or a shell, wherein the profile or the shell is prepared from the color active mixed material, or the color active mixed material prepared from the color active mixed material. According to the section or the shell provided by the embodiment of the invention, the section or the shell is prepared by adopting the colored active mixed material, a new possibility is provided for the field of the existing household electrical appliances and/or digital products, and the impact strength of the obtained section or shell is 0.5-5J x m -1 The density is 1.1-1.3 g/cubic centimeter, the fire-proof grade is A grade, and the artificial aging resistance experiment can reach more than 3500 h.
Additional aspects and advantages of the invention will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the invention.
Drawings
The above and/or additional aspects and advantages of the present invention will become apparent and readily appreciated from the following description of the embodiments, taken in conjunction with the accompanying drawings of which:
FIG. 1 is a schematic flow diagram of a method for preparing a color active hybrid material according to one embodiment of the present invention;
fig. 2 is a schematic flow diagram of a method of preparing a color active hybrid material according to yet another embodiment of the present invention.
Detailed Description
Reference will now be made in detail to embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like or similar reference numerals refer to the same or similar elements or elements having the same or similar function throughout. The embodiments described below with reference to the accompanying drawings are illustrative and intended to explain the present invention and should not be construed as limiting the present invention.
In one aspect of the invention, the invention proposes a color active hybrid material, according to an embodiment of the invention, comprising: inactive inorganic substance, active inorganic substance, and surface coating agent. The inventor finds that the color active mixed material simultaneously has an inactive inorganic substance and an active inorganic substance, the surface coating agent is coated on the outer surfaces of the inactive inorganic substance and the active inorganic substance, the surface coating agent simultaneously contains the inactive inorganic substance and the active inorganic substance, the surfaces of the inactive inorganic substance and the active inorganic substance are homogenized and activated under the action of the surface coating agent, and the using amount of the active inorganic substance is obviously reduced under the condition that the obtained color active mixed material has stronger activity. Meanwhile, the inactive inorganic matters and the active inorganic matters have self colors, the color active mixed materials with the same color can be obtained by mixing the inactive inorganic matters with the same color and the active inorganic matters with the same color, and the color active mixed materials which are different from the primary colors of the inactive inorganic matters and the active inorganic matters can be obtained by mixing the inactive inorganic matters with different colors and the active inorganic matters, so that the colors of the color active mixed materials are obviously enriched.
According to some embodiments of the present invention, the specific types of the inactive inorganic substance and the active inorganic substance are not particularly limited, for example, the inactive inorganic substance may be selected from at least one of natural earth, quartz, and limestone. The active inorganic substance can be at least one selected from the group consisting of fired red brick waste, cement waste, volcanic ash, blast furnace slag, phosphate slag and fly ash. The inventors have found that the above-mentioned inactive inorganic substances can be classified into four colors of red, yellow, white and black according to their natural colors, and that the above-mentioned active inorganic substances can be classified into four colors of red, yellow, white and black according to their natural colors.
According to some embodiments of the present invention, the mass ratio of the inactive inorganic substance to the active inorganic substance in the color active hybrid material may not be particularly limited, and may be, for example, 1: (1-4), specifically, it may be 1:1/2/3/4.
In order to enrich the color of the color active mixed material, inactive inorganic powder with different colors can be mixed with active inorganic powder. Further, in order to make the color of the color active mixed material clearer, a mineral pigment may be added, and the color of the mineral pigment may be the same as or different from that of the mixture of the inactive inorganic substance and the active inorganic substance. According to some embodiments of the present invention, the specific type of the mineral pigment is not particularly limited, such as may be selected from at least one of red iron oxide, yellow iron oxide, black iron oxide, carbon black, zinc oxide, titanium white. Specifically, for example, when the color of the mixture of the active inorganic substance and the inactive inorganic substance is red, the mineral pigment may be red iron oxide, when the color of the mixture of the active inorganic substance and the inactive inorganic substance is yellow, the mineral pigment may be yellow iron oxide, when the color of the mixture of the active inorganic substance and the inactive inorganic substance is gray, the mineral pigment may be at least one of black iron oxide and carbon black, and when the color of the mixture of the active inorganic substance and the inactive inorganic substance is white, the mineral pigment may be at least one of zinc oxide and titanium white.
According to some embodiments of the invention, when the mineral pigment is added, the ratio of the sum of the masses of the inactive inorganic substance and the active inorganic substance to the mass of the mineral pigment may be 100: (0-20), as may be 100: (0.2/0.5/1.0/5.0/10.0/15.0/20). The inventors have found that by adding the mineral pigment in the above ratio, the color of the mixture of the inactive inorganic substance and the active inorganic substance can be made clearer or can be colored with a color different from that of the mixture of the inactive inorganic substance, the active inorganic substance, or both.
The surface coating agent is coated on the surfaces of the inactive inorganic substance and the active inorganic substance, so that the particle surfaces are homogenized and activated, and the activity of the obtained color active mixed material is further improved. According to some embodiments of the invention, when the color active blend material does not include mineral pigments, the surface coating agent may be used in an amount of 0.4 to 8% of the sum of the masses of the inactive inorganic substance and the active inorganic substance, such as 0.4%/1%/2%/3%/4%/5%/6%/7%/8%; when the color active blend material contains a mineral pigment, the amount of the surface coating agent may be 0.2 to 5% by mass of the sum of the amounts of the inactive inorganic substance and the active inorganic substance and the mineral pigment, and may be, for example, 0.2%/1%/2%/3%/4%/5%. Further, the specific type of the surface coating agent is not particularly limited, and may be at least one of a higher ammonium salt, octadecylamine, fluorocarbon surfactant, γ -aminopropyltriethoxysilane, glutathione, cysteine, gum arabic, gelatin, polypyrrolidone, 3-aminopropyltrimethoxysilane, dopamine, levodopa, dopamine hydrochloride, bovine serum albumin, polyethyleneimine, chitosan, tridecafluorooctyltrimethoxysilane, tridecafluorooctyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltrimethoxysilane, organoamine halide, and oligopeptide.
According to the colored active mixed material provided by the embodiment of the invention, the colored active mixed material simultaneously comprises the inactive inorganic substance and the active inorganic substance, the surface coating agent is coated on the outer surfaces of the inactive inorganic substance and the active inorganic substance, the surface coating agent simultaneously contains the inactive inorganic substance and the active inorganic substance, and the surfaces of the inactive inorganic substance and the active inorganic substance are homogenized and activated under the action of the surface coating agent, so that the using amount of the active inorganic substance is obviously reduced under the condition that the obtained colored active mixed material has stronger activity. Meanwhile, the inactive inorganic matters and the active inorganic matters have self colors, the color active mixed materials with the same color can be obtained by mixing the inactive inorganic matters with the same color and the active inorganic matters with the same color, and the color active mixed materials which are different from the primary colors of the inactive inorganic matters and the active inorganic matters can be obtained by mixing the inactive inorganic matters with different colors and the active inorganic matters, so that the colors of the color active mixed materials are obviously enriched.
In a further aspect of the present invention, there is provided a method of preparing the above color active hybrid material, according to an embodiment of the present invention, with reference to fig. 1, the method including:
s100: pulverizing inactive inorganic substances to predetermined particle diameter according to color
In this step, inactive inorganic substances are pulverized to predetermined particle diameters respectively according to colors so as to obtain inactive inorganic substance powders of predetermined particle diameters of different colors. The inventor finds that the subsequent color matching can be realized by classifying the inactive inorganic matters according to the colors and then crushing the inactive inorganic matters respectively, and in the practical process, a person skilled in the art can prepare the color active mixed materials with different colors according to the actual needs. And the inactive inorganic substance can retain the natural color of the inorganic substance, has excellent color fixing degree and is not easy to fade.
According to some embodiments of the present invention, the specific particle size range of the inactive inorganic powder may be selected according to the final product to be produced, and may be smaller when the final product requires smaller particle size of the inactive inorganic powder, and may be larger when the final product requires larger particle size of the inactive inorganic powder, such as 80-12000 mesh, and specifically, such as 80/120/200/300/400/600/800/1000/5000/10000/12000 mesh, and the inactive inorganic powder may be pulverized to 80-120 mesh, and/or 200-300 mesh, and/or 400-600 mesh, and/or 800-1000 mesh, and/or 2000-3000, and/or 4000-5000, and/or 6000-7000, and/or 8000-9000, and/or 10000-11000, and/or 11000-12000 mesh, and the like when the inactive inorganic powder is pulverized.
S200: pulverizing the active inorganic substances to predetermined particle diameter according to color
In this step, the active inorganic substances are pulverized to predetermined particle diameters respectively according to colors, so that active inorganic substance powders having different colors and predetermined particle diameters are obtained. The inventor finds that the active inorganic substances are classified according to the colors and then are respectively crushed, so that the subsequent color matching is favorably realized, and in the practical process, the skilled person can prepare the color active mixed materials with different colors according to the actual needs. And the active inorganic substance can retain the natural color of the active inorganic substance, has excellent color fixation degree and is not easy to fade.
According to some embodiments of the present invention, the specific particle size range of the active inorganic powder may be selected according to the final desired product, and may be smaller when the final product requires smaller particle size of the active inorganic powder, and may be larger when the final product requires larger particle size of the active inorganic powder, such as 80-12000 mesh, and specifically, such as 80/120/200/300/400/600/800/1000/5000/10000/12000 mesh, and the inactive inorganic powder may be pulverized to 80-120 mesh, and/or 200-300 mesh, and/or 400-600 mesh, and/or 800-1000 mesh, and/or 2000-3000, and/or 4000-5000, and/or 6000-7000, and/or 8000-9000, and/or 10000-11000, and/or 11000-12000 mesh, and the like when the inactive inorganic powder is pulverized.
S300: mixing the inactive inorganic powder and the active inorganic powder
In this step, the inactive inorganic substance powder and the active inorganic substance powder are mixed to obtain mixed inorganic substance powders of different colors. The inventors have found that in this step, it is possible to mix inactive inorganic powders of the same color with active inorganic powders to obtain mixed inorganic powders of the same color as the natural color of the inactive inorganic powders and/or the natural color of the active inorganic powders; or mixing the inactive inorganic substance powder with different colors with the active inorganic substance powder to obtain mixed inorganic substance powder with different colors from the natural color of the inactive inorganic substance powder and/or the natural color of the active inorganic substance powder. Therefore, the limitation of natural colors of the inactive inorganic substance powder and the active inorganic substance powder is avoided, and the color of the color active mixed material is obviously enriched. And the non-active inorganic substance and the active inorganic substance carry natural colors, so that the color appearance of the obtained colored active mixed material is more natural and the color fixing degree is higher. Similarly, inactive inorganic substance powder in the same particle size range and active inorganic substance powder can be mixed according to the requirements of the final product, or inactive inorganic substance powder in different particle size ranges and active inorganic substance powder in the same particle size range can be mixed, or inactive inorganic substance powder in the same particle size range and active inorganic substance powder in different particle size ranges can be mixed, or inactive inorganic substance powder in different particle size ranges and active inorganic substance powder in different particle size ranges can be mixed, so as to meet the requirements of different products.
S400: mixing and coating the mixed inorganic powder and the surface coating agent
In this step, the mixed inorganic powder and the surface coating agent are mixed and coated to obtain a color active mixed material. The inventor finds that when the uniformly mixed inorganic powder and the surface coating agent are mixed, the surface coating agent is coated on the surface of the mixed inorganic powder, on one hand, the surface coating agent can enable the surface of the mixed inorganic powder to be more uniform, on the other hand, the activity of the surface of the particle can be improved, so that the obtained color active mixed material has better activity, and further, because the mixed inorganic powder simultaneously contains the inactive inorganic powder particles and the active inorganic powder particles, under the action of the coating agent, the action between the inactive inorganic powder particles and the active inorganic powder particles is enhanced, the performance of the obtained color active mixed material is better than that of the independent inactive inorganic substance and the active inorganic substance, and the effect is remarkable. When the surface coating machine is directly coated on the surface of the mixed inorganic powder, multiple coating, such as twice coating, can be adopted.
According to an embodiment of the present invention, referring to fig. 2, before the mixed inorganic powder is subjected to the coating process, the method may further include:
s500: mixing the mixed inorganic powder and mineral pigment
In this step, the mixed inorganic powder and the mineral pigment are mixed, and the inventors have found that the mixed inorganic powder can be made more distinct in color by adding the mineral pigment. Furthermore, the color of the mineral pigment can be consistent with or inconsistent with that of the mixed inorganic powder, and can be selected according to actual needs. When the color of the inactive inorganic particles in the mixed inorganic powder is the same as that of the active inorganic particles, the use of mineral pigments having the same color as that of the inactive inorganic particles and/or the active inorganic particles can enhance the color development of the mixed inorganic powder to make the color more vivid. When the color of the inactive inorganic particles in the mixed inorganic powder is different from the color of the active inorganic particles, the obtained mixed inorganic can present a color different from the inactive inorganic particles and/or the active inorganic particles when the particle size is smaller, and in this case, a mineral pigment having the same color as the mixed inorganic powder can be used to make the color more vivid. Mineral pigments of a color different from that of the non-active mineral particles and/or mixed mineral powders may also be employed to enrich the color of the colored active mixed material. Meanwhile, the mineral pigment is different from a chemical coating, and has more excellent dyeing durability. When the mineral pigment is added to the color active blending material, the coating of the surface coating agent can adopt one-time coating.
According to the method for preparing the colored active mixed material provided by the embodiment of the invention, the inactive inorganic matters with different colors and the active inorganic matters with different colors are respectively crushed into powder, and then the inactive inorganic matter powder is mixed with the active inorganic matter powder, so that the mixed inorganic matter powder with the same or different color with the raw inactive inorganic matter powder or the active inorganic matter powder can be obtained, and the color of the finally obtained colored active mixed material is remarkably enriched. Furthermore, the color fixing degree of the obtained color active mixed material is much stronger than that of dyeing because the colors of the inactive inorganic substance powder and the active inorganic substance powder are the original colors of the material. By coating the mixed inorganic substance powder, the inactive inorganic substance powder and the active inorganic substance powder are both coated inside by the surface coating agent, so that the activity of the color active mixed material can be obviously improved, the using amount of the active inorganic substance is obviously reduced, and the economic value of the whole color active mixed material is obviously improved.
It should be noted that the advantages and features of the color active hybrid material are also applicable to the method for preparing the color active hybrid material, and are not described in detail herein.
In a further aspect of the invention, a cement component is proposed, which is prepared according to an embodiment of the invention from the above-mentioned color-active hybrid material or from the color-active hybrid material obtained by the above-mentioned method for preparing a color-active hybrid material. According to the cement member of the embodiment of the invention, the colored active mixed material can provide color blending for the cement member, meanwhile, due to the adoption of the colored active mixed material, the using amount of cement can be reduced by 30-100%, and the strength of the cement member can be increased by at least 20% due to the matching of the non-active inorganic substance and the active inorganic substance. Furthermore, in the aspect of saving and/or replacing cement, the color active mixed material can also be directly used as a pavement mixed material for rural and ecological scenic spots, and researches show that the color active mixed material has the characteristics of higher strength, more excellent color effect and more excellent rain erosion resistance compared with a pavement paved with pure soil stone.
In yet another aspect of the present invention, the present invention provides a coating material, which according to an embodiment of the present invention comprises 5-20wt% (e.g. 5/10/15/20 wt%) of a water-based high molecular polymer having a solid content of 50wt%, 2-17wt% of water, 70-95wt% (e.g. 70/75/80/85/90/95 wt%) of a color active blending material (e.g. the color active blending material is the color active blending material, or the color active blending material prepared by the method for preparing the color active blending material is the color active blending material. The coating provided by the embodiment of the invention has the advantages of good dispersibility, difficult agglomeration, long and stable gelling time, wind, sunlight and discoloration resistance after coating, and aging resistance experiment reaching more than 3500 h. When the paint is used for an outer wall, the paint has the characteristics of no color change and no chalking for a long time, and has good air permeability, moisture resistance and environmental protection when used for an inner wall. When the material is directly made into sheets, plates or blocks for external decoration of buildings, the material has the characteristics of no color change, no pulverization and durability like cement, stone and ceramics for a long time.
In a further aspect of the invention, the invention provides a building block, according to an embodiment of the invention, comprising: 8-16wt% of water, 0-10wt% (such as 0/2/4/6/8/10 wt%) of acrylic rubber powder, 0-15wt% (such as 0/3/6/9/12/15 wt%) of water glass, 80-92wt% (such as 80/82/84/86/88/90/92 wt%) of a color active mixed material, wherein the color active mixed material is the color active mixed material or the color active mixed material prepared by the method for preparing the color active mixed material. According to the building brick provided by the embodiment of the invention, the color active mixed material in the building brick can replace clay, a sintering process is omitted, the strength of the obtained building brick exceeds that of a red brick sintered at 800 ℃, meanwhile, the color of the building brick is completely controllable, and different colors can be selected according to requirements.
In another aspect of the present invention, the present invention provides a sheet or plate prepared from the above-mentioned color active hybrid material, or prepared from the above-mentioned color active hybrid material. According to the sheet or the plate provided by the embodiment of the invention, the sheet or the plate is prepared from the colored active mixed material, a new possibility is provided for the existing architectural decoration field, the flexibility of the obtained sheet or the plate can reach 40 ℃, the tensile strength and the elongation at break at standard temperature can respectively reach 5MPa and 80%, and the fire-proof grade can reach A1 grade.
According to some embodiments of the invention, the formulation of the sheet or plate may be: 80-91wt% of color active mixed material, 1-16wt% (such as 1/4/8/12/16 wt%) of water-based silicon PU,1-4wt% (1/2/3/4 wt%) of short fiber, 6-12wt% of water, 1-3wt% (1/2/3 wt%) of re-dispersible latex powder. Mixing the above materials, pulping, injecting into a mold, drying at 120 deg.C for 1h, and molding to obtain sheet or plate with thickness of 3-10mm (such as 3/4/5/6/7/8/9/10 mm). The flexibility of the sheet or plate can reach 40 ℃, the tensile strength and the elongation at break at standard temperature can respectively reach 5MPa and 80%, and the fire-proof grade is A1 grade.
In another aspect of the present invention, the present invention provides a profile or a housing, which is prepared by using the above color active mixed material, or the color active mixed material prepared by using the above color active mixed material. According to the section or the shell provided by the embodiment of the invention, the sheet or the plate is prepared by adopting the colored active mixed material, a new possibility is provided for the field of the existing household electrical appliances and/or digital products, and the impact strength of the obtained section or the shell is 0.5-5J x m -1 The density is 1.1-1.3 g/cubic centimeter, the fire-proof rating is A level, and the artificial aging resistance experiment can reach more than 3500 h.
According to some embodiments of the invention, the profile or housing may be formulated as: 80-90wt% of color active mixed material, 6-12wt% of acrylic polymer with solid content of 50%, 3-5wt% of redispersible latex powder and 1-3wt% of polyethylene fiber with length of 0.3 mm. And uniformly mixing the materials, injecting the mixture into a mold, and steaming and pressing the mixture for 1.5 to 3 hours at the temperature of between 140 and 160 ℃ to obtain the section or the shell. By selecting different moulds, the electric appliance suitable for different living and digital electricity can be obtainedThe shell product of the device can replace plastics, such as computer shells, refrigerator shells, washing machine shells, microwave oven shells, television shells, mobile phone shells and the like. The obtained section or shell has impact strength of 0.5-5J × m -1 The density is 1.1-1.3 g/cubic centimeter, the fire-proof grade is A grade, and the artificial aging resistance experiment can reach more than 3500 h.
The invention will now be described with reference to specific examples, which are intended to be illustrative only and not to be limiting in any way.
Example 1
The formula of the color active mixed material comprises the following components:
the brick comprises the following components of inactive inorganic matter natural soil, active inorganic matter sintered red brick discard blocks, surface coating agent octadecylamine, and the mass ratio of the inactive inorganic matter to the active inorganic matter is 1:1, the mass ratio of the inactive inorganic substance to the active inorganic substance and the surface coating agent is 100:0.4.
example 2
The formula of the color active mixed material comprises the following components:
the material comprises inactive inorganic quartz, active inorganic cement blocks, surface coating agents which are equal parts of fluorocarbon surfactant and gamma-aminopropyltriethoxysilane, wherein the mass ratio of the inactive inorganic substances to the active inorganic substances is 1:2, the mass ratio of the inactive inorganic substance to the active inorganic substance and the surface coating agent is 100:3.
example 3
The formula of the color active mixed material comprises the following components:
the limestone of non-active inorganic substances, the volcanic ash of active inorganic substances, the surface coating agent are equal parts of glutathione and cysteine, and the mass ratio of the non-active inorganic substances to the active inorganic substances is 1:3, the mass ratio of the inactive inorganic substance to the active inorganic substance and the surface coating agent is 100:8,
example 4
The formula of the color active mixed material comprises the following components:
the non-active inorganic matters are equal parts of natural soil and quartz, the active inorganic matters are blast furnace slag, the mineral pigment is iron oxide red, the surface coating agents are equal parts of Arabic gum and gelatin, and the mass ratio of the non-active inorganic matters to the active inorganic matters is 1:4, the mass ratio of the sum of the mass of the non-active inorganic matter and the active inorganic matter to the mass of the mineral pigment is 100:0.2, the mass ratio of the sum of the mass of the inactive inorganic substance, the active inorganic substance and the mineral pigment to the surface coating agent is 100:0.2.
example 5
The formula of the color active mixed material comprises the following components:
the non-active inorganic matters are equal parts of quartz and limestone, the active inorganic matters are phosphate rock ballast, the mineral pigment is iron oxide yellow, the surface coating agent is equal parts of polypyrrolidone and 3-aminopropyltrimethoxysilane, and the mass ratio of the non-active inorganic matters to the active inorganic matters is 1:1.5, the mass ratio of the sum of the mass of the inactive inorganic substance and the active inorganic substance to the mass of the mineral pigment is 100:5, the mass ratio of the sum of the mass of the non-active inorganic substance, the active inorganic substance and the mineral pigment to the mass of the surface coating agent is 100:2.
example 6
The formula of the color active mixed material comprises the following components:
the active inorganic matters are coal ash, mineral pigments are black iron oxide and carbon black, the surface coating agents are dopamine, levodopa, dopamine hydrochloride and bovine serum albumin, the mass ratio of the inactive inorganic matters to the active inorganic matters is 1:2.5, the mass ratio of the sum of the masses of the non-active inorganic matters and the active inorganic matters to the mineral pigment is 100:10, the mass ratio of the sum of the mass of the non-active inorganic substance, the active inorganic substance and the mineral pigment to the mass of the surface coating agent is 100:3;
example 7
The formula of the color active mixed material comprises the following components:
equal parts of quartz and limestone for inactive inorganic matters, equal parts of sintered red brick waste blocks, cement waste blocks and volcanic ash for active inorganic matters, equal parts of zinc oxide and titanium white for mineral pigments, equal parts of tridecafluorooctyltrimethoxysilane, tridecafluorooctyltriethoxysilane, heptadecafluorodecyltriethoxysilane and heptadecafluorodecyltrimethoxysilane for surface coating agents, and the mass ratio of the inactive inorganic matters to the active inorganic matters is 1:3.5, the mass ratio of the sum of the masses of the inactive inorganic matters and the active inorganic matters to the mineral pigment is 100:20, the mass ratio of the sum of the mass of the non-active inorganic substance, the active inorganic substance and the mineral pigment to the mass of the surface coating agent is 100:5.
example 8
Cement member
Preparation of the color active hybrid material in example 1: pulverizing inactive inorganic substance to 80-120 mesh to obtain inactive inorganic substance powder with predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 80-120 mesh to obtain active inorganic substance powder of a predetermined particle size; mixing the non-active inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing and coating the mixed inorganic substance powder and the surface coating agent to obtain the color active mixed material. And directly molding the obtained colored active mixed material to obtain the cement member. The cement member realizes percentage replacement of cement, the strength is increased by 30%, and the phenomenon of saltpetering does not occur.
Example 9
Pavement mixed material
Preparation of the color active hybrid material in example 2: pulverizing the inactive inorganic substance to a predetermined particle size of 200-300 mesh to obtain inactive inorganic substance powder of a predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 200-300 mesh to obtain active inorganic substance powder of a predetermined particle size; mixing the inactive inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing and coating the mixed inorganic substance powder and the surface coating agent to obtain the color active mixed material. And directly molding the obtained colored active mixed material to obtain the pavement mixed material. When the pavement mixed material is used as a pavement mixed material for rural and ecological scenic spots, the pavement mixed material has the characteristics of higher strength, more excellent color effect and more excellent rain wash resistance compared with a pavement paved by pure soil stones.
Example 10
Coating material
The method comprises the following steps: 5wt% of water-based high molecular polymer with solid content of 50wt%, 2wt% of water and 93wt% of color active mixed material. The color active mixed material is prepared by adopting the formula of the embodiment 3, and specifically comprises the following components: crushing the inactive inorganic substance to a predetermined particle size of 400-600 mesh to obtain inactive inorganic substance powder of a predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 400-600 mesh to obtain active inorganic substance powder of a predetermined particle size; mixing the non-active inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing and coating the mixed inorganic substance powder and the surface coating agent to obtain the color active mixed material. The water-based high molecular polymer, water and the color active mixed material are mixed to prepare the coating. The coating has good dispersibility, is not easy to agglomerate, has long and stable gelation time, is resistant to wind, wind and sunlight after coating, is not easy to discolor, and has an aging resistance experiment reaching more than 3500 h. When the paint is used for an outer wall, the paint has the characteristics of no color change and no chalking for a long time, and has good air permeability, moisture resistance and environmental protection when used for an inner wall.
Example 11
Coating material
The method comprises the following steps: 10wt% of water-based high molecular polymer with solid content of 50wt%, 10wt% of water and 80wt% of color active mixed material. The color active mixed material is prepared by adopting the formula of the embodiment 4, and specifically comprises the following components: crushing the inactive inorganic substance to a predetermined particle size of 800-1000 mesh to obtain inactive inorganic substance powder of a predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 800-1000 mesh to obtain active inorganic substance powder of a predetermined particle size; mixing the inactive inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing the mixed inorganic powder with the mineral pigment, and then mixing and coating the mixture with the surface coating agent to obtain the color active mixed material. The water-based high molecular polymer, water and the color active mixed material are mixed to prepare the coating. The coating has good dispersibility, is not easy to agglomerate, has long and stable gelation time, is resistant to wind, wind and sunlight after coating, is not easy to discolor, and has an aging resistance experiment reaching more than 3500 h. When the paint is used for an outer wall, the paint has the characteristics of long-term no color change and no chalking, and when the paint is used for an inner wall, the paint has good air permeability, moisture resistance and environmental protection.
Example 12
Coating material
The method comprises the following steps: 20wt% of water-based high molecular polymer with the solid content of 50wt%, 7wt% of water and 73wt% of color active mixed material. The color active mixed material is prepared by adopting the formula of the embodiment 5, and specifically comprises the following components: pulverizing inactive inorganic substance to predetermined particle size of 2000-3000 mesh to obtain inactive inorganic substance powder with predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 2000-3000 meshes to obtain active inorganic substance powder of a predetermined particle size; mixing the non-active inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing the mixed inorganic powder with the mineral pigment, and then mixing and coating the mixture with the surface coating agent to obtain the color active mixed material. The water-based high molecular polymer, water and the color active mixed material are mixed to prepare the coating. The coating has good dispersibility, is not easy to agglomerate, has long and stable gelation time, is resistant to wind, wind and sunlight after coating, is not easy to discolor, and can reach an aging resistance experiment for more than 3500 h. When the paint is used for an outer wall, the paint has the characteristics of no color change and no chalking for a long time, and has good air permeability, moisture resistance and environmental protection when used for an inner wall.
Example 13
Building brick
The method comprises the following steps: 8wt% of water, 12wt% of water glass and 80wt% of color active mixing material. The color active mixed material is prepared by adopting the formula of the embodiment 6, and specifically comprises the following components: crushing the inactive inorganic substance to a predetermined particle size of 4000-5000 mesh to obtain inactive inorganic substance powder of a predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 4000-5000 meshes to obtain active inorganic substance powder of a predetermined particle size; mixing the inactive inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing the mixed inorganic powder with the mineral pigment, and then mixing and coating the mixture with the surface coating agent to obtain the color active mixed material. The color active mixed material in the building brick can replace clay, a sintering process is omitted, the strength of the red brick sintered at the temperature of 800 ℃ is higher, meanwhile, the color of the red brick is completely controllable, and different colors can be selected according to requirements.
Example 14
Building brick
The method comprises the following steps: 12wt% of water, 3wt% of acrylic rubber powder and 85wt% of color active mixed material. Wherein, the color active mixed material is prepared by adopting the formula of the embodiment 7, and comprises the following specific components: pulverizing the inactive inorganic substance to a predetermined particle size of 6000-7000 mesh to obtain inactive inorganic substance powder of a predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 6000-7000 mesh to obtain active inorganic substance powder of a predetermined particle size; mixing the inactive inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing the mixed inorganic powder with the mineral pigment, and then mixing and coating the mixture with the surface coating agent to obtain the color active mixed material. The color active mixed material in the building brick can replace clay, a sintering process is omitted, the strength of the red brick sintered at the temperature of 800 ℃ is higher, meanwhile, the color of the red brick is completely controllable, and different colors can be selected according to requirements.
Example 15
Building brick
The method comprises the following steps: 8wt% of water, 92wt% of a color active blend material. The color active mixed material is prepared by adopting the formula of the embodiment 1, and specifically comprises the following components: pulverizing inactive inorganic substance to 80-120 mesh to obtain inactive inorganic substance powder with predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 80-120 meshes to obtain active inorganic substance powder of a predetermined particle size; mixing the non-active inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing and coating the mixed inorganic powder and the surface coating agent to obtain the color active mixed material. The color active mixed material in the building brick can replace clay, a sintering process is omitted, the strength of the red brick sintered at the temperature of 800 ℃ is higher, meanwhile, the color of the red brick is completely controllable, and different colors can be selected according to requirements.
Example 16
Sheet material
The method comprises the following steps: 80wt% of color active mixed material, 1wt% of water-based silicon PU,4wt% of short fiber, 12wt% of water and 3wt% of redispersible latex powder. The color active mixed material is prepared by adopting the formula of the embodiment 2, and specifically comprises the following components: crushing the inactive inorganic substance to a predetermined particle size of 8000-9000 meshes to obtain an inactive inorganic substance powder of a predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 8000-9000 meshes to obtain active inorganic substance powder of a predetermined particle size; mixing the inactive inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing and coating the mixed inorganic powder and the surface coating agent to obtain the color active mixed material. Mixing the materials, pulping, injecting into a mold, drying at 120 ℃ for 1h, and molding to obtain a sheet with the thickness of 3 mm. The flexibility of the sheet can reach 40 ℃, the tensile strength and the elongation at break can respectively reach 5MPa and 80% at standard temperature, and the fire-proof rating is A1. Meanwhile, the paint has the characteristics of no color change, no pulverization and durability like cement, stone and ceramic for a long time.
Example 17
Sheet material
The method comprises the following steps: 85wt% of color active mixed material, 5wt% of water-based silicon PU,2wt% of short fiber, 6wt% of water and 2wt% of redispersible latex powder. The color active mixed material is prepared by adopting the formula of the embodiment 3, and specifically comprises the following components: crushing the inactive inorganic substance to a predetermined particle size of 800-1000 mesh to obtain inactive inorganic substance powder of a predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 800-1000 mesh to obtain active inorganic substance powder of a predetermined particle size; mixing the inactive inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing and coating the mixed inorganic substance powder and the surface coating agent to obtain the color active mixed material. Mixing the materials, pulping, injecting into a mold, drying at 120 ℃ for 1h, and molding to obtain a sheet with the thickness of 6 mm. The flexibility of the sheet can reach 40 ℃, the tensile strength and the elongation at break at standard temperature can respectively reach 5MPa and 80%, and the fire-proof grade is A1 grade. Meanwhile, the paint has the characteristics of no color change, no pulverization and durability like cement, stone and ceramic for a long time.
Example 18
Plate material
The method comprises the following steps: 91wt% of color active mixed material, 1wt% of water-based silicon PU,1wt% of short fiber, 6wt% of water and 1wt% of re-dispersible latex powder. The color active mixed material is prepared by adopting the formula of the embodiment 4, and specifically comprises the following components: crushing the inactive inorganic substance to a predetermined particle size of 400-600 mesh to obtain inactive inorganic substance powder of a predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 400-600 mesh to obtain active inorganic substance powder of a predetermined particle size; mixing the inactive inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing the mixed inorganic powder and the mineral pigment, and then mixing and coating the mixture with a surface coating agent to obtain the color active mixed material. Mixing the materials, pulping, injecting into a mold, drying at 120 ℃ for 1h, and molding to obtain a plate with the thickness of 10 mm. The flexibility of the plate can reach 40 ℃, the tensile strength and the elongation at break at standard temperature can respectively reach 5MPa and 80%, and the fire-proof grade is A1 grade. Meanwhile, the paint has the characteristics of no color change, no pulverization and durability like cement, stone and ceramic for a long time.
Example 19
Computer casing
The method comprises the following steps: 80wt% of color active mixing material, 12wt% of acrylic polymer with solid content of 50%, 5wt% of re-dispersible latex powder, and 3wt% of polyethylene fiber with length of 0.3 mm. The color active mixed material is prepared by adopting the formula of the embodiment 3, and specifically comprises the following components: crushing the inactive inorganic substance to a predetermined particle size of 400-600 mesh to obtain inactive inorganic substance powder of a predetermined particle size; crushing the active inorganic substance to a predetermined particle size of 400-600 mesh to obtain active inorganic substance powder of a predetermined particle size; mixing the inactive inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing and coating the mixed inorganic substance powder and the surface coating agent to obtain the color active mixed material. And uniformly mixing the materials, injecting the mixture into a mold, and performing steam pressing at 140 ℃ for 3 hours to obtain the computer shell. Its impact strength is 5J m -1 The density is 1.1 g/cubic centimeter, the fire-proof grade is A grade, and the artificial aging resistance experiment can reach more than 3500h。
Example 20
Refrigerator shell
The method comprises the following steps: 85wt% of color active mixed material, 9wt% of acrylic polymer with solid content of 50%, 4wt% of re-dispersible latex powder, and 2wt% of polyethylene fiber with length of 0.3 mm. The color active mixed material is prepared by adopting the formula of the embodiment 6, and specifically comprises the following components: pulverizing the inactive inorganic substance to 10000-11000 meshes with a preset particle size to obtain inactive inorganic substance powder with the preset particle size; crushing the active inorganic substance to 10000-11000 meshes of preset particle size to obtain active inorganic substance powder of the preset particle size; mixing the inactive inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing the mixed inorganic powder and the mineral pigment, and then mixing and coating the mixture with a surface coating agent to obtain the color active mixed material. And uniformly mixing the materials, injecting the mixture into a mold, and steaming and pressing the mixture for 2 hours at the temperature of 150 ℃ to obtain the refrigerator shell. The impact strength is 4J m -1 The density is 1.25 g/cubic centimeter, the fire-proof grade is A grade, and the artificial aging resistance experiment can reach more than 3500 h.
Example 21
Mobile phone shell
The method comprises the following steps: 90wt% of a color active mixing material, 6wt% of an acrylic polymer having a solid content of 50%, 3wt% of a re-dispersible latex powder, and 1wt% of a polyethylene fiber having a length of 0.3 mm. The color active mixed material is prepared by adopting the formula of the embodiment 7, and specifically comprises the following components: crushing the inactive inorganic substance to 11000-12000 meshes of a preset particle size to obtain inactive inorganic substance powder of the preset particle size; crushing the active inorganic substance to 11000-12000 meshes of a preset particle size to obtain active inorganic substance powder of the preset particle size; mixing the inactive inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powder; and mixing the mixed inorganic powder and the mineral pigment, and then mixing and coating the mixture with a surface coating agent to obtain the color active mixed material. And (3) uniformly mixing the materials, injecting the mixture into a mold, and steaming and pressing the mixture at 160 ℃ for 1.5 hours to obtain the mobile phone shell. The impact strength of the material is 3.5J x m -1 Density of 1.1 g/cc, fire rating of AAnd the artificial aging resistance experiment can reach more than 3500 h.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
Although embodiments of the present invention have been shown and described above, it will be understood that the above embodiments are exemplary and not to be construed as limiting the present invention, and that changes, modifications, substitutions and alterations can be made to the above embodiments by those of ordinary skill in the art within the scope of the present invention.

Claims (9)

1. A color active hybrid material, comprising: inactive inorganic substances, active inorganic substances, surface coating agents; the mass ratio of the non-active inorganic substance to the active inorganic substance is 1: (1-4); the mass ratio of the inactive inorganic substance to the active inorganic substance to the surface coating agent is 100:0.4-8; the inactive inorganic substance is selected from at least one of natural soil, quartz and limestone; the active inorganic matter is selected from at least one of sintered red brick waste blocks, cement waste blocks, volcanic ash, blast furnace slag, phosphate rock slag and fly ash; the surface coating agent is at least one selected from the group consisting of a higher ammonium salt, octadecylamine, a fluorocarbon surfactant, gamma-aminopropyltriethoxysilane, glutathione, cysteine, acacia, gelatin, polypyrrolidone, 3-aminopropyltrimethoxysilane, dopamine, levodopa, dopamine hydrochloride, bovine serum albumin, polyethyleneimine, chitosan, tridecafluorooctyltrimethoxysilane, tridecafluorooctyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltrimethoxysilane, an organoamine halide acid, and an oligopeptide.
2. The color active hybrid material according to claim 1, further comprising a mineral pigment;
the mass ratio of the sum of the masses of the inactive inorganic substance and the active inorganic substance to the mineral pigment is 100: (0-20);
the mass ratio of the sum of the masses of the non-active inorganic substance, the active inorganic substance and the mineral pigment to the surface coating agent is 100:0.2 to 5;
the mineral pigment is at least one selected from iron oxide red, iron oxide yellow, iron oxide black, carbon black, zinc oxide and titanium white.
3. A method of preparing a colour active hybrid material according to any one of claims 1-2, comprising:
respectively crushing the inactive inorganic matters into preset particle sizes according to colors so as to obtain inactive inorganic matter powder with different colors and preset particle sizes;
respectively crushing the active inorganic matters into preset particle sizes according to colors so as to obtain active inorganic matter powder with different colors and preset particle sizes;
mixing the non-active inorganic substance powder and the active inorganic substance powder to obtain mixed inorganic substance powders with different colors;
and mixing and coating the mixed inorganic substance powder and the surface coating agent to obtain the color active mixed material.
4. The method according to claim 3, characterized in that the mixed inorganic powder is mixed with mineral pigments before the mixed inorganic powder is subjected to the coating treatment;
the particle size of the inactive inorganic substance powder is 80-12000 meshes;
the particle size of the active inorganic substance powder is 80-12000 meshes.
5. A cement member, characterized in that it is produced using the color active hybrid material according to any one of claims 1-2 or the color active hybrid material produced by the method according to any one of claims 3-4.
6. A coating, comprising: 5-20wt% of water-based high molecular polymer with solid content of 50wt%, 2-17wt% of water, 70-95wt% of color active mixed material, wherein the color active mixed material is the color active mixed material described in any one of claims 1-2, or the color active mixed material prepared by the method described in any one of claims 3-4.
7. A building block, comprising: 8-16wt% of water, 0-10wt% of acrylic rubber powder, 0-15wt% of water glass, and 80-92wt% of color active mixed material, wherein the color active mixed material is the color active mixed material in any one of claims 1-2, or the color active mixed material prepared by the method in any one of claims 3-4.
8. A sheet or plate, wherein the sheet or plate is prepared from the color active hybrid material according to any one of claims 1-2, or the color active hybrid material prepared by the method according to any one of claims 3-4.
9. A profile or a housing, characterized in that the profile or the housing is prepared by using the color active hybrid material according to any one of claims 1 to 2 or the color active hybrid material prepared by using the method according to any one of claims 3 to 4.
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