CN112433283A - Low-thermal-shrinkage self-adhesive optical reflecting film - Google Patents
Low-thermal-shrinkage self-adhesive optical reflecting film Download PDFInfo
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- CN112433283A CN112433283A CN202011399110.1A CN202011399110A CN112433283A CN 112433283 A CN112433283 A CN 112433283A CN 202011399110 A CN202011399110 A CN 202011399110A CN 112433283 A CN112433283 A CN 112433283A
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0033—Means for improving the coupling-out of light from the light guide
- G02B6/005—Means for improving the coupling-out of light from the light guide provided by one optical element, or plurality thereof, placed on the light output side of the light guide
- G02B6/0055—Reflecting element, sheet or layer
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0081—Mechanical or electrical aspects of the light guide and light source in the lighting device peculiar to the adaptation to planar light guides, e.g. concerning packaging
- G02B6/0086—Positioning aspects
- G02B6/0088—Positioning aspects of the light guide or other optical sheets in the package
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Nonlinear Science (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Laminated Bodies (AREA)
- Optical Elements Other Than Lenses (AREA)
Abstract
A low-thermal-shrinkage self-adhesive optical reflecting film comprises a reflecting film base layer, wherein resin layers are coated on two sides of the reflecting film base layer, and temperature-adjusting particles with a core-shell structure are filled in the resin layers; coating a glue layer containing an antistatic agent on the lower resin layer, and adhering a layer of stripping film on the glue layer; the reflection film base layer comprises a main body resin, organic particles incompatible with the main body resin and inorganic particles incompatible with the main body resin, the core layer is separated from the main body resin and the inorganic particles from the main body resin after being stretched to form cavities, and the density difference between the organic particles and the main body resin is less than 0.25g/cm3. The reflecting film is coated with the resin layer containing the temperature-regulating micro-particles on the two sides, so that the film layer can keep stable and proper working temperature by absorbing/releasing heat, and the reflecting film is prevented from shrinking and deforming due to the change of environmental temperature.
Description
Technical Field
The present invention relates to an optical reflective film.
Background
The liquid crystal display does not emit light, the display function benefits from modulating the light emitted by the backlight source, and the performance index of the display depends on the performance of the backlight source, so the quality of the light source performance of the backlight module directly influences the display quality of the liquid crystal. The reflective film is one of the most important optical films in the backlight module of the liquid crystal display, and in the liquid crystal display, the reflective film is arranged at the bottom of the backlight module of the light guide plate and reflects the light leaked from the light source back to the light guide plate, so that the light can be intensively projected from the front side, and the light is prevented from leaking, thereby achieving the purpose of increasing the use efficiency of the light. However, the heat generated by the long-time operation of the backlight module can cause the reflective film to generate thermal shrinkage deformation, and meanwhile, the reflective film is generally fixed in the backlight module by adhering shading glue at the edges of two surfaces, and the space above the reflective film is insufficient, so that the reflective film easily generates bad phenomena such as film arching, folding, layering and the like, and the display effect is seriously influenced. The structure of the reliability of the optical film is not designed in the traditional backlight module structure. Therefore, the prior art is not sufficient and needs to be improved.
Disclosure of Invention
In order to overcome the defects of the existing reflecting film, the invention provides a low-thermal-shrinkage self-adhesive optical reflecting film.
The technical scheme for solving the technical problem is as follows: a low-thermal-shrinkage self-adhesive optical reflecting film comprises a reflecting film base layer, wherein resin layers are coated on two sides of the reflecting film base layer, and temperature-adjusting particles with a core-shell structure are filled in the resin layers;
the lower resin layer is coated with a glue layer containing an antistatic agent, and a layer of stripping film is adhered on the glue layer;
the reflection film base layer comprises a main body resin, organic particles incompatible with the main body resin and inorganic particles incompatible with the main body resin, the core layer is separated from the main body resin and the inorganic particles from the main body resin after being stretched to form cavities, and the density difference between the organic particles and the main body resin is less than 0.25g/cm3。
Preferably, the resin layer is epoxy resin, acrylic resin or organic silicon.
Preferably, the shell layer of the temperature-adjusting particle with the core-shell structure is SiO2Or TiO2Or ZnO, or BaTiO3The core layer is paraffin, or polyethylene glycol, or butyl stearate.
Preferably, the antistatic agent is an antistatic agent SN, or an antistatic agent TM, or an antistatic agent SP, or an antistatic agent SH-105; the glue is acrylic glue, organic silicon glue or polyurethane glue.
Preferably, the difference in surface tension between the organic particles and the host resin is greater than 20 dyn/cm.
Preferably, the main resin is PET; the organic particles are PMMA particles with PTFE surface treated, and the particle diameter of the PMMA particles is less than 1 μm.
Preferably, the weight percentage of the PMMA particles in the reflecting film base layer is between 1 and 20 percent.
Preferably, the inorganic particles are titanium dioxide particles, the particle size of the titanium dioxide particles is 0.1-0.5 μm, and the weight percentage of the titanium dioxide particles in the reflecting film base layer is between 1% and 15%.
The invention has the beneficial effects that: the two sides of the reflecting film are coated with resin layers containing temperature-adjusting micro-particles, and the stable and proper working temperature of the film layer is kept by absorbing/releasing heat, so that the contraction and deformation of the reflecting film caused by the change of the environmental temperature are prevented. The reflection film after the stripping film is removed can be directly adhered in the backlight module, so that the phenomenon that the optical film is easy to generate film arch, wrinkle, layering and other bad phenomena due to large thermal shrinkage in the traditional shading glue fixing method is avoided, and the method is suitable for optical modules with different sizes.
Drawings
Fig. 1 is a schematic structural view of the present invention.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments.
Embodiment one, referring to fig. 1, a low thermal shrinkage, self-adhesive type optical reflection film includes a reflection film base layer 1, the reflection film base layer 1 being coated with resin layers 2 on both sides,the resin layer 2 is filled with temperature-adjusting particles 3 with a core-shell structure, and the resin layer 2 is epoxy resin in the embodiment; the shell layer of the temperature-adjusting particle 3 with the core-shell structure is SiO2The core layer is paraffin.
And the lower resin layer is coated with a glue layer 4 containing an antistatic agent, and a layer of stripping film 5 is adhered on the glue layer 4. In this embodiment, the antistatic agent is SN, and the glue is acrylic glue. The release film may be a commonly used release film, for example, a PET release film, a PMMA release film, a PE release film, a PVC release film, a PTFE release film, or the like.
The reflection film base layer comprises a main body resin, organic particles incompatible with the main body resin and inorganic particles incompatible with the main body resin, the core layer is separated from the main body resin and the inorganic particles from the main body resin after being stretched to form cavities 6, and the density difference between the organic particles and the main body resin is less than 0.25g/cm3And the difference in surface tension between the organic particles and the host resin is greater than 20 dyn/cm.
The main resin in this embodiment is PET; the organic particles are PMMA particles subjected to surface treatment by PTFE, the particle size of the PMMA particles is less than 1 mu m, and the weight percentage of the PMMA particles in the reflecting film base layer is 15%.
The inorganic particles described in this embodiment are titanium dioxide particles, the particle size of the titanium dioxide particles is controlled to be 0.1-0.5 μm, and the weight percentage of the titanium dioxide particles in the reflective film base layer is 10%.
In a second embodiment, referring to fig. 1, a low thermal shrinkage self-adhesive optical reflective film includes a reflective film base layer 1, wherein the reflective film base layer 1 is coated with resin layers 2 on both sides, the resin layers 2 are filled with temperature-adjusting particles 3 having a core-shell structure, and the resin layer 2 in this embodiment is an acrylic resin; the shell layer of the temperature-adjusting particle 3 with the core-shell structure is TiO2The core layer is polyethylene glycol.
And the lower resin layer is coated with a glue layer 4 containing an antistatic agent, and a layer of stripping film 5 is adhered on the glue layer 4. In this embodiment, the antistatic agent is an antistatic agent TM, and the glue is an organic silicon glue. The release film may be a commonly used release film, for example, a PET release film, a PMMA release film, a PE release film, a PVC release film, a PTFE release film, or the like.
The reflection film base layer comprises a main body resin, organic particles incompatible with the main body resin and inorganic particles incompatible with the main body resin, the core layer is separated from the main body resin and the inorganic particles from the main body resin after being stretched to form cavities 6, and the density difference between the organic particles and the main body resin is less than 0.25g/cm3And the difference in surface tension between the organic particles and the host resin is greater than 20 dyn/cm.
The main resin in this embodiment is PET; the organic particles are PMMA particles subjected to surface treatment by PTFE, the particle size of the PMMA particles is less than 1 mu m, and the weight percentage of the PMMA particles in the reflecting film base layer is 5%.
The inorganic particles described in this embodiment are titanium dioxide particles, the particle size of the titanium dioxide particles is controlled to be 0.1-0.5 μm, and the weight percentage of the titanium dioxide particles in the reflective film base layer is 8%.
In a third embodiment, referring to fig. 1, a low thermal shrinkage self-adhesive optical reflective film includes a reflective film base layer 1, wherein the reflective film base layer 1 is coated with resin layers 2 on both sides, temperature-adjusting particles 3 with a core-shell structure are filled in the resin layers 2, and in this embodiment, the resin layers 2 are made of silicone; the shell layer of the temperature adjusting particle 3 with the core-shell structure is ZnO, and the core layer is butyl stearate.
And the lower resin layer is coated with a glue layer 4 containing an antistatic agent, and a layer of stripping film 5 is adhered on the glue layer 4. In this embodiment, the antistatic agent SP is used as the antistatic agent, and the polyurethane glue is used as the glue. The release film may be a commonly used release film, for example, a PET release film, a PMMA release film, a PE release film, a PVC release film, a PTFE release film, or the like.
The reflection film base layer comprises a main resin, organic particles incompatible with the main resin, and inorganic particles incompatible with the main resin, and the core layer is stretched to obtain organic particlesThe inorganic particles are separated from the main resin to form cavities 6, and the density difference between the organic particles and the main resin is less than 0.25g/cm3And the difference in surface tension between the organic particles and the host resin is greater than 20 dyn/cm.
The main resin in this embodiment is PET; the organic particles are PMMA particles subjected to surface treatment by PTFE, the particle size of the PMMA particles is less than 1 mu m, and the weight percentage of the PMMA particles in the reflecting film base layer is 1%.
The inorganic particles described in this embodiment are titanium dioxide particles, the particle size of the titanium dioxide particles is controlled to be 0.1-0.5 μm, and the weight percentage of the titanium dioxide particles in the reflective film base layer is 12%.
In a fourth embodiment, referring to fig. 1, a low thermal shrinkage self-adhesive optical reflective film includes a reflective film base layer 1, wherein resin layers 2 are coated on both sides of the reflective film base layer 1, temperature-adjusting particles 3 with a core-shell structure are filled in the resin layers 2, and the resin layers 2 in this embodiment are epoxy resins; the shell layer of the temperature-adjusting particle 3 with the core-shell structure is BaTiO3The core layer is paraffin.
And the lower resin layer is coated with a glue layer 4 containing an antistatic agent, and a layer of stripping film 5 is adhered on the glue layer 4. In this embodiment, the antistatic agent SN is used as the antistatic agent, and the polyurethane glue is used as the glue. The release film may be a commonly used release film, for example, a PET release film, a PMMA release film, a PE release film, a PVC release film, a PTFE release film, or the like.
The reflection film base layer comprises a main body resin, organic particles incompatible with the main body resin and inorganic particles incompatible with the main body resin, the core layer is separated from the main body resin and the inorganic particles from the main body resin after being stretched to form cavities 6, and the density difference between the organic particles and the main body resin is less than 0.25g/cm3And the difference in surface tension between the organic particles and the host resin is greater than 20 dyn/cm.
The main resin in this embodiment is PET; the organic particles are PMMA particles subjected to surface treatment by PTFE, the particle size of the PMMA particles is less than 1 mu m, and the weight percentage of the PMMA particles in the reflecting film base layer is 20%.
The inorganic particles described in this embodiment are titanium dioxide particles, the particle size of the titanium dioxide particles is controlled to be 0.1-0.5 μm, and the weight percentage of the titanium dioxide particles in the reflective film base layer is 5%.
In fifth embodiment, referring to fig. 1, a low thermal shrinkage self-adhesive optical reflective film includes a reflective film base layer 1, wherein resin layers 2 are coated on both sides of the reflective film base layer 1, temperature-adjusting particles 3 with a core-shell structure are filled in the resin layers 2, and the resin layer 2 in this embodiment is acrylic resin; the shell layer of the temperature-adjusting particle 3 with the core-shell structure is SiO2The core layer is butyl stearate.
And the lower resin layer is coated with a glue layer 4 containing an antistatic agent, and a layer of stripping film 5 is adhered on the glue layer 4. In the embodiment, the antistatic agent is SH-105, and the glue is acrylic glue. The release film may be a commonly used release film, for example, a PET release film, a PMMA release film, a PE release film, a PVC release film, a PTFE release film, or the like.
The reflection film base layer comprises a main body resin, organic particles incompatible with the main body resin and inorganic particles incompatible with the main body resin, the core layer is separated from the main body resin and the inorganic particles from the main body resin after being stretched to form cavities 6, and the density difference between the organic particles and the main body resin is less than 0.25g/cm3And the difference in surface tension between the organic particles and the host resin is greater than 20 dyn/cm.
The main resin in this embodiment is PET; the organic particles are PMMA particles subjected to surface treatment by PTFE, the particle size of the PMMA particles is less than 1 mu m, and the weight percentage of the PMMA particles in the reflecting film base layer is 10%.
The inorganic particles described in this embodiment are titanium dioxide particles, the particle size of the titanium dioxide particles is controlled to be 0.1-0.5 μm, and the weight percentage of the titanium dioxide particles in the reflective film base layer is 1%.
Sixth embodiment, referring to fig. 1, a low thermal shrinkage self-adhesive optical reflective film includes a reflective film base layer 1, wherein resin layers 2 are coated on both sides of the reflective film base layer 1, temperature-adjusting particles 3 with a core-shell structure are filled in the resin layers 2, and the resin layers 2 in this embodiment are epoxy resins; the shell layer of the temperature-adjusting particle 3 with the core-shell structure is TiO2The core layer is polyethylene glycol.
And the lower resin layer is coated with a glue layer 4 containing an antistatic agent, and a layer of stripping film 5 is adhered on the glue layer 4. In this embodiment, the antistatic agent is SH-105, and the glue is polyurethane glue. The release film may be a commonly used release film, for example, a PET release film, a PMMA release film, a PE release film, a PVC release film, a PTFE release film, or the like.
The reflection film base layer comprises a main body resin, organic particles incompatible with the main body resin and inorganic particles incompatible with the main body resin, the core layer is separated from the main body resin and the inorganic particles from the main body resin after being stretched to form cavities 6, and the density difference between the organic particles and the main body resin is less than 0.25g/cm3And the difference in surface tension between the organic particles and the host resin is greater than 20 dyn/cm.
The main resin in this embodiment is PET; the organic particles are PMMA particles subjected to surface treatment by PTFE, the particle size of the PMMA particles is less than 1 mu m, and the weight percentage of the PMMA particles in the reflecting film base layer is 18%.
The inorganic particles described in this embodiment are titanium dioxide particles, the particle size of the titanium dioxide particles is controlled to be 0.1-0.5 μm, and the weight percentage of the titanium dioxide particles in the reflective film base layer is 15%.
Claims (9)
1. A low thermal contraction, self-adhesive optical reflection film, includes reflection film basic unit, its characterized in that: resin layers are coated on two sides of the reflecting film base layer, and temperature-adjusting particles with core-shell structures are filled in the resin layers;
the lower resin layer is coated with a glue layer containing an antistatic agent, and a layer of stripping film is adhered on the glue layer;
the reflection film base layer comprises a main body resin, organic particles incompatible with the main body resin and inorganic particles incompatible with the main body resin, the core layer is separated from the main body resin and the inorganic particles from the main body resin after being stretched to form cavities, and the density difference between the organic particles and the main body resin is less than 0.25g/cm3。
2. The low heat shrinkage, self-adhesive optical reflective film of claim 1, wherein: the resin layer is epoxy resin, or acrylic resin, or organic silicon.
3. The low heat shrinkage, self-adhesive optical reflective film of claim 2, wherein: the shell layer of the temperature-adjusting particle with the core-shell structure is SiO2Or TiO2Or ZnO, or BaTiO3The core layer is paraffin, or polyethylene glycol, or butyl stearate.
4. The low heat shrinkage, self-adhesive optical reflective film of claim 3, wherein: the antistatic agent is an antistatic agent SN, or an antistatic agent TM, or an antistatic agent SP, or an antistatic agent SH-105; the glue is acrylic glue, organic silicon glue or polyurethane glue.
5. The low heat shrinkage, self-adhesive optical reflective film according to any of claims 1 to 4, wherein: the difference in surface tension between the organic particles and the host resin is greater than 20 dyn/cm.
6. The low heat shrinkage, self-adhesive optical reflective film of claim 5, wherein: the main resin is PET; the organic particles are PMMA particles with PTFE surface treated, and the particle diameter of the PMMA particles is less than 1 μm.
7. The low heat shrinkage, self-adhesive optical reflective film of claim 6, wherein: the weight percentage of the PMMA particles in the reflecting film base layer is between 1 and 20 percent.
8. The low heat shrinkage, self-adhesive optical reflective film of claim 7, wherein: the inorganic particles are titanium dioxide particles, the particle size of the titanium dioxide particles is 0.1-0.5 mu m, and the weight percentage of the titanium dioxide particles in the reflecting film base layer is between 1% and 15%.
9. The low heat shrinkage, self-adhesive optical reflective film of claim 8, wherein: the inorganic particles are titanium dioxide particles, the particle size of the titanium dioxide particles is 0.1-0.5 mu m, and the weight percentage of the titanium dioxide particles in the reflecting film base layer is between 1% and 15%.
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CN202011399110.1A CN112433283B (en) | 2020-12-04 | 2020-12-04 | Low-thermal-shrinkage self-adhesive optical reflecting film |
KR1020237007125A KR20230042119A (en) | 2020-12-04 | 2021-09-18 | optical reflective film |
PCT/CN2021/119271 WO2022116647A1 (en) | 2020-12-04 | 2021-09-18 | Optical reflection film |
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CN202011399110.1A CN112433283B (en) | 2020-12-04 | 2020-12-04 | Low-thermal-shrinkage self-adhesive optical reflecting film |
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WO2022116647A1 (en) * | 2020-12-04 | 2022-06-09 | 宁波东旭成新材料科技有限公司 | Optical reflection film |
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CN112433283B (en) * | 2020-12-04 | 2021-09-21 | 宁波东旭成新材料科技有限公司 | Low-thermal-shrinkage self-adhesive optical reflecting film |
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2020
- 2020-12-04 CN CN202011399110.1A patent/CN112433283B/en active Active
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2021
- 2021-09-18 WO PCT/CN2021/119271 patent/WO2022116647A1/en active Application Filing
- 2021-09-18 KR KR1020237007125A patent/KR20230042119A/en unknown
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CN103502554A (en) * | 2011-05-26 | 2014-01-08 | 夏普株式会社 | Core-shell nanoparticle, film, glazing unit, double glazing unit and method of making a glazing unit |
CN104536066A (en) * | 2015-01-19 | 2015-04-22 | 苏州胜利精密制造科技股份有限公司 | Novel reflector plate and liquid crystal display module thereof |
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WO2022116647A1 (en) * | 2020-12-04 | 2022-06-09 | 宁波东旭成新材料科技有限公司 | Optical reflection film |
Also Published As
Publication number | Publication date |
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CN112433283B (en) | 2021-09-21 |
KR20230042119A (en) | 2023-03-27 |
WO2022116647A1 (en) | 2022-06-09 |
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