CN112342695A - Application of short fiber filament composite yarn in fabric - Google Patents

Application of short fiber filament composite yarn in fabric Download PDF

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Publication number
CN112342695A
CN112342695A CN202011421510.8A CN202011421510A CN112342695A CN 112342695 A CN112342695 A CN 112342695A CN 202011421510 A CN202011421510 A CN 202011421510A CN 112342695 A CN112342695 A CN 112342695A
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CN
China
Prior art keywords
short fiber
composite yarn
fabric
fiber
yarn
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Pending
Application number
CN202011421510.8A
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Chinese (zh)
Inventor
何英杰
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Keystone Textile Co ltd
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Keystone Textile Co ltd
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Publication date
Application filed by Keystone Textile Co ltd filed Critical Keystone Textile Co ltd
Priority to CN202011421510.8A priority Critical patent/CN112342695A/en
Publication of CN112342695A publication Critical patent/CN112342695A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/12Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with filaments or yarns secured together by chemical or thermo-activatable bonding agents, e.g. adhesives, applied or incorporated in liquid or solid form
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/002Inorganic yarns or filaments
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/007Addition polymers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/009Condensation or reaction polymers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/009Condensation or reaction polymers
    • D04H3/011Polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Woven Fabrics (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

The application relates to the technical field of anti-cutting yarns, in particular to application of a short fiber filament composite yarn in a fabric. The application method comprises the following steps: and (3) impregnating and compounding the short fiber filament composite yarn with resin, rubber or glue to form a finished product. This application adopts short fiber filament composite yarn as the substrate of fabric, and short fiber filament composite yarn is: the single yarn with the staple fiber as the base material or the composite yarn synthesized by the plied yarn and the multi-ply yarn including the covered yarn with the staple fiber as the base material. The outer layer of the staple fibers has high bonding force with resin, rubber, glue and the like, so that the strength of the manufactured fabric is higher than that of the fabric taking the filaments as the base material. The fabric has high strength, wear resistance, cutting resistance, softness and good ductility, and can meet the use requirements of fabrics in the automobile industry, the building industry and the military industry.

Description

Application of short fiber filament composite yarn in fabric
Technical Field
The application relates to the technical field of anti-cutting yarns, in particular to application of a short fiber filament composite yarn in a fabric.
Background
With the increasing requirements of national defense, aerospace, ocean operation and various civil fields on protection and reinforcement of composite materials, the composite materials meet the requirements of high strength, strong impact resistance, light weight and the like, and also often meet multiple requirements of chemical corrosion resistance, sunlight resistance, ultrahigh temperature/ultralow temperature resistance, flame retardance, heat insulation, chemical substance isolation and the like.
At present, fabrics formed by taking filament fibers as base materials, such as aramid filament non-woven cloth, high-strength high-modulus polyethylene fiber non-woven cloth and the like, are light in weight and high in protective capability, but the binding force between the filament fibers and resin and glue is low, so that the strength of the fabrics such as the non-woven cloth is insufficient.
In view of the above-mentioned related art, the inventors have considered that there is a high necessity to provide a fabric having a high substrate-resin bonding force.
Disclosure of Invention
In order to overcome the defect of low bonding force between a base material and resin, the application applies the short fiber filament composite yarn to fabrics such as non-woven fabrics so as to obtain new fabrics.
The specific scheme adopted is as follows: the application of the composite yarn of the short fiber and the long fiber in the fabric takes the composite yarn of the short fiber and the long fiber as the base material of the fabric, and the composite yarn of the short fiber and the long fiber is: the single yarn with the staple fiber as the base material or the composite yarn synthesized by the plied yarn and the multi-ply yarn including the covered yarn with the staple fiber as the base material.
By adopting the technical scheme, the cutting-resistant capability of the short fiber and long filament composite yarn is good, the short threads and the long filaments of the short fiber and long filament composite yarn can be made of different materials, the short threads and the long filaments can meet the requirements of different functions after being woven into fabrics such as non-woven fabrics, and the fabric is soft, good in fracture extensibility and high in strength, wear-resistant and cutting-resistant. The short fiber filament composite yarn is formed by a plurality of short fibers, the outer layers of the short fibers are provided with hairiness, the ends of the short fibers and the hairiness of the short fibers can be embedded into resin, rubber or glue, so that the short fibers are better combined with the resin, the rubber or the glue, and the strength of fabrics such as weftless fabrics is improved. The staple fiber can be single yarn or composite yarn.
Optionally, the short fiber and filament composite yarn comprises a long fiber and a short fiber or a short fiber yarn, wherein the short fiber is one or more of polyphenylene sulfide short fiber, aramid short fiber, polyester short fiber, polyethylene short fiber, acrylic short fiber, polypropylene short fiber, cellulose fiber, vinylon short fiber and polyamide short fiber.
By adopting the technical scheme, the short fiber ends are more, so that the binding force of the short fiber filament composite yarn and the colloid is high. The staple fibers and the staple fibers have gaps, and the prepared staple fiber filament composite yarn is softer, so that the fabric such as a non-woven fabric has better extensibility.
Optionally, the length of the short fiber is 15-75mm, and the thickness is 0.8D-3.5D.
By adopting the technical scheme, the yarns made of the short staple fibers are easy to loosen, and the yarns made of the short staple fibers are poor in softness, so that the length range is selected. The above thickness range is selected because too thin staple fibers are insufficient in strength and too thick staple fibers tend to make the composite spun yarn thick and hard.
Optionally, the filaments are chemical fiber filaments, mineral fiber filaments or metal filaments, and the thickness of the filaments is 20D-2000D.
By adopting the technical scheme, the filaments mainly provide higher strength performance for the staple fiber filament composite yarns. The chemical fiber filaments and the mineral fiber filaments can be selected according to different requirements of customers.
Optionally, one of the yarns used in the staple fiber filament composite yarn is: the bundle silk is used as core yarn, and the yarn of the short fiber is wrapped outside.
By adopting the technical scheme, the fabric has the staple fibers and the bunched filaments, so that the double requirements of softness and strength can be met, and the fabric has the advantages of the staple fibers and the filaments.
Optionally, the number of the bunched filaments is controlled to be between 1000 and 15000.
Through adopting above-mentioned technical scheme, the bundle silk has better intensity and prevents cutting performance.
Optionally, the bundle filaments are made of one of high-strength high-modulus polyethylene, aramid fiber 14, high-strength nylon and high-strength polyester.
By adopting the technical scheme, some high-performance bundle yarns are selected to participate in the weaving of the fabric, so that the overall cutting resistance of the fabric is better.
Optionally, the application method comprises the following steps: and (3) impregnating and compounding the short fiber filament composite yarn with resin, rubber or glue to form a finished product.
By adopting the technical scheme, the method for manufacturing the non-woven fabric by taking the short-fiber filament composite yarn as the base layer of the fabric such as the non-woven fabric is provided, and has the advantages of simple process and convenience in forming.
Optionally, in step S1, the resin is a high-strength elastomer.
By adopting the technical scheme, the high-strength elastomer has high strength, flexibility, good adherence with a base material, low use cost, high curing speed, high extensibility after film forming, good initial viscosity performance at the initial stage of use and easy leveling property adjustment.
Optionally, the glue is compounded with a color developing agent, anhydrous copper sulfate powder and an anti-ultraviolet agent, and the ratio of the glue to the color developing agent to the anhydrous copper sulfate powder to the anti-ultraviolet agent is 1:0.01: 0.02: 0.01.
by adopting the technical scheme, the anhydrous copper sulfate powder can display blue after meeting water, the color developing agent can help the compound generated after biochemical reaction to develop color, and the general color developing agent is purchased. The ultraviolet resistant agent can inhibit and delay the harm of ultraviolet rays to the photo-aging of the short-thread filament composite yarn. The scheme can ensure that newly manufactured fabrics such as weftless fabrics have an anti-counterfeiting function, are convenient for identifying the authenticity of products, have the effects of ultraviolet resistance and aging resistance and prolong the service life of the products.
In summary, the present application includes at least one of the following beneficial technical effects:
1. the composite yarn of the short fibers and the long filaments is used as the base material of the fabric, the outer layer of the short fibers has high bonding force with resin, rubber, glue and the like, so that the strength of the manufactured fabric such as the weftless fabric is higher than that of the weftless fabric taking the long filaments as the base material;
2. the product has the advantages of high strength, high modulus, cutting resistance, softness, good ductility and the like;
3. the forming process is simple, raw materials are convenient to obtain, and economic cost is low.
Detailed Description
Example 1
The embodiment of the application discloses an application of a short fiber filament composite yarn in a fabric, and particularly relates to the application of the short fiber filament composite yarn as a base material of the fabric. The fabric in this application refers to non-woven cloth, gloves, cuffs, knee pads, clothes, etc.
The staple fiber filament composite yarn in this application is: single yarn or composite yarn using short fiber as base material; the composite yarn is a yarn compounded by a plurality of strands of yarn including plied yarn and covered yarn by using short fibers as base materials. Staple filament composite yarns include filaments and staple fibers or spun yarns. The filaments include chemical fiber filaments, mineral fiber filaments, or metal filaments, such as glass fibers, steel filaments, and the like. The thickness of the filament is controlled to be 20D-2000D. The short fiber is one or more of polyphenylene sulfide short fiber, aramid short fiber, polyester short fiber and polyethylene short fiber. The length of the staple fibers is controlled to be 15-75mm, and the thickness of the staple fibers is controlled to be 0.8D-3.5D, so that the staple fiber filament composite yarn has hardness and softness. Spun yarns are yarns made by blending some of the above mentioned staple fibers.
In this embodiment 1, a non-woven fabric is taken as an example, wherein a combination of polyphenylene sulfide staple fibers, aramid staple fibers and polyester staple fibers is adopted for the staple fiber yarn, and the ratio of the three staple fibers is 1:2: 1. The staple fibers and the glass fibers in the three proportions are subjected to a core-spun process to form the staple fiber filament composite yarn I. The polyphenylene sulfide short fiber has good strength and elongation, and excellent thermal stability, flame retardance and chemical resistance. The aramid short fiber has high strength and wear resistance, and the polyester short fiber has high elasticity and elongation. Therefore, the wrapping yarn wrapping performance of the short-fiber filament composite yarn is good, and the manufactured weftless fabric is high in strength, good in wear resistance and good in ductility.
The application method process of the embodiment 1 is as follows:
s1, uniformly spreading the short fiber filament composite yarn I, and impregnating with resin to form a semi-finished product. The thickness of the laid filaments is controlled to be 0.1-5 mm. The resin can adopt a high-strength elastomer, such as a high-strength SEBS or a high-strength UV elastomer, wherein the high-strength SEBS is selected, and the volume ratio of the high-strength SEBS to the fabric 1 is 1: 1. the high-strength SEBS has good antioxidant and ozone resistance, improved thermal stability and aging resistance, can increase the service temperature, has good wear resistance and electrical property, and improves the compatibility with plastics such as polyethylene, polypropylene and the like. On one hand, the short fibers of the short fiber filament composite yarn I have more short fiber ends, and on the other hand, the short fibers also have a plurality of hairiness outside, and the ends and the hairiness increase the bonding capacity with resin, so that the overall strength of the product is improved.
S2, performing biorthogonal composite lamination on the semi-finished product at 0-90 degrees to form a finished product I of the non-woven fabric. The pressure of hot pressing is gradually increased from 2MPa to 4MPa, and the thermoplastic condition is controlled at 120 ℃ for 13 min. If the pressure is too low and the thermoplastic time is too short, the strength is not enough, and if the pressure is too high and the thermoplastic time is too long, the finished product is easy to become brittle.
The resin may be replaced with rubber.
Example 2:
the short fiber of this example 1 is a combination of polyphenylene sulfide short fiber, polyethylene short fiber, and polyester short fiber, and the ratio of the three short fibers is 1:2: 1. And forming the short fiber and glass fiber in the three proportions into the short fiber filament composite yarn II by a core-spun process. The polyethylene staple fibers have high strength and wear resistance, the wrapping yarn wrapping performance of the formed staple fiber filament composite yarn is good, the economic cost is low, and the manufactured weftless fabric is high in strength, good in wear resistance and good in ductility.
The application method process of the embodiment 1 is as follows:
and S1, uniformly spreading the staple fiber filament composite yarn II. And (5) dipping with glue to form a semi-finished product. The glue amount is: the volume ratio of the glue to the short fiber filament composite yarn is controlled to be 1.2: 1. The glue can be purchased from a thermoplastic adhesive in the market, and can also be compounded by self.
And S3, performing biorthogonal composite lamination at 0-90 degrees on the semi-finished product to form a finished product II of the non-woven fabric. The pressure is gradually increased from 2MPa to 4MPa during hot pressing, and the thermoplastic condition is controlled at 120 ℃ for 12 min.
The protective performance of the weft-free cloth finished product I in the embodiment 1 and the weft-free cloth finished product II in the embodiment 2 can reach 5.6kg/m27.5kg/m lead-resistant 54/51 lead core2Prevent 79/51 lead core, 4.6kg/m2NIJIIIA-grade 9mm6.0kg/m2Preventing NIJIIIA level.
Both the finished product I of the weftless fabric of the embodiment 1 and the finished product II of the weftless fabric of the embodiment 2 can meet the use requirements of the weftless fabric in the automobile body, for example, as a tarpaulin; can also meet the use requirements of the non-woven cloth in buildings, for example, as a wall decoration material.
In order to better combine the short fiber filament composite yarn with the glue, the embodiment 2 of the application specially prepares a novel glue, which has the basic functions of film softness, good rebound resilience and aging resistance of the short fiber filament composite yarn, and also has the functions of ultraviolet resistance and anti-counterfeiting. The glue used in the process of the embodiment 2 is a water-based polyurethane adhesive, and the purchased product is PU 840-1. After the glue is purchased, compounding a color developing agent, anhydrous copper sulfate powder and an anti-ultraviolet agent in the glue, wherein the ratio of the glue to the three is 1:0.01: 0.02: 0.01. the preparation method comprises the steps of mixing and stirring the raw materials in the weight ratio, and obtaining uniform slurry through a pulping machine. The anhydrous copper sulfate powder can display blue color after meeting water. The color developing agent can help the complex generated after biochemical reaction to develop color, and the universal color developing agent is purchased. The ultraviolet resistant agent can inhibit and delay the harm of ultraviolet rays to the photo-aging of the short-fiber long-thread composite yarn. The newly manufactured non-woven fabric also has an anti-counterfeiting function by combining the technology of the short fiber filament composite yarn layer and the resin layer through the blended glue. After the consumers wet the non-woven cloth, the consumers can see blue color in a hidden way, thereby identifying the authenticity. When the non-woven fabric is applied to the external environment, the non-woven fabric also has the functions of ultraviolet resistance and ageing resistance, and the service life of the non-woven fabric can be prolonged. The whole process is simple, the raw materials are convenient to purchase, and the economic cost is low.
To sum up, the fabric that uses short fiber filament composite yarn as the base body that this application provided for example no latitude cloth, the product has advantages such as high strength, resistant cutting, softness, ductility are good, ageing resistance, long service life, and the production technology of product is simple. The final product also has an anti-counterfeiting function, and can be convenient for consumers to identify the authenticity.
Example 3: the glove is knitted by taking the bundle silk as core yarn and taking the composite yarn with the short fiber wrapped outside as an example. The fasciculus is made of aramid fiber 14 with the number of the fasciculus in the range of about 1200. The bundle of threads is knitted into a glove. And then the glove and the rubber are impregnated and compounded to form a finished product. The obtained finished product has the common advantages of both short fibers and long bundle yarns, and has the advantages of high strength, cutting resistance, softness and high bonding force with resin.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art will understand that various changes, modifications and substitutions can be made without departing from the spirit and scope of the present invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. The application of the composite yarn of the short fiber and the long filament in the fabric is characterized in that: taking the short fiber filament composite yarn as a base material of a fabric, wherein the short fiber filament composite yarn is as follows: the single yarn with the staple fiber as the base material or the composite yarn synthesized by the plied yarn and the multi-ply yarn including the covered yarn with the staple fiber as the base material.
2. The staple filament composite yarn of claim 1, wherein: the short fiber and filament composite yarn comprises a long fiber and a short fiber or a short fiber yarn, wherein the short fiber comprises one or more of polyphenylene sulfide short fiber, aramid short fiber, polyester short fiber, polyethylene short fiber, acrylic short fiber, polypropylene short fiber, cellulose fiber, vinylon short fiber and polyamide short fiber.
3. Use of a staple filament composite yarn according to claim 2 in a fabric, wherein: the length of the short fiber is 15-75mm, and the thickness is 0.8D-3.5D.
4. Use of a staple filament composite yarn according to claim 2 in a fabric, wherein: the filaments are chemical fiber filaments, mineral fiber filaments or metal wires, and the thickness of the filaments is 20D-2000D.
5. Use of a staple filament composite yarn according to claim 2 in a fabric, wherein: one yarn adopted in the staple fiber filament composite yarn is as follows: the bundle silk is used as core yarn, and the yarn of the short fiber is wrapped outside.
6. Use of a staple fiber filament composite yarn according to claim 5 in a fabric, wherein: the number of the bunched filaments is controlled between 1000 and 15000.
7. Use of a staple fiber filament composite yarn according to claim 5 in a fabric, wherein: the bundle yarn is made of one of high-strength high-modulus polyethylene, aramid fiber 14, high-strength nylon and high-strength polyester.
8. The use of a staple fiber filament composite yarn according to claim 1 in a fabric, wherein the application process comprises the steps of: and (3) impregnating and compounding the short fiber filament composite yarn with resin, rubber or glue to form a finished product.
9. Use of a staple fiber filament composite yarn according to claim 8 in a fabric, wherein: the resin is high-strength elastomer.
10. Use of a staple fiber filament composite yarn according to claim 8 in a fabric, wherein: the glue is compounded with a color developing agent, anhydrous copper sulfate powder and an anti-ultraviolet agent, and the ratio of the glue to the color developing agent to the anhydrous copper sulfate powder to the anti-ultraviolet agent is 1:0.01: 0.02: 0.01.
CN202011421510.8A 2020-12-08 2020-12-08 Application of short fiber filament composite yarn in fabric Pending CN112342695A (en)

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