CN112359634B - New technology of traditional culture paper - Google Patents

New technology of traditional culture paper Download PDF

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Publication number
CN112359634B
CN112359634B CN202011185006.2A CN202011185006A CN112359634B CN 112359634 B CN112359634 B CN 112359634B CN 202011185006 A CN202011185006 A CN 202011185006A CN 112359634 B CN112359634 B CN 112359634B
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fibers
fiber
mulberry bark
mulberry
paper
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CN112359634A (en
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顾理富
顾萌珂
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/02Chemical or chemomechanical or chemothermomechanical pulp
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01CCHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
    • D01C1/00Treatment of vegetable material
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01CCHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
    • D01C1/00Treatment of vegetable material
    • D01C1/02Treatment of vegetable material by chemical methods to obtain bast fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F13/00Making discontinuous sheets of paper, pulpboard or cardboard, or of wet web, for fibreboard production
    • D21F13/02Making hand-made paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/06Long fibres, i.e. fibres exceeding the upper length limit of conventional paper-making fibres; Filaments

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Textile Engineering (AREA)
  • Paper (AREA)

Abstract

The invention discloses a new technology of traditional culture paper, which is characterized by comprising the following steps: step one, preparation of raw materials and additives, step two, preparation of fibers, step three, mixing of long fibers and short fibers according to a ratio, step four and subsequent processing. Mixing mulberry fibers and either straw fibers or bamboo fibers according to the mass ratio. The cultural paper prepared by the invention can meet the higher use requirements of people on paper in the aspects of flexibility, wet-dyeing property, ink absorption, durability, adhesiveness, glossiness and the like, and the whole preparation process is time-saving and labor-saving and plays a positive role in environmental protection.

Description

New technology of traditional culture paper
Technical Field
The invention relates to the technical field of papermaking technologies, in particular to a new technology of traditional cultural paper.
Background
The paper making technology is one of four inventions in ancient China, and is an outstanding invention creation in the human civilization history. The method has important significance for the development of Chinese cultural cause, and just because of the papermaking technology, people can learn more cultural knowledge at present, thereby widening the self eye.
The cultural paper manufactured in the prior art can not meet the higher use requirements of people on the paper in the aspects of flexibility, wet-dyeing property, ink absorption, durability, adhesive property, glossiness and the like. The prior art papermaking processes also suffer from a number of convenient drawbacks, such as: the pulping process consumes a large amount of manpower and material resources, and simultaneously causes certain pollution to the environment.
Based on this, a new technology of the traditional culture paper is urgently needed to solve the above-mentioned problems.
Disclosure of Invention
In order to solve the problem, the invention discloses a new technology of the traditional culture paper, which aims to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: a new technique of traditional culture paper is characterized in that the new technique comprises the following steps:
step one, preparing raw materials and additives
The raw materials are as follows: ramulus Mori, caulis et folium oryzae, and bamboo
The additive is as follows: sodium metasilicate, sodium pyrophosphate, hydrogen peroxide, sodium chloride, water and ripener
Wherein, the mass of the additive added into each ton of mulberry bark from which chlorophyll is removed is as follows:
Figure BSA0000223378870000011
step two, fiber preparation
The fiber preparation steps are as follows:
a. firstly, the mulberry bark obtained after the mulberry branches are peeled by a peeling machine is placed in equipment and is added with ethanol for soaking and distillation, so as to remove chlorophyll/flavone in the mulberry bark, thereby obtaining mulberry bark without chlorophyll;
b. adding 200 kg of sodium metasilicate, 5-25 kg of sodium chloride, 0.125 kg of ripener and 3500 kg of water into chlorophyll-free mulberry bark equipment, adding the additive, and boiling at normal temperature; after the slurry is boiled at normal temperature, adding sodium pyrophosphate with the mass of 5-10 kg per ton of mulberry bark while stirring, wherein the sodium pyrophosphate is used as a hydrogen peroxide inhibitor; after the mulberry bark is degreased and boiled, the total amount of hydrogen peroxide added into each ton of mulberry bark is 200-500 kg, the hydrogen peroxide is added for 4-5 times, the hydrogen peroxide is added once every 20 minutes, the adding amount is 40-125 kg each time, until the standard requirement of cellulose whiteness is met, and the mulberry bark fibers are generated;
c. putting the straws into a cooking device, adding water and alkali, cooking at normal temperature, wherein the water addition amount is 3500 kg per ton of straws, the alkali addition amount is 50-100 kg per ton of straws, cooking at normal temperature for 1-3 hours, washing, adding calcium hypochlorite or sodium hypochlorite for bleaching after washing, and generating straw fibers; the preparation method of the bamboo fiber is the same as that of the straw fiber;
step three, mixing the long and short fibers according to the proportion
The mulberry bark fibers prepared in the second step are called long fibers, and the straw fibers or the bamboo fibers are called short fibers; the length of the mulberry fiber is more than 2.2mm, wherein the ratio of the length of 2.0mm-3.0mm is 70%; the length of the straw fiber or bamboo fiber is more than 0.65mm, wherein the proportion of 0.5mm-1.0mm is 75%;
mixing long fibers and short fibers according to a certain mass ratio according to different prepared products, wherein the mass ratio of the long fibers to the short fibers is = 3: 7; the mass ratio of the clean paper to the short fiber is 6: 4; the mass ratio of the ultra-clean leather paper is long fiber to short fiber = 8: 2
Step four, subsequent processing
The long and short fibers are mixed according to the proportion and then are washed, fished, squeezed, dried and cut into finished products.
Further, the mulberry fiber and the straw fiber or the bamboo fiber are mixed according to the mass ratio.
Further, the comprehensive properties of the paper product manufactured by the invention are better than those of the traditional four-name paper.
The invention has the beneficial effects that:
the cultural paper prepared by the invention can meet the higher use requirements of people on paper in the aspects of flexibility, wet-dyeing property, ink absorption, durability, adhesiveness, glossiness and the like, and the whole preparation process is time-saving and labor-saving and plays a positive role in environmental protection.
A series of concepts in a simplified form are introduced in the summary section, which is described in further detail in the detailed description section. This summary is not intended to identify key features or essential features of the claimed subject matter, nor is it intended to be used as an aid in determining the scope of the claimed subject matter.
Advantages and features of the present invention are described in detail below.
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None.
Detailed Description
In the following description, numerous specific details are set forth in order to provide a more thorough understanding of the present invention. It will be apparent, however, to one skilled in the art, that the present invention may be practiced without one or more of these specific details. In other instances, well-known features have not been described in order to avoid obscuring the present invention.
In the following description, a detailed construction will be set forth in order to provide a thorough understanding of the present invention. It is apparent that the invention may be practiced without limitation to the specific details known to those skilled in the art. The following detailed description of the preferred embodiments of the invention, however, the invention is capable of other embodiments in addition to those detailed.
The following provides a detailed description of embodiments of the invention.
A new skill of a cultural traditional paper, wherein the new skill comprises the steps of:
step one, preparing raw materials and additives
The raw materials are as follows: ramulus Mori, caulis et folium oryzae, and bamboo
The additive is as follows: sodium metasilicate, sodium pyrophosphate, hydrogen peroxide, sodium chloride, water and ripener
Wherein, the mass of the additive added to each ton of mulberry bark without chlorophyll is as follows:
Figure BSA0000223378870000031
step two, fiber preparation
The fiber preparation steps are as follows:
a. firstly, the mulberry bark obtained after the mulberry branches are peeled by a peeling machine is placed in equipment and is added with ethanol for soaking and distillation, so as to remove chlorophyll/flavone in the mulberry bark, thereby obtaining mulberry bark without chlorophyll;
b. adding 200 kg of sodium metasilicate, 5-25 kg of sodium chloride, 0.125 kg of ripener and 3500 kg of water into chlorophyll-free mulberry bark equipment, adding the additive, and boiling at normal temperature; after the slurry is boiled at normal temperature, adding sodium pyrophosphate with the mass of 5-10 kg per ton of mulberry bark while stirring, wherein the sodium pyrophosphate is used as a hydrogen peroxide inhibitor; after the mulberry bark is degreased and boiled, the total amount of hydrogen peroxide added into each ton of mulberry bark is 200-500 kg, the hydrogen peroxide is added for 4-5 times, the hydrogen peroxide is added once every 20 minutes, the adding amount is 40-125 kg each time, until the standard requirement of cellulose whiteness is met, and the mulberry bark fibers are generated;
c. putting the straws into a cooking device, adding water and alkali, cooking at normal temperature, wherein the water addition amount is 3500 kg per ton of straws, the alkali addition amount is 50-100 kg per ton of straws, cooking at normal temperature for 1-3 hours, washing, adding calcium hypochlorite or sodium hypochlorite for bleaching after washing, and generating straw fibers; the preparation method of the bamboo fiber is the same as that of the straw fiber;
step three, mixing the long and short fibers according to the proportion
The mulberry bark fibers prepared in the second step are called long fibers, and the straw fibers or the bamboo fibers are called short fibers; the length of the mulberry fiber is more than 2.2mm, wherein the ratio of the length of 2.0mm-3.0mm is 70%; the length of the straw fiber or the bamboo fiber is more than 0.65mm, wherein the proportion of 0.5mm-1.0mm is 75 percent;
mixing long fibers and short fibers according to a certain mass ratio according to different prepared products, wherein the mass ratio of the long fibers to the short fibers is = 3: 7; the mass ratio of the clean paper to the skin paper is long fiber to short fiber = 6: 4; the mass ratio of the ultra-clean leather paper is long fiber to short fiber = 8: 2
Step four, subsequent processing
The long and short fibers are mixed according to the proportion and then are washed, fished, squeezed, dried and cut into finished products.
Further, the mulberry fiber and the straw fiber or the bamboo fiber are mixed according to the mass ratio.
Furthermore, the comprehensive properties of the paper product manufactured by the invention are better than those of the traditional four major papers.
Compared with the product prepared by the traditional process, the invention also has the following advantages:
1. flexibility: the paper has outstanding flexibility, is soft when being held in hands, is flexible when being written on the paper by a brush pen, and is easy to write and draw;
2. wet dyeing property: the ink has good diffusivity to the periphery when falling on the paper surface;
3. ink receptivity: the paper product has stronger adsorption performance;
4. and (3) durability: the calligraphy and painting written on the paper has durability and does not fade;
5. adhesiveness: the ink leakage phenomenon can not occur;
6. gloss: the luster is good and bright like silk.
The beneficial effect of this embodiment does:
the cultural paper prepared by the embodiment can meet higher use requirements of people on paper in the aspects of flexibility, wet-dyeing property, ink absorption, durability, adhesiveness, glossiness and the like, is time-saving and labor-saving in the whole preparation process, and plays a positive role in environmental protection.
The present invention has been illustrated by the above embodiments, but it should be understood that the above embodiments are for illustrative and descriptive purposes only and are not intended to limit the invention to the scope of the described embodiments. Furthermore, it will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and that many variations and modifications may be made in accordance with the teachings of the present invention, which variations and modifications are within the scope of the present invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.

Claims (2)

1. A new technique of traditional culture paper is characterized in that the new technique comprises the following steps:
step one, preparing raw materials and additives
The raw materials are as follows: ramulus Mori, caulis et folium oryzae, and bamboo
The additive is as follows: sodium metasilicate, sodium pyrophosphate, hydrogen peroxide, sodium chloride, water and ripener
Wherein, the mass of the additive added to each ton of mulberry bark without chlorophyll is as follows:
Figure FSA0000223378860000011
step two, fiber preparation
The fiber preparation steps are as follows:
a. firstly, the mulberry bark obtained by peeling mulberry twigs by a peeling machine is placed in equipment, and ethanol is added for soaking and distilling, so that chlorophyll/flavone in the mulberry bark is removed, and the mulberry bark without chlorophyll is obtained;
b. adding 200 kg of sodium metasilicate, 5-25 kg of sodium chloride, 0.125 kg of ripener and 3500 kg of water into chlorophyll-free mulberry bark equipment, adding the additive, and boiling at normal temperature; after the slurry is boiled at normal temperature, adding sodium pyrophosphate with the mass of 5-10 kg per ton of mulberry bark while stirring, wherein the sodium pyrophosphate is used as a hydrogen peroxide inhibitor; after the mulberry bark is degreased and boiled, the total amount of hydrogen peroxide added into each ton of mulberry bark is 200-500 kg, the hydrogen peroxide is added for 4-5 times, the hydrogen peroxide is added once every 20 minutes, the adding amount is 40-125 kg each time, until the standard requirement of cellulose whiteness is met, and the mulberry bark fiber is generated;
c. putting the straws into cooking equipment, adding water and alkali, cooking at normal temperature, wherein the water addition amount is 3500 kg per ton of straws, the alkali addition amount is 50-100 kg per ton of straws, cooking at normal temperature for 1-3 hours, washing, and adding calcium hypochlorite or sodium hypochlorite for bleaching to generate straw fibers; the preparation method of the bamboo fiber is the same as that of the straw fiber;
step three, mixing the long fiber and the short fiber according to the proportion
The mulberry bark fibers prepared in the second step are called long fibers, and the straw fibers or the bamboo fibers are called short fibers; the length of the mulberry fiber is more than 2.2mm, wherein the ratio of the length of 2.0mm-3.0mm is 70%; the length of the straw fiber or bamboo fiber is more than 0.65mm, wherein the proportion of 0.5mm-1.0mm is 75%;
mixing long fibers and short fibers according to a certain mass ratio according to different prepared products, wherein the mass ratio of the long fibers to the short fibers is = 3: 7; the mass ratio of the clean paper to the short fiber is 6: 4; the mass ratio of the ultra-clean leather paper is long fiber to short fiber = 8: 2
Step four, subsequent processing
The long and short fibers are mixed according to the proportion and then are washed, fished, squeezed, dried and cut into finished products.
2. A new technology of traditionally cultural paper as claimed in claim 1, wherein said mulberry fibers are mixed with either straw fibers or bamboo fibers by mass ratio.
CN202011185006.2A 2020-10-26 2020-10-26 New technology of traditional culture paper Active CN112359634B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1210173A (en) * 1997-08-31 1999-03-10 庄富泉 Technical paper and papermaking method
CN1793490A (en) * 2005-12-29 2006-06-28 山东海龙股份有限公司 Process of preparing mulberry root bark pulp for producing dustless paper
CN101333783A (en) * 2008-07-16 2008-12-31 安徽泾县千年古宣宣纸有限公司 Processing method of leather slurry for producing ancient xuan paper
CN103122596A (en) * 2013-03-12 2013-05-29 富阳市胥口镇中心小学 Experience-type manual paper-making method
CN103215840A (en) * 2013-03-27 2013-07-24 钱邦发 Wingceltis silkworm cocoon Xuan paper and manufacture technology thereof
CN104343032A (en) * 2013-07-30 2015-02-11 中国制浆造纸研究院 Mulberry bark slurry used for calligraphy and painting paper and production method thereof
CN105256626A (en) * 2015-10-27 2016-01-20 北京印刷学院 Mulberry bark chemi-mechanical pulp as well as preparation method and application thereof
CN109750550A (en) * 2018-12-27 2019-05-14 枞阳县中邦科技信息咨询有限公司 A kind of preparation method of ripe a surname

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI20051145A0 (en) * 2005-11-11 2005-11-11 Kemira Oyj New pulp and process for pulping

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1210173A (en) * 1997-08-31 1999-03-10 庄富泉 Technical paper and papermaking method
CN1793490A (en) * 2005-12-29 2006-06-28 山东海龙股份有限公司 Process of preparing mulberry root bark pulp for producing dustless paper
CN101333783A (en) * 2008-07-16 2008-12-31 安徽泾县千年古宣宣纸有限公司 Processing method of leather slurry for producing ancient xuan paper
CN103122596A (en) * 2013-03-12 2013-05-29 富阳市胥口镇中心小学 Experience-type manual paper-making method
CN103215840A (en) * 2013-03-27 2013-07-24 钱邦发 Wingceltis silkworm cocoon Xuan paper and manufacture technology thereof
CN104343032A (en) * 2013-07-30 2015-02-11 中国制浆造纸研究院 Mulberry bark slurry used for calligraphy and painting paper and production method thereof
CN105256626A (en) * 2015-10-27 2016-01-20 北京印刷学院 Mulberry bark chemi-mechanical pulp as well as preparation method and application thereof
CN109750550A (en) * 2018-12-27 2019-05-14 枞阳县中邦科技信息咨询有限公司 A kind of preparation method of ripe a surname

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