CN112301738A - Rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin and preparation method of rose fiber - Google Patents

Rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin and preparation method of rose fiber Download PDF

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Publication number
CN112301738A
CN112301738A CN202011248618.1A CN202011248618A CN112301738A CN 112301738 A CN112301738 A CN 112301738A CN 202011248618 A CN202011248618 A CN 202011248618A CN 112301738 A CN112301738 A CN 112301738A
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rose
essential oil
fiber
rose essential
beautifying
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刘翔鸥
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Shenzhen Qianwei Ecological Textile Co ltd
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Shenzhen Qianwei Ecological Textile Co ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/02—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fibres, slivers or rovings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/30—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with oxides of halogens, oxyacids of halogens or their salts, e.g. with perchlorates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/02—Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12—Processes in which the treating agent is incorporated in microcapsules
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin and a preparation method thereof, belonging to the technical field of fiber materials; the rose essence comprises, by mass, 10-15% of rose essential oil, 10-20% of modified cyclodextrin, 3-5% of Arabic gum, 2-5% of graphene, 30-40% of bamboo fiber and the balance of a solvent. The rose fiber provided by the invention not only has the unique faint scent and elegant pleasant smell of the rose essential oil, but also has the effects of moistening, beautifying and protecting skin, and has the health-care functions of soothing nerves, relieving depression, eliminating fatigue, promoting wound healing, resisting bacteria and the like. In the invention, the cyclodextrin is used for coating the rose essential oil, so that the slow release of the effective components in the rose essential oil can be realized on one hand, and the bonding force between the rose essential oil and the fiber material can be enhanced on the other hand, so that the rose essential oil is not easy to fall off. In addition, the rose fiber provided by the invention also has excellent wear resistance and antistatic performance.

Description

Rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin and preparation method of rose fiber
Technical Field
The invention relates to the technical field of fiber materials, in particular to rose fiber containing rose essential oil and capable of beautifying and protecting skin and a preparation method thereof.
Background
Along with the improvement of living conditions of people, the improvement of living quality is particularly important. The development of the novel functional cellulose fiber can meet the requirement of people on warm keeping and comfort of textiles, has good health care effect and conforms to the concept of healthy life.
The rose essential oil is referred to as "after essential oil". Can regulate female endocrine, nourish uterus, relieve dysmenorrhea, and improve hyposexuality and climacteric discomfort. Especially has good functions of beautifying and protecting skin, can nourish the interior and the exterior, lighten spots, promote the decomposition of melanin, improve skin dryness and restore skin elasticity, so that women have white and elastic healthy skin, and the essential oil is the aromatic essential oil suitable for the health care of women.
At present, the rose essential oil is mostly only applied to daily chemical products such as perfume, skin care products and the like, and is less applied to the fiber production, mainly because the functional material is easy to fall off on the surface of the fiber and the action time is short due to the weak bonding force between the functional material and the fiber. The rose fiber provided by the invention not only has the unique faint scent and elegant pleasant smell of the rose essential oil, but also has the health-care functions of moistening, beautifying, caring skin, soothing nerves, relieving depression, eliminating fatigue, promoting wound healing, resisting bacteria and the like.
Disclosure of Invention
In order to solve the problems, the invention provides a rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin, which comprises 10-15% of rose essential oil, 10-20% of modified cyclodextrin, 3-5% of Arabic gum, 2-5% of graphene, 30-40% of bamboo fiber and the balance of solvent by mass percent.
As a preferable technical scheme, the modified cyclodextrin is glucosyl-beta-cyclodextrin.
As a preferred technical solution, the graphene is aminated graphene.
As a preferable technical scheme, the nitrogen content of the aminated graphene is 8-10 wt%.
As a preferable technical scheme, the length of the bamboo fiber is 38-51 mm.
As a preferable technical scheme, the solvent is a mixture of polyvinylpyrrolidone and polyethylene glycol, and the mass ratio of the polyvinylpyrrolidone to the polyethylene glycol is 0.5-0.9: 1.
as a preferable technical scheme, the number average molecular weight of the polyvinylpyrrolidone is 3500-5500.
As a preferable technical scheme, the number average molecular weight of the polyethylene glycol is 180-660.
The second aspect of the invention also provides a preparation method of the rose fiber containing the rose essential oil and capable of beautifying and protecting skin, which comprises the following steps:
s1, adding glucose-beta-cyclodextrin and water into a container, stirring and dissolving for 0.5-1 h at 50-70 ℃, cooling to room temperature, adding rose essential oil, mixing uniformly, adding Arabic gum, and stirring and reacting for 1-2 h to obtain a rose microcapsule solution;
s2, placing the bamboo fiber in a sodium periodate solution to perform oxidation reaction for 2-4 hours in a dark place, wherein the reaction temperature is 40-90 ℃, and filtering, washing and drying to obtain oxidized bamboo fiber;
s3, blending the rose microcapsule solution, the aminated graphene and the solvent to obtain a blended solution, soaking the bamboo oxide fiber in the blended solution for 4-8 hours, filtering, washing with water, and drying to obtain the rose fiber.
The third aspect of the invention provides application of rose fibers containing rose essential oil and capable of beautifying and protecting skin in the field of textile fabrics.
Advantageous effects
The rose fiber provided by the invention not only has the unique faint scent and elegant pleasant smell of the rose essential oil, but also has the effects of moistening, beautifying and protecting skin, and has the health-care functions of soothing nerves, relieving depression, eliminating fatigue, promoting wound healing, resisting bacteria and the like. In the invention, the cyclodextrin is used for coating the rose essential oil, so that the slow release of the effective components in the rose essential oil can be realized on one hand, and the bonding force between the rose essential oil and the fiber material can be enhanced on the other hand, so that the rose essential oil is not easy to fall off. In addition, the rose fiber provided by the invention also has excellent wear resistance and antistatic performance.
Detailed Description
The disclosure may be understood more readily by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, including definitions, will control.
In order to solve the above problems, the first aspect of the present invention provides a rose fiber containing rose essential oil and capable of nourishing and caring skin, which comprises, by mass, 10-15% of rose essential oil, 10-20% of modified cyclodextrin, 3-5% of gum arabic, 2-5% of graphene, 30-40% of bamboo fiber, and the balance of a solvent.
In the invention, the rose essential oil is applied to the fiber material, so that the fiber has certain effects of soothing the nerves, helping sleep, beautifying the face, moistening the skin, diminishing inflammation, inhibiting bacteria and the like. The rose essential oil is referred to as "after essential oil". Can regulate female endocrine, nourish uterus, and relieve dysmenorrhea. Especially has good beautifying and skin-care effects, and is good health-care aromatic essential oil. In the system, the cyclodextrin is used for coating the rose essential oil, so that the slow release of the effective components in the rose essential oil can be realized, and the bonding force between the rose essential oil and a fiber material can be enhanced, so that the rose essential oil is not easy to fall off.
In some preferred embodiments, the modified cyclodextrin is glucosyl- β -cyclodextrin. The cyclodextrin is selected from glucose-beta-cyclodextrin, so that the combination between essential oil molecules and fiber materials is effectively improved; the cyclodextrin molecule has a slightly conical hollow cylinder three-dimensional annular structure, in the cavity structure of the cyclodextrin molecule, the upper end of the outer side is formed by secondary hydroxyl, the lower end of the outer side is formed by primary hydroxyl, the cyclodextrin molecule has hydrophilicity, a hydrophobic area is formed in the cavity due to the shielding effect of a C-H bond, the cyclodextrin molecule can well coat the essential oil molecule due to the special structure that the outer edge of the cyclodextrin is hydrophilic and the inner cavity of the cyclodextrin molecule is hydrophobic, and when the outer structure of the cyclodextrin molecule is glycosylated by glucosyl, the cyclodextrin molecule can interact with the oxidized bamboo fiber in a body system to form a large network structure through crosslinking, so that the essential oil molecule can be stably attached to the surface of the fiber, and meanwhile, the mechanical property of the fiber can be enhanced.
In the present invention, the glucosyl- β -cyclodextrin is commercially available from Zibo Qianji Biotech, Inc.
In some preferred embodiments, the graphene is aminated graphene.
In some preferred embodiments, the nitrogen content of the aminated graphene is 8-10 wt%. In the invention, the graphene is selected as aminated graphene, and graphene molecules are doped into the fiber, so that the wear resistance and the antistatic property of the fiber material can be enhanced; the graphene is sp2The hybridized and connected carbon atoms are tightly stacked to form a new material with a single-layer two-dimensional honeycomb lattice structure, the new material has excellent mechanical property and antistatic property, and after a certain amount of aminated graphene is added into a fiber material, on one hand, the antibacterial property of the fiber can be obviously improved, because the aminated graphene with positive charges on the surface is easy to interact with bacteria with negative charges on the surface through electrostatic attraction, the antibacterial property of the fiber is improved; on the other hand, due to the existence of the polar group, the compatibility of the graphene and a system can be improved, so that the graphene can be stably attached to the surface of a fiber material. The inventors have found that the effect is best when the nitrogen content of the aminated graphene is in the range of 8-10 wt%.
The aminated graphene is purchased from Jiangsu Xiifeng nano material science and technology limited company, and is one of XF005-4, XF005-2 and XF005-1 in model.
In some preferred embodiments, the length of the bamboo fiber is 38 to 51 mm. In the invention, after the bamboo fiber is oxidized by sodium periodate, the hydroxyl group on the surface of the bamboo fiber is oxidized into aldehyde group or carboxyl group, and the aldehyde group or carboxyl group is easy to generate a cross-linking reaction with the amino group on the surface of the aminated graphene, so that the aminated graphene is grafted to the bamboo fiber, and in addition, the oxidized bamboo fiber is also easy to react with glucosyl-beta-cyclodextrin, so that the action effect of rose essential oil on a fiber material is enhanced.
In the present invention, the bamboo fiber was purchased from Shandong Xuzhen textile Co., Ltd, and was sold under the designation 45456456.
In some preferred embodiments, the solvent is a mixture of polyvinylpyrrolidone and polyethylene glycol, and the mass ratio of the polyvinylpyrrolidone to the polyethylene glycol is 0.5-0.9: 1. the solvent in the system is selected from a mixture of polyvinylpyrrolidone and polyethylene glycol, the existence of polyvinylpyrrolidone can improve the dispersibility of aminated graphene, the aminated graphene has higher surface energy, and is easy to agglomerate in the application process to prevent the excellent performance of the aminated graphene, the polyvinylpyrrolidone and the polyethylene glycol are compounded for use, and the synergistic effect of the polyvinylpyrrolidone and the polyethylene glycol can improve the compatibility of the rose microcapsule solution, the aminated graphene and the bamboo fiber; in addition, the number average molecular weight of the polyvinylpyrrolidone is selected to be 3500-5500, and the number average molecular weight of the polyethylene glycol is selected to be 180-660 because polymers with different molecular weight ranges are easy to adjust the viscosity of the system, so that the impregnation effect of the bamboo fiber in the mixed liquid is better.
In some preferred embodiments, the polyvinylpyrrolidone has a number average molecular weight of 3500 to 5500.
The polyvinyl pyrrolidone of the invention is purchased from one of new material science and technology (Shanghai) Limited company of Bike, and the model is PVPK12 or PVPK 15.
In some preferred embodiments, the polyethylene glycol has a number average molecular weight of 180 to 660.
The polyethylene glycol is purchased from a Heian petrochemical plant in Jiangsu province, and the model is one of PPG-200, PPG-400 and PPG-600.
The second aspect of the invention also provides a preparation method of the rose fiber containing the rose essential oil and capable of beautifying and protecting skin, which comprises the following steps:
s1, adding the glucosyl-beta-cyclodextrin and water into a container, wherein the addition amount of the water is 2-3 times of the mass of the glucosyl-beta-cyclodextrin, stirring and dissolving for 0.5-1 h at 50-70 ℃, cooling to room temperature, adding rose essential oil, mixing uniformly, adding Arabic gum, and stirring and reacting for 1-2 h to obtain a rose microcapsule solution;
s2, placing the bamboo fiber in a sodium periodate solution with the concentration of 0.5-8g/L to carry out oxidation reaction for 2-4 hours in a dark place, wherein the reaction temperature is 40-90 ℃, and filtering, washing and drying to obtain the oxidized bamboo fiber;
s3, blending the rose microcapsule solution, the aminated graphene and the solvent to obtain a blended solution, soaking the bamboo oxide fiber in the blended solution for 4-8 hours, filtering, washing with water, and drying to obtain the rose fiber.
In some preferred embodiments, the rose essential oil is available from Guangzhou elegant to cosmetics, Inc. and the gum arabic is available from Henan Landing Biotech, Inc.
The third aspect of the invention provides application of rose fibers containing rose essential oil and capable of beautifying and protecting skin in the field of textile fabrics.
Examples
The technical solution of the present invention is described in detail by the following examples, but the scope of the present invention is not limited to the examples. Unless otherwise specified, all the raw materials in the present invention are commercially available.
Example 1
Embodiment 1 provides a rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin, which comprises 10% of rose essential oil, 10% of modified cyclodextrin, 3% of gum arabic, 5% of graphene, 40% of bamboo fiber and 32% of a solvent by mass.
The rose essential oil is available from Guangzhou Yazhi cosmetics Co.
The gum arabic is commercially available from henan lan ding biotechnology limited.
The modified cyclodextrin is glucosyl-beta-cyclodextrin (purchased from Zibo Qianji Biotech Co., Ltd.).
The graphene is aminated graphene, and the nitrogen content of the aminated graphene is 8 wt% (purchased from Jiangsu Xifeng nanometer material science and technology Co., Ltd., with the model of XF 005-1).
The length of the bamboo fiber is 38-51mm (available from Shandong Xuzhen textile Co., Ltd., Cat. 45456456).
The solvent is a mixture of polyvinylpyrrolidone and polyethylene glycol, and the mass ratio of polyvinylpyrrolidone to polyethylene glycol is 0.5: 1.
the polyvinylpyrrolidone has a number average molecular weight of 3500 (purchased from Shanghai Bike New materials science and technology (Shanghai) Co., Ltd., model number of PVPK 12).
The number average molecular weight of the polyethylene glycol is 180-220 (purchased from Haian petrochemical plant of Jiangsu province, and the model is PPG-200).
The embodiment also provides a preparation method of the rose fiber containing the rose essential oil and capable of beautifying and protecting skin, which comprises the following steps:
s1, adding the glucosyl-beta-cyclodextrin and water into a container, wherein the adding amount of the water is 2 times of the mass of the glucosyl-beta-cyclodextrin, stirring and dissolving for 1 hour at 50 ℃, cooling to room temperature, adding rose essential oil, mixing uniformly, adding Arabic gum, and stirring and reacting for 1 hour to obtain a rose microcapsule solution;
s2, placing the bamboo fibers in a sodium periodate solution with the concentration of 0.5g/L (the using amount of the sodium periodate solution is that the bamboo fibers can be immersed) to carry out oxidation reaction for 4 hours in a dark place, wherein the reaction temperature is 90 ℃, and filtering, washing and drying the bamboo fibers to obtain oxidized bamboo fibers;
s3, blending the rose microcapsule solution, the aminated graphene and the solvent to obtain a blended solution, soaking the bamboo oxide fiber in the blended solution for 4 hours, filtering, washing and drying to obtain the rose fiber.
Example 2
Embodiment 2 provides a rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin, which comprises 15% of rose essential oil, 20% of modified cyclodextrin, 5% of gum arabic, 2% of graphene, 30% of bamboo fiber and 28% of a solvent by mass.
The rose essential oil is available from Guangzhou Yazhi cosmetics Co.
The gum arabic is commercially available from henan lan ding biotechnology limited.
The modified cyclodextrin is glucosyl-beta-cyclodextrin (purchased from Zibo Qianji Biotech Co., Ltd.).
The graphene is aminated graphene, and the nitrogen content of the aminated graphene is 10 wt% (purchased from Jiangsu Xifeng nanometer material science and technology Co., Ltd., with the model of XF 005-2).
The length of the bamboo fiber is 38-51mm (available from Shandong Xuzhen textile Co., Ltd., Cat. 45456456).
The solvent is a mixture of polyvinylpyrrolidone and polyethylene glycol, and the mass ratio of the polyvinylpyrrolidone to the polyethylene glycol is 0.9: 1.
the polyvinylpyrrolidone has a number average molecular weight of 5500 (purchased from jacobi new materials science and technology (shanghai) ltd., model number PVPK 15).
The number average molecular weight of the polyethylene glycol is 260-440 (purchased from Haian petrochemical plant of Jiangsu province, with the model of PPG-400).
The embodiment also provides a preparation method of the rose fiber containing the rose essential oil and capable of beautifying and protecting skin, which comprises the following steps:
s1, adding the glucosyl-beta-cyclodextrin and water into a container, wherein the adding amount of the water is 3 times of the mass of the glucosyl-beta-cyclodextrin, stirring and dissolving for 0.5h at 70 ℃, cooling to room temperature, adding rose essential oil, mixing uniformly, adding Arabic gum, and stirring for reacting for 2h to obtain a rose microcapsule solution;
s2, placing the bamboo fibers in a sodium periodate solution with the concentration of 8g/L (the using amount of the sodium periodate solution can be only enough to immerse the bamboo fibers) to be oxidized away from light for 2 hours at the reaction temperature of 40 ℃, and filtering, washing and drying to obtain the oxidized bamboo fibers;
s3, blending the rose microcapsule solution, the aminated graphene and the solvent to obtain a blended solution, soaking the bamboo oxide fiber in the blended solution for 8 hours, filtering, washing and drying to obtain the rose fiber.
Example 3
Embodiment 3 provides a rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin, which comprises 13% of rose essential oil, 15% of modified cyclodextrin, 4% of gum arabic, 4% of graphene, 35% of bamboo fiber and 29% of solvent by mass.
The rose essential oil is available from Guangzhou Yazhi cosmetics Co.
The gum arabic is commercially available from henan lan ding biotechnology limited.
The modified cyclodextrin is glucosyl-beta-cyclodextrin (purchased from Zibo Qianji Biotech Co., Ltd.).
The graphene is aminated graphene, and the nitrogen content of the aminated graphene is 9.34 wt% (purchased from Jiangsu Xifeng nanometer material science and technology Co., Ltd., type XF 005-4).
The length of the bamboo fiber is 38-51mm (available from Shandong Xuzhen textile Co., Ltd., Cat. 45456456).
The solvent is a mixture of polyvinylpyrrolidone and polyethylene glycol, and the mass ratio of polyvinylpyrrolidone to polyethylene glycol is 0.7: 1.
the polyvinylpyrrolidone has a number average molecular weight of 3500 (purchased from Shanghai Bike New materials science and technology (Shanghai) Co., Ltd., model number of PVPK 12).
The number average molecular weight of the polyethylene glycol is 540-660 (purchased from Haian petrochemical plant of Jiangsu province, and the model is PPG-600).
The embodiment also provides a preparation method of the rose fiber containing the rose essential oil and capable of beautifying and protecting skin, which comprises the following steps:
s1, adding the glucosyl-beta-cyclodextrin and water into a container, wherein the addition amount of the water is 2.5 times of the mass of the glucosyl-beta-cyclodextrin, stirring and dissolving for 45min at the temperature of 60 ℃, cooling to room temperature, adding rose essential oil, mixing uniformly, adding Arabic gum, and stirring for reacting for 2h to obtain a rose microcapsule solution;
s2, placing the bamboo fibers in a sodium periodate solution with the concentration of 5g/L (the using amount of the sodium periodate solution can be only that the bamboo fibers can be immersed) to be oxidized away from light for 3 hours at the reaction temperature of 60 ℃, filtering, washing and drying to obtain oxidized bamboo fibers;
s3, blending the rose microcapsule solution, the aminated graphene and the solvent to obtain a blended solution, soaking the bamboo oxide fiber in the blended solution for 6 hours, filtering, washing and drying to obtain the rose fiber.
Comparative example 1
The modified cyclodextrin was changed to 2, 6-dimethyl-beta-cyclodextrin (available from zephytyl biotech inc.) and the remainder of example 3.
Comparative example 2
The nitrogen content of the aminated graphene was changed to 5 wt% (from the new material of da lian mei co., type GO300), and the rest was the same as in example 3.
Comparative example 3
The solvent was changed to polyvinylpyrrolidone alone (model number PVPK12, available from jabeck new materials science and technology (shanghai)) and the remainder was the same as in example 3.
Comparative example 4
The solvent was changed to a single polyethylene glycol (purchased from Haian petrochemical plant of Jiangsu province, model number PPG-600), as in example 3.
Comparative example 5
The number average molecular weight of polyvinylpyrrolidone was changed to 10100 (model number PVPK17, available from jacobi new materials science and technology (shanghai)) and the rest of example 3 was repeated.
Comparative example 6
The number average molecular weight of polyethylene glycol was changed to 1700 to 3300 (obtained from Haian petrochemical plant of Jiangsu province, model number PPG-3000), and the rest was the same as in example 3.
Performance testing
1. And (3) testing mechanical properties: the rose fibers prepared in examples 1 to 3 and comparative examples 1 to 6 were tested for breaking strength and breaking elongation, and the mechanical properties of the rose fibers were tested by an LLY-06E type electronic single fiber strength tester according to the method in GB/T9997-1988 determination of chemical fiber single fiber breaking strength and breaking elongation, and the results are shown in Table 1.
2. And (3) testing antibacterial performance: and (3) carrying out an antibacterial performance test on the rose fibers prepared in the examples 1-3 and the comparative examples 1-6, wherein the method refers to the third part of the evaluation of the antibacterial performance of the textile in GB/T20944.3-2008: an oscillation method, wherein the bacteriostasis rate is the ratio of the difference between the number of colonies of the sample before oscillation and the number of colonies of the sample after oscillation to the number of colonies of the sample before oscillation, and the experimental strains are escherichia coli and staphylococcus aureus; wherein, the results of the inhibition rate of more than 90 percent are recorded as excellent, 70 percent to 90 percent are recorded as good, 50 percent to 70 percent are recorded as medium and less than 50 percent are poor, and the results are shown in table 1.
TABLE 1
Figure BDA0002770857960000121
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that can be easily conceived by those skilled in the art within the technical scope of the present invention are included in the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.

Claims (10)

1. The rose fiber containing rose essential oil and capable of maintaining beauty and protecting skin is characterized by comprising, by mass, 10-15% of rose essential oil, 10-20% of modified cyclodextrin, 3-5% of Arabic gum, 2-5% of graphene, 30-40% of bamboo fiber and the balance of a solvent.
2. The rose fiber containing rose essential oil for beautifying and caring skin according to claim 1, wherein the modified cyclodextrin is glucosyl-beta-cyclodextrin.
3. The rose fiber containing rose essential oil and capable of beautifying and caring skin according to claim 1, wherein the graphene is aminated graphene.
4. The rose fiber containing rose essential oil for beautifying and caring skin according to claim 3, wherein the nitrogen content of the aminated graphene is 8-10 wt%.
5. The rose fiber containing rose essential oil and capable of beautifying and caring skin according to claim 1, wherein the length of the bamboo fiber is 38-51 mm.
6. The rose fiber containing rose essential oil and capable of beautifying and caring skin according to claim 1, wherein the solvent is a mixture of polyvinylpyrrolidone and polyethylene glycol, and the mass ratio of the polyvinylpyrrolidone to the polyethylene glycol is 0.5-0.9: 1.
7. the rose fiber containing rose essential oil and capable of beautifying and caring skin according to claim 6, wherein the number average molecular weight of the polyvinylpyrrolidone is 3500-5500.
8. The rose fiber containing rose essential oil and capable of beautifying and caring skin according to claim 6, wherein the number average molecular weight of the polyethylene glycol is 180-660.
9. A method for preparing the rose fiber containing rose essential oil and capable of beautifying and caring skin according to any one of claims 1 to 8, which comprises the following steps:
s1, adding glucose-beta-cyclodextrin and water into a container, stirring and dissolving for 0.5-1 h at 50-70 ℃, cooling to room temperature, adding rose essential oil, mixing uniformly, adding Arabic gum, and stirring and reacting for 1-2 h to obtain a rose microcapsule solution;
s2, placing the bamboo fiber in a sodium periodate solution to perform oxidation reaction for 2-4 hours in a dark place, wherein the reaction temperature is 40-90 ℃, and filtering, washing and drying to obtain oxidized bamboo fiber;
s3, blending the rose microcapsule solution, the aminated graphene and the solvent to obtain a blended solution, soaking the bamboo oxide fiber in the blended solution for 4-8 hours, filtering, washing with water, and drying to obtain the rose fiber.
10. Use of the rose essential oil-containing rose fiber for beautifying and caring skin according to any one of claims 1 to 8, wherein the rose fiber can be used in the field of textile fabrics.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115216860A (en) * 2022-05-07 2022-10-21 李庆生 Health-care sterilizing lavender fiber and preparation method thereof
CN115522392A (en) * 2022-06-16 2022-12-27 李庆生 Aromatic fiber containing rose essential oil and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115216860A (en) * 2022-05-07 2022-10-21 李庆生 Health-care sterilizing lavender fiber and preparation method thereof
CN115216860B (en) * 2022-05-07 2024-03-01 李庆生 Health-care sterilizing lavender fiber and preparation method thereof
CN115522392A (en) * 2022-06-16 2022-12-27 李庆生 Aromatic fiber containing rose essential oil and preparation method thereof
CN115522392B (en) * 2022-06-16 2024-03-01 李庆生 Aromatic fiber containing rose essential oil and preparation method thereof

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Application publication date: 20210202