CN1793490A - Process of preparing mulberry root bark pulp for producing dustless paper - Google Patents

Process of preparing mulberry root bark pulp for producing dustless paper Download PDF

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Publication number
CN1793490A
CN1793490A CN 200510104677 CN200510104677A CN1793490A CN 1793490 A CN1793490 A CN 1793490A CN 200510104677 CN200510104677 CN 200510104677 CN 200510104677 A CN200510104677 A CN 200510104677A CN 1793490 A CN1793490 A CN 1793490A
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China
Prior art keywords
minutes
boiling
free paper
pulp
dust
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Pending
Application number
CN 200510104677
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Chinese (zh)
Inventor
王乐军
李琳
吕翠莲
邢春花
娄善好
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CHTC Helon Co Ltd
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Shandong Helon Co Ltd
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Publication date
Application filed by Shandong Helon Co Ltd filed Critical Shandong Helon Co Ltd
Priority to CN 200510104677 priority Critical patent/CN1793490A/en
Publication of CN1793490A publication Critical patent/CN1793490A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a mulberry skin pulp manufacturing method used to produce dust free paper. It adopts mulberry skin as raw material to manufacture dust free paper. It includes the following steps: preparing material; boiling; washing material; pulping; de-sanding; bleaching; washing; manufacturing pulp; drying; and storing. The dust free paper can be used to make hydroscopic property product such as women sanitary towel, baby diaper, and so on. The product is clean, soft, has elasticity, good hydroscopic property, antibiosis and health protection.

Description

Be used to produce the preparation method of the mulberry root bark pulp of dust-free paper
Technical field
The present invention relates to pulp technology for making paper, especially relating to a kind of mulberry skin that adopts is the preparation method of mulberry root bark pulp who is used to produce dust-free paper that raw pulp is produced dust-free paper.
Background technology
The raw material that paper pulp adopts of paper grade (stock) is varied in the factory at present, have and adopt herbaceous plant to carry out slurrying, also have and adopt xylophyta to carry out slurrying, and the paper type with respect to different purposes adopts different raw materials to produce different paper pulp, resembles filter paper, toilet paper, printing paper etc.Be used for making the dust-free paper of lives such as sanltary towel, baby diaper and resemble with product, because it directly contacts with the skin of human body, require that product after the processing is pure white, soft, flexible, good hygroscopicity and asepticly human body is damaged preventing, so require high to the dust-free paper that is used to produce this series products.The current raw material that is used to produce dust-free paper is mainly needlebush, cotton linter, chemical modified fiber etc.Use needlebush, cotton linter, though the dust-free paper of raw material production such as chemical modified fiber meets people to sanltary towel, some basic demands of products such as baby diaper, but people are when using these products, because these products directly contact with human body skin, draw people's sweat and urine at these products after, be easy to grow some bacteriums, skin to human body damages, thereby influence the healthy of people, therefore people press for a kind of raw material with antibiotic health care and produce these products, and needlebush, cotton linter, raw materials such as chemical modified fiber all do not have antibiotic health-care function, are used to make sanltary towel by what their were produced, the dust-free paper of products such as baby diaper does not have antibiotic health-care function yet.
Mulberry tree is except that breeding silkworms for picking leaves, the ramulus mori of mulberry leaf and mulberry tree, the dispelling wind and heat from the body of the root bark of white mulberry, feelings liver, make eye bright, sharp joint, diuresis, pharmacologic action such as hypotensive just utilize by China people since ancient times, Shennong's Herbal, " Bencao Tujing ", " property of medicine opinion " etc. are early on the books.The Japanology person finds that the flavone compound that contains in the ramulus mori extract has the effect of resisting genetic cell cancer cellization, and studies show that this compounds has stronger scavenging action, and degree is 5 μ mMl -1The time, this compounds clearance rate of extracting from ramulus mori, mulberry skin is respectively 83.1%, 56.8%, and its scavenging action is stronger than rutin, ascorbic acid.Therefore, the fiber that the mulberry skin can be used for papermaking has the excellent antibiotic health properties, it can be used for producing the paper pulp of the dust-free paper that is used to make products such as sanltary towel, baby diaper fully, but still is difficult the technology that the mulberry skin is the paper pulp of raw material production dust-free paper in the society at present.
Summary of the invention
The technical problem to be solved in the present invention has provided that a kind of to adopt the mulberry skin be raw pulp is used to produce the preparation method of the mulberry root bark pulp of dust-free paper with production.
For solving the problems of the technologies described above, technical scheme of the present invention is: the preparation method who is used to produce the mulberry root bark pulp of dust-free paper, adopting the mulberry skin is that raw pulp is produced dust-free paper, it mainly comprises gets the raw materials ready, boiling, wash material, making beating, desanding, bleaching, washing, copy steps such as slurry, wherein boiling is to adopt in 10~30% of the relative over dry material of NaOH amount, liquor ratio 1: 3~5,60~120 minutes heating-up times, 130~170 ℃ of boiling maximum temperatures, temperature retention time 180~360 minutes, cooking quality is a permanganate number 3~6, dynamic viscosity 100 ± 10mpa.s, alpha cellulose 〉=90%; Chlorination is adopted in bleaching, in 1~5% of the relative over dry material of effective chlorine dosage amount, starch dense 2~6%, PH9~10,40~60 ℃ of bleaching temperatures, time of chlorinating 40~60 minutes.
As a kind of optimal way, described making beating is 5~10% at slurry concentration, and beating time is under 30~90 minutes, adopts shiny beating, and no little slurry group in the slurry that requires to obtain.
As another kind of optimal way, adopting in the boiling in NaOH is 23~25% with respect to over dry material amount, and liquor ratio is 1: 3~4,60~90 minutes heating-up times, 150~170 ℃ of boiling maximum temperatures, temperature retention time 240~300 minutes.
As another kind of optimal way, effective chlorine dosage is 3~5% with respect to over dry material amount in the employing chlorination bleaching.
In the present invention, the mulberry micromicro is to adopt mechanical mode from acquisitions such as ramulus moris when getting the raw materials ready, and can adopt machineries such as skinning machine that the epidermis of mulberry skin is removed, also can adopt the mode of the biology enzyme that current people generally adopt that it is removed, then the mulberry skin is screened, produce the mulberry skin that needs with the selector symphysis, and cut off, clean, preparation is given in removal of impurities etc., carry out boiling again, after boiling, bleed off raffinate, and the mulberry cladding after the boiling is washed, after meeting production requirement, pull an oar, operations such as desanding, desanding are carried out in desander, and purpose is to remove impurity in the slurry and tiny fiber; And the slurry that obtains washed, be washed to slurry and advance to meet production standard, in pulp machine, slurry is copied slurry afterwards, afterwards, can carry out dried to the slurry that obtains so that store.The equipment that is adopted in whole processing step is current people applied equipment in actual production like an elephant potcher and sand removing machine, the pulp machine etc. in the boiling vessel in the boiling-off, the bleaching, there is no special feature; Each raw material also is that people are used in daily production.
In the present invention, because mulberry fibre is a kind of of bast plant fiber, and the main composition of natural bast plant fiber is a cellulose, wherein also contains part pectin, hemicellulose, lignin, adipocere matter and the hydrotrope, and wherein content of cellulose accounts for about 40~60% of whole mulberry skin.Every physical index of mulberry fibre is as follows:
Average length mm 21.0~31.0
Mean breadth mm 0.01~0.03
Mean aspect ratio 1800~968
Filament tension stress g 20.0
Fracture strength cn/dtex 3.5~5.1
Having adopted better simply production technology among the present invention that the mulberry skin of mulberry fibre with above premium properties is carried out slurrying to it under than the situation of short liquor ratio handles, can make the production that to finish mulberry root bark pulp in the present invention with less supplies consumption, not only technology is simple, be convenient in the production operation of reality, use, and the mulberry fibre function admirable in the mulberry root bark pulp of producing, its every technical indicator can reach: alpha cellulose 〉=92%, paper pulp permanganate number≤3, whiteness 〉=70%, fibre length 〉=20mm, filament tension stress 〉=15g.With the slurry that contains this mulberry fibre is that the dust-free paper of raw material production is made moisture absorption products such as sanltary towel, baby diaper, and product is not only pure white, soft, flexible, good hygroscopicity, aseptic, but also has antibiotic health-care function.
Specific embodiment
Embodiment 1
To put into boiling vessel through the raw material mulberry skin that meets the production needs that preparatory process such as screening, cut-out, cleaning, removal of impurities were handled, employing is 25% in the relative over dry material of NaOH amount, liquor ratio is dosing in 1: 3, be warmed up to 150 ℃ in 60 minutes, and the insulation be 240 minutes, bleed off raffinate after boiling finishes, and the mulberry skin after the boiling washed, making its cooking quality is permanganate number 3~6, dynamic viscosity 100 ± 10mpa.s, alpha cellulose 〉=90%; In beater, the mulberry skin after the boiling is pulled an oar afterwards, adopt shiny beating, and require beating consistency between 5%~10%, pulled an oar 30~90 minutes, in slurry, do not have little slurry group to exist; Again the slurry that obtains is carried out desanding in desander, to remove impurity in the slurry and tiny fiber; Slurry is carried out the chlorination bleaching, adopt the effective chlorine dosage with respect to over dry material amount 5%, slurry concentration can under the condition of 40 ℃ of temperature, pH value 9~10, carry out chlorination 40 minutes about 2~6%; Bleed off raffinate then and it is washed,, just can in pulp machine, copy slurry afterwards and get final product slurry until meeting production standard.
The performance that adopts being used in the mulberry root bark pulp that the foregoing description obtained to produce the mulberry fibre of dust-free paper is: alpha cellulose can reach 95%, paper pulp permanganate number 1.23, whiteness 72%, fibre length 21mm, filament tension stress 16g.
Embodiment 2
The processing step that present embodiment adopted is consistent with embodiment 1, just in technology carry out boiling the time NaOH to count relative over dry material amount be 23%, liquor ratio 1: 3,90 minutes heating-up times, temperature retention time 300 minutes, 170 ℃ of boiling maximum temperatures; When bleaching, then adopt effective chlorine dosage, PH9~10,48 ℃ of bleaching temperatures, time of chlorinating 50 minutes with respect to over dry material amount 3%;
The performance that adopts being used in the mulberry root bark pulp that the foregoing description obtained to produce the mulberry fibre of dust-free paper is: alpha cellulose 96%, paper pulp permanganate number 1.2, whiteness 74%, fibre length 22mm, filament tension stress 17g.
Embodiment 3
The processing step that present embodiment adopted is consistent with embodiment 1, just in technology carry out boiling the time NaOH to count relative over dry material amount be 30%, liquor ratio 1: 5 was warmed up to 170 ℃ of boiling maximum temperatures, temperature retention time 180 minutes in 120 minutes; And when bleaching adopts with respect to over dry material amount 2% effective chlorine dosage, PH9~10,45 ℃ of bleaching temperatures, chlorination 50 minutes.
The performance that adopts being used in the mulberry root bark pulp that the foregoing description obtained to produce the mulberry fibre of dust-free paper is: alpha cellulose 96%, paper pulp permanganate number 1.12, whiteness 76%, fibre length 20mm, filament tension stress 18g.
Embodiment 4
The processing step that present embodiment adopted is consistent with embodiment 1, just in technology carry out boiling the time NaOH to count relative over dry material amount be 15%, liquor ratio 1: 4 was warmed up to 130 ℃ of boiling maximum temperatures, and was incubated 360 minutes in 60 minutes; And when bleaching adopts with respect to over dry material amount 1%, PH9~10,60 ℃ of bleaching temperatures, chlorination 60 minutes.
The performance that adopts being used in the mulberry root bark pulp that the foregoing description obtained to produce the mulberry fibre of dust-free paper is: alpha cellulose 94.8%, paper pulp permanganate number 2.1, whiteness 73%, fibre length 20mm, filament tension stress 17g.
Embodiment 5
The processing step that present embodiment adopted is consistent with embodiment 1, and to count relative over dry material amount be 10% to NaOH when just carrying out boiling in technology, and liquor ratio 1: 3.5 was warmed up to 135 ℃ of boiling maximum temperatures, and was incubated 360 minutes in 120 minutes; And when bleaching adopts with respect to over dry material amount 3.5%, PH9~10,60 ℃ of bleaching temperatures, chlorination 50 minutes.
The performance that adopts being used in the mulberry root bark pulp that the foregoing description obtained to produce the mulberry fibre of dust-free paper is: alpha cellulose 92%, paper pulp permanganate number 27, whiteness 70%, fibre length 20mm, filament tension stress 15g.

Claims (4)

1, is used to produce the preparation method of the mulberry root bark pulp of dust-free paper, adopting the mulberry skin is that raw pulp is produced dust-free paper, it is characterized in that it mainly comprises gets the raw materials ready, boiling, washes material, making beating, desanding, bleaching, washes, copies steps such as slurry, wherein boiling is to adopt in 10~30% of the relative over dry material of NaOH amount, liquor ratio 1: 3~5,60~120 minutes heating-up times, 130~170 ℃ of boiling maximum temperatures, temperature retention time 180~360 minutes, and cooking quality is a permanganate number 3~6, dynamic viscosity 100 ± 10mpa.s, alpha cellulose 〉=90%; Chlorination is adopted in bleaching, in 1~5% of the relative over dry material of effective chlorine dosage amount, starch dense 2~6%, PH9~10,40~60 ℃ of bleaching temperatures, time of chlorinating 40~60 minutes.
2, the preparation method who is used to produce the mulberry root bark pulp of dust-free paper according to claim 1, it is characterized in that: described making beating is 5~10% at slurry concentration, beating time is under 30~90 minutes, adopts shiny beating, and no little slurry group in the slurry that requires to obtain.
3, the preparation method who is used to produce the mulberry root bark pulp of dust-free paper according to claim 1, it is characterized in that: adopting in NaOH in the described boiling is 23~25% with respect to over dry material amount, and liquor ratio is 1: 3~4,60~90 minutes heating-up times, 150~170 ℃ of boiling maximum temperatures, temperature retention time 240~300 minutes.
4, the preparation method who is used to produce the mulberry root bark pulp of dust-free paper according to claim 1 is characterized in that: in the described employing chlorination bleaching effectively chlorine dosage be 3~5% with respect to over dry material amount.
CN 200510104677 2005-12-29 2005-12-29 Process of preparing mulberry root bark pulp for producing dustless paper Pending CN1793490A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200510104677 CN1793490A (en) 2005-12-29 2005-12-29 Process of preparing mulberry root bark pulp for producing dustless paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200510104677 CN1793490A (en) 2005-12-29 2005-12-29 Process of preparing mulberry root bark pulp for producing dustless paper

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CN1793490A true CN1793490A (en) 2006-06-28

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102154887A (en) * 2011-02-22 2011-08-17 杨和荣 Method for producing high-whiteness bleached ramulus mori pulp by caustic soda-anthraquinone continuous stewing technology
CN107964822A (en) * 2017-11-14 2018-04-27 潍坊友容实业有限公司 The method of the white willow papermaking of salt-soda soil plant
CN112359634A (en) * 2020-10-26 2021-02-12 顾理富 New technology of traditional culture paper

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102154887A (en) * 2011-02-22 2011-08-17 杨和荣 Method for producing high-whiteness bleached ramulus mori pulp by caustic soda-anthraquinone continuous stewing technology
CN107964822A (en) * 2017-11-14 2018-04-27 潍坊友容实业有限公司 The method of the white willow papermaking of salt-soda soil plant
CN112359634A (en) * 2020-10-26 2021-02-12 顾理富 New technology of traditional culture paper
CN112359634B (en) * 2020-10-26 2022-10-21 顾理富 New technology of traditional culture paper

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