CN112553009A - Cleaning agent for rubber mold and using method thereof - Google Patents
Cleaning agent for rubber mold and using method thereof Download PDFInfo
- Publication number
- CN112553009A CN112553009A CN202011363099.3A CN202011363099A CN112553009A CN 112553009 A CN112553009 A CN 112553009A CN 202011363099 A CN202011363099 A CN 202011363099A CN 112553009 A CN112553009 A CN 112553009A
- Authority
- CN
- China
- Prior art keywords
- parts
- cleaning agent
- agent
- nano
- rubber mold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 75
- 229920001971 elastomer Polymers 0.000 title claims abstract description 74
- 238000000034 method Methods 0.000 title claims description 13
- 239000002245 particle Substances 0.000 claims abstract description 55
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000003960 organic solvent Substances 0.000 claims abstract description 37
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 27
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000013556 antirust agent Substances 0.000 claims abstract description 24
- 239000004094 surface-active agent Substances 0.000 claims abstract description 24
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 23
- 239000002270 dispersing agent Substances 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 18
- -1 polyoxyethylene sodium Polymers 0.000 claims abstract description 17
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 16
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims abstract description 10
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 10
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 claims abstract description 8
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011259 mixed solution Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 8
- 239000000243 solution Substances 0.000 claims abstract description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 27
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- 238000004140 cleaning Methods 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000002791 soaking Methods 0.000 claims description 7
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 6
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 6
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 239000011780 sodium chloride Substances 0.000 claims description 5
- 239000001488 sodium phosphate Substances 0.000 claims description 5
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 239000008096 xylene Substances 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 3
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims description 3
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 3
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000000176 sodium gluconate Substances 0.000 claims description 3
- 235000012207 sodium gluconate Nutrition 0.000 claims description 3
- 229940005574 sodium gluconate Drugs 0.000 claims description 3
- SYBYTAAJFKOIEJ-UHFFFAOYSA-N 3-Methylbutan-2-one Chemical compound CC(C)C(C)=O SYBYTAAJFKOIEJ-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 abstract description 2
- 239000002002 slurry Substances 0.000 description 3
- 125000005587 carbonate group Chemical group 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/185—Hydrocarbons cyclic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/44—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/46—Specific cleaning or washing processes applying energy, e.g. irradiation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
A cleaning agent for rubber molds is composed of, by mass, 5-15 parts of 1, 3-dioxolane, 2-10 parts of imidazole, 1-10 parts of a surfactant, 1-5 parts of a dispersing agent, 5-10 parts of an antirust agent, 2-5 parts of an inorganic salt, 1-10 parts of hydrogen peroxide, 2-6 parts of nano-oxide particles, 0.1-1 part of an antifoaming agent, 0.001-0.01 part of nano-platinum particles and 40-60 parts of an organic solvent, wherein the surfactant is a mixture of sodium dodecyl benzene sulfonate and sodium alkyl polyoxyethylene ether sulfate in a mass ratio of 1:3, and the antirust agent is long-chain carboxylate polyoxyethylene sodium sulfonate; the preparation steps of the cleaning agent are as follows: A. mixing cyclohexane, imidazole, a surfactant, a dispersant, inorganic salt, hydrogen peroxide, a defoaming agent and an organic solvent according to the mass portion ratio, and stirring at the temperature of 50-80 ℃ at the speed of 800 revolutions per minute until the solution is uniform; B. and D, adding the antirust agent, the nano oxide particles and the nano platinum particles into the mixed solution obtained in the step A, and continuously stirring for 2-5 hours to obtain the cleaning agent.
Description
Technical Field
The invention relates to the field of rubber molds, in particular to a cleaning agent for a rubber mold and a using method thereof.
Background
The rubber mold is very easy to form particles on the surface when being used for a long time, which may be volatile components generated during heating or exudation on the surface of a formed product, and may also be residues of a release agent, and due to the existence of the particles or impurities, the next use of the mold is poor, and the forming size, the appearance and the release property of the product are adversely affected, so that the rubber mold needs to be cleaned after being used to remove oil stains and pollutants on the surface. Although the cleaning agent widely used at present can play a certain role, the cleaning agent cannot effectively remove the nano-scale particles remained on the surface of the rubber mold, so that the cleaning agent capable of effectively removing the surface residual slurry and removing the nano-scale magazines with the surfaces not easy to remove needs to be developed.
Disclosure of Invention
The invention provides a cleaning agent for a rubber mold and a using method thereof, aiming at solving the problems that residual slurry is easy to adhere to the surface of the mold after the mold is used and the mold is difficult to clean in the prior art.
The scheme adopted by the invention is as follows:
a cleaning agent for rubber molds is composed of, by mass, 5-15 parts of 1, 3-dioxolane, 2-10 parts of imidazole, 1-10 parts of a surfactant, 1-5 parts of a dispersing agent, 5-10 parts of an antirust agent, 2-5 parts of an inorganic salt, 1-10 parts of hydrogen peroxide, 2-6 parts of nano-oxide particles, 0.1-1 part of an antifoaming agent, 0.001-0.01 part of nano-platinum particles and 40-60 parts of an organic solvent, wherein the surfactant is a mixture of sodium dodecyl benzene sulfonate and sodium alkyl polyoxyethylene ether sulfate in a mass ratio of 1:3, and the antirust agent is long-chain carboxylate polyoxyethylene sodium sulfonate;
the preparation steps of the cleaning agent are as follows:
A. mixing cyclohexane, imidazole, a surfactant, a dispersant, inorganic salt, hydrogen peroxide, a defoaming agent and an organic solvent according to the mass portion ratio, and stirring at the temperature of 50-80 ℃ at the speed of 800 revolutions per minute until the solution is uniform;
B. and D, adding the antirust agent, the nano oxide particles and the nano platinum particles into the mixed solution obtained in the step A, and continuously stirring for 2-5 hours to obtain the cleaning agent.
As a preferred technical scheme of the invention, the dispersing agent is one or a mixture of more of polyacrylic acid, sodium polyacrylate, sodium gluconate, tetrasodium ethylene diamine tetraacetate, disodium ethylene diamine tetraacetate, polyisobutylene amine, alkyl polyurethane or diethylaminoethanol.
In a preferred embodiment of the present invention, the inorganic salt is a mixture of one or more of carbonate, phosphate, sulfate, or nitrate.
In a preferred embodiment of the present invention, the inorganic salt includes at least one of a sodium salt and a potassium salt.
As a preferred technical scheme of the invention, the inorganic salt is composed of 30-50 parts of sodium carbonate, 30-50 parts of sodium phosphate and 30-50 parts of sodium chloride by mass.
As a preferred technical scheme of the invention, the nano oxide particles are one or a mixture of several of nano alumina particles, nano silica particles, nano titanium oxide particles, nano iron oxide particles, nano zinc oxide particles and nano zirconium oxide particles.
In a preferred embodiment of the present invention, the defoaming agent is one of polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether and polyoxypropylene polyoxyethylene glycerol ether.
As a preferred technical scheme of the invention, the organic solvent is one or a mixture of more of methanol, ethanol, propanol, isopropanol, benzene, toluene, xylene, styrene, perchloroethylene, trichloroethylene, hexane, cyclohexane, chlorobenzene, diethyl ether, propylene oxide, acetone, methyl butanone, acetonitrile and phenol.
A use method of a cleaning agent for a rubber mold comprises the following steps:
A. coating the cleaning agent for the rubber mold on the surface of the rubber mold to be cleaned, and standing for 10-30 minutes;
B. b, placing the rubber mold coated with the cleaning agent obtained in the step A into an ultrasonic cleaner, and ultrasonically cleaning for 0.5-3 hours at the temperature of 50-80 ℃, wherein the same cleaning agent is added into the ultrasonic cleaner in an amount such that the liquid level is 5-20 cm higher than that of the rubber mold;
C. and D, soaking the rubber mold subjected to ultrasonic cleaning treatment in the step B in an organic solvent, ultrasonically cleaning for 30-60 minutes to remove the residual cleaning agent on the surface, and drying to obtain the cleaned rubber mold.
As a preferred technical scheme of the invention, the organic solvent in the step C is one or a mixture of acetone, xylene or absolute ethyl alcohol.
Compared with the prior art, the invention has the beneficial effects that: the prepared cleaning agent has a good cleaning effect, can effectively remove slurry remained on the surface of the rubber mold, and is convenient for the next use of the mold.
Detailed Description
The present invention is further described with reference to the following examples, which are provided for illustration only and are not to be construed as limiting the scope of the claims, and other alternatives which may occur to those skilled in the art are also within the scope of the claims.
Example 1
The cleaning agent for the rubber mold comprises, by mass, 5 parts of 1, 3-dioxolane, 2 parts of imidazole, 1 part of a surfactant, 1 part of a dispersing agent, 5 parts of an antirust agent, 2 parts of an inorganic salt, 1 part of hydrogen peroxide, 2 parts of nano oxide particles, 0.1 part of an antifoaming agent, 0.001 part of nano platinum particles and 40 parts of an organic solvent, wherein the surfactant is a mixture of sodium dodecyl benzene sulfonate and sodium alkyl polyoxyethylene ether sulfate in a mass ratio of 1:3, and the antirust agent is long-chain carboxylic ester polyoxyethylene sodium sulfonate;
the preparation steps of the cleaning agent are as follows:
A. mixing cyclohexane, imidazole, a surfactant, a dispersing agent, inorganic salt, hydrogen peroxide, a defoaming agent and an organic solvent according to the mass ratio, and stirring at the temperature of 50 ℃ at the speed of 300 r/min until the solution is uniform;
B. and D, adding the antirust agent, the nano oxide particles and the nano platinum particles into the mixed solution obtained in the step A, and continuously stirring for 2 hours to obtain the cleaning agent.
In particular, the dispersant is polyacrylic acid.
In particular, the inorganic salt is a carbonate.
In particular, the nano-oxide particles are nano-alumina particles.
Specifically, the antifoaming agent is polyoxyethylene polyoxypropylene ether.
Specifically, the organic solvent is methanol.
The use method of the cleaning agent for the rubber mold comprises the following steps:
A. coating the cleaning agent for the rubber mold on the surface of the rubber mold to be cleaned, and standing for 10 minutes;
B. b, placing the rubber mold coated with the cleaning agent obtained in the step A into an ultrasonic cleaner, controlling the temperature to be 50 ℃, and ultrasonically cleaning for 0.5 hour, wherein the same cleaning agent is added into the ultrasonic cleaner in an amount such that the liquid level is 5 cm higher than that of the rubber mold;
C. and D, soaking the rubber mold subjected to ultrasonic cleaning treatment in the step B in an organic solvent, ultrasonically cleaning for 30 minutes to remove residual cleaning agent on the surface, and drying to obtain a cleaned rubber mold.
Specifically, the organic solvent in step C is acetone.
Example 2
A cleaning agent for rubber molds is composed of 15 parts of 1, 3-dioxolane, 10 parts of imidazole, 10 parts of surfactant, 5 parts of dispersant, 10 parts of antirust agent, 5 parts of inorganic salt, 10 parts of hydrogen peroxide, 6 parts of nano oxide particles, 1 part of defoaming agent, 0.01 part of nano platinum particles and 60 parts of organic solvent according to mass parts, wherein the surfactant is a mixture of sodium dodecyl benzene sulfonate and sodium alkyl polyoxyethylene ether sulfate in a mass ratio of 1:3, and the antirust agent is long-chain carboxylic ester polyoxyethylene sodium sulfonate;
the preparation steps of the cleaning agent are as follows:
A. mixing cyclohexane, imidazole, a surfactant, a dispersing agent, inorganic salt, hydrogen peroxide, a defoaming agent and an organic solvent according to the mass ratio, and stirring at the temperature of 80 ℃ at the speed of 800 revolutions per minute until the solution is uniform;
B. and D, adding the antirust agent, the nano oxide particles and the nano platinum particles into the mixed solution obtained in the step A, and continuously stirring for 5 hours to obtain the cleaning agent.
Specifically, the dispersant is disodium ethylenediaminetetraacetate.
Specifically, the inorganic salt is composed of 50 parts by mass of sodium carbonate, 50 parts by mass of sodium phosphate and 50 parts by mass of sodium chloride.
In particular, the nano-oxide particles are nano-silica particles.
Specifically, the antifoaming agent is polyoxyethylene polyoxypropylene ether.
Specifically, the organic solvent is ethanol.
The use method of the cleaning agent for the rubber mold comprises the following steps:
A. coating the cleaning agent for the rubber mold on the surface of the rubber mold to be cleaned, and standing for 30 minutes;
B. b, placing the rubber mold coated with the cleaning agent obtained in the step A into an ultrasonic cleaner, and ultrasonically cleaning for 3 hours at the temperature of 80 ℃, wherein the same cleaning agent is added into the ultrasonic cleaner in an amount such that the liquid level is 20 cm higher than that of the rubber mold;
C. and D, soaking the rubber mold subjected to ultrasonic cleaning treatment in the step B in an organic solvent, ultrasonically cleaning for 60 minutes to remove residual cleaning agent on the surface, and drying to obtain a cleaned rubber mold.
Specifically, the organic solvent in step C is acetone.
Example 3
A cleaning agent for rubber molds comprises, by mass, 10 parts of 1, 3-dioxolane, 5 parts of imidazole, 5 parts of a surfactant, 3 parts of a dispersant, 8 parts of an antirust agent, 3 parts of an inorganic salt, 5 parts of hydrogen peroxide, 5 parts of nano-oxide particles, 0.5 part of an antifoaming agent, 0.005 part of nano-platinum particles and 50 parts of an organic solvent, wherein the surfactant is a mixture of sodium dodecyl benzene sulfonate and sodium alkyl polyoxyethylene ether sulfate in a mass ratio of 1:3, and the antirust agent is long-chain carboxylic ester polyoxyethylene sodium sulfonate;
the preparation steps of the cleaning agent are as follows:
A. mixing cyclohexane, imidazole, a surfactant, a dispersing agent, inorganic salt, hydrogen peroxide, a defoaming agent and an organic solvent according to the mass part ratio, and stirring at the speed of 500 revolutions per minute at the temperature of 60 ℃ until the solution is uniform;
B. and D, adding the antirust agent, the nano oxide particles and the nano platinum particles into the mixed solution obtained in the step A, and continuously stirring for 2-5 hours to obtain the cleaning agent.
In particular, the dispersant is an alkyl polyurethane.
Specifically, the inorganic salt is composed of 30 parts by mass of sodium carbonate, 30 parts by mass of sodium phosphate and 30 parts by mass of sodium chloride.
In particular, the nano-oxide particles are nano-zinc oxide particles.
Specifically, the antifoaming agent is polyoxyethylene polyoxypropylene ether.
Specifically, the organic solvent is cyclohexane.
The use method of the cleaning agent for the rubber mold comprises the following steps:
A. coating the cleaning agent for the rubber mold on the surface of the rubber mold to be cleaned, and standing for 20 minutes;
B. b, placing the rubber mold coated with the cleaning agent obtained in the step A into an ultrasonic cleaner, and ultrasonically cleaning for 2 hours at the temperature of 60 ℃, wherein the same cleaning agent is added into the ultrasonic cleaner in an amount which enables the liquid level to be 10 cm higher than that of the rubber mold;
C. and D, soaking the rubber mold subjected to ultrasonic cleaning treatment in the step B in an organic solvent, ultrasonically cleaning for 30-60 minutes to remove the residual cleaning agent on the surface, and drying to obtain the cleaned rubber mold.
Specifically, the organic solvent in step C is acetone.
Example 4
A cleaning agent for rubber molds comprises, by mass, 8 parts of 1, 3-dioxolane, 6 parts of imidazole, 8 parts of a surfactant, 3 parts of a dispersant, 8 parts of an antirust agent, 3 parts of an inorganic salt, 3 parts of hydrogen peroxide, 5 parts of nano-oxide particles, 0.3 part of an antifoaming agent, 0.006 part of nano-platinum particles and 50 parts of an organic solvent, wherein the surfactant is a mixture of sodium dodecyl benzene sulfonate and sodium alkyl polyoxyethylene ether sulfate in a mass ratio of 1:3, and the antirust agent is long-chain carboxylic ester polyoxyethylene sodium sulfonate;
the preparation steps of the cleaning agent are as follows:
A. mixing cyclohexane, imidazole, a surfactant, a dispersing agent, inorganic salt, hydrogen peroxide, a defoaming agent and an organic solvent according to the mass ratio, and stirring at the speed of 800 revolutions per minute at the temperature of 50 ℃ until the solution is uniform;
B. and D, adding the antirust agent, the nano oxide particles and the nano platinum particles into the mixed solution obtained in the step A, and continuously stirring for 2-5 hours to obtain the cleaning agent.
In particular, the dispersant is diethylaminoethanol.
Specifically, the inorganic salt is composed of 30 parts by mass of sodium carbonate, 30 parts by mass of sodium phosphate and 50 parts by mass of sodium chloride.
In particular, the nano-oxide particles are nano-zinc oxide particles.
Specifically, the antifoaming agent is polyoxypropylene glycerol ether.
Specifically, the organic solvent is ethanol.
The use method of the cleaning agent for the rubber mold comprises the following steps:
A. coating the cleaning agent for the rubber mold on the surface of the rubber mold to be cleaned, and standing for 20 minutes;
B. b, placing the rubber mold coated with the cleaning agent obtained in the step A into an ultrasonic cleaner, and ultrasonically cleaning for 2 hours at the temperature of 70 ℃, wherein the same cleaning agent is added into the ultrasonic cleaner in an amount which enables the liquid level to be 15 cm higher than that of the rubber mold;
C. and D, soaking the rubber mold subjected to ultrasonic cleaning treatment in the step B in an organic solvent, ultrasonically cleaning for 50 minutes to remove the residual cleaning agent on the surface, and drying to obtain the cleaned rubber mold.
Specifically, the organic solvent in step C is acetone.
Example 5
A cleaning agent for rubber molds comprises, by mass, 7 parts of 1, 3-dioxolane, 6 parts of imidazole, 3 parts of a surfactant, 2 parts of a dispersant, 8 parts of an antirust agent, 3 parts of an inorganic salt, 1 part of hydrogen peroxide, 5 parts of nano-oxide particles, 0.6 part of an antifoaming agent, 0.01 part of nano-platinum particles and 50 parts of an organic solvent, wherein the surfactant is a mixture of sodium dodecyl benzene sulfonate and sodium alkyl polyoxyethylene ether sulfate in a mass ratio of 1:3, and the antirust agent is long-chain carboxylic ester polyoxyethylene sodium sulfonate;
the preparation steps of the cleaning agent are as follows:
A. mixing cyclohexane, imidazole, a surfactant, a dispersing agent, inorganic salt, hydrogen peroxide, a defoaming agent and an organic solvent according to the mass part ratio, and stirring at the temperature of 70 ℃ at the speed of 600 revolutions per minute until the solution is uniform;
B. and D, adding the antirust agent, the nano oxide particles and the nano platinum particles into the mixed solution obtained in the step A, and continuously stirring for 5 hours to obtain the cleaning agent.
Specifically, the dispersant is sodium gluconate.
In particular, the inorganic salt is a carbonate.
Specifically, the nano-oxide particles are a mixture of nano-alumina particles and nano-silica particles in a mass ratio of 1: 1.
Specifically, the antifoaming agent is polyoxyethylene polyoxypropylene ether.
Specifically, the organic solvent is methanol.
A use method of a cleaning agent for a rubber mold comprises the following steps:
A. coating the cleaning agent for the rubber mold on the surface of the rubber mold to be cleaned, and standing for 10 minutes;
B. b, placing the rubber mold coated with the cleaning agent obtained in the step A into an ultrasonic cleaner, and ultrasonically cleaning for 2 hours at the temperature of 50 ℃, wherein the same cleaning agent is added into the ultrasonic cleaner in an amount which enables the liquid level to be 10 cm higher than that of the rubber mold;
C. and D, soaking the rubber mold subjected to ultrasonic cleaning treatment in the step B in an organic solvent, ultrasonically cleaning for 50 minutes to remove the residual cleaning agent on the surface, and drying to obtain the cleaned rubber mold.
Specifically, the organic solvent in step C is acetone.
The above examples are merely illustrative for clarity and are not intended to limit the embodiments. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. And obvious variations or modifications therefrom are within the scope of the invention.
Claims (10)
1. A cleaning agent for a rubber mold is characterized in that: the antirust paint consists of 5-15 parts by mass of 1, 3-dioxolane, 2-10 parts by mass of imidazole, 1-10 parts by mass of surfactant, 1-5 parts by mass of dispersant, 5-10 parts by mass of antirust agent, 2-5 parts by mass of inorganic salt, 1-10 parts by mass of hydrogen peroxide, 2-6 parts by mass of nano-oxide particles, 0.1-1 part by mass of defoaming agent, 0.001-0.01 part by mass of nano-platinum particles and 40-60 parts by mass of organic solvent, wherein the surfactant is a mixture of sodium dodecyl benzene sulfonate and sodium alkyl polyoxyethylene ether sulfate in a mass ratio of 1:3, and the antirust agent is long-chain carboxylic ester polyoxyethylene sodium sulfonate;
the preparation steps of the cleaning agent are as follows:
A. mixing cyclohexane, imidazole, a surfactant, a dispersant, inorganic salt, hydrogen peroxide, a defoaming agent and an organic solvent according to the mass portion ratio, and stirring at the temperature of 50-80 ℃ at the speed of 800 revolutions per minute until the solution is uniform;
B. and D, adding the antirust agent, the nano oxide particles and the nano platinum particles into the mixed solution obtained in the step A, and continuously stirring for 2-5 hours to obtain the cleaning agent.
2. The cleaning agent for a rubber mold as claimed in claim 1, wherein: the dispersing agent is one or a mixture of more of polyacrylic acid, sodium polyacrylate, sodium gluconate, tetrasodium ethylene diamine tetraacetate, disodium ethylene diamine tetraacetate, polyisobutene amine, alkyl polyurethane or diethylamino ethanol.
3. The cleaning agent for a rubber mold as claimed in claim 1, wherein: the inorganic salt is one or more of carbonate, phosphate, sulfate or nitrate.
4. The cleaning agent for a rubber mold as claimed in claim 1, wherein: the inorganic salt at least comprises one of sodium salt or potassium salt.
5. The cleaning agent for a rubber mold as claimed in claim 4, wherein: the inorganic salt is composed of 30-50 parts of sodium carbonate, 30-50 parts of sodium phosphate and 30-50 parts of sodium chloride by mass.
6. The cleaning agent for a rubber mold as claimed in claim 1, wherein: the nano oxide particles are one or a mixture of several of nano alumina particles, nano silica particles, nano titanium oxide particles, nano iron oxide particles, nano zinc oxide particles and nano zirconium oxide particles.
7. The cleaning agent for a rubber mold as claimed in claim 1, wherein: the defoaming agent is one of polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether or polyoxypropylene polyoxyethylene glycerol ether.
8. The cleaning agent for a rubber mold as claimed in claim 1, wherein: the organic solvent is one or a mixture of methanol, ethanol, propanol, isopropanol, benzene, toluene, xylene, styrene, perchloroethylene, trichloroethylene, hexane, cyclohexane, chlorobenzene, diethyl ether, propylene oxide, acetone, methyl butanone, acetonitrile and phenol.
9. The use method of the cleaning agent for rubber molds as defined in claim 1, wherein: the method comprises the following steps:
A. coating the cleaning agent for the rubber mold on the surface of the rubber mold to be cleaned, and standing for 10-30 minutes;
B. b, placing the rubber mold coated with the cleaning agent obtained in the step A into an ultrasonic cleaner, and ultrasonically cleaning for 0.5-3 hours at the temperature of 50-80 ℃, wherein the same cleaning agent is added into the ultrasonic cleaner in an amount such that the liquid level is 5-20 cm higher than that of the rubber mold;
C. and D, soaking the rubber mold subjected to ultrasonic cleaning treatment in the step B in an organic solvent, ultrasonically cleaning for 30-60 minutes to remove the residual cleaning agent on the surface, and drying to obtain the cleaned rubber mold.
10. The use method of the cleaning agent for rubber molds according to claim 9, characterized in that: and C, the organic solvent is one or a mixture of acetone, xylene or absolute ethyl alcohol.
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| CN202011363099.3A CN112553009A (en) | 2020-11-28 | 2020-11-28 | Cleaning agent for rubber mold and using method thereof |
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| CN202011363099.3A CN112553009A (en) | 2020-11-28 | 2020-11-28 | Cleaning agent for rubber mold and using method thereof |
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| JP2001293730A (en) * | 2000-04-17 | 2001-10-23 | Bridgestone Corp | Rubber composition for washing mold |
| TW567213B (en) * | 2000-05-06 | 2003-12-21 | Geun-Bong Jung | Rubber composition for washing mold |
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