CN112386530A - Waterproof eyeliner refill and preparation method thereof - Google Patents
Waterproof eyeliner refill and preparation method thereof Download PDFInfo
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- CN112386530A CN112386530A CN201910765743.0A CN201910765743A CN112386530A CN 112386530 A CN112386530 A CN 112386530A CN 201910765743 A CN201910765743 A CN 201910765743A CN 112386530 A CN112386530 A CN 112386530A
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- cyclopentasiloxane
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
Abstract
The invention relates to the technical field of eyeliner refills, in particular to a waterproof eyeliner refill which comprises the following raw materials in parts by weight: 10-20 parts of film forming agent, 15-18 parts of thickening agent, 5-10 parts of emollient, 5-8 parts of suspending agent, 10-12 parts of filler, 8-15 parts of colorant, 6-10 parts of skin conditioner, 1-4 parts of preservative and 2-5 parts of antioxidant; the film forming agent comprises one or a compound of more of trimethylsiloxy silicate, cyclopentasiloxane, polypropylsilsesquioxane, dimethiconol cross-linked polymer and isododecane. By adding trimethylsiloxy silicate, cyclopentasiloxane and isododecane, the invention has the advantages of excellent transfer resistance and washing resistance, long-lasting effect, improved gloss and color intensity, no stickiness and smooth feeling after drying, and excellent film forming property and water resistance.
Description
Technical Field
The invention relates to the technical field of eyeliner refills, in particular to a waterproof eyeliner refill and a preparation method thereof.
Background
The makeup is to use cosmetics and tools, adopt and accord with regular step and skill, render, draw, arrange in order to the face, five sense organs and other parts of the human body, enhance the stereoscopic impression, adjust the form and color, cover the defect, represent the spirit, thus achieve the goal of beautifying the visual sensation, make up is not female exclusive, there is no sex restriction even more, and the makeup of the eye is an important step in the whole makeup, the current tide flows, the eyeliner is a more common makeup way, except paying the help of the eye shadow, mascara, usually also utilize the modification of the eyeliner, make eyes have stereoscopic impression, the good eyeliner makes the eyes seem beautiful and spiritual; the existing eyeliner cosmetic products in the market at present comprise eyeliner, eyeliner and the like, and the eyeliner is needed to be painted on the parts of eyelids close to the eye sockets by smearing, so that the more delicious eye makeup effect is often drawn through the eyeliner, the stereoscopic degree of the eyes is shown, and the eyes are deeper; the eyeliner is a beauty cosmetic for drawing eyeliner, eyeliner powder drawn by friction in the eyeliner can be naturally and uniformly filled in pores among eyeliner hairs, so that the makeup effect is natural, but the existing eyeliner has poor water resistance and oil resistance, so that the eyeliner is easy to make up after being smeared, and the beauty is influenced.
Disclosure of Invention
The invention aims to solve the defect of poor waterproofness in the prior art, and provides a waterproof eyeliner refill and a preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
a waterproof eyeliner refill is designed, and the waterproof eyeliner refill comprises the following raw materials in parts by weight: 10-20 parts of film forming agent, 15-18 parts of thickening agent, 5-10 parts of emollient, 5-8 parts of suspending agent, 10-12 parts of filler, 8-15 parts of colorant, 6-10 parts of skin conditioner, 1-4 parts of preservative and 2-5 parts of antioxidant;
the film forming agent comprises one or a plurality of compounds of trimethylsiloxysilicate, cyclopentasiloxane, polypropylsilsesquioxane, dimethiconol cross-linked polymer and isododecane, wherein the percentage content of the trimethylsiloxysilicate is 40-50%, the percentage content of the cyclopentasiloxane is 20-25%, the percentage content of the polypropylsilsesquioxane is 10-20%, the percentage content of the dimethiconol cross-linked polymer is 15-20%, and the percentage content of the isododecane is 15-18%;
the thickening agent comprises hydrogenated polycyclopentadiene, polyethylene, microcrystalline wax, vitamin compound and beeswax, wherein the percentage content of the hydrogenated polycyclopentadiene is 20% -25%. The percentage content of the polyethylene is 40% -45%, the percentage content of the microcrystalline wax and the vitamin compound is 20% -30%, and the percentage content of the beeswax is 20% -24%.
Preferably, the emollient comprises one or a mixture of isooctyl palmitate, cyclopentasiloxane and cyclohexasiloxane; the percentage content of the isooctyl palmitate is 35% -40%, the percentage content of the cyclopentasiloxane is 45% and 5% -50%, and the percentage content of the cyclohexasiloxane is 20% -30%.
Preferably, the suspending agent is a complex of disteardimonium hectorite, isododecane, and propylene carbonate.
Preferably, the filler includes silica and boron nitride, and the mass ratio of the silica is 60% and the mass ratio of the boron nitride is 40%.
Preferably, the colorant is a compound consisting of iron oxide, titanium dioxide and silica.
Preferably, the skin conditioner is a complex consisting of hydrogenated coconut oil glycerin mixed ester and shea butter.
Preferably, the preservative is a compound consisting of phenoxyethanol and ethylhexyl glycerol.
Preferably, the antioxidant is a complex of vitamin E acetate and tocopherol
The invention also provides a preparation method of the waterproof eyeliner refill, which comprises the following steps;
step 1: preparing 60% by mass of trimethyl siloxane acid ester, cyclopentasiloxane, polypropylene silsesquioxane, dimethiconol cross-linked polymer and isododecane in advance for later use;
step 2: preparing color paste; adding ferric oxide, titanium dioxide, silica and boron nitride into the mixture of the poly-propylsilsesquioxane, the dimethiconol cross-linked polymer and the isododecane, stirring and mixing uniformly, and then grinding three to five times by using a three-roll machine until the mixture is completely and uniformly dispersed to obtain color paste;
and step 3: then adding hydrogenated polycyclopentadiene, polyethylene, microcrystalline wax, vitamin compound, beeswax, isooctyl palmitate, cyclopentasiloxane, cyclohexasiloxane, disteardimonium hectorite, isododecane, propylene glycol, hydrogenated coconut oil glycerin mixed ester, shea butter, acetate vitamin E and tocopherol into a heating and stirring barrel in sequence, stirring for 100 revolutions per minute, and heating until the temperature is raised to 90-95 ℃ and the materials are completely dissolved;
and 4, step 4: adding the color paste prepared in the step 2 into the mixture in the step 3, and continuously stirring until the color paste is completely and uniformly dispersed;
and 5: cooling to 65 ℃, discharging to a stainless steel barrel, and sealing and storing.
The waterproof eyeliner refill and the preparation method thereof provided by the invention have the beneficial effects that:
1. by adding trimethylsiloxy silicate, cyclopentasiloxane and isododecane, the product has excellent transfer resistance and washing resistance, is long-lasting, improves the gloss and color intensity of the product, is not sticky and smooth after being dried, and has excellent film forming property and water resistance;
2. the hydrogenated coconut oil glyceride and the shea butter are added, the polarity of the hydrogenated coconut oil glyceride is weak, the extensibility and the absorbability in the skin are good, and the hydrogenated coconut oil glyceride can be fully extended on the surface of the skin to form a protective film of the skin. The skin can permeate into the skin and be digested and absorbed by a tricarboxylic acid nutrient absorption system in the body, so that the nutrition of the skin is enhanced and the skin can resist the erosion of external free radicals; the shea butter has good skin care effect.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments.
The waterproof eyeliner refill comprises the following raw materials in parts by weight: 10-20 parts of film forming agent, 15-18 parts of thickening agent, 5-10 parts of emollient, 5-8 parts of suspending agent, 10-12 parts of filler, 8-15 parts of colorant, 6-10 parts of skin conditioner, 1-4 parts of preservative and 2-5 parts of antioxidant;
the film forming agent comprises one or a plurality of compounds of trimethylsiloxysilicate, cyclopentasiloxane, polypropylsilsesquioxane, dimethiconol cross-linked polymer and isododecane, wherein the percentage content of the trimethylsiloxysilicate is 40-50%, the percentage content of the cyclopentasiloxane is 20-25%, the percentage content of the polypropylsilsesquioxane is 10-20%, the percentage content of the dimethiconol cross-linked polymer is 15-20%, and the percentage content of the isododecane is 15-18%; the dimethiconol cross-linked polymer has excellent film-forming property, good pigment compatibility and good make-up effect, and the skin feel after film forming is comfortable and smooth without tight feel; and by adding trimethylsiloxy silicate, cyclopentasiloxane and isododecane, the product has excellent transfer resistance and washing resistance, is long-lasting, improves the luster and color intensity of the product, does not have greasy and smooth feeling after being dried, and has excellent film forming property and water resistance.
The thickening agent comprises hydrogenated polycyclopentadiene, polyethylene, microcrystalline wax, vitamin compound and beeswax, wherein the percentage content of the hydrogenated polycyclopentadiene is 20-25%. 40-45% of polyethylene, 20-30% of microcrystalline wax and vitamin compound and 20-24% of beeswax; the combination of microcrystalline wax with vitamins imparts a very high level of adhesion and staining to skin, hair, nails and eyelashes, and additionally improves the water, rub and transfer resistance of the formulation.
The emollient comprises one or more of isooctyl palmitate, cyclopentasiloxane, and cyclohexasiloxane; 35-40% of isooctyl palmitate, 5-50% of cyclopentasiloxane and 20-30% of cyclohexasiloxane; the isooctyl palmitate has good skin care performance and extensibility.
The suspending agent is a compound consisting of disteardimonium hectorite, isododecane and propylene carbonate; the filler comprises silica and boron nitride, wherein the mass ratio of the silica is 60%, and the mass ratio of the boron nitride is 40%; the colorant is a compound composed of ferric oxide, titanium dioxide and silica.
A skin conditioner is a compound consisting of hydrogenated coconut oil glycerin mixed ester and shea butter ester; hydrogenated coconut glyceride is very weak in polarity, has good extensibility and absorbability in the skin, and can be sufficiently extended on the skin surface to form a protective film on the skin. The skin can permeate into the skin and be digested and absorbed by a tricarboxylic acid nutrient absorption system in the body, so that the nutrition of the skin is enhanced and the skin can resist the erosion of external free radicals; the shea butter has good skin care effect.
The preservative is a compound consisting of phenoxyethanol and ethylhexyl glycerol; the antioxidant is a compound of acetate vitamin E and tocopherol; the acetate vitamin E and the tocopherol can make the suspension pigment more stable and avoid the pigment from oxidative discoloration.
The invention also provides a preparation method of the waterproof eyeliner refill, which comprises the following steps;
step 1: preparing 60% by mass of trimethyl siloxane acid ester, cyclopentasiloxane, polypropylene silsesquioxane, dimethiconol cross-linked polymer and isododecane in advance for later use;
step 2: preparing color paste; adding ferric oxide, titanium dioxide, silica and boron nitride into the mixture of the poly-propylsilsesquioxane, the dimethiconol cross-linked polymer and the isododecane, stirring and mixing uniformly, and then grinding three to five times by using a three-roll machine until the mixture is completely and uniformly dispersed to obtain color paste;
and step 3: then adding hydrogenated polycyclopentadiene, polyethylene, microcrystalline wax, vitamin compound, beeswax, isooctyl palmitate, cyclopentasiloxane, cyclohexasiloxane, disteardimonium hectorite, isododecane, propylene glycol, hydrogenated coconut oil glycerin mixed ester, shea butter, acetate vitamin E and tocopherol into a heating and stirring barrel in sequence, stirring for 100 revolutions per minute, and heating until the temperature is raised to 90-95 ℃ and the materials are completely dissolved;
and 4, step 4: adding the color paste prepared in the step 2 into the mixture in the step 3, and continuously stirring until the color paste is completely and uniformly dispersed;
and 5: cooling to 65 ℃, discharging to a stainless steel barrel, and sealing and storing.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (9)
1. The waterproof eyeliner refill is characterized by comprising the following raw materials in parts by weight: 10-20 parts of film forming agent, 15-18 parts of thickening agent, 5-10 parts of emollient, 5-8 parts of suspending agent, 10-12 parts of filler, 8-15 parts of colorant, 6-10 parts of skin conditioner, 1-4 parts of preservative and 2-5 parts of antioxidant;
the film forming agent comprises one or a plurality of compounds of trimethylsiloxysilicate, cyclopentasiloxane, polypropylsilsesquioxane, dimethiconol cross-linked polymer and isododecane, wherein the percentage content of the trimethylsiloxysilicate is 40-50%, the percentage content of the cyclopentasiloxane is 20-25%, the percentage content of the polypropylsilsesquioxane is 10-20%, the percentage content of the dimethiconol cross-linked polymer is 15-20%, and the percentage content of the isododecane is 15-18%;
the thickening agent comprises hydrogenated polycyclopentadiene, polyethylene, microcrystalline wax, vitamin compound and beeswax, wherein the percentage content of the hydrogenated polycyclopentadiene is 20% -25%. The percentage content of the polyethylene is 40% -45%, the percentage content of the microcrystalline wax and the vitamin compound is 20% -30%, and the percentage content of the beeswax is 20% -24%.
2. The waterproof eyeliner core according to claim 1, wherein said emollient comprises one or a mixture of isooctyl palmitate, cyclopentasiloxane, and cyclohexasiloxane; the percentage content of the isooctyl palmitate is 35% -40%, the percentage content of the cyclopentasiloxane is 45% and 5% -50%, and the percentage content of the cyclohexasiloxane is 20% -30%.
3. A waterproof eyeliner refill according to claim 1, wherein the suspending agent is a composite of disteardimonium hectorite, isododecane and propylene carbonate.
4. The waterproof eyeliner refill according to claim 1, wherein the filler comprises silica and boron nitride, the mass ratio of the silica is 60%, and the mass ratio of the boron nitride is 40%.
5. The waterproof eyeliner core according to claim 1, wherein said coloring agent is a compound of iron oxide, titanium dioxide, silica.
6. A water resistant eyeliner cartridge of claim 1 wherein said skin conditioner is a complex of hydrogenated coco glycerin mixed ester, shea butter.
7. The waterproof eyeliner core according to claim 1, wherein said preservative is a compound consisting of phenoxyethanol and ethylhexyl glycerin.
8. A waterproof eyeliner core according to claim 1, wherein said antioxidant is a complex of acetate vitamin E and tocopherol.
9. A method of preparing a waterproof eyeliner cartridge according to any one of claims 1 to 8, comprising the steps of;
step 1: preparing 60% by mass of trimethyl siloxane acid ester, cyclopentasiloxane, polypropylene silsesquioxane, dimethiconol cross-linked polymer and isododecane in advance for later use;
step 2: preparing color paste; adding ferric oxide, titanium dioxide, silica and boron nitride into the mixture of the poly-propylsilsesquioxane, the dimethiconol cross-linked polymer and the isododecane, stirring and mixing uniformly, and then grinding three to five times by using a three-roll machine until the mixture is completely and uniformly dispersed to obtain color paste;
and step 3: then adding hydrogenated polycyclopentadiene, polyethylene, microcrystalline wax, vitamin compound, beeswax, isooctyl palmitate, cyclopentasiloxane, cyclohexasiloxane, disteardimonium hectorite, isododecane, propylene glycol, hydrogenated coconut oil glycerin mixed ester, shea butter, acetate vitamin E and tocopherol into a heating and stirring barrel in sequence, stirring for 100 revolutions per minute, and heating until the temperature is raised to 90-95 ℃ and the materials are completely dissolved;
and 4, step 4: adding the color paste prepared in the step 2 into the mixture in the step 3, and continuously stirring until the color paste is completely and uniformly dispersed;
and 5: cooling to 65 ℃, discharging to a stainless steel barrel, and sealing and storing.
Priority Applications (1)
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CN201910765743.0A CN112386530A (en) | 2019-08-19 | 2019-08-19 | Waterproof eyeliner refill and preparation method thereof |
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CN201910765743.0A CN112386530A (en) | 2019-08-19 | 2019-08-19 | Waterproof eyeliner refill and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113750016A (en) * | 2021-10-27 | 2021-12-07 | 娇时日化(杭州)股份有限公司 | Eyeliner pen not easy to remove makeup and preparation method thereof |
CN115400040A (en) * | 2022-08-25 | 2022-11-29 | 宁波爱诗化妆品有限公司 | Silicon-system eyebrow pencil lead without whitening and preparation method thereof |
CN116473876A (en) * | 2022-11-25 | 2023-07-25 | 宁波爱诗化妆品有限公司 | Oily eyeliner and preparation method and application thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109431923A (en) * | 2018-09-27 | 2019-03-08 | 广州艾蓓生物科技有限公司 | A kind of informer's pen core and preparation method thereof not faded persistently |
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2019
- 2019-08-19 CN CN201910765743.0A patent/CN112386530A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109431923A (en) * | 2018-09-27 | 2019-03-08 | 广州艾蓓生物科技有限公司 | A kind of informer's pen core and preparation method thereof not faded persistently |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113750016A (en) * | 2021-10-27 | 2021-12-07 | 娇时日化(杭州)股份有限公司 | Eyeliner pen not easy to remove makeup and preparation method thereof |
CN115400040A (en) * | 2022-08-25 | 2022-11-29 | 宁波爱诗化妆品有限公司 | Silicon-system eyebrow pencil lead without whitening and preparation method thereof |
CN116473876A (en) * | 2022-11-25 | 2023-07-25 | 宁波爱诗化妆品有限公司 | Oily eyeliner and preparation method and application thereof |
CN116473876B (en) * | 2022-11-25 | 2023-12-05 | 宁波爱诗化妆品有限公司 | Oily eyeliner and preparation method and application thereof |
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