CN112386527A - Emulsion type base makeup cosmetic and method for producing same - Google Patents
Emulsion type base makeup cosmetic and method for producing same Download PDFInfo
- Publication number
- CN112386527A CN112386527A CN202010824800.0A CN202010824800A CN112386527A CN 112386527 A CN112386527 A CN 112386527A CN 202010824800 A CN202010824800 A CN 202010824800A CN 112386527 A CN112386527 A CN 112386527A
- Authority
- CN
- China
- Prior art keywords
- pigment
- mass
- makeup
- trade name
- hydrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
- FYGDTMLNYKFZSV-BYLHFPJWSA-N β-1,4-galactotrioside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-BYLHFPJWSA-N 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention provides an emulsion type base makeup cosmetic which can obtain natural and bright skin color which is not easily influenced by the type of a light source after makeup, has good use feeling and excellent long-term stability of appearance color, and a manufacturing method thereof. An emulsion-type makeup base cosmetic comprising an organic pigment hydrate, a polyglycerol-modified silicone, a polyether-modified silicone having a hydrophilic-lipophilic balance value of 8.0 or less, and water.
Description
Technical Field
The invention relates to an emulsion type base makeup cosmetic and a manufacturing method thereof.
Background
There is a demand for makeup cosmetics such as foundation cosmetics that can cover up the dullness of skin color (i.e., the state in which brightness decreases and yellow chroma increases) caused by poor blood circulation, the pigmentation that can be perceived with age, and the like, and the natural color tone after makeup. In response to such a demand, various makeup cosmetics have been proposed.
For example, patent document 1 discloses a foundation containing (a) 0.1 to 40 mass% of a yellow coloring material at a wavelength of 510nm ± 25nm at an inflection point in a region where the reflectance of the coloring material sharply increases, and (B) 0.05 to 20 mass% of a red coloring material at a wavelength of 620nm ± 25nm at the inflection point, and having a spectral dip (a so-called portion where the reflectance is decreased) in a wavelength region of 500nm to 620nm in the spectral reflectance spectrum.
Patent document 1: japanese patent No. 3514915
It is required to make up a makeup base cosmetic that a bright skin color can be obtained after makeup is completed. However, conventional makeup cosmetics have the following problems: the color of the skin color seems to turn yellow according to the type of the light source, and the natural skin color is difficult to obtain after makeup.
In addition, although a coloring material is usually blended in an oil phase in an emulsion type makeup base (so-called emulsion type makeup base), when an organic pigment is blended in an oil phase as a coloring material, the appearance color of the makeup base may change with time.
Therefore, it is required for emulsion-type makeup cosmetics to obtain a natural and bright skin color which is not easily affected by the kind of light source after makeup, and to have an appearance color which is not easily changed with time even when an organic pigment is used as a coloring material.
Further, emulsion type makeup cosmetics are also required to have a feeling of use that is good in spreadability and easy to spread when applied to the skin.
Disclosure of Invention
An object of one embodiment of the present invention is to provide an emulsion-type makeup base that provides a natural and bright skin color that is not easily affected by the type of light source after makeup is completed, has a good feel in use, and has excellent stability of appearance color over time.
Another object of the present invention is to provide a method for producing the above emulsion type makeup base.
Specific methods for solving the above problems include the following embodiments.
[1] An emulsion type makeup base, comprising:
an organic pigment hydrate;
a polyglycerol-modified silicone;
a polyether-modified silicone having a Hydrophilic-Lipophilic Balance (HLB) value of 8.0 or less; and
and (3) water.
[2] The emulsion-type makeup base cosmetic according to [1], wherein the organic pigment hydrate is an organic red pigment hydrate.
[3] The emulsion-type makeup base according to [2], which further comprises an inorganic red pigment, and the content of an organic red pigment hydrate in terms of organic red pigment is 0.33 times or more by mass relative to the content of the inorganic red pigment.
[4] The emulsion-type makeup base according to [2], which does not contain an inorganic red pigment.
[5] The emulsion-type makeup base cosmetic according to any one of [1] to [4], wherein the hydrate of the organic pigment is a hydrate of a composite pigment containing silica.
[6] The emulsion-type makeup base cosmetic according to any one of [1] to [5], which further comprises a polyhydric alcohol.
[7] A method for producing an emulsion type makeup cosmetic according to any one of [1] to [6], the method comprising:
the mixture of the oil phase composition containing the organic pigment hydrate and the aqueous phase composition is subjected to emulsification treatment.
Effects of the invention
According to one embodiment of the present invention, an emulsion-type makeup base can be provided that has a natural and bright skin color that is not easily affected by the type of light source after makeup is completed, has a good feel in use, and has excellent stability over time in appearance color.
Further, according to another embodiment of the present invention, there is provided a method for producing the above-mentioned emulsion type makeup base.
Detailed Description
Hereinafter, an example of an embodiment to which the emulsion type makeup cosmetic of the present invention is applied will be described. However, the present invention is not limited to the following embodiments, and can be implemented by applying modifications as appropriate within the scope of the object of the present invention.
In the present invention, the numerical range represented by the term "to" means a range in which the numerical values recited before and after the term "to" are respectively included as a minimum value and a maximum value.
In the numerical ranges recited in the present invention in stages, the upper limit value or the lower limit value recited in a certain numerical range may be replaced with the upper limit value or the lower limit value recited in other numerical ranges recited in stages. In the numerical ranges recited in the present invention, the upper limit or the lower limit of a certain numerical range may be replaced with the values shown in the examples.
In the present invention, a combination of two or more preferred embodiments is a more preferred embodiment.
In the present invention, when a plurality of substances corresponding to each component are present in the emulsion type makeup base, the amount of each component in the emulsion type makeup base means the total amount of the plurality of substances present in the emulsion type makeup base unless otherwise specified.
In the present invention, "good feeling in use" means that when an emulsion type makeup base is applied to the skin, spreadability is good and spreading is easy without color unevenness.
In the present invention, "oil phase" refers to a continuous phase in a water-in-oil type dosage form and refers to a dispersed phase in an oil-in-water type dosage form. The "oil phase" in a water-in-oil dosage form comprises the liquid medium of the continuous phase and the ingredients dispersed or dissolved in the liquid medium. The "oil phase" in an oil-in-water dosage form comprises the liquid medium of the dispersed phase and the ingredients dispersed or dissolved in the liquid medium.
In the present invention, "aqueous phase" refers to the dispersed phase in a water-in-oil dosage form and the continuous phase in an oil-in-water dosage form. The "aqueous phase" in a water-in-oil dosage form comprises the liquid medium of the dispersed phase and the ingredients dispersed or dissolved in the liquid medium. The "aqueous phase" in an oil-in-water dosage form comprises the liquid medium of the continuous phase and the ingredients dispersed or dissolved in the liquid medium.
In the present invention, the term "step" includes not only an independent step but also a step that can achieve the intended purpose of the step even when the step is not clearly distinguished from other steps.
[ emulsion type makeup cosmetics ]
The emulsion-type makeup base (hereinafter, may be simply referred to as "makeup base") according to the present invention includes an organic pigment hydrate, a polyglycerol-modified silicone, and a polyether-modified silicone having an HLB value of 8.0 or less (hereinafter, appropriately referred to as "specific polyether-modified silicone").
According to the makeup cosmetic composition of the present invention, a natural and bright skin color that is not easily affected by the type of light source can be obtained after makeup. Further, the base makeup cosmetic of the present invention has a good feeling of use and excellent stability of appearance color over time.
In the emulsion type makeup cosmetics, the coloring material is usually blended in the oil phase. However, when the coloring material is an organic coloring material, if the organic coloring material is blended in the oil phase, there is a possibility that the organic coloring material is gradually hydrated by the water content of the water phase. When the organic pigment is hydrated, the reflectance spectrum changes, and thus the appearance color of the cosmetic changes.
The makeup base cosmetic of the present invention contains the organic pigment in the form of a hydrate, and thus not only can obtain a natural and bright skin color which is not easily affected by the type of light source after makeup, but also the appearance color is not easily changed with time due to gradual hydration of the organic pigment. Further, the makeup base cosmetic of the present invention contains the polyglycerol-modified silicone and the specific polyether-modified silicone together with the organic pigment hydrate, and thus, the appearance color is less likely to change with time, and a good feeling of use can be obtained.
Hereinafter, each component of the makeup base cosmetic of the present invention will be described in detail.
[ organic pigment hydrate ]
The makeup base cosmetic of the present invention contains an organic pigment hydrate.
In the makeup cosmetic of the present invention, the organic pigment hydrate is a component capable of functioning as a colorant component.
The "organic dye hydrate" as used herein refers to a compound in which water molecules are added to molecules of an organic dye or ions generated by ionization of the organic dye.
The organic pigment forming the hydrate of the organic pigment is not particularly limited.
Examples of the organic dye forming the organic dye hydrate include organic dyes known as organic synthetic dyes (so-called tar dyes) applicable to the skin in the fields of cosmetics and quasi-drugs.
As the organic dye forming the organic dye hydrate, an organic dye is preferable.
Examples of the organic pigment include azo pigments, indigo pigments, and phthalocyanine pigments.
Among these, azo pigments are preferable, for example, from the viewpoint that a natural and bright skin color which is less affected by the kind of light source can be more effectively obtained after makeup.
As the azo-based pigment, red No. 3, red No. 202 (hereinafter, referred to as "R-202" or "lithol red BCA" as appropriate), red No. 204, red No. 226, yellow No. 205, yellow No. 401, and the like can be given.
Further, for example, the organic pigment is preferably an organic pigment having an absorption maximum at a wavelength of 400nm to 600nm from the viewpoint of easy adjustment of the skin color after makeup.
The color of the organic pigment hydrate is not particularly limited.
Examples of the color of the hydrate of organic pigment include red, yellow, orange, green, and blue.
For example, the organic pigment hydrate is preferably an organic red pigment hydrate which is a red organic pigment hydrate, from the viewpoint that a natural and bright skin color which is not easily affected by the type of light source can be more effectively obtained after makeup.
As the organic pigment hydrate, for example, from the viewpoint of adjusting the skin color after makeup, in addition to an organic pigment hydrate of a color close to the skin color (for example, a color such as red or yellow in the case of a mongolian person), an organic pigment hydrate of a color such as a complementary color of the skin color or a contrast color may be used.
The organic pigment hydrate is preferably a composite pigment with an inorganic substance (hereinafter, simply referred to as "composite pigment"), and more preferably a composite pigment containing silica, that is, a hydrate of a composite pigment containing a pigment as an organic pigment (i.e., an organic pigment) and silica.
When the organic pigment hydrate contained in the makeup cosmetic composition of the present invention is a hydrate of a composite pigment containing silica, natural and bright skin color which is not easily affected by the type of light source tends to be more effectively obtained after makeup. Further, if the organic pigment hydrate contained in the makeup base cosmetic of the present invention is a hydrate of a composite pigment containing silica, the feeling of use when applying the makeup base cosmetic to the skin tends to be further improved.
The method for producing the silica-containing composite pigment is not particularly limited, and the silica-containing composite pigment can be produced by a known method. For example, a composite pigment containing silica can be produced according to the methods described in Japanese patent laid-open Nos. 2007-100082 and 11-181329.
The organic pigment hydrate may be, for example, a hydrate of a composite pigment having a structure in which an organic pigment is incorporated into an inorganic substance to form a composite.
In the present invention, "intercalation" refers to a phenomenon in which a molecule, atom or ion is intercalated between layers constituting a substance having a layered structure.
Composite pigments having a structure in which an organic pigment is incorporated into an inorganic substance to form a composite are described in paragraphs [0017] to [0028] of Japanese patent laid-open publication No. 2015-199727. These descriptions are incorporated herein by reference.
The average particle diameter of the composite pigment is preferably 1 μm or more and 10 μm or less, and more preferably 2 μm or more and 8 μm or less.
In the present invention, the average particle diameter of the pigment is a value obtained from a number-based particle size distribution measured by a laser diffraction scattering method by preparing a solvent dispersion containing the pigment to be measured at a predetermined concentration. The measuring apparatus used was a laser diffraction/scattering particle size distribution measuring apparatus.
As the laser diffraction/scattering type particle size distribution measuring apparatus, LMS-30 (product name) of SEISHIN ENTER PRISE co. However, the laser diffraction/scattering particle size distribution measuring apparatus is not limited to this.
As the composite pigment, commercially available products can be used.
As an example of a commercially available product of a composite pigment containing silica, F-RED-C (trade name) of Daito Kasei Ko gyo Co., Ltd.
As an example of a commercially available composite pigment having a structure in which an organic pigment is incorporated into an inorganic substance to form a composite, HNB RED7 (trade name) is given.
The makeup base cosmetic of the present invention may contain only one kind of organic pigment hydrate, or may contain two or more kinds.
The content of the organic pigment hydrate in the makeup cosmetic composition of the present invention is not particularly limited, and is, for example, preferably 0.1 mass% or more and 3.0 mass% or less, more preferably 0.12 mass% or more and 2.5 mass% or less, and further preferably 0.15 mass% or more and 2.0 mass% or less in terms of the organic pigment based on the total mass of the makeup cosmetic composition.
When the content of the organic pigment hydrate in the makeup cosmetic composition according to the present invention is 0.1% by mass or more in terms of organic pigment based on the total mass of the makeup cosmetic composition, a bright skin color after makeup tends to be obtained more favorably.
When the content of the organic pigment hydrate in the makeup cosmetic composition according to the present invention is 3% by mass or less based on the total mass of the makeup cosmetic composition in terms of organic pigment, the stability of the appearance color of the makeup cosmetic composition over time tends to be further improved.
In the present invention, "conversion into an organic dye" means calculation using the mass of the organic dye contained in the organic dye hydrate.
It can be confirmed by measurement of absorption spectrum that the makeup base cosmetic of the present invention contains an organic pigment hydrate.
[ polyglycerol-modified Silicone ]
The makeup base cosmetic of the present invention contains a polyglycerol-modified silicone.
In the makeup cosmetic composition of the present invention, the polyglycerin-modified silicone can contribute to an improvement in the feeling of use and an improvement in the stability of the appearance color over time.
In the present invention, the "polyglycerol-modified silicone" refers to a compound having a structure in which a silicone chain as a hydrophobic portion is branched from a polyglycerol chain as a hydrophilic portion.
The silicone chain may be a linear silicone chain or a branched silicone chain.
The value of the hydrophilic-lipophilic balance (i.e., HLB) of the polyglycerol-modified silicone is not particularly limited.
The HLB value of the polyglycerol-modified silicone may be, for example, 1 or more and 10 or less.
Examples of the polyglycerin-modified silicone include lauryl polyglycerin-3 dimethiconoethyl dimethicone, (lauryl dimethicone/polyglycerin-3) crosspolymer, cetyl diglycerin tris (trimethylsiloxy) silylethyl dimethicone, (polyglycerin-3/lauryl dimethiconoethyl dimethicone) crosspolymer, and the like.
Commercially available products can be used as the polyglycerin-modified silicone.
Examples of commercially available products of polyglycerol-modified silicone include KF-6105 [ trade name, component name: lauryl polyglycerol-3 dimethiconoethyl polydimethylsiloxane, Shin-Etsu Chemical co., ltd. ], KF-6106 [ trade name, component name: polyglycerol-3 polydimethylsiloxane, Shin-Etsu Chemical co., ltd. ], KSG-820 [ trade name, component name: a compound obtained by swelling (lauryl dimethicone/polyglycerin-3) crosslinked polymer, (lauryl dimethicone/polyglycerin-3) crosslinked polymer in isododecane, Shin-Etsu Chemical co., ltd. ], ES-5600Silicone glycol emulsier [ trade name, component name: cetyl diglycerol tris (trimethylsiloxy) silylethyl polydimethylsiloxane, Dow Chemical Japan Limited, KSG-820Z [ trade name, component name: a crosslinked polymer of (polyglycerin-3/lauryldimethylsiloxyethyl polydimethylsiloxane), a compound obtained by swelling the crosslinked polymer in isododecane, Shin-Etsu Chemical Co., Ltd., and the like.
The makeup base cosmetic of the present invention may contain only one kind of polyglycerin-modified silicone, or may contain two or more kinds.
The content of the polyglycerol-modified silicone in the makeup cosmetic composition of the invention is not particularly limited, but is, for example, preferably 0.01% by mass or more and 7% by mass or less, more preferably 0.05% by mass or more and 6% by mass or less, still more preferably 0.05% by mass or more and 5% by mass or less, still more preferably 0.1% by mass or more and 5% by mass or less, still more preferably 0.5% by mass or more and 4% by mass or less, and particularly preferably 0.8% by mass or more and 3% by mass or less, based on the total mass of the makeup cosmetic composition.
When the content of the polyglycerol-modified silicone in the makeup cosmetic composition of the present invention is within the above range with respect to the total mass of the makeup cosmetic composition, the feel of use and the emulsion stability over time tend to be better satisfied at the same time.
[ polyether-modified Silicone having an HLB value of 8.0 or less ]
The makeup base cosmetic of the present invention contains a polyether-modified silicone (i.e., a specific polyether-modified silicone) having an HLB value of 8.0 or less.
In the makeup cosmetic of the invention, the specific polyether-modified silicone can contribute to an improvement in the feeling of use.
In the present invention, the "polyether-modified silicone" refers to a polymer having a silicone chain as a main chain and a polyether chain introduced by modification.
The silicone chain may be a linear silicone chain or a branched silicone chain. Examples of the polyether chain include a polyethylene glycol (PEG) chain and a polypropylene glycol (PPG) chain.
For example, from the viewpoint of emulsion stability over time of a base makeup cosmetic, the polyether-modified silicone preferably further has an alkyl chain introduced by modification.
The number of carbon atoms in the alkyl chain is preferably 2 to 20, for example.
The HLB value of the specific polyether-modified silicone is 8.0 or less, preferably 7.5 or less, and more preferably 7.0 or less, from the viewpoint of the stability of the appearance color of the makeup cosmetic over time.
The lower limit of the HLB value of the specific polyether-modified silicone is not particularly limited, and is preferably 2.0 or more, for example.
HLB is an index representing a hydrophilic-hydrophobic balance used in the field of emulsifiers. In the present invention, the HLB value is calculated using a calculation formula (so-called sita formula) represented by the following formula (1). However, when a commercially available product is used as the specific polyether-modified silicone, the HLB value of the polyether-modified silicone is the product catalog value of the commercially available product.
HLB (Σ inorganic value/Σ organic value) × 10 formula (1)
In the formula (1), the inorganic value and the organic value are characteristic values given to each compound described in "organic conceptual diagram", and for example, reference can be made to literature such as "advanced life in the formazan, organic conceptual diagram-basis and application (1984)".
Specific examples of the polyether-modified silicone include PEG-3 polydimethylsiloxane, PEG-10 polydimethylsiloxane, PEG-9 polydimethylsiloxane, lauryl PEG-10 tris (trimethylsiloxy) silylethyl polydimethylsiloxane, cetyl PEG/PPG-10/1 polydimethylsiloxane, and PEG/PPG-20/22 butyl ether polydimethylsiloxane.
As the specific polyether-modified silicone, commercially available products can be used.
Examples of commercially available products of specific polyether-modified silicones include ES-5300Formulation A id [ trade name, component name: lauryl PEG-10 tris (trimethylsiloxy) silylethyl polydimethylsiloxane, HLB: 3.0, Dow Chemical Japan Limited, KF-6048 [ trade name, component name: cetyl PEG/PPG-10/1 dimethicone, HLB: 3.5 Shin-Etsu chemical Co., Ltd.,. Ltd. ], KF-6028 [ trade name, component name: PEG-9 dimethiconoethyl dimethicone, HLB: 4.0, Shin-Etsu Chemical co., ltd. ], KF-6015 [ trade name, component name: PEG-3 polydimethylsiloxane, HLB: 4.5, Shin-Etsu Chemical co., ltd. ], KF-6017P [ trade name, component name: PEG-10 polydimethylsiloxane, HLB: 4.5 Shin-Etsu chemical co., ltd. ], KF-6012 [ trade name, component name: PEG/PPG-20/22 butyl ether polydimethylsiloxane, HLB: 7.0 Shin-Etsu Chemical Co., Ltd. ], and the like.
The makeup base cosmetic of the present invention may contain only one specific polyether-modified silicone, or may contain two or more types.
The content of the specific polyether-modified silicone in the makeup cosmetic composition of the present invention is not particularly limited, and is, for example, preferably 0.1% by mass or more and 8% by mass or less, more preferably 0.15% by mass or more and 7% by mass or less, further preferably 0.17% by mass or more and 6% by mass or less, further preferably 0.2% by mass or more and 6% by mass or less, further preferably 1% by mass or more and 5% by mass or less, and particularly preferably 2% by mass or more and 4% by mass or less, based on the total mass of the makeup cosmetic composition.
When the content of the specific polyether-modified silicone in the makeup cosmetic composition of the present invention is within the above range with respect to the total mass of the makeup cosmetic composition, the use feeling of the makeup cosmetic composition and the emulsion stability with time tend to be more favorably satisfied.
In addition, for example, from the viewpoint of the stability of the appearance color of the makeup cosmetic over time, the content of the specific polyether-modified silicone in the makeup cosmetic of the present invention is preferably 0.1 times or more, more preferably 0.1 times or more and 10 times or less, further preferably 0.2 times or more and 8 times or less, further preferably 0.3 times or more and 7 times or less, further preferably 0.5 times or more and 7 times or less, and particularly preferably 1 time or more and 7 times or less, on a mass basis, relative to the content of the polyglycerol-modified silicone.
[ Water ]
The make-up base cosmetic of the present invention contains water.
In the makeup cosmetic of the present invention, water is a component that serves as a solvent or a dispersion medium in a composition constituting an aqueous phase (so-called aqueous phase composition).
The water is not particularly limited as long as it can be used in cosmetics.
Examples of the water include natural water, purified water, distilled water, ion-exchanged water, purified water, ultrapure water (e.g., Milli-Q water), and the like.
As the water, for example, pure water, distilled water, ion-exchanged water, pure water, or ultrapure water is preferable from the viewpoint of a small amount of impurities.
The content of water in the makeup cosmetic of the present invention is not particularly limited.
The content of water in the makeup cosmetic composition of the present invention is, for example, preferably 10 mass% to 50 mass%, more preferably 12.5 mass% to 45 mass%, and still more preferably 15 mass% to 40 mass% with respect to the total mass of the makeup cosmetic composition.
The content of water does not include water derived from an organic pigment hydrate.
[ polyol ]
The makeup base cosmetic of the present invention preferably further comprises a polyol.
When the makeup base cosmetic contains a polyhydric alcohol, the moisture retention of the makeup base cosmetic tends to be improved.
The polyol is not particularly limited as long as it can be used in cosmetics.
Examples of the polyhydric alcohol include glycerin, polyglycerin, ethylene glycol, propylene glycol, dipropylene glycol, 1, 3-butylene glycol (cosmetic component name: BG), 1, 2-pentanediol, 1, 2-hexanediol, polyethylene glycol, pentanediol, glucose, galactose, sorbitol, maltotriose, and trehalose.
When the makeup base cosmetic of the present invention contains a polyhydric alcohol, only one kind of polyhydric alcohol may be contained, or two or more kinds may be contained.
When the makeup base cosmetic of the present invention contains a polyhydric alcohol, the content of the polyhydric alcohol is not particularly limited, and is, for example, preferably 0.1% by mass or more and 15% by mass or less, more preferably 0.2% by mass or more and 12% by mass or less, and further preferably 0.4% by mass or more and 10% by mass or less, based on the total mass of the makeup base cosmetic.
When the content of the polyol in the makeup cosmetic composition of the present invention is 0.1% by mass or more based on the total mass of the makeup cosmetic composition, the moisture retention of the makeup cosmetic composition tends to be further improved.
When the content of the polyol in the makeup cosmetic composition of the present invention is 15 mass% or less based on the total mass of the makeup cosmetic composition, the sticky feeling after the makeup cosmetic composition is applied tends to be further suppressed.
When glycerin is included as the polyhydric alcohol, the makeup base cosmetic of the present invention preferably further includes di (isostearyl alcohol/phytosterol) dimer dilinoleate.
The makeup base cosmetic of the present invention can further improve moisture retention by containing a combination of glycerin and di (isostearyl alcohol/phytosterol) dimer dilinoleate.
[ inorganic Red pigment ]
The makeup base cosmetic of the present invention may contain an inorganic red pigment.
In the makeup cosmetic composition of the present invention, the inorganic red pigment can contribute to adjustment of the hue.
The inorganic red pigment is not particularly limited, and examples thereof include inorganic red pigments known as inorganic red pigments applicable to the skin in the field of cosmetics and quasi-drugs.
Examples of the inorganic red pigment include red inorganic pigments.
Examples of the red inorganic pigment include red iron oxide (also known as red iron oxide).
The shape and size of the inorganic red pigment are not particularly limited, and for example, an inorganic red pigment having a spherical or needle-like shape and a size of several nm or more and several hundred nm or less is preferably used.
As the inorganic red pigment, commercially available products can be used.
Examples of commercially available products of inorganic RED pigments include OTS-2RED R-516L [ product name, component: red iron oxide, Daito Kasei Kogyo co., ltd. ], R-516L [ trade name, ingredient: red iron oxide, Titan Kogyo, ltd.), and the like.
When the makeup base cosmetic of the present invention contains an inorganic red pigment, it may contain only one inorganic red pigment, or may contain two or more inorganic red pigments.
The content of the inorganic red pigment in the makeup cosmetic composition of the present invention is not particularly limited.
For example, from the viewpoint of obtaining a natural and bright skin color which is less susceptible to the kind of light source after makeup, the makeup base cosmetic of the present invention preferably contains no inorganic red pigment or inorganic red pigment in an amount of more than 0% by mass and not more than 1% by mass, more preferably contains no inorganic red pigment or inorganic red pigment in an amount of more than 0% by mass and not more than 0.7% by mass, still more preferably contains no inorganic red pigment or inorganic red pigment in an amount of more than 0% by mass and not more than 0.5% by mass, and particularly preferably contains no inorganic red pigment.
In addition, when the makeup base cosmetic of the present invention contains an inorganic red pigment and the organic pigment hydrate described above is an organic red pigment hydrate, the content of the organic red pigment hydrate in terms of the organic red pigment is preferably a specific ratio or more to the content of the inorganic red pigment, for example, from the viewpoint of obtaining a natural and bright skin color which is less susceptible to the kind of light source after makeup.
For example, the content of the organic red pigment hydrate in terms of the organic red pigment in the makeup cosmetic composition of the present invention is preferably 0.33 times or more, more preferably 0.45 times or more, and still more preferably 0.55 times or more, on a mass basis, the content of the inorganic red pigment.
[ inorganic pigment ]
The makeup base cosmetic of the present invention may contain an inorganic pigment.
The "inorganic pigment" as used herein does not include the inorganic red pigment already described.
In the makeup cosmetic composition of the present invention, the inorganic pigment can contribute to adjustment of the color tone.
The inorganic pigment is not particularly limited, and examples thereof include inorganic pigments known as inorganic pigments applicable to the skin in the field of cosmetics and quasi drugs.
Examples of the inorganic pigment include inorganic pigments.
Examples of the inorganic pigment include a coloring pigment, a white pigment, an extender pigment and a pearlescent pigment.
< coloring pigment >
The colored pigment is a pigment that contributes to hue adjustment.
Examples of the coloring pigment include iron oxide (except red), chromium oxide, carbon black, ultramarine blue, and the like.
Among these, as the coloring pigment, for example, iron oxide is preferable from the viewpoint of adjusting the hue.
Examples of the iron oxide other than red include yellow iron oxide and black iron oxide.
As the iron oxide, iron oxide having a spherical or needle-like shape and a size of several nm or more and several hundred nm or less is preferably used.
Commercially available coloring pigments can be used.
Examples of commercially available products of coloring pigments include OTS-2YELLOW LLXLO [ trade name, YELLOW iron oxide, Daito Kasei Kogyo Co., Ltd., Ltd. ], OTS-2BLACK BL-100 [ trade name, BLACK iron oxide, Daito Kasei Kogyo Co., Ltd. ], LL-100 [ trade name, YELLOW iron oxide, Titan Kogyo, Ltd. ], BL-10 [ trade name, BLACK iron oxide, Titan Kogyo, Ltd. ], and the like.
When the makeup base cosmetic of the present invention contains a coloring pigment, it may contain only one coloring pigment, or may contain two or more kinds.
When the makeup base cosmetic of the present invention contains a coloring pigment, the content of the coloring pigment is not particularly limited, and is preferably 0.2 mass% or more and 5 mass% or less, for example, with respect to the total mass of the makeup base cosmetic.
< white pigment >
The white pigment is a pigment that contributes to hue adjustment.
Examples of the white pigment include titanium oxide and zinc oxide.
When titanium oxide, zinc oxide, or the like is contained as the white pigment, the white pigment can also function as a masking agent for spots, freckles, or the like, an ultraviolet inhibitor, or the like.
As the white pigment, iron oxide having a spherical shape and a size of several nm or more and several hundred nm or less is preferably used.
Commercially available white pigments can be used.
Examples of commercially available white pigments include OTS-2TiO2CR-50 [ trade name, titanium oxide, Daito Kasei Kogyo Co., Ltd. ], MP-1133 [ trade name, pigment grade titanium oxide, T AYCA Co., Ltd. ], and the like.
When the makeup base cosmetic of the present invention contains a white pigment, it may contain only one white pigment, or may contain two or more kinds.
When the makeup cosmetic composition of the present invention contains a white pigment, the content of the white pigment is not particularly limited, and is preferably 1 mass% or more and 15 mass% or less, for example, based on the total mass of the makeup cosmetic composition.
< extender pigment >
The extender pigment is a pigment which does not substantially contribute to hue adjustment.
Examples of the extender pigment include talc, kaolin, mica, sericite, magnesium carbonate, calcium carbonate, silicic anhydride, alumina, barium sulfate, synthetic phlogopite, and the like.
The average particle diameter of the extender pigment is preferably 1 μm or more and 100 μm or less, and more preferably 5 μm or more and 80 μm or less.
As the extender pigment, commercially available products can be used.
Examples of commercially available extender pigments include SERICITE FSE [ trade name, sericite, Sanshin Mining ind. co., ltd. ], TALK JA-46R [ trade name, talc, ASADAMILLING CO., LTD. ], and EX-15 [ trade name, talc, YAMAGUCHI MICA CO., L TD. ].
When the makeup base cosmetic of the present invention contains an extender pigment, it may contain only one extender pigment, or may contain two or more kinds.
When the makeup base cosmetic of the present invention contains an extender, the content of the extender is not particularly limited, and is preferably 3 mass% or more and 25 mass% or less with respect to the total mass of the makeup base cosmetic, for example.
< pearlescent pigment >
Pearlescent pigments are pigments having pearl luster, and contribute to adjustment of hue.
Examples of the pearl pigment include titanium oxide-coated mica (so-called mica titanium), titanium oxide-coated glass flake, and titanium oxide-coated talc. Further, a pigment obtained by laminating a plurality of coating layers of titanium oxide, a pigment obtained by laminating a coating layer of silicon oxide on a coating layer of titanium oxide, or the like can also be preferably used.
The average particle diameter of the pearlescent pigment is preferably 0.5 μm or more and 100 μm or less, and more preferably 1 μm or more and 80 μm or less.
Commercially available pearlescent pigments can be used.
Examples of commercially available pearlescent pigments include Timiron (registered trademark) SupersheenMP-1001 (trade name, mica titanium, MERCK Co., Ltd.).
When the makeup base cosmetic of the present invention contains a pearl pigment, it may contain only one pearl pigment, or may contain two or more kinds.
When the makeup cosmetic of the present invention contains a pearlescent pigment, the content of the pearlescent pigment is not particularly limited, and is preferably 0.1 mass% or more and 8 mass% or less, for example, with respect to the total mass of the makeup cosmetic.
[ oil agent ]
The makeup base cosmetic of the present invention may contain an oil agent.
"oil agent" means a component having a solubility in water at 25 ℃ of less than 0.1 mass% (less than 1g/L) and generally used as an oil agent in the field of cosmetics.
The oil agent is not particularly limited as long as it is an oil agent that can be applied to cosmetics.
The oil agent may be liquid, semisolid or solid, but is preferably liquid at 25 ℃ from the viewpoint of production suitability, for example.
"oil that is liquid at 25" means an oil having a melting point or softening point of less than 25 ℃.
Examples of the oil agent include ester oil, hydrocarbon oil, and silicone oil.
Specific examples of the ester oil include fatty acid esters such as cetyl ethylhexanoate, isotridecyl isononanoate, isopropyl myristate, isocetyl myristate, octyldodecyl myristate, isopropyl palmitate, ethylhexyl palmitate, butyl stearate, ethylhexyl stearate, isotridecyl stearate, methyl oleate, ethyl oleate, isobutyl oleate, triisocaprylic glyceride (triethyl hexanoin), tri (caprylic/capric) glyceride, diisopropyl adipate, and diethyl sebacate.
Specific examples of the hydrocarbon oil include liquid paraffin, isoparaffin, vaseline, paraffin, ceresin, microcrystalline wax, and squalane.
Specific examples of the silicone oil include polydimethylsiloxane, trisiloxane, polycyclomethylsiloxane, cyclopentasiloxane, methylpolytrimethylsiloxane, octylmethicone, phenylpolytrimethylsiloxane, diphenylpolydimethylsiloxane, diphenylsiloxyphenyltrimethicone, and the like.
When the makeup base cosmetic of the present invention contains an oil agent, it may contain only one oil agent, or may contain two or more kinds.
When the makeup base cosmetic of the present invention contains an oil, the content of the oil is not particularly limited, and is, for example, preferably 10 mass% or more and 70 mass% or less, more preferably 12 mass% or more and 65 mass% or less, and further preferably 15 mass% or more and 60 mass% or less, based on the total mass of the makeup base cosmetic.
[ other Components ]
The makeup cosmetic composition of the present invention may contain components (so-called other components) other than the above-described components as necessary within the range that does not impair the effects of the present invention.
Examples of the other components include additional components generally used in cosmetics (hereinafter, may be simply referred to as "additional components").
< addition of ingredients >
The makeup base cosmetic of the present invention may contain additional ingredients.
Examples of the additive component include functional components that exhibit a useful cosmetic effect (moisturizing effect, whitening effect, skin care effect, and the like) when used in cosmetics.
Examples of such functional components include carotenoids such as β -carotene, astaxanthin, zeaxanthin, lycopene, and lutein; vitamin E such as tocopherol and tocotrienol; ubiquinone such as coenzyme Q10; glycosphingolipids such as acetylhydroxyproline and glucosylceramide; hydrolyzed collagen, water-soluble collagen and other collagens; amino acids such as acetylhydroxyproline; hydrolyzing lupin protein; nicotinamide; polyvinyl alcohol, and the like.
Further, examples of the additive component include a texture improving agent [ polymethylsilsesquioxane, (vinyl dimethicone/polymethylsilsesquioxane) crosspolymer, glyceryl behenate, etc. ], a coating film forming agent [ trimethylsiloxysilicate, etc. ], a thickener [ (dimethicone/vinyl dimethicone) crosspolymer, etc. ], a preservative [ phenoxyethanol, etc. ], an ultraviolet absorber [ ethylhexyl methoxycinnamate, bisethylhexyloxyphenol methoxyphenyl triazine, etc. ], an anti-inflammatory agent, a clay mineral [ disteardimonium hectorite, etc. ], a perfume, and the like.
These additional components may be components in which one component performs two or more functions.
[ formulation of makeup cosmetics ]
The formulation of the base makeup cosmetic of the present invention may be of an oil-in-water type or a water-in-oil type, but from the viewpoint of more effectively exerting the effects of the present invention, a water-in-oil type is preferable.
[ application form of makeup cosmetics ]
Examples of suitable forms of the makeup base cosmetic of the present invention include foundation liquid, foundation cream, makeup base, concealer, CC cream (control color), and the like.
[ method for producing makeup cosmetics ]
The method for producing the makeup cosmetic of the present invention is not particularly limited.
The makeup base cosmetic of the present invention can be obtained, for example, by a production method (hereinafter, referred to as "production method X") including the steps of: the mixture of the oil phase composition containing the organic pigment hydrate and the aqueous phase composition is subjected to emulsification treatment.
Hereinafter, the production method X will be described in detail. However, the matters common to the makeup cosmetics described above, such as the components and amounts of the makeup cosmetics, will not be described.
The production method X includes a step of subjecting a mixture of an oil phase composition containing an organic pigment hydrate and an aqueous phase composition to emulsification treatment (hereinafter referred to as "emulsification treatment step").
The oil phase composition comprises an organic pigment hydrate.
As described above, in an emulsion type makeup base, when an organic pigment is blended in an oil phase, there is a possibility that the organic pigment is gradually hydrated by the water content of an aqueous phase. If the organic pigment is hydrated, the reflectance spectrum changes, and the appearance color of the cosmetic changes, which is not preferable.
In the production method X, the oil phase composition for forming the oil phase contains the organic pigment in the form of a hydrate, and therefore, a makeup cosmetic with an appearance color that is less likely to change with time due to gradual hydration of the organic pigment can be obtained.
The oil phase composition may contain ingredients other than the organic pigment hydrate.
The oil phase composition preferably contains a polyglycerol-modified silicone and a specific polyether-modified silicone, and may contain any components that can be blended as oil phase components as needed. As an optional component which can be blended as an oil phase component, an oil agent, an inorganic pigment, and the like can be given.
The oil phase composition may contain an emulsifier other than the polyglycerin-modified silicone and the specific polyether-modified silicone as necessary within a range not impairing the effects of the present invention.
The components contained in the oil phase composition may be simply mixed in the oil phase composition, and are preferably uniformly mixed.
The oil phase composition may be prepared in one step or in multiple steps.
For example, when the oil phase composition contains an inorganic pigment, the preparation of the oil phase composition is preferably performed in multiple steps. As an example of a method for producing an oil phase composition containing an inorganic pigment, the following method can be mentioned: a slurry containing an inorganic pigment (hereinafter, also referred to as "inorganic pigment slurry" as appropriate) is prepared in advance, and after the obtained inorganic pigment slurry and an oil phase component other than an organic pigment hydrate are mixed, the obtained mixture and an organic pigment hydrate are mixed to prepare an oil phase composition.
The details of the method for producing the inorganic pigment slurry will be described later.
The method of mixing the components contained in the oil phase composition is not particularly limited, and examples thereof include a method of mixing by stirring.
The stirring mechanism is not particularly limited, and a general stirrer or a stirring device can be used.
Examples of the stirring tool or the stirring device include a stirrer, a paddle mixer, an impeller mixer, a homomixer, a dispersion mixer, a super mixer, and a homogenizer (high-pressure homogenizer, ultrasonic homogenizer, etc.).
The stirring time is not particularly limited, and can be appropriately set according to the type of the stirrer or the stirring device, the composition of the oil phase composition, and the like.
For example, the temperature at which the components contained in the oil phase composition are mixed is preferably set to 70 ℃ or higher from the viewpoint of solubility.
The mechanism for adjusting the temperature is not particularly limited, and a general heating device can be used.
The method for producing the inorganic pigment slurry is not particularly limited.
The inorganic pigment slurry can be prepared by, for example, subjecting a mixture containing an inorganic pigment, an oil agent, and an emulsifier to a dispersion treatment. The mixture may contain at least one selected from the group consisting of polyglycerin-modified silicones and specific polyether-modified silicones as an emulsifier.
The method of mixing the components contained in the inorganic pigment slurry is not particularly limited, and examples thereof include a method of mixing by stirring.
The stirring mechanism is not particularly limited, and a general stirrer or a stirring device can be used. Examples of the stirring tool or the stirring apparatus include the same stirring tool or the same stirring apparatus as those used in the preparation of the oil phase composition.
The stirring time is not particularly limited, and may be appropriately set according to the type of the stirrer or the stirring device, the composition of the inorganic pigment slurry, and the like.
For example, the temperature at the time of mixing the components contained in the inorganic pigment paste is preferably set to 50 ℃ or lower from the viewpoint of more uniformly mixing the inorganic pigment paste while keeping the viscosity thereof constant.
The mechanism for adjusting the temperature is not particularly limited, and a general refrigeration apparatus can be used.
The method of the dispersion treatment is not particularly limited, and examples thereof include a method using an apparatus such as a three-roll mill, a planetary mixer, a henschel mixer, a homogenizer, a dispersion mixer, a bead mill, or a ball mill.
The conditions of the dispersion treatment are not particularly limited, and can be appropriately set according to the composition of the inorganic pigment slurry, the type of the apparatus, and the like.
The aqueous phase composition preferably contains water, an aqueous component such as a polyol, and may contain any component which can be blended as an aqueous phase component as needed.
The ingredients contained in the aqueous phase composition may be simply mixed in the aqueous phase composition, and are preferably uniformly mixed.
The preparation of the aqueous phase composition may be carried out in one step or in multiple steps.
The method of mixing the components contained in the aqueous phase composition is not particularly limited, and examples thereof include a method of mixing by stirring.
The stirring mechanism is not particularly limited, and a general stirrer or a stirring device can be used. Examples of the stirring tool or the stirring apparatus include the same stirring tool or the same stirring apparatus as those used in the preparation of the oil phase composition.
The stirring time is not particularly limited, and can be appropriately set according to the kind of the stirrer or the stirring apparatus, the composition of the aqueous phase composition, and the like.
For example, from the viewpoint of preventing bumping, the temperature at the time of mixing the components contained in the aqueous phase composition is preferably set to 100 ℃ or lower, more preferably 70 ℃ or higher and 100 ℃ or lower, and still more preferably 70 ℃ or higher and 90 ℃ or lower.
The mechanism for adjusting the temperature is not particularly limited, and a general heating device can be used.
The oil phase composition and the aqueous phase composition may be mixed at a time, or may be mixed while adding one of them little by little.
The method of mixing the oil phase composition and the aqueous phase composition is not particularly limited, and examples thereof include a method of mixing by stirring.
The stirring mechanism is not particularly limited, and a general stirrer or a stirring device can be used. Examples of the stirring tool or the stirring apparatus include the same stirring tool or the same stirring apparatus as those used in the preparation of the oil phase composition described above.
The stirring time is not particularly limited, and can be appropriately set according to the type of the stirrer or the stirring device, the composition of the oil phase composition and the aqueous phase composition, and the like.
The method of emulsification treatment is not particularly limited, and a known method can be used.
For the emulsification treatment, for example, a stirrer or a stirring device such as a stirrer, a paddle mixer, a vane mixer, a homomixer, a dispersion mixer, a super mixer, or a homogenizer (high-pressure homogenizer, ultrasonic homogenizer, etc.) can be used.
The time and temperature of the emulsification treatment are not particularly limited, and can be appropriately set according to the type of the stirrer or the stirring device, the composition of the oil phase composition and the aqueous phase composition, and the like.
The emulsification treatment may be carried out in two or more steps by changing the stirring conditions.
The ratio of the oil phase composition to the aqueous phase composition (oil phase composition: aqueous phase composition) is not particularly limited, and is, for example, preferably 1:9 to 9:1, more preferably 1:5 to 5:1, and still more preferably 1:4 to 4:1 on a mass basis.
The method for producing a base makeup cosmetic of the present invention may include a step (so-called other step) other than the emulsification treatment step, as necessary.
Examples of the other steps include a step of preparing an organic pigment hydrate, a defoaming step, a sterilization step, and a removal step.
The defoaming step, the sterilization step, the removal step, and the like may be applied by methods known in the industry.
The step of preparing the organic pigment hydrate may be a step of preparing a previously prepared organic pigment hydrate, or may be a step of preparing an organic pigment hydrate.
The method for producing the hydrate of the organic pigment is not particularly limited as long as the hydrate form of the organic pigment can be produced.
The organic pigment hydrate can be obtained by, for example, mixing an organic pigment with water.
The method of mixing the organic pigment and water is not particularly limited, and examples thereof include a method of mixing by stirring.
The stirring mechanism is not particularly limited, and a general stirrer or a stirring device can be used. Examples of the stirring tool or the stirring apparatus include the same stirring tool or the same stirring apparatus as those used in the preparation of the oil phase composition.
The stirring conditions are not particularly limited as long as the organic pigment can be made into a hydrate form, and can be appropriately set according to the type of a stirrer or a stirring device, for example.
From the viewpoint of more uniformly carrying out the hydration reaction, the temperature at the time of mixing the organic pigment and water is preferably set to, for example, 50 ℃ or lower. The mechanism for adjusting the temperature is not particularly limited, and a general refrigeration apparatus can be used.
The ratio of the organic dye to water (organic dye: water) is not particularly limited, and is, for example, preferably 1:20 to 20:1, more preferably 1:18 to 18:1, still more preferably 1:16 to 16:1, and particularly preferably 1:12 to 12:1 on a mass basis.
A preferred example of the method for producing the organic pigment hydrate is a method for producing a red paste described in [ example ] described later.
Examples
Hereinafter, the emulsion type makeup cosmetic of the present invention will be described in more detail with reference to examples. However, the emulsion type makeup base according to the present invention is not limited to the following examples as long as it is not beyond the scope of the present invention.
The details of each component used in the present example are shown below.
< ingredients of aqueous phase composition >
Water [ purified Water ] [ component (D) ]
Glycerin [ trade name: concentrated glycerin for cosmetics, Kao Corporation [ moisturizer; polyhydric alcohol ]
Pentanediol [ trade name: diol PD, component name: 1, 2-pentanediol, KOKYU ALCOHOL KOGYO co., ltd.) [ humectant; polyhydric alcohol ]
Phenoxyethanol [ trade name: caflect PE-1, KOYO fine chemical Co., Ltd. ] [ antiseptic ]
BG [ trade name: 1, 3-butanediol, component name: 1, 3-butanediol, Daicel Corporation [ humectant; polyhydric alcohol ]
< ingredient (1) of oil phase composition >
Pigment slurries
Cyclopentasiloxane [ trade name: KF-995, Shin-Etsu Chemical co., ltd.) [ oil: silicone oil
Diphenylsiloxyphenyl trimethicones [ trade name: KF-56A, Shin-Etsu chemical co., ltd.) [ oil: silicone oil
Lauryl PEG-10 tris (trimethylsiloxy) silylethyl polydimethylsiloxane [ trade name: ES-5300Formulation Aid, HLB: 3.0, Dow Chemical Japan Limited [ specific polyether-modified silicones; component (C) ]
Polyglycerin-2 diisostearate [ trade name: EMALEX DISG-2, NIHON EMULSIO N Co., Ltd. ] [ emulsifier ]
Titanium oxide (pigment grade) [ trade name: MP-1133, TAYCA co., ltd.) [ inorganic pigments; white pigment ]
Talc [ trade name: EX-15, YAMAGUCHI MICA co., ltd.) [ inorganic pigments; extender pigment
Iron oxide (yellow) [ trade name: LL-100, yellow iron oxide, Titan Kogyo, ltd.) [ inorganic pigment; coloring pigment ]
Iron oxide (black) [ trade name: BL-10, black iron oxide, Titan Kogyo, ltd.) [ inorganic pigment; coloring pigment ]
Iron oxide (red) [ trade name: R-516L, red iron oxide, Titan Kogyo, ltd.) [ inorganic red pigment; component (a) ]
< ingredient (2) of oil phase composition >
Cyclopentasiloxane [ trade name: KF-995, Shin-Etsu Chemical co., ltd.) [ oil: silicone oil
PEG-10 polydimethylsiloxane [ trade name: KF-6017P, HLB: 4.5 Shin-Etsu chemical co., ltd.) [ specific polyether-modified silicones; component (C) ]
PEG/PPG-20/22 butyl ether dimethicone [ trade name: KF-6012, HLB: 7.0, Shin-Etsu Chemical co., ltd.) [ specific polyether-modified silicone; component (C) ]
PEG-3 polydimethylsiloxane [ trade name: KF-6015, HLB: 4.5 Shin-Etsu chemical co., ltd.) [ specific polyether-modified silicones; component (C) ]
Cetyl PEG/PPG-10/1 dimethicone [ trade name: KF-6048, HLB: 3.5, S hin-Etsu Chemical co., ltd.) [ specific polyether-modified silicone; component (C) ]
PEG-9 dimethiconoethyl dimethicone [ trade name: KF-6028, HLB: 4.0, Shin-Etsu Chemical co., ltd.) [ specific polyether-modified silicone; component (C) ]
(PEG-15/lauryl dimethicone) crosspolymer [ trade name: KSG-320, (P EG-15/lauryl Dimethicone) crosslinked Polymer swollen in Isododecane, Shin-Etsu Chemical Co., Ltd. ] [ emulsifier ]
(PEG-15/lauryl Dimethylsiloxyethyl polydimethylsiloxane) crosspolymer [ trade name: KSG-320Z, a compound obtained by swelling a crosslinked polymer of (PEG-15/lauryl Dimethylsiloxyethyl polydimethylsiloxane) in isododecane, Shin-Etsu Chemical Co., Ltd. ] [ emulsifier ]
PEG-11 methyl ether polydimethylsiloxane [ trade name: KF-6011, HLB: 14.5 Shin-Et su Chemical Co., Ltd. ] [ emulsifiers ]
PEG-32 methyl ether polydimethylsiloxane [ trade name: KF-6004, HLB: 9.0 Shin-Ets u Chemical Co., Ltd. ] [ emulsifiers ]
PEG-10 polydimethylsiloxane [ trade name: KF-6043, HLB: 14.5 Shin-Etsu chemical Co., Ltd.) [ emulsifier ]
Lauryl polyglycerol-3 dimethiconoethyl polydimethylsiloxane [ trade name: KF-6105, Shin-Etsu Chemical co., ltd.) [ polyglycerol-modified silicone; component (B) ]
Polyglycerol-3 dimethiconoethyl polydimethylsiloxane [ trade name: KF-6106, Shin-Ets u Chemical co., ltd.) [ polyglycerol-modified silicone; component (B) ]
(lauryl dimethicone/polyglyceryl-3) crosspolymer [ trade name: KSG-820, (lauryl dimethicone/polyglycerin-3) crosslinked polymer swollen in isododecane, Shin-Etsu Chemical co., ltd.) [ polyglycerin-modified silicone; component (B) ]
Cetyl diglycerol tris (trimethylsiloxy) silylethyl polydimethylsiloxane [ trade name: ES-5600Silicone Glycerol Emulsifier, Dow Chemical Japan Limited [ polyglycerol-modified Silicone; component (B) ]
(polyglycerol-3/lauryl dimethiconoethyl dimethicone) crosspolymer [ trade name: KSG-820Z, (polyglycerol-3/lauryldimethylsiloxyethyl polydimethylsiloxane) a compound obtained by swelling a crosslinked polymer in isododecane, Shin-Etsu Chemical co., ltd.) [ polyglycerol-modified silicone; component (B) ]
Polyglycerin-2 diisostearate [ trade name: EMALEX DISG-2, NIHON EMULSIO N Co., Ltd. ] [ emulsifier ]
Cetyl ethylhexanoate [ trade name: NIKKOL (registered trademark) CIO, Nikko chemicals co., ltd.) [ oil solution: ester oil
Ethylhexyl methoxycinnamate [ trade name: uvinul (registered trademark) MC80, BASF Japan Ltd. ] [ ultraviolet light absorber ]
Bis (ethylhexyloxyphenol) methoxyphenyl triazine [ trade name: tinosorb (registered trademark) S, BASF Japan Ltd. ] [ ultraviolet absorbent ]
Disteardimonium hectorite [ trade name: bentone 38V CG, Elementis Japan KK. [ Clay minerals ]
Polymethylsilsesquioxane [ trade name: GANZPAIRL SI-04SC, Aica Kogyo Company, Limited [ feel modifier ]
(vinyl dimethicone/methicone silsesquioxane) crosspolymer [ trade name: KSP-105, Shin-Etsu Chemical Co., Ltd. ] [ feel improver ]
Glyceryl behenate [ trade name: SYNCROWAX HRC, Croda Japan KK. [ feel modifier ]
Di (isostearyl alcohol/phytosterol) dimer dilinoleate [ trade name: LUSPLAN (registered trademark) PI-DA, Dainiciseika Color & Chemicals Mfg. Co., Ltd. ] [ humectant ]
Haematococcus pluvialis oil [ trade name: ASTOTS (registered trademark) -S, astaxanthin content: about 20% by mass, Fujifilm Corporation
Trimethylsiloxysilicate [ trade name: KF-7312J, Shin-Etsu Chemical Co., L td.) [ coating Forming agent ]
(polydimethylsiloxane/vinyl polydimethylsiloxane) crosspolymer [ trade name: KSG-15, (Dimethicone/vinyl Dimethicone) crosslinked Polymer swollen in Cyclopentasiloxane Compound Shin-Etsu Chemical Co., Ltd.) [ thickener ]
Mica [ trade name: timicron (registered trademark) superseren MP-1001, mica titanium, ME RCK corporation [ inorganic pigments; extender pigment) ]
< ingredient (3) of oil phase composition >
Red slurry-
Organic red pigment (R-202) [ trade name: red No. 202, Taketombo Co., Ltd.) [ organic pigment ]
Organic RED composite pigment (F-RED-C) [ trade name: F-RED-C, RED 202, composite pigment containing silicic anhydride (silica) or the like, Daito Kasei Kogyo co., ltd.) [ organic pigment; composite pigment comprising silica ]
[ preparation of Foundation make-up solution ]
[ example 1]
A liquid foundation as an emulsion type makeup base cosmetic is prepared. The specific method is as follows.
Each component of the pigment slurry shown in Table 1 was mixed for 10 minutes at a rotation speed of 3000rpm (revolutions per minute) in a state where water (liquid temperature: 19 ℃) was put into a jacket of an outer phase using SPIN MIX HOMEGENIZER (model: SX10) of MITSUI ELECTRIC Co., Ltd. Next, the resultant mixture was subjected to a dispersion treatment 4 times using a three-roll mill (model: BR-100V) of AIMEX co., ltd. under a rotation ratio of 1:2.4:6.0 to obtain a pigment slurry.
Next, the components of the oil phase composition described in table 1, excluding the pigment slurry and the red slurry, were dissolved by stirring for 20 minutes while heating to 75 to 80 ℃ in a hot water bath. Next, the pigment paste obtained in the above was added to the obtained solution. Subsequently, the obtained solution was mixed for 15 minutes at 3000rpm while putting water (liquid temperature: 19 ℃) in a jacket of an external phase using SPIN MIX homo mixer (model: SX10, MITSUI EL ECTRIC co.
Next, each component of the red slurry described in Table 1 (i.e., organic pigment hydrate; the same applies hereinafter) was mixed for 20 minutes at a rotation speed of 3000rp m while water (liquid temperature: 19 ℃) was put into a jacket of the outer phase using SPIN MIX HOMEGENIZER (model: SX10) of MITSUI ELECTRIC Co., Ltd. Next, the obtained mixture was allowed to stand at room temperature until the liquid temperature became 30 ℃ or lower to obtain a red slurry.
Subsequently, the composition X obtained in the above and the red slurry obtained in the above were mixed for 20 minutes at a rotation speed of 3000rp m in a state where water (liquid temperature: 19 ℃) was put into a jacket of an outer phase using SPIN MIX HOMEGENIZER (model: SX10) of MITSUI ELECTRIC Co., Ltd. to obtain an oil phase composition.
Next, each component of the aqueous phase composition described in table 1 was dissolved by stirring for 5 minutes while heating to 75 to 80 ℃ by a hot water bath. Then, the obtained solution was allowed to stand at room temperature until the liquid temperature became 35 ℃ or lower to obtain an aqueous phase composition.
Next, the oil phase composition obtained in the above was placed in a 100mL container and stirred at a rotation speed of 50rpm by a blade of an anchor stirrer using a digital stirrer (trade name: MICROSCAR 7.5 control) manufactured by IKA. Then, the aqueous phase composition obtained in the above was added dropwise to the oil phase composition under stirring at a constant rate of 10 mL/min. After completion of the dropwise addition, the resulting mixture was emulsified at 4000rpm for 5 minutes using a homogenizer (trade name: ULTRA-TURRAX T25 digital) from IKA to obtain a foundation of example 1.
[ example 2 to example 6]
The same operations as in example 1 were carried out except that the composition of the oil phase composition was changed to the composition shown in table 1 in the preparation of the foundation liquid of example 1, to obtain respective foundation liquids of examples 2 to 6.
[ example 7 to example 12 ]
The same operations as in example 1 were carried out except that the composition of the oil phase composition was changed to the composition shown in table 2 in the preparation of the foundation liquid of example 1, to obtain foundation liquids of examples 7 to 12.
[ example 13 to example 16 ]
The same operations as in example 1 were carried out except that the composition of the oil phase composition was changed to the composition shown in table 3 in the preparation of the foundation liquid of example 1, to obtain respective foundation liquids of examples 13 to 16.
[ example 17 to example 21 ]
The same operations as in example 1 were carried out except that the composition of the oil phase composition was changed to the composition shown in table 4 in the preparation of the foundation liquid of example 1, to obtain foundation liquids of examples 17 to 21.
[ comparative example 1]
Each component of the pigment pastes described in Table 5 and the organic pigment [ organic red pigment (R-202) ] were mixed for 10 minutes at a rotation speed of 3000rpm in a state where water (liquid temperature: 19 ℃) was put into a jacket of an external phase using SPIN MIX HOMEGENIZER (model: SX10) manufactured by MITSUI ELECTRIC Co., Ltd. Next, the resultant mixture was subjected to a dispersion treatment 4 times using a three-roll mill (model: BR-100V) of AIMEX co., ltd. under a rotation ratio of 1:2.4:6.0 to obtain a pigment slurry X.
Next, the components of the oil phase composition described in table 5, excluding the pigment slurry and the organic pigment [ organic red pigment (R-202) ], were dissolved by stirring for 20 minutes while heating to 75 to 80 ℃ in a hot water bath. Next, the pigment paste X obtained in the above was added to the obtained solution. Next, the resulting solution was mixed with water (liquid temperature: 19 ℃) in a jacket of an outer phase at 3000rpm for 15 minutes using SPIN MIX HOMEGENIZ ER (model: SX10) manufactured by MITSUI ELECTRIC Co., Ltd.
Next, each component of the aqueous phase composition described in table 5 was dissolved by stirring for 5 minutes while heating to 75 to 80 ℃ by a hot water bath. Then, the obtained solution was allowed to stand at room temperature until the liquid temperature became 35 ℃ or lower to obtain an aqueous phase composition.
Next, the oil phase composition obtained in the above was placed in a 100mL container and stirred at 50rpm using a digital stirrer (trade name: MICROSTATOR 7.5 control) manufactured by IKA. Then, the aqueous phase composition obtained in the above was added dropwise to the oil phase composition under stirring at a constant rate of 10 mL/min. After completion of the addition, the resulting mixture was emulsified at 4000rpm for 5 minutes using a homogenizer (trade name: U LTRA-TURRAX T25 digital) from IKA to obtain a foundation of comparative example 1.
[ comparative examples 2 to 6]
The same operations as in example 1 were carried out except that the composition of the oil phase composition was changed to the composition shown in table 5 in the preparation of the foundation liquid of example 1, to obtain respective foundation liquids of comparative examples 2 to 6.
[ measurement and evaluation ]
The following measurements and evaluations were carried out using each of the foundation solutions of examples 1 to 21 and comparative examples 1 to 6. The results are shown in tables 1 to 5.
1. Skin color after makeup
The following evaluation test was performed on 10 female subjects.
First, the skin color of the female face of the test subject was visually observed under a fluorescent lamp to confirm the color tone.
Next, the liquid foundation was applied to the face of a female subject using a puff, and the color of the applied skin color was visually observed under a fluorescent lamp.
Then, the female subject was moved to the sun (color temperature: 5000K in direct sunlight at noon on a fine day), and the change in color of the skin color at that time was visually observed.
The above observations were scored according to the scoring criteria described below. After the scoring results were arithmetically averaged, the first place after the decimal point was obtained by four-sheet five-fold, and the obtained value was taken as an evaluation score (only marked as "score" in the table).
Then, evaluation was performed based on the evaluation score according to the following evaluation criteria.
If the evaluation result is "AA", "a" or "B", it is judged that the makeup base liquid is a natural and bright skin color foundation which is not easily affected by the type of light source after makeup.
-score criteria-
And 5, dividing: after makeup is finished, a bright and ruddy skin color is obtained, and the type of the light source is not changed at all even if the makeup is finished.
And 4, dividing: bright and ruddy skin color can be obtained after makeup is finished, and the type of the light source is not changed at all after makeup is finished.
And 3, dividing: bright skin color can be obtained after makeup is finished, and the type of the light source is not changed at all after makeup is finished.
And 2, dividing: bright skin color can hardly be obtained after makeup is finished.
1 minute: bright skin color cannot be obtained after makeup is finished and/or the skin color becomes yellow under sunlight.
Evaluation criteria-
AA: the evaluation score exceeded 4.5 points.
A: the evaluation score was more than 3.5 points and 4.5 points or less.
B: the evaluation score was more than 2.5 points and 3.5 points or less.
C: the evaluation score was more than 1.5 points and 2.5 points or less.
D: the evaluation score was 1.5 or less.
2. Feeling of use
The liquid foundation was applied to 10 women.
Specifically, a powder puff is used to apply a liquid foundation to the face of a female subject. Then, the spreadability and ease of application of the foundation liquid at the time of application were evaluated according to the following evaluation criteria. After the scoring results were arithmetically averaged, the first place after the decimal point was obtained by four-sheet five-fold, and the obtained value was taken as an evaluation score (only marked as "score" in the table).
Then, evaluation was performed based on the evaluation score according to the following evaluation criteria.
If the evaluation result is "a" or "B", it is determined that the foundation liquid is a foundation liquid having a good feeling of use.
-score criteria-
And 4, dividing: the spreadability is very good, it is easy to spread, and color unevenness is not generated at all when coating.
And 3, dividing: the spreading property is good, the coating is easy to spread, and the color unevenness is hardly generated during the coating.
And 2, dividing: although spreadable, it is difficult to spread and produces color unevenness when coated.
1 minute: the spreadability is poor.
Evaluation criteria-
A: the evaluation score was 3.5 or more.
B: the evaluation score was 3.0 points or more and less than 3.5 points.
C: the evaluation score was 2.0 points or more and less than 3.0 points.
D: the evaluation score was less than 2.0 points.
3. Stability of appearance color over time
A disk (dish) having a quartz glass bottom surface (trade name: SF-G-D27, bottom opening diameter:
techno Alpha co., ltd. ], 5mL of foundation solution was put in, and the diameter was measured using a spectrocolorimeter (trade name: SE7700) from NIPPON DENSHOKU INDUSTRIES co., ltd.: MA V, light source: c light source and angle of view: l was measured from the bottom side of the dish under the condition of 2 °*a*b*And (4) chromatic aberration.
Then, the foundation liquid was sealed in a plastic container and allowed to stand at 50 ℃ for 3 months. For the foundation after standing for 3 months, L was measured in the same manner as described above*a*b*And (4) chromatic aberration.
The color difference (. DELTA.E) before and after 3-month standing was calculated and evaluated according to the following evaluation criteria. The first decimal place of the color difference (Δ E) is obtained by four-sheet-flat-five.
If the evaluation result is "a" or "B", it is judged that the foundation liquid is excellent in the stability of the appearance color with time.
Evaluation criteria-
A: the color difference (Delta E) is 1.5 or less.
B: the color difference (Δ E) is more than 1.5 and not more than 2.0.
C: the color difference (Δ E) is more than 2.0 and not more than 3.0.
D: the color difference (. DELTA.E) exceeds 3.0.
[ Table 1]
[ Table 2]
[ Table 3]
[ Table 4]
[ Table 5]
In tables 1 to 5, components corresponding to the organic dye hydrate, the polyglycerol-modified silicone, the specific polyether-modified silicone, water, and the inorganic red dye are respectively classified into (a), (B), (C), (D), and (a) and labeled.
In tables 1 to 5, "-" in the composition columns indicates that the corresponding components are not contained. In tables 1 to 5, "-" shown in columns other than the composition columns indicates that there is no corresponding item.
Example 2 shown in tables 2 to 5 is described for comparison, and is the same as example 2 shown in table 1. Example 1 shown in table 5 is for comparison and is the same as example 1 shown in table 1.
In tables 1 to 5, "the ratio of the blending amount of the organic red pigment hydrate in terms of the organic red pigment to the blending amount of the inorganic red pigment on a mass basis" is denoted as "organic red pigment/inorganic red pigment (a) in the organic red pigment hydrate (a)".
As shown in tables 1 to 4, it was confirmed that natural and bright skin colors which were not easily affected by the type of light source were obtained after makeup was completed from the foundation liquids of examples 1 to 21 containing an organic pigment hydrate, a polyglycerol-modified silicone, a specific polyether-modified silicone, and water. Further, it was confirmed that the foundation liquids of examples 1 to 21 were excellent in feeling of use. In addition, it was confirmed that the foundation liquids of examples 1 to 21 are excellent in stability with time of appearance color.
On the other hand, as shown in table 5, it was confirmed that a natural and bright skin color could not be obtained from the makeup base of comparative example 1 containing an organic pigment in a non-hydrate form instead of an organic pigment hydrate. Further, it was confirmed that the foundation liquid of comparative example 1 was poor in feeling of use. In addition, the foundation liquid of comparative example 1 was confirmed to have poor stability of the appearance color with time.
From the foundation of comparative example 2 containing no polyglycerol-modified silicone, it was confirmed that a natural and bright skin color could not be obtained after makeup had been completed. Further, it was confirmed that the stability with time of the appearance color of the foundation liquid of comparative example 2 was poor.
From the foundation of comparative example 3 containing no specific polyether-modified silicone, it was confirmed that a natural and bright skin color could not be obtained after makeup had been completed. Further, it was confirmed that the foundation liquid of comparative example 3 had poor feeling of use. In addition, the foundation liquid of comparative example 3 was confirmed to have poor stability with time in appearance color.
It was confirmed that all of the foundation liquids of comparative examples 4 to 6, which contain a polyether-modified silicone having an HLB value exceeding 8.0 instead of the specific polyether-modified silicone, had poor stability with time.
[ reference formulation example (1) ] A pressed powder
A dust having the following composition was prepared by a conventional method. The names of the components are all names of the components of the cosmetic.
(composition)
55.00 parts by mass of talc
[ trade name: EX-15, YAMAGUCHI MICA CO., LTD. ]
10.00 parts by mass of Zinc oxide
[ trade name: FINEX-50S-LP2, Sakai Chemical Industry Co., Ltd. ]
Polymethyl methacrylate 4.00 parts by mass
[ trade name: ACX-806C, SEKISUI PLASTIC CO., Ltd. ]
4.00 parts by mass of Ba sulfate
[ trade name: HG-LFP, Sakai Chemical Industry Co., Ltd. ]
3.00 parts by mass of octyldodecanol
[ trade name: RISONOL 20SP, KOKYU ALCOOL KOGYO CO., LTD. ]
3.00 parts by mass of squalane
[ trade name: NIKKOL (registered trademark) SUGAR SQUALAN, Nikko Chemicals Co., Ltd. ]
Synthetic fluorophlogopite 3.00 parts by mass
[ trade name: DK PEARL-SY SYLVER, DAITO CHEMICAL CO., LTD. ]
1.00 parts by mass of silica
[ trade name: sunsphere H-121, AGC Si-Tech.Co., Ltd. ]
(vinyl Dimethicone/polymethylsiloxane silsesquioxane) crosspolymer
1.00 part by mass
[ trade name: KSP-105, Shin-Etsu Chemical Co., Ltd. ]
1.00 parts by mass of diphenylsiloxyphenyl trimethicone
[ trade name: KF-56A, Shin-Etsu Chemical Co., Ltd.,. Ltd. ]
Diisostearyl malate 1.00 part by mass
[ trade name: NIKKOL (registered trademark) DISM, Nikko Chemicals co., ltd. ]
0.50 part by mass of polyglycerin-2 triisostearate
[ trade name: NIKKOL (registered trademark) DGTIS, Nikko Chemicals co., ltd. ]
0.10 parts by mass of di (isostearyl alcohol/phytosterol) dimer dilinoleate
[ trade name: LUSPLAN (registered trademark) PI-DA, Dainiciseika Color & Chemi colors Mfg. Co., Ltd., Ltd. ]
0.10 parts by mass of tocopherol
[ trade name: tocopherol, Eisai Food & Chemical Co., Ltd. ]
0.10 parts by mass of acetylhydroxyproline
[ trade name: AHYP, KYOWA HAKKO BIO CO., LTD. ]
0.10 parts by mass of Haematococcus pluvialis oil
[ trade name: ASTOTS (registered trademark) -S, Fujifilm Corporation ]
Hydrolyzed collagen 0.10 parts by mass
[ trade name: promois (registered trademark) W-52P, SEIWA KASEI Co, Ltd. ]
0.10 parts by mass of phenoxyethanol
[ trade name: seisept (registered trademark) P, SEIWA KASEI Co, Ltd.)
0.10 parts by mass of water-soluble collagen
[ trade name: PANCOGENs MARIN 2, IKEDA CORPORATION
6.50 parts by mass of mica
[ trade name: TM-10, YAMAGUGCHI MICA CO., LTD. ]
3.00 parts by mass of titanium oxide
[ trade name: STR-100C-LP, Sakai Chemical Industry Co., Ltd. ]
2.00 parts by mass of titanium oxide
[ trade name: MKR-1, Sakai Chemical Industry Co., Ltd. ]
0.80 parts by mass of iron oxide
[ trade name: LL-100, Titan Kogyo, Ltd. ]
0.50 parts by mass of iron oxide
[ trade name: R-MR, Titan Kogyo, Ltd. ]
0.01 parts by mass of iron oxide
[ trade name: BL-100, Titan Kogyo, Ltd. ]
0.0001 parts by mass of F-RED-C
[ trade name: F-RED-C, DAITO CHEMICAL CO., LTD. ]
[ reference formulation example (2) ] powdery foundation
A powder foundation having the following composition was prepared by a conventional method. The names of the components are all names of the components of the cosmetic.
(composition)
12.0 parts by mass of silica
[ trade name: sunsphere H-121, AGC Si-Tech.Co., Ltd. ]
11.0 parts by mass of boron nitride
[ trade name: BN09H, INA TRADIING co., ltd. ]
5.0 parts by mass of Zinc myristate
[ trade name: powder Base M, NOF CORPORATION ]
Polymethyl methacrylate 4.5 parts by mass
[ trade name: ACX-806C, SEKISUI PLASTIC CO., Ltd. ]
Synthetic fluorophlogopite 5.0 parts by mass
[ trade name: DKPEARL-SY SYLVER, DAITO CHEMICAL CO., LTD. ]
(vinyl Dimethicone/polymethylsiloxane silsesquioxane) crosspolymer
5.0 parts by mass
[ trade name: KSP-105, Shin-Etsu Chemical Co., Ltd. ]
5.0 parts by mass of ethylhexyl methoxycinnamate
[ trade name: uvinul (registered trademark) MC80N, BASF Japan Ltd.)
3.0 parts by mass of diphenylsiloxyphenyl trimethicone
[ trade name: KF-56A, Shin-Etsu Chemical Co., Ltd.,. Ltd. ]
0.5 parts by mass of Vaseline
[ trade name: nom Coat W, The Nisshin OilliO Group, Ltd. ]
0.5 parts by mass of tocopherol
[ trade name: tocopherol, Eisai Food & Chemical Co., Ltd. ]
0.5 parts by mass of bisabolol
[ trade name: bisabolol nat, BASF Japan Ltd. ]
Di (isostearyl alcohol/phytosterol) dimer dilinoleate 0.1 part by mass
[ trade name: LUSPLAN (registered trademark) PI-DA, Dainiciseika Color & Chemi colors Mfg. Co., Ltd., Ltd. ]
0.1 part by mass of purified water
0.1 part by mass of Ba sulfate
[ trade name: HG-LFP, Sakai Chemical Industry Co., Ltd. ]
0.1 part by mass of acetylhydroxyproline
[ trade name: AHYP, KYOWA HAKKO BIO CO., LTD. ]
0.1 part by mass of Haematococcus pluvialis oil
[ trade name: ASTOTS (registered trademark) -S, Fujifilm Corporation ]
Hydrolyzed collagen 0.1 part by mass
[ trade name: promois (registered trademark) W-52P, SEIWA KASEI Co, Ltd. ]
0.1 part by mass of phenoxyethanol
[ trade name: seisept (registered trademark) P, SEIWA KASEI Co, Ltd.)
0.1 part by mass of water-soluble collagen
[ trade name: PANCOGENs MARIN 2, IKEDA CORPORATION
19.0 parts by mass of talc
[ trade name: EX-15, YAMAGUCHI MICA CO., LTD. ]
14.5 parts by mass of mica
[ trade name: TM-10, YAMAGUGCHI MICA CO., LTD. ]
6.0 parts by mass of titanium oxide
[ trade name: STR-100C-LP, Sakai Chemical Industry Co., Ltd. ]
5.0 parts by mass of titanium oxide
[ trade name: MKR-1, Sakai Chemical Industry Co., Ltd. ]
1.2 parts by mass of iron oxide
[ trade name: LL-100, Titan Kogyo, Ltd. ]
0.8 parts by mass of iron oxide
[ trade name: R-MR, Titan Kogyo, Ltd. ]
0.085 parts by mass of iron oxide
[ trade name: BL-100, Titan Kogyo, Ltd. ]
Claims (10)
1. An emulsion type makeup base, comprising:
an organic pigment hydrate;
a polyglycerol-modified silicone;
a polyether-modified silicone having a value of the hydrophilic-lipophilic balance of 8.0 or less; and
and (3) water.
2. The emulsion type makeup base according to claim 1, wherein,
the content of the hydrate of organic dye is 0.1 to 3.0 mass% in terms of organic dye based on the total mass of the emulsion type makeup base.
3. The emulsion type makeup base according to claim 1 or 2, wherein,
the organic pigment hydrate is organic red pigment hydrate.
4. The emulsion-type makeup base according to claim 3, further comprising an inorganic red pigment, wherein the content of the hydrate of the organic red pigment in terms of the organic red pigment is 0.33 times or more by mass relative to the content of the inorganic red pigment.
5. The emulsion type makeup base according to claim 3, which does not contain an inorganic red pigment.
6. The emulsion type makeup base according to claim 1 or 2, wherein,
the organic pigment hydrate is a hydrate of a composite pigment containing silica.
7. The emulsion type makeup base according to claim 1 or 2, wherein,
the content of the polyglycerol-modified silicone is 0.01 to 7 mass% based on the total mass of the emulsion-type makeup base.
8. The emulsion type makeup base according to claim 1 or 2, wherein,
the content of the polyether-modified silicone is 0.1 mass% or more and 8 mass% or less based on the total mass of the emulsion-type makeup base.
9. The emulsion-type makeup base according to claim 1 or 2, further comprising a polyol.
10. A method for producing an emulsion type makeup cosmetic according to any one of claims 1 to 9, comprising the steps of:
the mixture of the oil phase composition containing the organic pigment hydrate and the aqueous phase composition is subjected to emulsification treatment.
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| JP2019149679A JP7220638B2 (en) | 2019-08-19 | 2019-08-19 | Emulsion type base makeup cosmetic and method for producing the same |
| JP2019-149679 | 2019-08-19 |
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| JP2006306868A (en) * | 2005-03-31 | 2006-11-09 | Kose Corp | Water-in-oil cosmetic emulsion |
| JP2011126808A (en) * | 2009-12-16 | 2011-06-30 | Kao Corp | Water-in-oil emulsion cosmetic |
| CN103596547A (en) * | 2011-06-13 | 2014-02-19 | 富士胶片株式会社 | Emulsion-type make-up base and method for producing same |
| CN104970992A (en) * | 2014-04-04 | 2015-10-14 | 富士胶片株式会社 | Liquid makeup |
| JP2015199728A (en) * | 2014-04-04 | 2015-11-12 | 富士フイルム株式会社 | Liquid Foundation |
| WO2018216696A1 (en) * | 2017-05-25 | 2018-11-29 | 富士フイルム株式会社 | Water-in-oil type cosmetic |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3788680B2 (en) * | 1997-12-22 | 2006-06-21 | 花王株式会社 | Organic-inorganic composite pigment and method for producing the same |
| JP4536538B2 (en) | 2005-02-02 | 2010-09-01 | 株式会社ファンケル | Water-in-oil cosmetics |
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2019
- 2019-08-19 JP JP2019149679A patent/JP7220638B2/en active Active
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006306868A (en) * | 2005-03-31 | 2006-11-09 | Kose Corp | Water-in-oil cosmetic emulsion |
| JP2011126808A (en) * | 2009-12-16 | 2011-06-30 | Kao Corp | Water-in-oil emulsion cosmetic |
| CN103596547A (en) * | 2011-06-13 | 2014-02-19 | 富士胶片株式会社 | Emulsion-type make-up base and method for producing same |
| CN104970992A (en) * | 2014-04-04 | 2015-10-14 | 富士胶片株式会社 | Liquid makeup |
| JP2015199728A (en) * | 2014-04-04 | 2015-11-12 | 富士フイルム株式会社 | Liquid Foundation |
| WO2018216696A1 (en) * | 2017-05-25 | 2018-11-29 | 富士フイルム株式会社 | Water-in-oil type cosmetic |
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| JP7220638B2 (en) | 2023-02-10 |
| JP2021031403A (en) | 2021-03-01 |
| CN112386527B (en) | 2024-02-13 |
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