CN112457710A - Temperature-resistant composite-color water-based ink applied to helmet - Google Patents

Temperature-resistant composite-color water-based ink applied to helmet Download PDF

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Publication number
CN112457710A
CN112457710A CN202011275981.2A CN202011275981A CN112457710A CN 112457710 A CN112457710 A CN 112457710A CN 202011275981 A CN202011275981 A CN 202011275981A CN 112457710 A CN112457710 A CN 112457710A
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Prior art keywords
water
based ink
composite
temperature
color
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Inventor
张刚
霍朝晖
潘艺林
韦毅
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Shenzhen Fangrun Environment Technology Co ltd
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Shenzhen Fangrun Environment Technology Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides a temperature-resistant composite color water-based ink applied to a helmet, and relates to the technical field of fine chemical industry and coating industry. The temperature-resistant composite color water-based ink applied to the helmet comprises the following specific components: the temperature-resistant water-based ink and the water-based ink gloss oil comprise the following components in percentage by mass: 34.5 percent of B-301 acrylic resin; 27% of B-305 acrylic resin; 25% of B-103 polyurethane resin; 0.5 percent of alkali regulator; 8% of composite film-forming additive; 1% of a composite leveling agent; s-101, 1% of matte powder; 0.5-1% of composite thickening agent; 1% of composite defoaming agent. The orange printing ink comprises the following components in percentage by mass: 44.65% of water-based ink gloss oil. The water-based ink gloss oil prepared by the formula is used as the main material of the composite ink, and the temperature-resistant composite color water-based ink is compounded by adding color pastes with different colors and deionized water, so that the problem of color leakage in the plastic suction process is effectively solved, and the overall performance of the water-based ink gloss oil is greatly improved.

Description

Temperature-resistant composite-color water-based ink applied to helmet
Technical Field
The invention relates to the technical field of fine chemical industry and coating industry, in particular to temperature-resistant composite color water-based ink applied to helmets.
Background
The water-based ink is a uniform slurry-like substance composed of a binder, a pigment, an auxiliary agent and the like, wherein the binder provides the necessary transfer performance of the ink, and the pigment provides the color to the ink. The vehicle of the water-based ink is mainly divided into two types, namely a water-diluted type and a water-dispersed type. The former can be used in a wide variety of resin types, such as maleic acid resin, shellac, maleic acid resin-modified shellac, urethane, water-soluble acrylic resin, and aqueous amino resin; the water dispersion type vehicle is obtained by polymerizing an emulsified monomer in water, and is considered to be an oil-in-water emulsion type because it is a two-phase system in which an oil phase is dispersed in a water phase in the form of particles and can be diluted with water although it cannot be dissolved in water.
The water-based ink usually adopts purified water as a diluent, VOC volatilization is less, residual toxics are reduced, when a screen printing plate is cleaned, oil-based ink needs to be cleaned by a large amount of organic solvent, and water-based ink only needs water to achieve the cleaning purpose.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a temperature-resistant composite color water-based ink applied to a helmet, which solves the problem that the color of the existing ink prepared by composite color is greatly different from a sample plate due to color leakage in the process of plastic suction.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: a temperature-resistant composite color water-based ink applied to a helmet comprises the following specific components:
temperature-resistant water-based ink
The water-based ink gloss oil comprises the following components in percentage by mass:
Figure BDA0002779067930000021
temperature-resistant composite color water-based ink
A. The orange printing ink comprises the following components in percentage by mass:
Figure BDA0002779067930000022
B. the gray ink comprises the following components in percentage by mass:
Figure BDA0002779067930000023
Figure BDA0002779067930000031
preferably, the temperature-resistant composite color water-based ink is prepared by taking the temperature-resistant water-based ink as a base material and adding color pastes with different colors and deionized water.
A preparation method of temperature-resistant composite color water-based ink applied to a helmet comprises the following specific steps:
s1, sequentially adding 34.5% of B-301 acrylic resin, 27% of B-305 acrylic resin, 25% of B-103 polyurethane resin, 0.5% of an alkali regulator, 8% of a composite film-forming aid, 1% of a composite leveling agent, 1% of S-101 matte powder and 1% of a composite thickening agent into a stirrer for uniform stirring;
s2, after the raw materials are fully fused, adding 1% of composite defoaming agent to continue stirring, controlling the rotating speed of a stirrer within 1000r/min, and stirring for a while to obtain the water-based ink gloss oil;
s3, adding 44.65% of white paste, 8.3% of 210 yellow paste, 0.4% of 3020% of red paste and 2% of deionized water into the prepared water-based ink gloss oil in sequence, and stirring to obtain orange ink;
s4, adding 44.65% of white slurry, 0.5% of carbon black, 7.88% of 210 yellow slurry, 0.32% of CA457 red slurry and 2% of deionized water into the prepared water-based ink gloss oil in sequence, and stirring to obtain gray ink;
preferably, the stirring time of each raw material added into the S1 is 3-5 min.
Preferably, the stirring time after the composite antifoaming agent is added to S2 is 10 min.
(III) advantageous effects
The invention provides a temperature-resistant composite color water-based ink applied to a helmet. The method has the following beneficial effects:
1. the temperature-resistant composite-color water-based ink applied to the helmet is convenient to produce and process quickly by adopting a simple processing technology, and meanwhile, the overall quality of the processed composite-color water-based ink is also ensured, so that the overall color of the composite-color water-based ink can reach the quality of a sample plate.
2. According to the temperature-resistant composite-color water-based ink applied to the helmet, the water-based ink gloss oil prepared by the formula is used as the main material of the composite ink, and the temperature-resistant composite-color water-based ink is compounded by adding color pastes with different colors and deionized water, so that the problem of color leakage in the plastic suction process is effectively solved, the overall performance of the composite-color water-based ink is greatly improved, and the composite-color water-based ink is worthy of vigorous popularization.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the embodiment of the invention provides a temperature-resistant composite color water-based ink applied to a helmet, which comprises the following specific components:
temperature-resistant water-based ink
The water-based ink gloss oil comprises the following components in percentage by mass:
Figure BDA0002779067930000041
temperature-resistant composite color water-based ink
A. The orange printing ink comprises the following components in percentage by mass:
Figure BDA0002779067930000042
Figure BDA0002779067930000051
B. the gray ink comprises the following components in percentage by mass:
Figure BDA0002779067930000052
the temperature-resistant composite color water-based ink is prepared by taking the temperature-resistant water-based ink as a base material and adding color pastes with different colors and deionized water.
A preparation method of temperature-resistant composite color water-based ink applied to a helmet comprises the following specific steps:
s1, sequentially adding 34.5% of B-301 acrylic resin, 27% of B-305 acrylic resin, 25% of B-103 polyurethane resin, 0.5% of an alkali regulator, 8% of a composite film-forming aid, 1% of a composite leveling agent, 1% of S-101 matte powder and 1% of a composite thickening agent into a stirrer for uniform stirring;
s2, after the raw materials are fully fused, adding 1% of composite defoaming agent to continue stirring, controlling the rotating speed of a stirrer within 1000r/min, and stirring for a while to obtain the water-based ink gloss oil;
s3, adding 44.65% of white paste, 8.3% of 210 yellow paste, 0.4% of 3020% of red paste and 2% of deionized water into the prepared water-based ink gloss oil in sequence, and stirring to obtain orange ink;
s4, adding 44.65% of white slurry, 0.5% of carbon black, 7.88% of 210 yellow slurry, 0.32% of CA457 red slurry and 2% of deionized water into the prepared water-based ink gloss oil in sequence, and stirring to obtain gray ink;
s1 the stirring time for each raw material is 3-5 min.
The stirring time after the composite antifoaming agent is added to S2 is 10 min.
Example two:
in this embodiment, on the basis of the first embodiment, the following specific components are mixed:
Figure BDA0002779067930000061
the preparation method comprises the following steps:
sequentially adding the materials into a stirrer in sequence, stirring uniformly, stirring for 3-5min each time to fully fuse, adding the defoaming agent, and stirring for 10min, wherein the rotating speed of the stirrer is controlled within 1000 r/min.
Adding color paste into the prepared water-based gloss oil, and matching the color paste with a sample plate for color matching, wherein the weight ratio of the color paste is as follows:
orange color:
Figure BDA0002779067930000062
gray:
Figure BDA0002779067930000063
Figure BDA0002779067930000071
orange and gray color change was observed at 260X1min, and the two sides of the PC sheet showed different colors.
Example three:
in this embodiment, on the basis of the first embodiment, the following specific components are mixed:
Figure BDA0002779067930000072
the preparation method comprises the following steps:
sequentially adding the components in sequence, stirring uniformly, stirring for 3-5min each time to fully fuse, adding defoaming agent, and stirring for 10min, wherein the rotation speed of the stirrer is controlled within 1000 r/min.
Adding color paste into the prepared water-based gloss oil, and matching the color paste with a sample plate for color matching, wherein the weight ratio of the color paste is as follows:
orange color:
Figure BDA0002779067930000073
gray:
Figure BDA0002779067930000081
under the test of 260X1min, moderate color migration is observed, the effect is better than that of the second embodiment, but the sample effect can not be achieved;
example four:
in this embodiment, on the basis of the first embodiment, the following specific components are mixed:
Figure BDA0002779067930000082
sequentially adding the components in sequence, stirring uniformly, stirring for 3-5min each time to fully fuse, adding defoaming agent, and stirring for 10min, wherein the rotation speed of the stirrer is controlled within 1000 r/min.
Adding color paste into the prepared water-based gloss oil, and matching the color paste with a sample plate for color matching, wherein the weight ratio of the color paste is as follows:
orange color:
Figure BDA0002779067930000083
Figure BDA0002779067930000091
gray:
Figure BDA0002779067930000092
the test time is 1min and 2min at 260 ℃, and the results are as follows:
temperature resistant gray: 260X1 min: Δ E ═ 0.686/0.92, 260X2 min: delta E1.05/1.13
Temperature resistance orange: 260X1 min: Δ E ═ 0.72/0.83, 260X2 min: delta E1.05/1.13
In conclusion, the aqueous ink gloss oil prepared by the formula is used as the main material of the composite ink, and the temperature-resistant composite color aqueous ink is compounded by adding color pastes with different colors and deionized water, so that the problem of color leakage in the plastic suction process is effectively solved, and the overall performance of the ink is greatly improved.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (5)

1. The heat-resistant composite color water-based ink applied to the helmet is characterized in that: comprises the following specific components:
temperature-resistant water-based ink
The water-based ink gloss oil comprises the following components in percentage by mass:
Figure FDA0002779067920000011
temperature-resistant composite color water-based ink
A. The orange printing ink comprises the following components in percentage by mass:
Figure FDA0002779067920000012
B. the gray ink comprises the following components in percentage by mass:
Figure FDA0002779067920000013
Figure FDA0002779067920000021
2. the temperature-resistant composite-color water-based ink applied to the helmet of claim 1, wherein: the temperature-resistant composite color water-based ink is prepared by taking the temperature-resistant water-based ink as a base material and adding color pastes with different colors and deionized water.
3. The preparation method of the temperature-resistant composite color water-based ink applied to the helmet according to claim 1, which is characterized in that: the method comprises the following specific steps:
s1, sequentially adding 34.5% of B-301 acrylic resin, 27% of B-305 acrylic resin, 25% of B-103 polyurethane resin, 0.5% of an alkali regulator, 8% of a composite film-forming aid, 1% of a composite leveling agent, 1% of S-101 matte powder and 1% of a composite thickening agent into a stirrer for uniform stirring;
s2, after the raw materials are fully fused, adding 1% of composite defoaming agent to continue stirring, controlling the rotating speed of a stirrer within 1000r/min, and stirring for a while to obtain the water-based ink gloss oil;
s3, adding 44.65% of white paste, 8.3% of 210 yellow paste, 0.4% of 3020% of red paste and 2% of deionized water into the prepared water-based ink gloss oil in sequence, and stirring to obtain orange ink;
s4, adding 44.65% of white slurry, 0.5% of carbon black, 7.88% of 210 yellow slurry, 0.32% of CA457 red slurry and 2% of deionized water into the prepared water-based ink gloss oil in sequence, and stirring to obtain gray ink;
4. the temperature-resistant composite-color water-based ink applied to the helmet according to claim 3, wherein: the stirring time of each raw material added into the S1 is 3-5 min.
5. The temperature-resistant composite-color water-based ink applied to the helmet according to claim 3, wherein: and the stirring time after the composite antifoaming agent is added into the S2 is 10 min.
CN202011275981.2A 2020-11-16 2020-11-16 Temperature-resistant composite-color water-based ink applied to helmet Pending CN112457710A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113831801A (en) * 2021-10-29 2021-12-24 闽江学院 Coating for inhibiting ink migration and preparation method and application thereof
CN115725203A (en) * 2021-08-31 2023-03-03 敬业（东莞）印刷包装厂有限公司 Orange printing ink and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105504974A (en) * 2016-01-14 2016-04-20 董耀辉 Water-based lottery printing ink for flexography and preparing method thereof
CN106479262A (en) * 2016-10-20 2017-03-08 中华制漆（深圳）有限公司 IMR dumb light ink and its preparation and application
CN108084784A (en) * 2018-02-10 2018-05-29 深圳市博力美实业有限公司 A kind of LED light cures helmet plastic uptake ink
CN108864813A (en) * 2018-09-10 2018-11-23 东莞市美吉高分子材料有限公司 A kind of environment-friendly energy-saving LED-UV helmet plastic uptake ink and its production method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105504974A (en) * 2016-01-14 2016-04-20 董耀辉 Water-based lottery printing ink for flexography and preparing method thereof
CN106479262A (en) * 2016-10-20 2017-03-08 中华制漆（深圳）有限公司 IMR dumb light ink and its preparation and application
CN108084784A (en) * 2018-02-10 2018-05-29 深圳市博力美实业有限公司 A kind of LED light cures helmet plastic uptake ink
CN108864813A (en) * 2018-09-10 2018-11-23 东莞市美吉高分子材料有限公司 A kind of environment-friendly energy-saving LED-UV helmet plastic uptake ink and its production method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115725203A (en) * 2021-08-31 2023-03-03 敬业（东莞）印刷包装厂有限公司 Orange printing ink and preparation method thereof
CN115725203B (en) * 2021-08-31 2024-04-12 当纳利(广东)印务有限公司 Orange ink and preparation method thereof
CN113831801A (en) * 2021-10-29 2021-12-24 闽江学院 Coating for inhibiting ink migration and preparation method and application thereof
CN113831801B (en) * 2021-10-29 2022-06-03 闽江学院 Coating for inhibiting ink migration and preparation method and application thereof

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Application publication date: 20210309